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    • 24. 发明授权
    • Copolymers of vinyl dioxolanes and imidized derivatives of maleic
anhydride
    • 乙烯基二氧戊环和马来酸酐的酰亚胺化衍生物的共聚物
    • US5304611A
    • 1994-04-19
    • US998304
    • 1992-12-30
    • Richard W. BlevinsS. Richard Turner
    • Richard W. BlevinsS. Richard Turner
    • C08F8/32
    • C08F8/32C08F8/30C08F2800/10
    • Copolymers are produced when a 4-vinyl-1,3 dioxolane monomer is copolymerized with an imidized maleic anhydride (for example, maleimide) monomer in the presence of a free radical initiator. Alternatively, a maleamic acid or maleimide functionally may be introduced into a copolymer containing a 4-vinyl-1,3 dioxolane and maleic anhydride by introducing a primary amine into the reaction mixture. Also, the dioxolane reactant may be introduced into the polymer by reacting 3,4-epoxy-1-butene in a ketone reaction solvent. The structure and composition of the product copolymer are controlled by both the sequence and conditions of the reaction. Products of the present invention can be cast as clear films and can also be used as reactive polymers.
    • 当4-乙烯基-1,3-二氧戊环单体与酰亚胺化马来酸酐(例如马来酰亚胺)单体在自由基引发剂存在下共聚时,产生共聚物。 或者,通过将伯胺引入反应混合物中,可以将马来酰胺酸或马来酰亚胺官能化引入到含有4-乙烯基-1,3-二氧戊环和马来酸酐的共聚物中。 此外,二氧戊环反应物可以通过在酮反应溶剂中使3,4-环氧-1-丁烯反应而引入聚合物中。 产物共聚物的结构和组成由反应的顺序和条件两者来控制。 本发明的产品可以作为透明膜浇铸,也可以用作反应性聚合物。