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21. 发明授权

US5118737A Water-soluble dye 失效
标题翻译：水溶性染发剂
公开(公告)号：US5118737A
公开(公告)日：1992-06-02
申请号：US541077
申请日：1990-06-22
申请人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
发明人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
IPC分类号： C09B29/30 , C09B31/28 , C09B33/10 , C09B33/18 , C09B33/22 , C09B33/26 , C09B33/28 , C09B35/38 , C09B43/16 , C09D11/00 , C09D11/02
CPC分类号： C09D11/328 , C09B29/30 , C09B43/16 , Y10S260/38
摘要： A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 and R.sup.2 together with the nitrogen atom form a morpholine ringa and b are different and from 1 to 8m is from 1 to 10;n is from 0 to 9;M is H, ammonium, or a monovalent metal;X (i) NR.sup.1 R.sup.2, (ii) NR.sup.3 R.sup.4, in which R.sup.3 and R.sup.4 are each independently selected from H, alkyl and aryl, or (iii) the residue of a mono- or bis-azo chromophore comprising benzene, naphthalene or mono- or bi-cyclic heteroaryl diazo and coupling components linked to the triazine nucleus through an amino linking group;and Y is (i) the residue of a benzene, naphthalene or mono or bi-cyclic heteroaryl diazo component or (ii) the residue of a mono- or bis-azo chromophore carrying a diazotisable amino group and comprising benzene, naphthalene or mono-or bi-cyclic heteroaryl diazo and coupling components;provided that the dye contains one or at least three azo groups and an ink derived from the dye which is suitable for use in printing, especially ink jet printing.

22. 发明授权

US4780532A Water-soluble triazine dyestuffs free from cellulose reactive groups and suitable for use in inks 失效
标题翻译：水溶性三嗪染料不含纤维素反应性基团，适用于油墨
公开(公告)号：US4780532A
公开(公告)日：1988-10-25
申请号：US765001
申请日：1985-08-12
申请人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
发明人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
IPC分类号： C09B45/14 , C09B43/16 , C09B45/04 , C09B45/24 , C09B45/26 , C09B45/30 , C09D11/00 , C09D11/02 , C09B11/02 , C09D11/16
CPC分类号： C09D11/328 , C09B43/16 , C09B45/04
摘要： A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 & R.sup.2 together with the nitrogen atom form a morpholine ringa & b are different and from 1 to 8m is from 1 to 10;n is from 0 to 9;q is 1/2 or 1p is 1 or 2L is a transition metal capable of complexing with a dyeM is H, ammonium, or a monovalent metal;B, D, F & E are H or substituents;X is NR.sup.1 R.sup.2, NR.sup.3 R.sup.4, --NR.sup.3 --Z--NR.sup.4 --, OR.sup.3, or the residue of a mono- or dis-azo chromophore comprising benzene, naphthalene or hetero-mono- or bi-cyclic diazo and coupling components, linked to the triazine nucleus through a primary or secondary amino linking group in which R.sup.3 and R.sup.4 are each independently H, alkyl or aryl; andZ is a divalent linking group;suitable for use in the preparation of a printing ink, especially for ink jet printing.
摘要翻译：其中R1为 - （CaH2aO）m（CbH2bO）nH，R2为H或 - （CaH2aO）m（CbH2bO）nH，或R1和R2为不含纤维素反应性基团的水溶性染料，与氮原子一起形成吗啉环a＆b不同，1至8m为1至10; n为0〜9; q为1/2或1 p为1或2 L为能与染料络合的过渡金属，M为H，铵或一价金属; B，D，F和E是H或取代基; X是NR1R2，NR3R4，-NR3-Z-NR4-，OR3，或包含苯，萘或异单 - 或双环重氮和偶联组分的单或二偶氮发色团的残基，与三嗪通过伯或仲氨基连接基团，其中R 3和R 4各自独立地为H，烷基或芳基; Z为二价连接基团; 适用于制备印刷油墨，特别适用于喷墨印刷。

23. 发明授权

US4772323A Ink comprising at least one water soluble-formazan dye, free from cellulose-reactive groups 失效
标题翻译：油墨包含至少一种不含纤维素反应性基团的水溶性甲az染料
公开(公告)号：US4772323A
公开(公告)日：1988-09-20
申请号：US67262
申请日：1987-06-29
申请人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
发明人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
IPC分类号： C09B45/02 , C09B50/00 , C09B56/10 , C09D11/00 , C09D11/16 , D06P5/00 , C09D11/02 , C09D11/18
CPC分类号： C09D11/328 , C09B50/00 , C09B56/10
摘要： An ink comprising at least one water-soluble dye, free from cellulose-reactive groups, of the formula: ##STR1## wherein, R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 and R.sup.2 together with the nitrogen atom form a morpholine ring;a and b are different and from 2 to 8m is from 1 to 10; n is from 0 to 9;M is H, ammonium or sodium, potassium or lithium;X is (i) NR.sup.1 R.sup.2, (ii) NR.sup.3 R.sup.4, in which R.sup.3 and R.sup.4 are each independently selected from H, alkyl and aryl, or (iii) a mono- or dis-azo chromophore consisting of benzene, naphthalene or mono- or bi-cyclic heteroaryl diazo and coupling components linked to the triazine nucleus through an amino linking group, NR.sup.9, in which R.sup.9 is H, C.sub.1-4 -alkyl or phenyl;R.sup.5 and R.sup.6 are selected from SO.sub.3 M and H provided at least one is SO.sub.3 M;R.sup.7 is H, halogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, SO.sub.3 M or COOM; and R.sup.8 is H or SO.sub.3 M.The ink is particularly suited for ink jet printing having improved solution stability, excellent recording properties, ejection stability, ejection responsiveness and continuous recording workability.

24. 发明授权

US4767459A Ink 失效
标题翻译：墨水
公开(公告)号：US4767459A
公开(公告)日：1988-08-30
申请号：US97176
申请日：1987-09-16
申请人： David Greenwood , John E. Presgrave
发明人： David Greenwood , John E. Presgrave
IPC分类号： C09D11/00 , C09D11/02
CPC分类号： C09D11/328
摘要： An ink for ink-jet printing comprising a solution of C.I. Direct Black 168.

25. 发明授权

US4758658A Water-soluble formazan dye 失效
标题翻译：水溶性甲an染料
公开(公告)号：US4758658A
公开(公告)日：1988-07-19
申请号：US909848
申请日：1986-09-22
申请人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
发明人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
IPC分类号： C09B45/02 , C09B50/00 , C09B56/10 , C09D11/00 , C09D11/16 , D06P5/00 , C09D11/02
CPC分类号： C09D11/328 , C09B50/00 , C09B56/10
摘要： A water-soluble dye, free from cellulose-reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 & R.sup.2 together with the nitrogen atom form a morpholine ring;a & b are different and from 1 to 8m is from 1 to 10; n is from 0 to 9;M is H, ammonium or a monovalent metal;X is (i) NR.sup.1 R.sup.2, (ii) NR.sup.3 R.sup.4, in which R.sup.3 and R.sup.4 are each independently selected from H, alkyl and aryl, or (ii) a mono- or dis-azo chromophore comprising benzene, naphthalene or mono - or bi-cyclic heteroaryl diazo and coupling components linked to the triazine nucleus through an amino linking group;R.sup.5 & R.sup.6 are selected from SO.sub.3 M and H provided at least one is SO.sub.3 M;R.sup.7 is H, halogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, SO.sub.3 M or COOM;and R.sup.8 is H or SO.sub.3 M,a printing ink containing the dye and a method of printing.
摘要翻译：没有纤维素反应性基团的水溶性染料，其具有下式：其中R 1是 - （CaH 2 H）m（C b H b B）n H，R 2是H或 - （CaH 2 H）m（C b H b B）n H或R 1 ＆R2与氮原子一起形成吗啉环; a＆b是不同的，1到8 m是1到10; n为0〜9; M是H，铵或一价金属; X是（i）NR 1 R 2，（ii）NR 3 R 4，其中R 3和R 4各自独立地选自H，烷基和芳基，或（ⅱ）单或二偶氮发色团，包括苯，萘或单 - 或双 - 环状杂芳基重氮和通过氨基连接基团与三嗪核连接的偶联组分; R5和R6选自SO3M和H，至少一个是SO 3 M; R 7为H，卤素，C 1-4烷基，C 1-4烷氧基，SO 3 M或COOM; R8是H或SO3M，含有染料的印刷油墨和印刷方法。

26. 发明授权

US4738721A Ink comprising a water-soluble triphendioxazine dye 失效
标题翻译：油墨包含水溶性三苯并二恶嗪染料
公开(公告)号：US4738721A
公开(公告)日：1988-04-19
申请号：US943090
申请日：1986-12-18
申请人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
发明人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
IPC分类号： C09B19/02 , C09D11/00 , C09D11/02
CPC分类号： C09D11/328 , C09B19/02
摘要： A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 and R.sup.2 together with the nitrogen atom form a morpholine ringa and b are different and from 1 to 8m is from 1 to 10;n is from 0 to 9;Y is a triphendioxazinylene (TPD) group;M is H, ammonium, or a metal;X is NR.sup.1 R.sup.2, alkoxy, NR.sup.3 R.sup.4 in which R.sup.3 and R.sup.4 are each independently selected from H, alkyl, aryl and heteroaryl, or the residue of a mono- or dis-azo chromophore comprising benzene, naphthalene or mono- or bi-cyclic heteroaryl diazo and coupling components, linked to the triazine nucleus through a primary or secondary amine linking group; andZ is an alkylene, arylene or aralkylene group, suitable for the preparation of a printing ink, especially for ink jet printing.
摘要翻译：其中R1为 - （CaH2aO）m（CbH2bO）nH，R2为H或 - （CaH2aO）m（CbH2bO）nH，或R1和R2为不含纤维素活性基团的水溶性染料，与氮原子一起形成吗啉环a和b不同，1至8m为1至10; n为0〜9; Y是三苯基二氮杂茚（TPD）组; M是H，铵或金属; X是NR 1 R 2，烷氧基，NR 3 R 4，其中R 3和R 4各自独立地选自H，烷基，芳基和杂芳基，或包含苯，萘或单环或双环杂芳基重氮的单或二偶氮发色团的残基和通过伯胺或仲胺连接基与三嗪核连接的偶联组分; Z是亚烷基，亚芳基或亚芳基，适于制备印刷油墨，特别是用于喷墨印刷。

27. 发明授权

US4735657A Water-soluble dye in an ink 失效
标题翻译：油墨中的水溶性染料
公开(公告)号：US4735657A
公开(公告)日：1988-04-05
申请号：US903456
申请日：1986-09-04
申请人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
发明人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
IPC分类号： C09B47/08 , C09B47/26 , C09D11/00 , C09D11/02
CPC分类号： C09D11/328 , C09B47/26
摘要： A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 and R.sup.2 together with the nitrogen atom form a morpholine ringa and b are different and from 1 to 8m is from 1 to 10;n is from 0 to 9;Y is the residue of a copper phthalocyanine sulphonic acid of the formula:CuPc(SO.sub.3 M).sub.qp is from 1 to 3q is from 1 to 3p+q is from 3 to 4M is H, ammonium, or a monovalent metal;X is NR.sup.1 R.sup.2, alkoxy, NR.sup.3 R.sup.4 in which R.sup.3 and R.sup.4 are each independently selected from H, alkyl and aryl, or the residue of a mono- or dis-azo chromophore comprising benzene, naphthalene or mono- or bi-cyclic heteroaryl diazo and coupling components, linked to the triazine nucleus through a primary or secondary amine linking group; andZ is a divalent linking group,which is suitable for the preparation of a printing ink, especially for ink jet printing.

28. 发明授权

US4705528A Water-soluble triazine black dyes from cellulose reactive groups and suitable for use in inks 失效
标题翻译：来自纤维素反应性基团的水溶性三嗪黑色染料，适用于油墨
公开(公告)号：US4705528A
公开(公告)日：1987-11-10
申请号：US764997
申请日：1985-08-12
申请人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
发明人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
IPC分类号： C09B45/14 , C09B43/16 , C09B45/04 , C09B45/24 , C09D11/00 , C09D11/02 , C09B45/26 , C09B45/28 , C09B45/30
CPC分类号： C09D11/328 , C09B43/16 , C09B45/04 , Y10S534/01 , Y10S534/02
摘要： A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 & R.sup.2 together with the nitrogen atom form a morpholine ringa & b are different and from 1 to 8m is from 1 to 10;n is from 0 to 9;q is 1/2 or 1p is 1 or 2L is a transition metal capable of complexing with a dyeM is H, ammonium, or a monovalent metal;Q is H or SO.sub.3 MT is H or C.sub.1-4 -alkyl;D is a substituted azo group;B, E & F are H or substituents;X is NR.sup.1 R.sup.2, NR.sup.3 R.sup.4, --NR.sup.3 --Z--NR.sup.4 --, Or.sup.3, or the residue of a mono- or bis-azo chromophore comprising benzene, naphthalene or mono- or bi- cyclic heteroaryl diazo and coupling components, linked to the triazine nucleus through a primary or secondary amine linking group, wherein R.sup.3 & R.sup.4 each independantly are H, alkyl or aryl; andZ is a divalent linking group;a mixture of this dye with an unmetallized orange dye of similar structure and an ink derived from the dye or dye mixture which is suitable for use in printing, especially ink jet printing.
摘要翻译：其中R1为 - （CaH2aO）m（CbH2bO）nH，R2为H或 - （CaH2aO）m（CbH2bO）nH，其中R1为 - （CaH2aO）m ，或R1和R2与氮原子一起形成吗啉环a＆b不同，1至8m为1至10; n为0〜9; q为1/2或1 p为1或2 L为能够与染料络合的过渡金属，M为H，铵或一价金属; Q是H或SO 3 M T是H或C 1-4 - 烷基; D是取代偶氮基团; B，E和F为H或取代基; X是NR1R2，NR3R4，-NR3-Z-NR4-，Or3或包含苯，萘或单或双环杂芳基重氮和偶联组分的单或双偶氮发色团的残基，与三嗪核连接通过伯或仲胺连接基团，其中R 3和R 4各自独立地为H，烷基或芳基; Z为二价连接基团; 该染料与具有相似结构的未金属化的橙色染料和衍生自适合用于印刷，特别是喷墨印刷的染料或染料混合物的油墨的混合物。

29. 发明授权

US4703113A Water-soluble triazine black dyes free from cellulose reactive groups and suitable for use in inks 失效
标题翻译：不含纤维素反应性基团的水溶性三嗪黑色染料，适用于油墨
公开(公告)号：US4703113A
公开(公告)日：1987-10-27
申请号：US764999
申请日：1985-08-12
申请人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
发明人： Anthony G. W. Baxter , Stephen B. Bostock , David Greenwood
IPC分类号： C09B29/30 , C09B31/28 , C09B33/10 , C09B33/18 , C09B33/22 , C09B33/26 , C09B33/28 , C09B35/38 , C09B43/16 , C09D11/00 , C09D11/02 , C09B35/58 , C09B35/64
CPC分类号： C09D11/328 , C09B29/30 , C09B43/16 , Y10S260/38
摘要： A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 & R.sup.2 together with the nitrogen atom form a morpholine ringa & b are different and from 1 to 8m is from 1 to 10;n is from 0 to 9;M is H, ammonium, or a monovalent metal;X (i) NR.sup.1 R.sup.2, (ii) NR.sup.3 R.sup.4, in which R.sup.3 and R.sup.4 are each independently selected from H, alkyl and aryl, or (iii) the residue of a mono- or bis-azo chromophore comprising benzene, naphthalene or mono- or bi-cyclic heteroaryl diazo and coupling components linked to the triazine nucleus through an amino linking group; andY is (i) the residue of a benzene, naphthalene or mono or bi-cyclic heteroaryl diazo component or (ii) the residue of a mono- or bis-azo chromophore carrying a diazotisable amino group and comprising benzene, naphthalene or mono- or bi-cyclic heteroaryl diazo and coupling components;provided that the dye contains one or at least three azo groups and an ink derived from the dye which is suitable for use in printing, especially ink jet printing.
摘要翻译：其中R1为 - （CaH2aO）m（CbH2bO）nH，R2为H或 - （CaH2aO）m（CbH2bO）nH，或R1和R2为不含纤维素反应性基团的水溶性染料，与氮原子一起形成吗啉环a＆b不同，1至8m为1至10; n为0〜9; M是H，铵或一价金属; X（i）NR1R2，（ii）NR3R4，其中R3和R4各自独立地选自H，烷基和芳基，或（iii）单或双偶氮发色团的残基，其包含苯，萘或单或双环杂芳基重氮和通过氨基连接基团与三嗪核连接的偶联组分; 并且Y是（i）苯，萘或单环或双环杂芳基重氮组分的残基，或（ii）携带重氮化氨基的单或双偶氮发色团的残基，并且包含苯，萘或单 - 或双环杂芳基重氮和偶联组分; 条件是染料含有一种或至少三种偶氮基和衍生自染料的油墨，其适用于印刷，特别是喷墨印刷。

30. 发明授权

US4591476A Injection moulding casting method 失效
标题翻译：注塑成型法
公开(公告)号：US4591476A
公开(公告)日：1986-05-27
申请号：US687252
申请日：1984-12-28
申请人： David Greenwood , Roger J. Smith
发明人： David Greenwood , Roger J. Smith
IPC分类号： B22D17/20 , B22D17/02 , B22D17/22 , B29C45/46 , B29C45/53 , B29C45/18
CPC分类号： B29C45/46 , B22D17/02
摘要： A method of injection moulding or casting comprises forcing a solid bar of the material to be moulded or cast as a plunger into a closed heating chamber having a discharge opening. The heating chamber is maintained at a temperature above the melting or plasticizing temperature of the moulding or casting material so that the leading end of the bar on entering the chamber melts or plasticizes therein and displaces molten or plasticized material from the chamber through the discharge opening. Apparatus comprises a body member formed with a heating chamber and a straight passage leading into the chamber, a plunger formed of the material to be moulded or cast being slidable in the passage. A thermal barrier may divide the passage into two successive portions.
摘要翻译：注射成型或铸造的方法包括将待模塑或铸造的材料的实心棒作为柱塞强制进入具有排出口的封闭加热室。加热室保持在高于模制或铸造材料的熔化或增塑温度的温度，使得进入腔室中的棒的前端在其中熔化或塑化，并使熔融或塑化的材料从腔室排出通过排出口。装置包括形成有加热室的主体构件和通向腔室的直通道，由待模制或铸造的材料形成的柱塞可在通道中滑动。热障可以将通道分成两个连续的部分。

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