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21. 发明授权

US5013423A Reforming and dehydrocyclization 失效
标题翻译：改革和脱水循环
公开(公告)号：US5013423A
公开(公告)日：1991-05-07
申请号：US295959
申请日：1989-01-11
申请人： Nai Y. Chen , Ralph M. Dessau , Randall D. Partride , Ernest W. Valyocsik
发明人： Nai Y. Chen , Ralph M. Dessau , Randall D. Partride , Ernest W. Valyocsik
IPC分类号： B01J29/44 , B01J29/74 , C07C5/41 , C10G35/085 , C10G35/095
CPC分类号： C10G35/095 , B01J29/04 , B01J29/068 , B01J29/44 , B01J29/7415 , B01J29/7438 , B01J29/84 , B01J29/86 , C07C5/417
摘要： Improved, dehydrocyclization and low-pressure reforming processes based on a non-acidic metal containing crystalline microporous indium catalyst, in which the feed is rich in C.sub.6 -C.sub.7 low octane hydrocarbons, such as paraffins, and in which the reformate has increased aromatic content and increased octane value over that of the feed are disclosed.
摘要翻译：基于非酸性金属结晶微孔铟催化剂的改进的脱氢环化和低压重整方法，其中进料富含C6-C7低辛烷值烃，如链烷烃，其中重整油具有增加的芳族含量，公开了比饲料中辛烷值增加的值。

22. 发明授权

US4840929A Zeolite beta with improved regeneration characteristics 失效
标题翻译：沸石β具有改进的再生特性
公开(公告)号：US4840929A
公开(公告)日：1989-06-20
申请号：US218438
申请日：1988-07-11
申请人： Nai Y. Chen , Sharon B. McCullen
发明人： Nai Y. Chen , Sharon B. McCullen
IPC分类号： B01J29/70 , B01J29/74
CPC分类号： B01J29/7415 , B01J29/7007 , B01J2229/16 , B01J2229/37
摘要： The present invention describes a method for preparing a noble metal Zeolite Beta containing catalyst with improved platinum redispersion characteristics. The method includes using a mineral acid to extract the framework aluminum from the zeolite and forming the catalyst particles without the use of inorganic oxide binders.
摘要翻译：本发明描述了一种制备具有改进的铂再分散特性的贵金属沸石β的催化剂的方法。该方法包括使用无机酸从沸石中提取骨架铝并在不使用无机氧化物粘合剂的情况下形成催化剂颗粒。

23. 发明授权

US4814543A Nitrogen resistant paraffin hydroisomerization catalysts 失效
标题翻译：耐氮石蜡加氢异构化催化剂
公开(公告)号：US4814543A
公开(公告)日：1989-03-21
申请号：US138749
申请日：1987-12-28
申请人： Nai Y. Chen , William E. Garwood , Sharon B. McCullen
发明人： Nai Y. Chen , William E. Garwood , Sharon B. McCullen
IPC分类号： B01J29/66 , B01J29/70 , B01J29/74 , C07C5/27 , C10G45/64 , C07C5/13
CPC分类号： C10G45/64 , B01J29/064 , B01J29/67 , B01J29/7484 , B01J29/7492 , C07C5/2791 , B01J2229/42
摘要： The present invention includes a process and catalyst composition for paraffinic isomerization of a hydrocarbon feedstock which has a paraffin content having no more than 20 carbon atoms per molecule. The feedstock is contacted with a crystalline aluminosilicate zeolite catalyst having pore openings defined by: (1) a ratio of sorption of n-hexane to o-xylene, on a volume percent basis, of greater than about 3, which sorption is determined at a P/P.sub.o of 0.1 and at a temperature of 50.degree. C. for n-hexane and 80.degree. C. for o-xylene and (2) by the ability of selectively cracking 3-methylpentane (3MP) in preference to the doubly branched 2,3-dimethylbutane (DMB) at 1000.degree. F. and 1 atmosphere pressure from a 1/1/1 weight ratio mixture of n-hexane/3-methyl-pentane/2,3-dimethylbutane, with the ratio of rate constants k.sub.3MP/ k.sub.DMB determined at a temperature of 1000.degree. F. being in excess of about 2, e.g., ZSM-22, ZSM-23, AXM-35 and mixtures thereof, in combination with a Group VIII metal, and having a zeolite SiO.sub.2 /Al.sub.2 O.sub.3 ratio of at least about 20:1 at a temperature and pressure suitable for isomerization.
摘要翻译：本发明包括用于烃原料的链烷烃异构化的方法和催化剂组合物，其具有每分子具有不超过20个碳原子的链烷烃含量。原料与具有孔开口的结晶铝硅酸盐沸石催化剂接触，所述沸石催化剂的定义如下：（1）正丁烷与邻二甲苯的吸附比例，以体积百分数计，大于约3，该吸附在 P / Po为0.1，温度为50℃，正己烷和80℃为邻二甲苯，（2）选择性裂解3-甲基戊烷（3MP）优于双支链2 ，三甲基丁烷（DMB）在1000°F和1大气压下，由正己烷/ 3-甲基戊烷/ 2,3-二甲基丁烷的1/1/1重量比混合物与速率常数比例k3MP / kDMB在1000°F的温度下测定为超过约2，例如ZSM-22，ZSM-23，AXM-35及其混合物，与VIII族金属组合，并具有SiO 2 / Al 2 O 3沸石在适于异构化的温度和压力下至少约20:1的比例。

24. 发明授权

US4717465A Process for producing jet fuel with ZSM-22 containing catalist 失效
标题翻译：用含有催化剂的ZSM-22生产喷气燃料的方法
公开(公告)号：US4717465A
公开(公告)日：1988-01-05
申请号：US915935
申请日：1986-10-06
申请人： Nai Y. Chen , William E. Garwood
发明人： Nai Y. Chen , William E. Garwood
IPC分类号： B01J29/00 , B01J29/70 , B01J29/74 , C10G45/64 , C10L1/04
CPC分类号： B01J29/7484 , C10G45/64 , B01J29/7284 , B01J29/7684
摘要： A novel process is disclosed for the production of high boiling jet fuels which comprises contacting a chargestock with an end boiling point of about 750.degree. F. with ZSM-22 under carefully controlled conditions of temperature and pressure and blending the 330.degree. F. plus fraction with a conventional jet fuel in order to obtain a product having acceptable jet fuel properties and having a high boiling range.
摘要翻译：公开了一种用于生产高沸点喷气燃料的新方法，其包括在精心控制的温度和压力条件下将具有约750°F的终沸点的电荷料与ZSM-22接触，并将330°F加级分使用常规的喷气燃料，以获得具有可接受的喷气燃料性能并具有高沸点范围的产品。

25. 发明授权

US4627911A Dispersed catalyst cracking with methanol as a coreactant 失效
标题翻译：用甲醇作为共反应剂分散催化剂裂解
公开(公告)号：US4627911A
公开(公告)日：1986-12-09
申请号：US815660
申请日：1985-12-30
申请人： Nai Y. Chen , Thomas F. Degnan, Jr.
发明人： Nai Y. Chen , Thomas F. Degnan, Jr.
IPC分类号： C10G11/05 , C07C1/24 , C10G47/16
CPC分类号： C10G11/05
摘要： A catalytic cracking process is described in which methanol is a coreactant with gas oil in combination with a small amount (catalyst/oil 0.01) of a dispersed, very fine, and highly active catalyst powder, such as ZSM-5B. The methanol is preferably admixed with the catalyst before admixture with the oil in order to protect the catalyst from adsorption of poisonous compounds (e.g., nitrogenous compounds) during the initial stages of the reaction, particularly if the methanol is insoluble in a non-polar hydrocarbon feed. The premixed materials are fed into a riser reactor. The residence time in the reactor is 6-15 seconds. Preferably, the catalyst is not regenerated. The quantity of methanol is maintained so that its exothermic reaction is approximately heat balanced with the endothermic catalytic cracking reaction.
摘要翻译：描述了催化裂化方法，其中甲醇是与少量（催化剂/油0.01）的分散的，非常细的和高活性的催化剂粉末如ZSM-5B组合的助燃油的共反应物。在与油混合之前，甲醇优选与催化剂混合，以便在反应的初始阶段保护催化剂免受有毒化合物（例如含氮化合物）的吸附，特别是如果甲醇不溶于非极性烃饲料。将预混材料进料到提升管反应器中。反应器中的停留时间为6-15秒。优选地，催化剂不再生。维持甲醇的量，使其放热反应与吸热催化裂化反应近似热平衡。

26. 发明授权

US4615997A Method for preparing hydroisomerization catalysts 失效
标题翻译：制备加氢异构化催化剂的方法
公开(公告)号：US4615997A
公开(公告)日：1986-10-07
申请号：US740690
申请日：1985-06-03
申请人： Nai Y. Chen , Sharon B. McCullen , Stephen M. Oleck
发明人： Nai Y. Chen , Sharon B. McCullen , Stephen M. Oleck
IPC分类号： B01J29/068 , B01J29/74 , B01J37/22 , B01J29/06
CPC分类号： B01J29/7415 , B01J29/068 , B01J2229/36 , B01J37/22
摘要： A method for preparing hydroisomerization zeolite catalysts containing a highly dispersed noble metal is described. The method includes mix mulling the zeolite, noble metal and binder into an extrudate and chemically treating the formed particles in order to achieve a high dispersion of noble metal on the catalyst.
摘要翻译：描述了一种制备含有高度分散的贵金属的加氢异构化沸石催化剂的方法。该方法包括将沸石，贵金属和粘合剂混合到挤出物中并化学处理形成的颗粒，以便实现贵金属在催化剂上的高分散性。

27. 发明授权

US4446004A Process for upgrading vacuum resids to premium liquid products 失效
标题翻译：将优质真空泵升级至优质液体产品的工艺
公开(公告)号：US4446004A
公开(公告)日：1984-05-01
申请号：US452529
申请日：1982-12-23
申请人： Nai Y. Chen , Lillian A. Rankel , Leslie R. Rudnick
发明人： Nai Y. Chen , Lillian A. Rankel , Leslie R. Rudnick
IPC分类号： C10B55/00 , C10G69/06
CPC分类号： C10B55/00 , C10G2300/107
摘要： An improved process for upgrading vacuum resids to premium liquid products which comprises mild hydrotreating of the vacuum resids followed by fractionating and short contact time thermal cracking of the fraction boiling above 850.degree. F.+, such as by short contact time thermal cracking or rapid pyrolysis.
摘要翻译：将真空渣油提升到优质液体产品的改进方法，其包括对真空渣油进行轻度加氢处理，然后分馏和短时接触时间热裂解馏分沸点高于850°F +，例如通过短接触时间热裂解或快速热解。

28. 发明授权

US4222855A Production of high viscosity index lubricating oil stock 失效
标题翻译：生产高粘度指数润滑油原料
公开(公告)号：US4222855A
公开(公告)日：1980-09-16
申请号：US23855
申请日：1979-03-26
申请人： Bruce P. Pelrine , Nai Y. Chen
发明人： Bruce P. Pelrine , Nai Y. Chen
IPC分类号： B01J29/46 , B01J29/70 , C10G45/64 , C10G11/05 , C10G47/16
CPC分类号： B01J29/7049 , B01J29/46 , B01J29/70 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C10G2400/10
摘要： Waxy hydrocarbon oils, e.g., of petroleum origin, boiling within the approximate range of 450.degree. to 1050.degree. F. are catalytically dewaxed utilizing a catalyst comprising a crystalline aluminosilicate zeolite possessing particularly characterized pore openings, such as, for example, ZSM-23 or ZSM-35, which may be associated with a hydrogenation metal.
摘要翻译：使用包含具有特别表征的孔开口的结晶铝硅酸盐沸石的催化剂，在450至1050°F的近似范围内沸腾的石油来源的蜡质烃油进行催化脱蜡，所述结晶硅铝酸盐沸石包括例如ZSM-23或 ZSM-35，其可与氢化金属缔合。

29. 发明授权

US4197214A Crystalline zeolite catalysts of chemical reactions 失效
标题翻译：结晶沸石催化剂的化学反应
公开(公告)号：US4197214A
公开(公告)日：1980-04-08
申请号：US949703
申请日：1978-10-10
申请人： Nai Y. Chen , William J. Reagan , Vern W. Weekman, Jr.
发明人： Nai Y. Chen , William J. Reagan , Vern W. Weekman, Jr.
IPC分类号： C10G11/00 , B01J29/06 , B01J29/90 , B01J38/12 , C01B39/20 , C01B39/26 , C01B39/30 , C01B39/36 , C01B39/38 , C01B39/42 , C01B39/44 , C10G2/00 , C10G3/00 , B01J29/38 , C07C15/00 , C10G35/06
CPC分类号： B01J29/90 , C10G3/49 , C10G3/62 , C10G2300/4006 , C10G2300/807 , C10G2400/02 , Y02P30/20
摘要： Crystalline zeolite catalysts are stabilized against reducing and moisture containing atmospheres by providing and maintaining substantial metal cationic sites in the zeolite during use in chemical reactions encountering reducing and/or moisture rich atmospheres at high temperature.
摘要翻译：结晶沸石催化剂通过在使用期间在沸石中提供和维持大量的金属阳离子位点而稳定，以减少和含水气氛。在化学反应中遇到在高温下还原和/或富含水分的气氛。

30. 发明授权

US4194964A Catalytic conversion of hydrocarbons in reactor fractionator 失效
$Catalytic conversion of hydrocarbons in reactor fractionator$
标题翻译：反应器分馏塔中碳氢化合物的催化转化
公开(公告)号：US4194964A
公开(公告)日：1980-03-25
申请号：US922915
申请日：1978-07-10
申请人： Nai Y. Chen , Ikai Wang
发明人： Nai Y. Chen , Ikai Wang
IPC分类号： B01J8/04 , C10G47/00 , C10G49/00 , C10G65/14 , C10G13/02 , C10G23/02 , C10G37/06
CPC分类号： C10G49/002 , B01J8/0453 , B01J2208/00274 , B01J2208/00283 , C10G2300/107 , Y10S203/06
摘要： Heavy petroliferous stocks such as vacuum and atmospheric resids, tar sand oils, shale oils, liquids from conversion of coal and the like are concurrently distilled and hydroprocessed for removal of sulfur, nitrogen and metals and are hydrocracked or otherwise hydroprocessed in a packed distillation column under hydrogen pressure wherein the packing is constituted, at least to a substantial extent in both stripping and rectifying sections by catalyst suited to the desired conversions.
摘要翻译：同时蒸馏并加氢处理重金属含量如真空和常压渣油，焦油砂油，页岩油，转化煤等液体，并进行加氢处理以除去硫，氮和金属，并加氢裂化或以其他方式加氢处理在填料蒸馏塔中通过适合所需转化率的催化剂，至少大大地在汽提和精馏段中构成填料的氢气压力。

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