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    • 21. 发明授权
    • Method for making positive working printing plates from a heat mode
sensitive image element
    • 从加热模式敏感图像元件制作正性印刷版的方法
    • US06060218A
    • 2000-05-09
    • US163372
    • 1998-09-30
    • Marc Van DammeJoan VermeerschGeert Deroover
    • Marc Van DammeJoan VermeerschGeert Deroover
    • B41C1/10B41M5/36G03F7/30
    • B41C1/1008B41C2210/02B41C2210/06B41C2210/22B41C2210/262Y10S430/145Y10S430/165
    • According to the present invention there is provided a method for making lithographic printing plates including the following stepsa) preparing a heat mode imaging element consisting of a lithographic base with a hydrophilic surface and a top layer which top layer is sensitive to IR-radiation, comprises a polymer, soluble in an aqueous alkaline solution and is unpenetrable for an alkaline developer containing SiO.sub.2 as silicates;b) exposing imagewise said heat mode imaging element to IR-radiation;c) developing said imagewise exposed heat mode imaging element with said alkaline developer so that the exposed areas of the top layer are dissolved and the unexposed areas of the top layer remain undissolved characterized in that said top layer includes an IR-dye selected from the group consisting of indoaniline dyes, cyanine dyes, merocyanine dyes, oxonol dyes, porphine derivatives, anthraquinone dyes, merostyryl dyes, pyrylium compounds, diphenyl and triphenyl azo compounds and squarylium derivatives.
    • 根据本发明,提供了一种制备平版印刷版的方法,包括以下步骤:a)制备由具有亲水表面的光刻基底和顶层对IR辐射敏感的顶层组成的热模式成像元件, 包含可溶于碱性水溶液的聚合物,并且对于含有SiO2的碱性显影剂不可穿透,作为硅酸盐; b)将成像的所述热模式成像元件暴露于IR辐射; c)用所述碱性显影剂显影所述成像曝光的热模式成像元件,使得顶层的暴露区域溶解,并且顶层的未曝光区域保持未溶解,其特征在于,所述顶层包括选自以下的IR-染料 由吲哚苯胺染料,花青染料,部花菁染料,氧杂菁染料,卟吩衍生物,蒽醌染料,merostyryl染料,吡喃鎓化合物,二苯基和三苯基偶氮化合物和方晶衍生物组成。
    • 26. 发明授权
    • Positive-working lithographic printing plate precursor
    • 正版平版印刷版前体
    • US07294447B2
    • 2007-11-13
    • US10243750
    • 2002-09-13
    • Marc Van DammeJoan VermeerschGeert Deroover
    • Marc Van DammeJoan VermeerschGeert Deroover
    • G03F7/004
    • B41N1/14B41C1/1008B41C2210/02B41C2210/06B41C2210/22B41C2210/24B41N1/08
    • A lithographic printing plate precursor is disclosed which comprises (i) a support having a hydrophilic surface or which is provided with a hydrophilic layer and (ii) a coating provided thereon, the coating comprising an oleophilic layer which, upon image-wise exposure to heat or infrared light and subsequent immersion in an aqueous alkaline developer, dissolves in the developer at a higher dissolution rate in exposed areas than in unexposed areas, wherein the oleophilic layer comprises a polymer that is soluble in the developer and an organic dye in a amount sufficient to provide a visible color to the coating, characterized in that said organic dye does not reduce the dissolution rate of the unexposed areas in the developer.By using non-inhibiting dyes, the sensitivity of the precursor upon image-wise exposure is increased.
    • 公开了一种平版印刷版原版,其包括(i)具有亲水性表面的或具有亲水层的载体,和(ii)在其上提供的涂层,所述涂层包含亲油层,其在成像时暴露于热 或红外光并随后浸入含水碱性显影剂中,在暴露的区域中以比未曝光的区域更高的溶解速率溶解在显影剂中,其中亲油层包含可溶于显影剂的聚合物和足够量的有机染料 以向涂层提供可见的颜色,其特征在于所述有机染料不会降低显影剂中未曝光区域的溶解速率。 通过使用非抑制染料,前体在成像曝光时的灵敏度增加。