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    • 22. 发明专利
    • PRODUCTION OF BAZRO3 DIELECTRIC POWDER
    • JPS62256727A
    • 1987-11-09
    • JP10062686
    • 1986-04-28
    • MITSUBISHI ELECTRIC CORP
    • HIGUMA HIROKONOZAKI AYUMIWATAI HISAOIDO TAKEO
    • H01B3/00C01G25/00H01B3/10
    • PURPOSE:To easily produce fine BaZrO3 dielectric power having high surface activity by adding a water-alcohol soln. mixture dissolved therein with an inorg. zirconium salt to an alcohol soln. contg. the alkoxide of Ba to hydrolyze said soln. CONSTITUTION:Metallic Ba is dissolved in an alcohol soln. at 40 deg.C-the b.p. of alcohol in an inert gaseous atmosphere to form the alkoxide of the Ba. On the other hand, an inorg. zirconium salt is dissolved in a water-alcohol sol. mixture contg. water of 1-40 times mol of the above-mentioned metallic Ba and the alcohol of the amt. larger than the same at the above-mentioned temp. range. Said water-alcohol soln. mixture is then added to said alcohol soln. to hydrolyze the same in the above-mentioned atmosphere and temp. range. The precipitate obtd. by the coprecipitation is separated from the soln. and is subjected to a heating treatment in a 400-1,000 deg.C range after drying, by which the precipitate is pulverized. The BaZrO3 dielectric power which has small particle sizes and high surface activity and with which the dense dielectric ceramic material having less defects is obtainably by sintering is thus stably obtd.
    • 26. 发明专利
    • PRODUCTION OF DETECTING ELEMENT FOR GAS AND HUMIDITY
    • JPS5821155A
    • 1983-02-07
    • JP11980581
    • 1981-07-30
    • MITSUBISHI ELECTRIC CORP
    • WATAI HISAOIDO TAKEOSATOU TOSHIAKI
    • H01C7/00G01N27/12
    • PURPOSE:To obtain a detecting element having good thermal efficiency and excellent sensitivity and durability by superposing two sheets formed by adding a binder to powder of a metallic oxide having sensitivity to gas or humidity with metallic paste for a heater printed on one side of said sheets in-between, and calcining the superposed sheets. CONSTITUTION:Alloy powder paste of Au and Pd, Pt and Pd, etc. is screen- printed on one side of the sheet 1 out of the two sheets 1, 1' prepd. by adding a plasticizer, a binder such as resins to the powder of a metallic oxide having sensitivity to gas or humidity or both, whereby a heater 2 is formed. After electrodes 3, 3' are formed on the other surface of the sheet 1 and one surface of the sheet 1', the sheets 1, 1' are laminated under pressure with the heaters 2 in- between; thereafter the sheets are calcined to one body. Terminals 4, 4' for the electrodes 3, 3' and terminals 5, 5' for the heater 2 are mounted by a bonding method or the like, whereby the detecting element is obtained. The element having good heating efficiency of the heater and having excellent durability and high sensitivity is obtained.
    • 29. 发明专利
    • OPTICAL MODULATOR AND ITS PRODUCTION
    • JPH05173100A
    • 1993-07-13
    • JP33742491
    • 1991-12-20
    • MITSUBISHI ELECTRIC CORP
    • UCHIKAWA HIDEFUSAIMADA KATSUHIROYOSHIARA KIICHIWATAI HISAOMIZUOCHI TAKASHIKITAYAMA TADAYOSHI
    • G02F1/035
    • PURPOSE:To decrease the propagation loss of high frequency by forming an Mg-Nb-0 oxide layer on a crystal substrate consisting of LiNbO3 formed with a Ti diffused waveguide layer and forming oxide superconducting electrodes thereon. CONSTITUTION:An oxide layer 3 contg. the Mg-Nb-0 oxide is formed as the essential component on the surface of the LiNbO3 crystal substrate 1 formed with the optical waveguide 2 and the oxide superconducting electrodes 4 are formed thereon. The oxide layer 3 does not contain Li ions, unlike the substrate 1 itself, and hardly reacts with the oxide superconducting material forming the electrodes 4. In addition, this layer acts to enhance the orientability of the oxide superconducting film. The oxide layer 3 has the refractive index lower than the refractive index of the waveguide 2 and, therefore, plays the role as a buffer layer. Namely, the deterioration in the superconducting characteristics of the electrodes 4 in the diffusion reaction of the constituting elements of the oxide superconducting material and the crystal substrate components is suppressed by the oxide layer 3 and the surface resistance of the electrodes 4 is lowered, by which the high-frequency propagation losses are decreased and the leakage of light from the waveguide 2 is simultaneously prevented.