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    • 24. 发明授权
    • Process for preparing resin for printing ink use
    • 制备用于印刷油墨用途的树脂的方法
    • US3929736A
    • 1975-12-30
    • US46175774
    • 1974-04-17
    • NIPPON OIL CO LTD
    • SATO HISATAKE
    • C08F8/00C08F8/14C08F8/46C09D11/00C09D11/10C08G63/18C08F240/00
    • C08F8/14C08F8/46C08F2810/30C09D11/108C08F240/00
    • A process for preparing a resin suitable for printing ink use, using as the starting oil to be polymerized either a heat-reacted mixture of that fraction having a boiling point of 20* - 80*C. of the thermally cracked product oil of petroleum fractions or a mixture of this heat-reacted mixture with that fraction of a boiling point 140* - 280*C. of the foregoing thermally cracked product oil, which starting oil is polymerized in the presence of a Friedel-Crafts type catalyst, after which the resulting polymer is reacted with an unsaturated carboxylic acid or an anhydride thereof and, if necessary, the resulting reaction product is further reacted with a monohydric alcohol to obtain a resin having a softening point of above 100*C. and soluble in the nonaromatic hydrocarbon solvents.
    • 用于制备适于印刷油墨用途的树脂的方法,使用作为起始油的原料油,该馏分将沸点为20-80℃的石油馏分的热裂化产物油的馏分的热反应混合物 或这种热反应混合物与上述热裂化产物油的沸点140-280℃的混合物,该起始油在Friedel-Crafts型催化剂存在下聚合,然后将 使所得聚合物与不饱和羧酸或其酸酐反应,如果需要,所得反应产物进一步与一元醇反应,得到软化点高于100℃并可溶于非芳族烃溶剂的树脂 。
    • 27. 发明授权
    • Method for producing thermoplastic resin
    • 热塑性树脂的制造方法
    • US3880820A
    • 1975-04-29
    • US44113474
    • 1974-02-11
    • NIPPON OIL CO LTD
    • SATO HISATAKE
    • C08F240/00C08F15/04C08F15/42
    • C08F240/00
    • A method for producing a thermoplastic resin for adhesive base materials of pressure-sensitive adhesives and hot-melt adhesives, which comprises the steps of: heating a C5 cracked petroleum oil fraction having a boiling point of 20* to 100*C at a temperature in the range of 100* to 300*C, whereby a Diels-Alder reaction occurs; separating the unreacted C5 component from the resulting fraction, and polymerizing the resulting fraction in the presence of Friedel-Crafts catalyst. The invention is characterized in that the raw material for the resin can be obtained in a large quantity and at a low cost, and the obtained resin has excellent properties compared to the conventionally used terpene resin.
    • 一种压敏粘合剂和热熔粘合剂用粘合剂基材的热塑性树脂的制造方法,其特征在于,在以下温度下加热沸点为20〜100℃的C5裂化石油馏分 范围在100〜300℃,由此发生狄尔斯 - 阿尔德反应; 从所得馏分中分离出未反应的C5成分,并在Friedel-Crafts催化剂存在下聚合得到的馏分。 本发明的特征在于可以大量且低成本地获得树脂原料,与常规使用的萜烯树脂相比,所得树脂具有优异的性能。
    • 29. 发明专利
    • PROCESS FOR PREPARING A MODIFIED PETROLEUM RESIN FOR USE IN GRAVURPROCESS FOR PREPARING A MODIFIED PETROLEUM RESIN FOR USE IN GRAVURE INK E INK
    • CA959997A
    • 1974-12-24
    • CA130682
    • 1971-12-21
    • NIPPON OIL CO LTD
    • HAYASHI HIDEOMIZUNO YUSAKUSATO HISATAKE
    • C08F8/14C09D11/10
    • 1379037 Modified petroleum resins NIPPON OIL CO Ltd 21 Dec 1971 [29 Dec 1970] 59486/71 Heading C3P Modified petroleum resins for use in gravure inks are prepared by polymerizing in the presence of a Friedel-Crafts catalyst distillate fractions having boiling points in the range 140‹ to 220‹ C. and obtained from thermal cracking of petroleum, to obtain a resin having a softening point above 160‹ C., adding an unsaturated carboxylic acid or anhydride in amount of 0À01 to 0À4 mol per 100 gm. resin, and esterifying the resulting acid modified petroleum resin with 0À2 to 2 mols of a monohydric alcohol per mol of acid or anhydride to produce a resin having a softening point above 145‹ C. The acid material may be acrylic, methacrylic, maleic, tetrahydrophthalic, fumaric, citraconic or itaconic acid or maleic or tetrahydrophthalic anhydride, and may be reacted with the resin at 140‹ to 250‹ C., optionally in the presence of an organic peroxide. The alcohol may be methyl, ethyl, n-propyl, nonyl, decyl or lauryl alcohol. In examples distillate fractions from cracked petroleum are polymerized with (1 and 2) boron trifluoride etherate and (3) boron trifluoride phenol complex, the products are reacted with (1 and 2) maleic anhydride and (3) tetrahydrophthalic anhydride, and subsequently with (1) butyl alcohol, (2) lauryl alcohol and (3) n-decyl alcohol. The products are dissolved in toluene and mixed with colorants to provide gravure inks.