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    • 21. 发明授权
    • Heterocyclylalkyl esters of 2-imidazolinonenicotinic acids
    • 2-咪唑啉基烟酸的杂环烷基酯
    • US4824466A
    • 1989-04-25
    • US166276
    • 1988-03-10
    • Dieter DurrHenry Szczepanski
    • Dieter DurrHenry Szczepanski
    • A01N43/50A01N43/54A01N43/56A01N43/707A01N43/80C07D401/04C07D401/14C07D405/14C07D413/14C07D521/00A01N43/40
    • C07D231/12A01N43/50A01N43/54A01N43/56A01N43/707A01N43/80C07D233/56C07D249/08C07D401/04C07D401/14C07D405/14C07D413/14
    • Novel heterocyclylalkyl esters of 2-imidazolinonenicotinic acids of formula I below have good selective herbicidal properties pre- and postemergence and also influence or inhibit plant growth.The novel esters have the formula I ##STR1## wherein A is a straight chain or branched C.sub.1 -C.sub.4 alkylene bridge,X and Y are each independently of the other hydrogen,C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkoxy or halogen, or X and Y together form the butadiene bridge, which may be substituted by halogen, cyano or C.sub.1 -C.sub.4 alkyl, andHet is a 5- or 6-membered heterocycle which contains one to three nitrogen atoms and/or one oxygen or sulfur atom and which may further contain one or two carbonyl groups, which heterocycle may also be fused to benzene rings and/or substituted by halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkoxy, nitro, amino, C.sub.1 -C.sub.3 alkylamino or di(C.sub.1 -C.sub.3)alkylamino.
    • 式I的2-咪唑啉一enic酸的新型杂环基烷基酯在芽前和芽后具有良好的选择性除草性,并且还影响或抑制植物生长。 新的酯具有式I(I)其中A是直链或支链的C 1 -C 4亚烷基桥,X和Y各自独立于另一个氢,C 1 -C 3烷基,C 1 -C 3卤代烷基,C 1 -C 3烷氧基,C 1 -C 3卤代烷氧基或卤素,或X和Y一起形成可被卤素,氰基或C 1 -C 4烷基取代的丁二烯桥,Het是含有1-3个氮原子和/或一个氮原子的5-或6-元杂环 氧或硫原子,并且其还可以含有一个或两个羰基,该杂环还可以与苯环稠合和/或被卤素,C 1 -C 3烷基,C 1 -C 3卤代烷基,C 1 -C 3烷氧基,C 1 -C 3卤代烷氧基,硝基,氨基 ,C 1 -C 3烷基氨基或二(C 1 -C 3)烷基氨基。
    • 22. 发明授权
    • Heterocyclically fused pyridine compounds as herbicides
    • 杂环稠合吡啶化合物作为除草剂
    • US4743296A
    • 1988-05-10
    • US936214
    • 1986-12-01
    • Dieter DurrHans-Georg BrunnerHenry Szczepanski
    • Dieter DurrHans-Georg BrunnerHenry Szczepanski
    • A01N43/90C07D471/14A01N43/40A01N43/42
    • C07D471/14A01N43/90
    • This is a continuation in part application derived from our copending application Ser. No. 837,977 (filing date Mar. 10, 1986). This continuation in part is directed to novel pyridine compounds of formula I below have good selective herbicidal properties pre- and postemergence and also influence or inhibit plant growth. The compounds are of formula I ##STR1## wherein each of X, Y and Z independently of one another is hydrogen or a C.sub.1 -C.sub.4 alkyl group, or two adjacent substituents together also form a saturated or unsaturated 3- or 4-membered alkylene chain or alkenyl chain, each of which chains may in turn by substituted by one to four C.sub.1 -C.sub.4 alkyl groups, R is a C.sub.1 -C.sub.4 nitroalkyl group, a substituted C.sub.1 -C.sub.4 alkylthio group or C.sub.1 -C.sub.4 alkoxy group, an unsubstituted or substituted C.sub.3 -C.sub.4 alkenylthio or C.sub.3 -C.sub.4 alkynylthio group, the hydroxyamino group, a C.sub.1 -C.sub.4 alkoxyamino, C.sub.3 -C.sub.4 alkenyloxyamino or C.sub.3 -C.sub.4 alkynyloxyamino group, a --PO(C.sub.1 -C.sub.4 alkyl).sub.2 or --PO(CH.sub.3)OC.sub.1 -C.sub.4 -alkyl radical or an unsubstituted or substituted hydrazino radical.
    • 这是来自我们的共同未决申请Ser的部分申请的延续。 837,977号(1986年3月10日提交)。 这一延续部分涉及式I的新型吡啶化合物具有良好的选择性除草性能和芽后效应,并且还影响或抑制植物生长。 所述化合物具有式I(I)其中X,Y和Z各自独立地为氢或C 1 -C 4烷基,或两个相邻的取代基一起也形成饱和或不饱和的3-或4-元 亚烷基链或烯基链,其中每个链依次可被一至四个C 1 -C 4烷基取代,R是C 1 -C 4硝基烷基,取代的C 1 -C 4烷硫基或C 1 -C 4烷氧基,未取代或取代的C 3 -C 4烷氧基, C 4链烯基硫基或C 3 -C 4炔硫基,羟基氨基,C 1 -C 4烷氧基氨基,C 3 -C 4链烯氧基氨基或C 3 -C 4炔氧基氨基,-PO(C 1 -C 4烷基)2或-PO(CH 3)OC 1 -C 4烷基或未取代或未取代的 取代的肼基。
    • 24. 发明授权
    • Novel phenoxyphenylamino acid derivatives, the production thereof,
compositions containing them and use thereof
    • US4649212A
    • 1987-03-10
    • US719632
    • 1985-04-04
    • Dieter Durr
    • Dieter Durr
    • A01N33/18A01N33/22A01N37/44A01N37/46A01N47/34C07C237/00C07C243/34C07C275/50C07D207/16C07C79/46
    • C07C255/00A01N37/44A01N37/46A01N47/34C07C243/34C07C275/50C07D207/16
    • The invention relates to novel phenoxyphenylamino acid derivatives of the formula I ##STR1## wherein X is hydrogen, chlorine, fluorine or bromine,R.sup.1 is hydrogen, nitroso, or C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.1 -C.sub.4 alkylcarbonyl or C.sub.2 -C.sub.4 alkenylcarbonyl, each of which is unsubstituted or substituted by one or more halogen atoms,Q is a straight chain or branched aliphatic radical of 1 to 5 carbon atoms ##STR2## in which A', E', G', L' and M' are hydrogen or C.sub.1 -C.sub.4 alkyl, or two adjacent substituents A', E', G', L' and M' together are also a bond between the two carbon atoms to which they are attached; A, E, G, L and M are hydrogen or one or two of A, E, G, L and M are also --OR.sup.2, --SR.sup.3, --COOR.sup.4, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkyl substituted by --OR.sup.5, --SR.sup.6 or --COOR.sup.7, where R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 are hydrogen or C.sub.1 -C.sub.4 alkyl; a, b, c and d are 0 or 1; or R.sup.1 and G together are a trimethylene bridge and a, b, c and d are 0; andZ is --COO.sup..crclbar. Me.sup..sym., --COOR.sup.8, --COSR.sup.8, --CONR.sup.9 R.sup.10, --COR.sup.11 or --CN, where Me.sup..sym. is a cation, R.sup.8 is hydrogen, C.sub.1 -C.sub.8 alkyl which is unsubstituted or substituted by halogen, cyano or C.sub.1 -C.sub.4 alkoxy, or is C.sub.2 -C.sub.8 alkenyl or C.sub.3 -C.sub.8 alkynyl, R.sup.9 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.3 -C.sub.6 cycloalkyl, R.sup.10 is hydrogen, amino, hydroxyl, C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkoxy, or is C.sub.2 -C.sub.4 alkynyl, C.sub.1 -C.sub.4 alkoxy or C.sub.3 -C.sub.6 cycloalkylaminocarbonyl and R.sup.11 is hydrogen or C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkoxy, with the proviso that, in compounds in which simultaneously R.sup.1 is hydrogen and a, b, c and d are O, (i) G is --OR.sup.2, -- COOR.sup.4 or C.sub.1 -C.sub.4 alkyl which is substituted by --OR.sup.5, --SR.sup.6 or --COOR.sup.7, or (ii) G and G' are both C.sub.1 -C.sub.4 alkyl and also to the preparation of these compounds. The compounds of formula I or compositions containing them may be used for controlling undesirable plant growth and for desiccating and defoliating cotton and potato plants.
    • 30. 发明授权
    • Herbicidal alkoxyamino- and polyalkoxyaminodiphenyl ethers
    • 除草烷氧基氨基和聚烷氧基氨基二苯醚
    • US4694105A
    • 1987-09-15
    • US679860
    • 1984-12-10
    • Dieter Durr
    • Dieter Durr
    • A01N33/22A01N37/02A01N37/04A01N37/26A01N37/34A01N37/42A01N41/04A01N43/16A01N43/28A01N43/32A01N43/90C07C43/13C07C67/00C07C213/00C07C217/90C07C253/00C07C255/13C07C301/00C07C303/30C07C309/63C07C313/00C07D307/20C07D309/10C07D309/12C07D317/28C07D317/36C07D319/00C07D319/12C07D493/08C07C93/14C07C149/42
    • C07D493/08A01N33/22A01N37/02A01N37/04A01N37/26A01N37/42A01N41/04A01N43/16A01N43/28A01N43/32A01N43/90C07C43/135C07D307/20C07D309/12C07D317/28C07D317/36C07D319/12
    • Herbicidal and plant growth regulating 3-alkoxyamino- and 3-polyalkoxyamino-2'-chloro-4-nitro-4'-trifluoromethyldiphenyl ethers of formula I ##STR1## wherein each of A, A', A" and A'" is an identical or different C.sub.1 -C.sub.4 alkylene radical which may be straight chain or branched; n is a value from 1 to 5; each of n', n" and n'" is zero or a value from 1 to 5; R is a C.sub.1 -C.sub.4 alkyl radical or a C.sub.1 -C.sub.4 alkylcarbonyl radical, which alkyl radicals may be substituted by halogen or cyano, or is a benzoyl or phenylsulfonyl radical which may be substituted by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy or nitro, or, if A-O is not oxyethylene and/or if the sum of n+n'+n"+n'" is greater than 1, R is also hydrogen; R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 hydroxyalkyl, C.sub.2 -C.sub.8 alkoxyalkyl, C.sub.1 -C.sub.4 alkylcarbonyl or C.sub.1 -C.sub.4 haloalkylcarbonyl, which radicals R and R.sub.1 may be branched through C-C or C-O bonds or may be linked to each other to form a ring; and R.sub.2 is hydrogen, chlorine or fluorine, are suitable for selectively controlling weeds in crops of useful plants, e.g. cereals, maize, rice or soybeans.These compounds are effective when applied at lower concentrations than the concentrations at which comparable similar known diphenyl ethers are applied. In addition, these compounds are effective against insects and representatives of the order Acarina.
    • 除草剂和植物生长调节式I的3-烷氧基氨基 - 和3-聚烷氧基氨基-2'-氯-4-硝基-4'-三氟甲基二苯基醚(I)(A''O)n“(A” 其中A,A',A“和A”'中的每一个是可以是直链或支链的相同或不同的C 1 -C 4亚烷基; n为1至5的值; n',n“和n”“中的每一个为零或1至5的值; R是C 1 -C 4烷基或C 1 -C 4烷基羰基,该烷基可以被卤素或氰基取代,或者是可以被卤素,C 1 -C 4烷基,C 1 -C 4烷氧基,C 1 -C 4卤代烷基取代的苯甲酰基或苯基磺酰基 ,如果AO不是氧化乙烯,和/或如果n + n'+ n“+ n”'的和大于1,则R也是氢; R1是氢,C1-C4烷基,C1-C4羟烷基,C2-C8烷氧基烷基,C1-C4烷基羰基或C1-C4卤代烷基羰基,其中R和R1可以通过C-C或C-O键分支,或者可以彼此连接形成环; 和R2是氢,氯或氟,适于选择性地控制有用植物的作物中的杂草,例如 谷物,玉米,大米或大豆。 当以比应用可比较的相似的已知二苯醚的浓度低的浓度施用时,这些化合物是有效的。 此外,这些化合物对昆虫和蜱螨目的代表是有效的。