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21. 发明授权

US4135028A Process for fireproofing synthetic fiber materials with sulphonamides 失效
标题翻译：具有磺化物防火合成纤维材料的工艺
公开(公告)号：US4135028A
公开(公告)日：1979-01-16
申请号：US808005
申请日：1977-06-20
申请人： Armin Hiestand , Peter Rohringer
发明人： Armin Hiestand , Peter Rohringer
IPC分类号： C09K21/10 , D06M13/02 , D06M13/322 , D06M13/402 , D06M13/438 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/32 , D06M101/34 , B32B27/36 , B05D3/02 , C09D5/18 , C09K3/28
CPC分类号： D06M13/438 , C09K21/10 , Y10S428/921 , Y10T428/2969 , Y10T442/2721 , Y10T442/2861
摘要： A process for fireproofing polyester fibers in which a sulphonamide of the formula ##STR1## in which R is an aromatic, cycloaliphatic or aliphatic radical or hydrogen and in which the ring A is unsubstituted or further substituted or in which a hydrazonium or ammonium salt of such a sulphonamide is applied to the fiber material which is then dried and subjected to a heat treatment. The sulphonamide may also be applied in the presence of a dispersant, a protective colloid and/or water. The composition of matter for performing this process is also provided.

22. 发明授权

US4116702A Agent for flame proofing synthetic fibrous material 失效
标题翻译：防火合成纤维材料代理
公开(公告)号：US4116702A
公开(公告)日：1978-09-26
申请号：US723279
申请日：1976-09-15
申请人： Peter Rohringer , Frank Lohmann , Rudolf F. Wurster
发明人： Peter Rohringer , Frank Lohmann , Rudolf F. Wurster
IPC分类号： C09K21/08 , D06M13/08 , C09D5/18
CPC分类号： D06M13/08 , C09K21/08 , Y10S260/24
摘要： The invention relates to a flameproofing agent which contains a brominated cycloalkane and a dispersant. The flame-proofing agent may also contain a protective colloid and/or water. In addition, a method of providing synthetic materials of polyester or polyamide with a flame-retardant finish with the aqueous flameproofing agents is disclosed.
摘要翻译：本发明涉及一种含有溴化环烷烃和分散剂的防火剂。防火剂还可以含有保护胶体和/或水。另外，公开了一种使用含水防火剂提供具有阻燃整理剂的聚酯或聚酰胺合成材料的方法。

23. 发明申请

US20080135805A1 Fluorescent Pigments for Coating Compositions 审中-公开
标题翻译：用于涂料组合物的荧光颜料
公开(公告)号：US20080135805A1
公开(公告)日：2008-06-12
申请号：US11659646
申请日：2005-08-03
申请人： Fabienne Cuesta , Ted Deisenroth , Kamalesh Pai Fondekar , Ramachandra V. Joshi , Peter Rohringer , Uma Ganeshram , Josef Zelger
发明人： Fabienne Cuesta , Ted Deisenroth , Kamalesh Pai Fondekar , Ramachandra V. Joshi , Peter Rohringer , Uma Ganeshram , Josef Zelger
IPC分类号： C09K11/06
CPC分类号： C09B67/0063 , C09B67/0033 , C09B67/009 , D21H19/42 , D21H21/30
摘要： The invention relates to a fluorescent pigment comprising a) a melamine-formaldehyde polycondensation product, b) a distyryl biphenyl fluorescent whitening agent (FWA) of the formula (1), in which R1 represents hydrogen, chlorine or C1-C4alkoxy and M represents hydrogen, an alkaline or alkaline earth metal, ammonium or ammonium that is mono-, di-, tri- or tetrasubstituted by C1-C4alkyl or C2-C4hydroxyalkyl and, optionally, c) at least one additional fluorescent whitening agent, a process for its preparation and use thereof for the fluorescent whitening of paper, especially in coating.
摘要翻译：本发明涉及一种荧光颜料，其包含a）三聚氰胺 - 甲醛缩聚产物，b）式（1）的二苯乙烯基联苯荧光增白剂（FWA），其中R 1代表氢，氯或C 1 -C 4烷氧基，M表示氢，碱金属或碱土金属，铵或铵，其被C， C 1 -C 4烷基或C 2 -C 4羟烷基，和任选地，c）至少一个另外的荧光增白剂，其制备方法以及用于纸的荧光增白的用途，特别是在涂料中。

24. 发明申请

US20080040865A1 Fluorescent Whitening Pigments 审中-公开
公开(公告)号：US20080040865A1
公开(公告)日：2008-02-21
申请号：US10579490
申请日：2004-11-08
申请人： Ted Deisenroth , Kamalesh Pai Fondekar , Peter Rohringer , Fabienne Cuesta , Ramachandra V. Joshi , Smita G. Kavishwar , Uma Shadakshari
发明人： Ted Deisenroth , Kamalesh Pai Fondekar , Peter Rohringer , Fabienne Cuesta , Ramachandra V. Joshi , Smita G. Kavishwar , Uma Shadakshari
IPC分类号： C08G12/32 , C08G12/38 , C09B69/10 , D21H17/49
CPC分类号： C08G12/38 , C08G12/32 , C09B23/148 , D21H17/51 , D21H21/18 , D21H21/30
摘要： A whitening pigment comprising the reaction product of (a) a melamine-formaldehyde and/or a melamine-urea poly-condensation product and (b) a water-soluble fluorescent whitening agent of the formula (1), wherein each of the two R1 groups, independent of the other, represents a C1-C6alkyl or C1-C4alkyl-O—C1-C4alkyl residue, which is substituted by one or two —CONH2, —CONHC1-C4alkyl, —COOH, —SO2NH2, —SO2NHC1-C4alkyl or —NH2 groups, each of the two R2 groups, independent of the other, represents hydrogen, C1-C4alkyl, C2-C4hydroxyalkyl or C1-C4alkoxyC1-C4alkyl, or R1 and R2 together with the nitrogen atom complete a piperazine ring, each of the two X1 groups, independently, represent —OH, —OC1-C4alkyl, —Oaryl or the group —NR3R4, wherein R3 and R4 each, independently, represent hydrogen, C1-C4alkyl, C2-C4hydroxyalky, C1-C4alkoxyC1-C4alkyl, a phenyl, phenyl mono- or disulphonic acid residue or, R3 and R4, together with the nitrogen atom to which they are attached, complete a morpholino, piperidino or pyrrolidino ring or, alternatively, X1 represents an amino acid residue from which a hydrogen atom has been abstracted from the amino group and M is hydrogen, an alkaline or alkaline earth metal ion, ammonium, mono- di-, tri- or tetra-substituted C1-C4alkylammonium or C2-C4hydroxyalkylammonium or mixtures thereof, a process for preparation of the pigments and the use thereof for the fluorescent whitening of paper.

25. 发明申请

US20060155124A1 Amphoteric fluorescent whitening agents 失效
标题翻译：两性荧光增白剂
公开(公告)号：US20060155124A1
公开(公告)日：2006-07-13
申请号：US10534315
申请日：2003-11-11
申请人： Goetz Scheffler , Peter Rohringer , Ian Fletcher
发明人： Goetz Scheffler , Peter Rohringer , Ian Fletcher
IPC分类号： C07D487/00
CPC分类号： D21H21/30
摘要： The present invention provides novel bis-triazinylaminostilbene amphoteric fluorescent whitening agents, comprising both individual components and mixtures thereof, a process for their preparation, intermediates useful for their prepartion and use of the fluorescent whitening agents for the fluorescents whitening of paper.
摘要翻译：本发明提供了新颖的双 - 三嗪基氨基芪两性荧光增白剂，其包括单独组分及其混合物，其制备方法，可用于其制备的中间体和使用荧光增白剂用于荧光增白纸。

26. 发明申请

US20060030707A1 Triazinylaminostibene disulphonic acid mixtures 有权
标题翻译：三嗪基氨基二苯二磺酸混合物
公开(公告)号：US20060030707A1
公开(公告)日：2006-02-09
申请号：US10519031
申请日：2003-06-26
申请人： Fabienne Cuesta , Georges Mertzger , Roland Naef , Peter Rohringer , Rainer Traber
发明人： Fabienne Cuesta , Georges Mertzger , Roland Naef , Peter Rohringer , Rainer Traber
IPC分类号： C09B29/00 , C07D403/02
CPC分类号： D06M13/358 , C09K11/06 , C09K2211/1011 , C09K2211/1022 , C09K2211/1059 , C11D3/42 , D06L4/621 , D06L4/65 , D21H17/07 , D21H17/09 , D21H17/57 , D21H19/44 , D21H21/30 , D21H23/04
摘要： The present invention relates to a fluorescent whitening agent comprising a mixture of two symmetrically and one asymmetrically substituted triazinylaminostilbene disulphonic acids, novel asymmetrically substituted derivatives, a process for their preparations and use of the mixture for whitening synthetic or natural organic materials, especially paper and for the fluorescent whitening and improvement of sun protection factors of textile materials.
摘要翻译：本发明涉及一种荧光增白剂，其包含两个对称和一个不对称取代的三嗪基氨基芪二磺酸的混合物，新的不对称取代的衍生物，其制备方法和使用该混合物以使合成或天然有机材料，特别是纸和荧光增白和改善纺织材料防晒因素。

27. 发明授权

US06797752B1 Use of whitening pigments for whitening paper coating compositions 失效
标题翻译：使用美白颜料增白纸涂料组合物
公开(公告)号：US06797752B1
公开(公告)日：2004-09-28
申请号：US10048758
申请日：2002-02-01
申请人： Peter Rohringer
发明人： Peter Rohringer
IPC分类号： C08K534
CPC分类号： D21H21/30 , D21H19/42
摘要： The use of whitening pigments comprising (a) a melamine-formaldehyde or phenol-formaldehyde polycondensation product and (b) a water-soluble fluorescent whitening agent of formula (1), wherein R1 and R2 are each independently of the other —OH, —Cl, —NH2, —O—C1-C4alkyl, —O—aryl, —NH—C1-C4alkyl, —N(C1-C4alkyl)2, —N(C1-C4alkyl)(C1-C4hydroxyalkyl), —N(C1-C4hydroxyalkyl)2, or —NH—aryl, for example aniline-mono- or -di-sulfonic acid or an anilinesulfon-amide, morpholino, S—C1-C4alkyl(aryl), or a radical of an amino acid, for example aspartic acid or inimoacetic acid, which radical is substited at the amino group, and M is hydrogen; sodium; potassium; calcium; magnesium; ammonium; mono-, di-, tri- or tetra-C1-C4alkylammoniun; mono-, di- or tri-C1-C4hydroxyalkylammonium; or ammonium di- or tri-substitue by a mixture of C1-C4 alkyl and C1-C4hydroxyalkyl groups, for whitening paper coating compositions.
摘要翻译：使用美白颜料，其包含（a）三聚氰胺 - 甲醛或苯酚 - 甲醛缩聚产物和（b）式（1）的水溶性荧光增白剂，其中R1和R2各自独立地为-OH， Cl，-NH 2，-O-C 1 -C 4烷基，-O-芳基，-NH-C 1 -C 4烷基，-N（C 1 -C 4烷基）2，-N（C 1 -C 4烷基）（C 1 -C 4羟烷基） -C 1-4羟烷基）2或-NH-芳基，例如苯胺一 - 或二 - 磺酸或苯胺磺酰胺，吗啉代，S-C 1 -C 4烷基（芳基）或氨基酸的基团，例如天冬氨酸或咪唑乙酸，其自由基在氨基处被取代，M是氢; 钠; 钾; 钙; 镁; 铵; 单 - ，二 - ，三 - 或四 - C 1 -C 4烷基铵; 单，二或三-C 1 -C 4羟烷基铵; 或通过C 1 -C 4烷基和C 1 -C 4羟烷基的混合物的二取代或三取代，用于增白纸涂料组合物。

28. 发明授权

US06458169B2 Fluorescent whitening agents 失效
标题翻译：荧光增白剂
公开(公告)号：US06458169B2
公开(公告)日：2002-10-01
申请号：US09767112
申请日：2001-01-22
申请人： Peter Rohringer , Georges Metzger , Dieter Reinehr
发明人： Peter Rohringer , Georges Metzger , Dieter Reinehr
IPC分类号： C07D25100
CPC分类号： C09B23/148 , C07D251/68 , C11D3/42 , D06L4/621 , D06L4/657 , D06L4/75 , D06M13/07 , D06M13/358 , D06P1/6426 , D21H21/30 , Y10S8/919
摘要： The present invention provides new compounds having the formula: in which X is O or, preferably, NH; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; n is 1 or 2; and each R2, independently, is hydrogen, C1-C3alkyl, halogen, cyano, COOR in which R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, SO3M in which M has its previous significance or, when n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl; provided that those compounds are excluded in which a) X is NH, n is 1 and R2 is SO3M in which M has its previous significance; or b) X is NH, n is 2 and one R2 is SO3M in which M has its previous significance, and the other R2 is hydrogen, methyl or halogen; or c) X is NH, n is 1, R1 is glycine and R2 is H or CO2H; or d) X is NH, n is 2, each R2 is SO3M in which M has its previous significance and the SO3M groups are in 2,5-positions in the phenyl ring and R1 is D,L-alanine, L-valine, L-leucine, L-isoleucine, L-threonine, L-aspartic acid, L-glutamic acid, L-phenylalanine, L-proline, D,L-methionine or glycine. Most of the new class of 4,4′-diaminostilbene-2,2′-disulfonic acid compounds are useful as fluorescent whitening agents, especially for paper.
摘要翻译：本发明提供了新的具有下式的化合物：其中X为O或优选为NH; M是氢，碱金属原子，铵或由胺形成的阳离子; 每个R 1独立地是氨基酸被除去的氨基酸残基; n为1或2; 并且每个R 2独立地是氢，C 1 -C 3烷基，卤素，氰基，其中R是氢或C 1 -C 3烷基的COOR，其中R具有其先前含义的CONH-R，其中R具有其先前含义的SO 2 NH- 其中R具有其先前意义的NH-COR，其中M具有其先前含义的SO 3 M，或当n为1时，R 2也可以是其中R 3为C 1 -C 3烷基或苯基的CO-R 3;条件是将这些化合物排除在哪一个）X是NH，n是1，R2是SO3M，其中M具有其先前的意义; 环）X是NH，n是2，一个R2是SO3M，其中M具有其先前的意义，另一个R 2是氢，甲基或卤素; orc）X是NH，n是1，R1是甘氨酸，R2是H或CO2H; ord）X是NH，n是2，每个R2是SO3M，其中M具有其先前的意义，SO3M基团在苯环中是2,5位，R1是D，L-丙氨酸，L-缬氨酸，L L-亮氨酸，L-异亮氨酸，L-苏氨酸，L-天冬氨酸，L-谷氨酸，L-苯丙氨酸，L-脯氨酸，D，L-甲硫氨酸或甘氨酸。新的4,4'-二氨基芪 - 2,2'-二磺酸化合物可用作荧光增白剂，特别是用于纸。

29. 发明授权

US4735685A Process for sizing paper or cardboard with anionic hydrophobic sizing agents and cationic retention aids 失效
标题翻译：使用阴离子疏水施胶剂和阳离子助留剂调整纸张或纸板的方法
公开(公告)号：US4735685A
公开(公告)日：1988-04-05
申请号：US773705
申请日：1985-09-09
申请人： Michael Bernheim , Hubert Meindl , Peter Rohringer
发明人： Michael Bernheim , Hubert Meindl , Peter Rohringer
IPC分类号： C07D307/89 , D21H17/07 , D21H17/16 , D21H17/56 , D21H3/08
CPC分类号： C07D307/89 , D21H17/07 , D21H17/16
摘要： Anionic sizing agents containing anhydride groups, which are novel compounds and which contain a single N,N-C.sub.6 -C.sub.22 di(alkyl- or alkenyl)amido group, a N-C.sub.6 -C.sub.22 (alkyl- or alkenyl)amido group or a C.sub.6 -C.sub.22 -(alkyl or alkenyl) ester group as hydrophobic substituent, and at least one anionic group in acid or salt form, in particular the anhydride of a N,N-C.sub.6 -C.sub.22 dialkylamido- or N,N-C.sub.6 -C.sub.22 dialkenylamidocarboxylic acid, the anhydride of a N-C.sub.6 -C.sub.22 alkylamido- or N,N-C.sub.6 -C.sub.22 alkenylamidocarboxylic acid, or the C.sub.6 -C.sub.22 alkyl ester or C.sub.6 -C.sub.22 alkenyl ester of an aromatic tetracarboxylic acid anhydride or a salt thereof, are particularly suitable, together with commerically available retention aids, for use in a process for pulp-sizing or surface-sizing paper or cardboard.
摘要翻译：含有酸酐基团的阴离子施胶剂是新型化合物，其含有单个N，N-C 6 -C 22二（烷基 - 或烯基）酰氨基，N-C 6 -C 22（烷基 - 或烯基）酰氨基或C 6 -C 22二 C 22 - （烷基或烯基）酯基作为疏水性取代基，以及至少一种酸或盐形式的阴离子基团，特别是N，N-C6-C22二烷基酰氨基或N，N-C6-C22二烯酰基氨基羧酸的酸酐， N-C6-C22烷基酰氨基或N，N-C6-C22链烯基酰胺羧酸或芳香族四羧酸酐或其盐的C 6 -C 22烷基酯或C 6 -C 22烯基酯的酸酐特别合适，以及商业上可获得的保留辅助材料，用于纸浆尺寸或表面尺寸纸张或纸板的过程中。

30. 发明授权

US4243418A Compositions for fireproofing polyester fiber materials with substituted sulphurylamides 失效
标题翻译：防火聚酯纤维材料与取代磺酰胺的组合物
公开(公告)号：US4243418A
公开(公告)日：1981-01-06
申请号：US944662
申请日：1978-09-21
申请人： Hermann Nachbur , Armin Hiestand , Peter Rohringer
发明人： Hermann Nachbur , Armin Hiestand , Peter Rohringer
IPC分类号： C09K21/10 , D06M13/02 , D06M13/322 , D06M13/402 , D06M13/438 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/32 , C09K3/28
CPC分类号： D06M13/438 , Y10S428/921 , Y10T428/2969 , Y10T442/2721 , Y10T442/2861
摘要： A process for fireproofing polyester fibers is provided in which a substituted mono- or disulphurylamide of the formula ##STR1## wherein n is 1 or 2, R are aromatic, cycloaliphatic or aliphatic radicals or hydrogen and A is alkylene or an ammonium salt of such a sulphurylamide is applied to the fiber material which is then dried and subjected to a heat treatment. The sulphurylamide may also be applied in the presence of a dispersant, a protective colloid and/or water. The composition of matter for performing this process is also provided.
摘要翻译：提供一种耐热聚酯纤维的方法，其中通式为：其中n为1或2，R为芳族，脂环族或脂族基团或氢原子的取代的单或二硫酰胺并且A是亚烷基或这种磺酰胺的铵盐施加到纤维材料上，然后将其干燥并进行热处理。磺酰胺也可以在分散剂，保护胶体和/或水的存在下使用。还提供了用于执行该过程的物质的组成。

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