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21. 发明申请

US20140187821A1 Process for Producing Cycloalkylaromatic Compounds 有权
标题翻译：生产环烷基芳族化合物的方法
公开(公告)号：US20140187821A1
公开(公告)日：2014-07-03
申请号：US13989903
申请日：2011-10-25
申请人： Kun Wang , Jihad M. Dakka , Stephen Zushma , James R. Lattner , Christopher L. Becker , Tan-Jen Chen
发明人： Kun Wang , Jihad M. Dakka , Stephen Zushma , James R. Lattner , Christopher L. Becker , Tan-Jen Chen
IPC分类号： C07C2/74 , C07C45/53 , C07C37/08
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2601/14 , C07C39/04 , C07C49/403 , C07C13/28
摘要： In a process for producing a cycloalkylaromatic compound, an aromatic compound and a cyclic olefin are contacted with a first catalyst under conditions effective to produce a reaction product comprising the cycloalkylaromatic compound and at least one non-fused bicyclic by-product. The at least one non-fused bicyclic by-product is then contacted with a second catalyst under conditions effective to convert at least a portion of the at least one non-fused bicyclic by-product to a converted by-product.
摘要翻译：在制备环烷基芳族化合物的方法中，芳族化合物和环状烯烃在有效产生包含环烷基芳族化合物和至少一种非稠合双环副产物的反应产物的条件下与第一催化剂接触。然后至少一种非稠合双环副产物在有效将至少一部分非稠合双环副产物转化为转化副产物的条件下与第二催化剂接触。

22. 发明申请

US20110190546A1 Process For Producing Phenol 失效
标题翻译：生产苯酚的方法
公开(公告)号：US20110190546A1
公开(公告)日：2011-08-04
申请号：US13061601
申请日：2009-07-14
申请人： Jihad M. Dakka , Kun Wang , Edmund J. Mozeleski , Stephen Zushma
发明人： Jihad M. Dakka , Kun Wang , Edmund J. Mozeleski , Stephen Zushma
IPC分类号： C07C37/08
CPC分类号： B01J23/002 , B01J21/066 , B01J23/28 , B01J23/30 , B01J23/888 , B01J31/0247 , B01J31/38 , B01J37/031 , B01J37/10 , B01J2523/00 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/08 , C07C409/14 , C07C2601/08 , C07C2601/14 , C07C2601/18 , Y02P20/52 , C07C39/04 , C07C49/10 , C07C49/403 , B01J2523/17 , B01J2523/48 , B01J2523/69 , B01J2523/842 , B01J2523/68
摘要： In a process for producing phenol or a substituted phenol, an alkylaromatic hydroperoxide having a general formula (I): in which R1 and R2 each independently represents an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with a catalyst comprising an oxide of at least one metal from Groups 3 to 5 and Groups 7 to 14 of the Periodic Table of the Elements and an oxide of at least one metal from Group 6 of the Periodic Table of the Elements.
摘要翻译：在制备苯酚或取代苯酚的方法中，具有通式（I）的烷基芳基氢过氧化物：其中R 1和R 2各自独立地表示具有1至4个碳原子的烷基，条件是R 1和R 2可以连接到形成具有4至10个碳原子的环状基团，所述环状基团任选被取代，并且R 3表示氢，具有1至4个碳原子的一个或多个烷基或环己基与包含以下化合物的催化剂接触：元素周期表第3至5族和第7至14族中的至少一种金属和至少一种元素周期表第6族金属的氧化物。

23. 发明授权

US06730757B2 Sulfur-containing and sulfur-nitrogen-containing catalysts for polymerization of olefins and polar monomers 失效
标题翻译：含硫和含硫的催化剂用于烯烃和极性单体的聚合
公开(公告)号：US06730757B2
公开(公告)日：2004-05-04
申请号：US10093601
申请日：2002-03-08
申请人： Kun Wang , Abhimanyu Onkar Patil , Stephen Zushma , Ernestine Williams Hill , Edward Ira Stiefel
发明人： Kun Wang , Abhimanyu Onkar Patil , Stephen Zushma , Ernestine Williams Hill , Edward Ira Stiefel
IPC分类号： C08F470
CPC分类号： C08F20/12 , B01J31/226 , C08F10/00 , C08F110/02 , C08F210/02 , C08F4/54 , C08F220/18
摘要： The inventions disclosed herein are catalyst systems comprising a complex having one of the formulas LMX1X2 and LML′ and an activating cocatalyst, and use of the catalyst system in polymerizing olefinic monomers. In either of the foregoing formulas, L is a chelating ligand containing sulfur donors; M is a transition metal selected from either copper, silver, gold, manganese, iron, cobalt, palladium or nickel; X1 and X2 are independently selected from either halides, hydride, triflate, acetate, borate, alkyl, alkoxyl, cycloalkyl, cycloalkoxyl, aryl, thiolate, carbon monoxide, cyanate or olefins; and L′ is a bidentate ligand selected from either dithiolene, dithiolate, diphosphine, bisimine, bispyridine, phenanthroline, oxolate, catecholate, thiolatoamide, thiolatoimine or thiolatophosphine.
摘要翻译：本文公开的发明是包含具有式LMX1X2和LML'之一的络合物和活化助催化剂的催化剂体系，以及催化剂体系在烯烃单体聚合中的用途。在上述任一式中，L是含硫供体的螯合配体; M是选自铜，银，金，锰，铁，钴，钯或镍的过渡金属; X 1和X 2独立地选自卤化物，氢化物，三氟甲磺酸酯，乙酸酯，硼酸酯，烷基，烷氧基，环烷基，环烷氧基，芳基，硫醇酯，一氧化碳，氰酸酯或烯烃; L'是选自二硫醇，二硫醇盐，二膦，双亚胺，双吡啶，菲咯啉，草酸盐，儿茶酚酸盐，硫醇酰胺，硫醇胺或硫醇化膦的双齿配体。

24. 发明授权

US08969272B2 Hydroxyaromatic functionalized polyalpha-olefins 有权
标题翻译：羟基芳香族官能化聚α-烯烃
公开(公告)号：US08969272B2
公开(公告)日：2015-03-03
申请号：US12108312
申请日：2008-04-23
申请人： Abhimanyu Onkar Patil , Margaret May-Som Wu , Stephen Zushma , Anura Abhimanyu Patil
发明人： Abhimanyu Onkar Patil , Margaret May-Som Wu , Stephen Zushma , Anura Abhimanyu Patil
IPC分类号： C09K15/08 , C08K5/13 , C10L1/16 , C10L1/18 , C07C37/66 , C08F8/00 , C07C37/14 , C07C39/06 , C08L101/00 , C10M107/30 , C10M177/00
CPC分类号： C08F8/00 , C07C37/14 , C07C39/06 , C08L101/00 , C10M107/30 , C10M177/00 , C10M2205/0245 , C10M2205/0265 , C10M2205/0285 , C10N2220/022 , C10N2220/023 , C10N2230/02 , C10N2230/08 , C10N2230/10 , C08F10/14 , C08L2666/06 , C10N2260/06 , C08F110/10 , C08F10/04
摘要： This invention relates to a hydroxyaromatic functionalized polyalpha-olefin comprising the product of the combination of: a) a polyalpha-olefin comprising one or more C3 to C20 linear alpha-olefins and having at least 10% vinylidene unsaturation, a viscosity index of 80 to 400, an Mn of 300 to about 20,000, and a pour point of 0° C. or less; and b) a hydroxyaromatic moiety; wherein the analine point of the functionalized polyalpha-olefin is at least 10° C. lower than the analine point of the polyalpha-olefin.
摘要翻译：本发明涉及包含以下组合的产物的羟基芳族官能化聚α-烯烃：a）包含一种或多种C 3至C 20直链α-烯烃并且具有至少10％亚乙烯基不饱和度的聚α-烯烃，粘度指数为80至 400，Mn为300〜约20,000，倾点为0℃以下; 和b）羟基芳族部分; 其中官能化的聚α-烯烃的分析点比聚α-烯烃的分析点低至少10℃。

25. 发明授权

US08921609B2 Oxidation of hydrocarbons 有权
标题翻译：碳氢化合物的氧化
公开(公告)号：US08921609B2
公开(公告)日：2014-12-30
申请号：US13498998
申请日：2010-09-30
申请人： Jihad M. Dakka , Stephen Zushma , Nicolas P. Coute , Francisco M. Benitez , Edmund J. Mozeleski
发明人： Jihad M. Dakka , Stephen Zushma , Nicolas P. Coute , Francisco M. Benitez , Edmund J. Mozeleski
IPC分类号： C07C409/00 , C07C29/50 , C07C407/00
CPC分类号： C07C29/50 , C07C407/00 , C07C2601/14 , C07C35/08 , C07C409/14 , C07C409/04
摘要： In a process for oxidizing a hydrocarbon, the hydrocarbon is contacted with oxygen in the presence of an N-substituted cyclic imide and under conditions to oxidize the hydrocarbon to produce an oxidized hydrocarbon product and at least one decomposition product of the N-substituted cyclic imide. At least a portion of the at least one decomposition product is contacted with hydroxylamine or a salt thereof under conditions to convert the at least one decomposition product back to said imide.
摘要翻译：在氧化烃的方法中，在N-取代的环状酰亚胺的存在下，在氧化烃的条件下，使烃与氧接触以产生氧化的烃产物和至少一种N-取代的环状酰亚胺的分解产物。将至少一种分解产物的至少一部分与羟胺或其盐在将至少一种分解产物转化回所述酰亚胺的条件下接触。

26. 发明授权

US08487138B2 Oxidation of hydrocarbons 失效
标题翻译：碳氢化合物的氧化
公开(公告)号：US08487138B2
公开(公告)日：2013-07-16
申请号：US12601549
申请日：2008-07-11
申请人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
发明人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
IPC分类号： C07C45/00 , C07C309/00 , C07C37/08 , C07C51/16
CPC分类号： C07C409/08 , C07C29/50 , C07C37/08 , C07C37/20 , C07C45/53 , C07C51/313 , C07C407/00 , C07C407/003 , C07C409/04 , C07C409/10 , C07C2601/14 , Y02P20/52 , C07C55/14 , C07C35/08 , C07C39/04 , C07C39/16 , C07C409/14
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and an element of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R3 can be any of the entities listed for R1. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of formula (I) and the effluent is treated with an aqueous solution of a base to produce an aqueous phase comprising at least part of the unreacted imide catalyst of formula (I) and an organic phase comprising oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，烃在含有通式（I）的环状酰亚胺的催化剂存在下与含氧气体接触：其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或者来自SO 3 H，NH 2，OH和NO 2基团，或者从原子H，F，Cl，Br和I 并且R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; 1为0,1或2; m为1至3，R3可为R1列出的任何实体。接触产生包含氧化烃产物和式（I）的未反应酰亚胺催化剂的流出物，流出物用碱的水溶液处理以产生包含至少部分式（I）的未反应的酰亚胺催化剂的水相，和包含氧化烃产物的有机相。然后可以回收有机相。

27. 发明授权

US06864319B2 Geminally disubstituted olefin-carbon monoxide-ethylene polymer useful as a polyvinyl chloride plasticizer and a method of making same 失效
标题翻译：可用作聚氯乙烯增塑剂的金属二取代烯烃 - 一氧化碳 - 乙烯聚合物及其制备方法
公开(公告)号：US06864319B2
公开(公告)日：2005-03-08
申请号：US10789172
申请日：2004-02-27
申请人： Abhimanyu O. Patil , Nicholas V. Smith , Jose G. Santiesteban , Allen D. Godwin , Steven P. Rucker , Stephen Zushma
发明人： Abhimanyu O. Patil , Nicholas V. Smith , Jose G. Santiesteban , Allen D. Godwin , Steven P. Rucker , Stephen Zushma
IPC分类号： C08L73/00 , C08G61/00 , C08G67/02 , C08L27/06
CPC分类号： C08G67/02 , C08L27/06 , C08L73/00 , C08L2666/14
摘要： The invention is related to a geminally disubstituted olefin-carbon monoxide-ethylene polymer. The invention is also related to a method for preparing geminally disubstituted olefin-carbon monoxide-ethylene polymers by reacting a geminally disubstituted olefin feed, a carbon monoxide feed and an ethylene feed under free radical polymerization conditions. The invention is further related to a geminally disubstituted olefin-carbon monoxide-ethylene-X polymer, where monomer X is a free radical polymerizable monomer. The invention is also directed to a method for preparing geminally disubstituted olefin-carbon monoxide-ethylene-X polymers by reacting a geminally disubstituted olefin feed, a carbon monoxide feed, an ethylene feed and a feed containing monomer X under free radical polymerization conditions. The polymers of the invention are useful as polyvinyl chloride plasticizers.
摘要翻译：本发明涉及一种双重取代的烯烃 - 一氧化碳 - 乙烯聚合物。本发明还涉及通过在自由基聚合条件下使双重取代烯烃进料，一氧化碳进料和乙烯进料反应来制备双重取代的烯烃 - 一氧化碳 - 乙烯聚合物的方法。本发明还涉及一种双重取代的烯烃 - 一氧化碳 - 乙烯-X聚合物，其中单体X是可自由基聚合的单体。本发明还涉及一种通过在自由基聚合条件下使双重取代的烯烃进料，一氧化碳进料，乙烯进料和含有单体X的进料反应来制备双重取代的烯烃 - 一氧化碳 - 乙烯-X聚合物的方法。本发明的聚合物可用作聚氯乙烯增塑剂。

28. 发明申请

US20050004334A1 MULTI-DENTATE LATE TRANSITION METAL CATALYST COMPLEXES AND POLYMERIZATION METHODS USING THOSE COMPLEXES 失效
标题翻译：多叶酸过渡金属催化剂复合物和使用这些复合物的聚合方法
公开(公告)号：US20050004334A1
公开(公告)日：2005-01-06
申请号：US10893429
申请日：2004-07-16
申请人： Lisa Boffa , Abhimanyu Patil , Donald Schulz , Robert Stibrany , Joseph Sissano , Stephen Zushma
发明人： Lisa Boffa , Abhimanyu Patil , Donald Schulz , Robert Stibrany , Joseph Sissano , Stephen Zushma
IPC分类号： C07F1/00 , C08F4/44 , C08F4/54 , C08F10/02 , C08F110/02 , C08F210/02 , B01J31/00 , C07F1/08 , C07F1/10
CPC分类号： C08F4/54 , C07F1/005 , C08F10/02 , C08F110/02 , C08F210/02 , C08F220/10
摘要： The instant invention provides a late transition metal complex which can be used with an activating cocatalyst to produce polymers and copolymers. The invention also provides methods for polymerizing olefins, as well as copolymers having polar monomers incorporated therein. More specifically, the invention provides a composition having the formula LMXZn, wherein M is selected from the group consisting of Cu, Ag and Au; X is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolate, nitrate, sulfate, nitrile, hydroxide and any other moiety into which a monomer can insert; Z is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolate, carbon monoxide, nitrate, nitrile, hydroxide, sulfate, olefins, water, any other neutral coordinating ligand and any other moiety into which a monomer can insert; n equals 0, 1 or 2; and L is a multi-dentate nitrogen-containing ligand.
摘要翻译：本发明提供了可与活性助催化剂一起使用以产生聚合物和共聚物的后过渡金属络合物。本发明还提供了聚合烯烃的方法以及其中掺入极性单体的共聚物。更具体地，本发明提供具有式LMXZn的组合物，其中M选自Cu，Ag和Au; X选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，硝酸盐，硫酸盐，腈，氢氧化物和单体可以插入的任何其他部分; Z选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，硝酸盐，腈，氢氧化物，硫酸盐，烯烃，水，任何其它中性配位配体和单体可插入的任何其它部分; n等于0,1或2; L是多齿氮含量配体。

29. 发明授权

US5783735A Process for preparing polymeric amides useful as additives in fuels and lubricating oils 失效
标题翻译：制备用作燃料和润滑油中添加剂的聚合酰胺的方法
公开(公告)号：US5783735A
公开(公告)日：1998-07-21
申请号：US441029
申请日：1995-05-25
申请人： Jacob I. Emert , Joseph V. Cusumano , David C. Dankworth , William D. Diana , William B. Eckstrom , Keith R. Gorda , Antonio Gutierrez , Jon E. Stanat , Warren A. Thaler , Stephen Zushma
发明人： Jacob I. Emert , Joseph V. Cusumano , David C. Dankworth , William D. Diana , William B. Eckstrom , Keith R. Gorda , Antonio Gutierrez , Jon E. Stanat , Warren A. Thaler , Stephen Zushma
IPC分类号： C10M159/12 , C08F8/00 , C08F8/32 , C10L1/2383 , C10L1/30 , C10L10/00 , C10M129/93 , C10M129/95 , C10M133/56 , C07C231/02 , C10M149/00 , C10M149/18
CPC分类号： C10M133/56 , C08F8/14 , C08F8/32 , C10L1/2383 , C10L1/303 , C10L10/04 , C10M129/93 , C10M129/95 , C10M2207/125 , C10M2207/129 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2215/04 , C10M2215/26 , C10M2217/046 , C10M2217/06
摘要： A process for preparing polymeric amides is disclosed. The process comprises sequentially reacting a hydrocarbon polymer functionalized (e.g., via the Koch reaction) to contain acid, ester, thioacid and/or thioester groups with a heavy polyamine to form a partially derivatized product in which at least about 85% of the functional groups are converted to heavy (thio)amide groups, and then reacting the partially derivatized product with an excess of light amine to complete the derivatization by converting substantially all of the remaining functional groups to light (thio)amide groups. Products of the foregoing process are also disclosed, which products are useful as additives in fuels and in lubricants.
摘要翻译：公开了一种制备聚合酰胺的方法。该方法包括使官能化（例如通过Koch反应）的烃聚合物顺序地反应以将酸，酯，硫代酸和/或硫酯基团与重多胺反应以形成部分衍生化的产物，其中至少约85％的官能团转化为重（硫）酰胺基团，然后使部分衍生化的产物与过量的轻胺反应，通过将基本上所有剩余的官能团转化为轻（硫）酰胺基来完成衍生化。还公开了上述方法的产物，哪些产品可用作燃料和润滑剂中的添加剂。

30. 发明授权

US5639396A Mannich base polymers 失效
公开(公告)号：US5639396A
公开(公告)日：1997-06-17
申请号：US670476
申请日：1996-06-26
申请人： Warren A. Thaler , Stephen Zushma , Antonio Gutierrez
发明人： Warren A. Thaler , Stephen Zushma , Antonio Gutierrez
IPC分类号： C07D233/02 , C08G14/073 , C08G73/02 , C08L79/02 , C10M159/16 , C10M149/00
CPC分类号： C07D233/02 , C08G73/02 , C08G73/0213 , C08L79/02 , C10M159/16 , C10M2217/042 , C10M2217/043 , C10M2227/061 , C10N2240/02 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/106 , C10N2270/02
摘要： A process for producing an oil soluble interpolymer polymer of 1,2-alkylenediamine such as N-ethyl ethylenediamine, aldehyde-provider such as formaldehyde, and ortho-unsubstituted hydroxyaromatics such as 4-polyalkylene phenol is disclosed. The decyclized Mannich Base monomer units provide a higher viscosity material which is suitably substituted with a long chain hydrocarbyl para substituent such as polyisobutylene or ethylene/alpha-olefin polymer. Various ortho-substituted hydroxyaromatics such as o-cresol may be used to control the degree of polymerization. The polymers are useful as dispersants or other lubricant additives.

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