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    • 24. 发明授权
    • Method for producing an integral, asymmetric membrane and the resultant
membrane
    • 用于制造整体,不对称膜和所得膜​​的方法
    • US4673418A
    • 1987-06-16
    • US739873
    • 1985-05-31
    • Klaus-Viktor Peinemann
    • Klaus-Viktor Peinemann
    • B01D53/22B01D69/12B01D71/64B01D13/04C08J9/28
    • B01D71/64B01D69/12
    • A method for producing integral, asymmetric membranes for separating mixtures of gases is disclosed. A membrane forming polymer, a solvent for the polymer, and a swelling agent are mixed to form a pourable liquid mixture; the solvent has a lower boiling point than the other components in the mixture, the polymer is not soluble in the swelling agent, and the swelling agent does not react with the polymer or the solvent. The liquid mixture is spread to form a thin film, the film is exposed to air or an inert gas to form a surface skin by evaporation and is thereafter contacted with a precipitation agent. A preferred integral, asymmetric membrane is produced when the membrane forming polymer is a polyetherimide, the solvent is a halogenated hydrocarbon and the swelling agent is one or more compound selected from the group consisting of an alkyl substituted benzene, an aliphatic carboxylic acid, and a chlorinated hydrocarbon.
    • 公开了一种制备用于分离气体混合物的整体非对称膜的方法。 将成膜聚合物,聚合物的溶剂和溶胀剂混合以形成可倾倒的液体混合物; 溶剂的沸点低于混合物中的其它组分,聚合物不溶于溶胀剂,溶胀剂不与聚合物或溶剂反应。 将液体混合物扩散以形成薄膜,将膜暴露于空气或惰性气体中以通过蒸发形成表面皮肤,然后与沉淀剂接触。 当膜形成聚合物是聚醚酰亚胺时,产生优选的整体不对称膜,溶剂是卤代烃,溶胀剂是一种或多种选自烷基取代的苯,脂族羧酸和 氯化烃。