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    • 26. 发明申请
    • AVERMECTIN B1 AND AVERMECTIN B1 MONOSACCHARIDE DERIVATIVES HAVING AN ALKOXYMETHYL SUBSTITUENT IN THE 4
    • 在4“-OR 4'-位置具有烷氧基取代基的AVERMECTIN B1和AVERMECTIN B1单糖衍生物
    • US20110230429A1
    • 2011-09-22
    • US13117292
    • 2011-05-27
    • Peter MaienfischFiona Murphy KessabiJérôme CassayreLaura QuarantaThomas PitternaOttmar Franz HueterPierre Jung
    • Peter MaienfischFiona Murphy KessabiJérôme CassayreLaura QuarantaThomas PitternaOttmar Franz HueterPierre Jung
    • A01N43/22C07H17/08A01P7/00
    • C07H17/08A61K31/7042
    • What is described are a compound of the formula wherein n is 0 or 1; A-B is —CH═CH— or —CH2—CH2—; R1 is C1-C12-alkyl, C3-C8-cycloalkyl or C2-C12-alkenyl; R2 is for example C1-C12-alkyl, C2-C12-alkenyl or C2-C12-alkinyl; which are optionally substituted with one to five substituents selected from the group consisting of OH, halogen, CN, —N3, —NO2, C3-C8-Cycloalkyl, norbornylenyl-, C3-C8-Cycloalkenyl; C3-C8-halocycloalkyl, C1-C12-alkoxy, C1-C6-alkoxy-C1-C6-alkoxy, C3-C8-cycloalkoxy, C1-C12-haloalkoxy, C1-C12-alkylthio, C3-C8-cycloalkylthio, C1-C12-haloalkylthio, C1-C12-alkylsulfinyl, C3-C8-cycloalkylsulfinyl, C1-C12-haloalkylsulfinyl, C3-C8-halocycloalkylsulfinyl, C1-C12-alkylsulfonyl, C3-C8-cycloalkylsulfonyl, C1-C12-haloalkylsulfonyl, C3-C8-halocycloalkylsulfonyl, —NR4R6, —X—C(═Y)—R4, —X—C(═Y)—Z—R4, —P(═O)(OC1-C6-alkyl)2, aryl, heterocyclyl, aryloxy, arylthio and heterocyclyloxy; R3 is for example H, C1-C12-alkyl or C1-C12-alkyl which is optionally substituted and, where applicable, to E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in salt form; a process for preparing and using these compounds and their tautomers; pesticides whose active compound is selected from these compounds and their tautomers; and a process for preparing these compounds and compositions, and the use of these compounds and compositions.
    • 描述的是下式的化合物,其中n是0或1; A-B是-CH = CH-或-CH 2 -CH 2 - ; R1是C1-C12-烷基,C3-C8-环烷基或C2-C12-烯基; R2是例如C1-C12-烷基,C2-C12-烯基或C2-C12-炔基; 其任选被一至五个选自OH,卤素,CN,-N 3,-NO 2,C 3 -C 8 - 环烷基,降冰片基 - ,C 3 -C 8 - 环烯基的取代基取代; C 3 -C 8卤代环烷基,C 1 -C 12烷氧基,C 1 -C 6烷氧基-C 1 -C 6 - 烷氧基,C 3 -C 8环烷氧基,C 1 -C 12卤代烷氧基,C 1 -C 12烷硫基,C 3 -C 8环烷硫基, C 1 -C 12烷基亚磺酰基,C 3 -C 8环烷基亚磺酰基,C 1 -C 12卤代烷基亚磺酰基,C 3 -C 8卤代环烷基亚磺酰基,C 1 -C 12烷基磺酰基,C 3 -C 8环烷基磺酰基,C 1 -C 12卤代烷基磺酰基, 卤代环烷基磺酰基,-NR4R6,-X-C(= Y)-R4,-X-C(= Y)-Z-R4,-P(= O)(OC1-C6-烷基)2,芳基,杂环基,芳氧基, 芳硫基和杂环氧基; R3是例如任选取代的H,C 1 -C 12 - 烷基或C 1 -C 12 - 烷基,并且在适用的情况下,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下为游离形式或 盐形式; 一种制备和使用这些化合物及其互变异构体的方法; 活性化合物选自这些化合物及其互变异构体的农药; 以及制备这些化合物和组合物的方法,以及这些化合物和组合物的用途。
    • 28. 发明授权
    • Insecticidal compounds
    • 杀虫化合物
    • US08193362B2
    • 2012-06-05
    • US12992711
    • 2009-05-13
    • Jerome Yves CassayreCamilla CorsiThomas PitternaPeter Maienfisch
    • Jerome Yves CassayreCamilla CorsiThomas PitternaPeter Maienfisch
    • C07D211/68A01N43/40
    • C07D401/14
    • A compound of formula (I): wherein R1 is pyrid-4-yl optionally substituted by one to four substituents independently selected from halogen, C1-3 alkyl or C1-3 haloalkyl; R2 is hydrogen, halogen, C1-4 haloalkyl or C1-4 haloalkoxy; R3 is trifluoromethyl, difluoromethyl or difluoromethoxy and R4 is hydrogen, fluoro or chloro, or R3 is fluoro, chloro or bromo and R4 is fluoro, chloro or trifluoromethyl; and R5 is hydrogen or halogen; or salts or N-oxides thereof. Furthermore, the present invention relates to intermediates used to prepare compounds of formula (I), to methods of using them to combat and control insect, acarine, mollusc and nematode pests and to insecticidal, acaricidal, molluscicidal and nematicidal compositions comprising them.
    • 式(I)的化合物:其中R 1是任选被一至四个独立地选自卤素,C 1-3烷基或C 1-3卤代烷基的取代基取代的吡啶-4-基; R2是氢,卤素,C1-4卤代烷基或C1-4卤代烷氧基; R3是三氟甲基,二氟甲基或二氟甲氧基,R4是氢,氟或氯,或R3是氟,氯或溴,R4是氟,氯或三氟甲基; R5为氢或卤素; 或其盐或N-氧化物。 此外,本发明涉及用于制备式(I)化合物的中间体,涉及使用它们来对抗和控制昆虫,螨类,软体动物和线虫以及包含它们的杀虫,杀螨,杀软体动物和杀线虫组合物的方法。