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21. 发明授权

US08222307B2 Flameproof expandable styrene polymers, and method for the production thereof 有权
标题翻译：隔爆性可发性苯乙烯聚合物及其制造方法
公开(公告)号：US08222307B2
公开(公告)日：2012-07-17
申请号：US12743755
申请日：2008-11-20
申请人： Markus Allmendinger , Bernhard Schmied , Joachim Ruch , Konrad Knoll , Michael Riethues , Klaus Hahn , Carsten Schips , Jessica Rylander
发明人： Markus Allmendinger , Bernhard Schmied , Joachim Ruch , Konrad Knoll , Michael Riethues , Klaus Hahn , Carsten Schips , Jessica Rylander
IPC分类号： C08J9/16 , C08J9/14 , C08F290/06 , C08K5/02
CPC分类号： C08K5/0066 , C08J9/0019 , C08J9/0023 , C08J9/16 , C08J2201/03 , C08J2325/06 , C08K5/02 , C08K5/14 , C08L25/06
摘要： Expandable styrene polymers (EPS) comprising, in each case based on the styrene polymer, a) from 0.05 to 5% by weight of an organic bromine compound whose bromine content is at least 50% by weight, as flame retardant, b) from 0.05 to 2% by weight of a flame retardant synergist, c) from 0.1 to 5% by weight of a metal salt as acid scavenger, and process for their production.
摘要翻译：包括在每种情况下基于苯乙烯聚合物的可发射苯乙烯聚合物（a）a）0.05至5重量％的溴含量为至少50重量％的有机溴化合物作为阻燃剂，b）0.05 至2重量％的阻燃增效剂，c）0.1至5重量％的作为酸清除剂的金属盐及其制备方法。

22. 发明授权

US08217104B2 Highly transparent and tough-stiff styrene-butadiene block copolymer mixtures 有权
标题翻译：高度透明和坚韧的苯乙烯 - 丁二烯嵌段共聚物混合物
公开(公告)号：US08217104B2
公开(公告)日：2012-07-10
申请号：US12306258
申请日：2007-06-13
申请人： Jennifer Stewart , Peter Merkel , Daniel Wagner , Konrad Knoll , Jürgen Koch
发明人： Jennifer Stewart , Peter Merkel , Daniel Wagner , Konrad Knoll , Jürgen Koch
IPC分类号： C08F293/00 , C08F295/00 , C08F297/04 , C08L53/00 , C08L53/02
CPC分类号： C08F297/044 , C08F297/04 , C08L53/02 , C08L2205/025 , C08L2205/03 , C08L2666/02 , C08L2666/24 , C08L25/06
摘要： A mixture which comprises a) from 25 to 75% by weight of a block copolymer A which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more soft blocks BA in each case composed of from 0 to 5% by weight of vinylaromatic monomers and from 95 to 100% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer A is from 65 to 90% by weight; b) from 5 to 25% by weight of a block copolymer B which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B in each case composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer B is from 25 to 70% by weight; c) from 0 to 70% by weight of polystyrene or of a block copolymer C other than A and B, and d) from 0 to 6% by weight of a plasticizer D, where the entirety of components A) to D) gives 100% by weight, and use for transparent thermoforming foils or transparent injection-molded items.
摘要翻译：一种混合物，其包含a）25至75重量％的嵌段共聚物A，其包含至少一种由乙烯基芳族单体组成的硬质块S，并且包含一种或多种软块BA，每种情况由0至5重量％的乙烯基芳族单体和95〜100重量％的二烯，其中嵌段共聚物A中的硬质块S的重量比为65〜90重量％ b）5至25重量％的嵌段共聚物B，其包含至少一种由乙烯基芳族单体组成的硬质块S，并且包含一种或多种共聚物嵌段（B / S）B，每种情况下由20至60％由乙烯基芳族单体的重量和80〜40重量％的二烯，其中嵌段共聚物B中的硬质块S的重量比为25〜70重量％ c）0至70重量％的聚苯乙烯或除A和B之外的嵌段共聚物C，以及d）0至6重量％的增塑剂D，其中组分A）至D）的总量为100 重量％，用于透明热成型箔或透明注塑件。

23. 发明授权

US08158722B2 Tough and rigid mixtures of alpha-methylstyrene-acrylnitrile copolymers and of block copolymers 失效
标题翻译： α-甲基苯乙烯 - 丙烯腈共聚物和嵌段共聚物的韧性和刚性混合物
公开(公告)号：US08158722B2
公开(公告)日：2012-04-17
申请号：US12921043
申请日：2009-03-04
申请人： Konrad Knoll , Koch Jürgen , Piyada Charoensirisomboon
发明人： Konrad Knoll , Koch Jürgen , Piyada Charoensirisomboon
IPC分类号： B32B1/08 , C08L53/02
CPC分类号： C08L25/16 , C08F297/02 , C08F297/04 , C08L25/06 , C08L53/00 , C08L53/02 , C08L2205/02 , Y10T428/139 , C08L2666/02 , C08L2666/04 , C08L2666/06
摘要： Composition comprising at least one copolymer A composed of at least one alkylated styrene, of acrylonitrile, and, if appropriate, of at least one further monomer, at least one block copolymer B which has at least one block forming a hard phase and composed of at least one vinylaromatic monomer and has at least one block forming a soft phase and composed of at least one vinylaromatic monomer and of at least one diene, and at least one further copolymer C, and, if appropriate, one polymer D, where the copolymer C is at least one triblock copolymer composed of a first block composed of at least one vinylaromatic monomer, of a second block composed of at least one diene, and of a third block composed of at least one methyl methacrylate monomer, or comprising at least 50% by weight of methyl methacrylate, and the polymer D is at least one styrene polymer selected from glass-clear and impact-resistant polystyrene. The present invention moreover relates to a process for the preparation of the inventive compositions, to the use of the inventive compositions for the production of moldings, of foils, of fibers, or of foams, to moldings, foils, fibers, or foams comprising the inventive composition, and also to the use of the inventive composition as packaging for electronic components, such as integrated circuits (microchips) (“electronic packing”), for applications in chemical engineering, in household products, in bathroom items, e.g. toothbrush tumblers, cosmetics holders, etc., as housings, as tubes, as profiles, for medical items or medical devices, and in toys.
摘要翻译：组合物，其包含至少一种由至少一种烷基化苯乙烯，丙烯腈和（如果合适的话）至少一种另外的单体组成的共聚物A，至少一种嵌段共聚物B，其具有至少一个形成硬相的嵌段，至少一种乙烯基芳族单体，并且具有至少一个形成软相并由至少一种乙烯基芳族单体和至少一种二烯构成的嵌段和至少一种其它共聚物C，以及如果合适的话，一种聚合物D，其中共聚物C 是由至少一种乙烯基芳族单体组成的第一嵌段，至少由一种二烯构成的第二嵌段和由至少一种甲基丙烯酸甲酯单体组成的第三嵌段或至少包含至少50％的甲基丙烯酸甲酯，聚合物D是选自玻璃透明和耐冲击聚苯乙烯的至少一种苯乙烯聚合物。本发明还涉及制备本发明组合物的方法，本发明组合物用于生产模制品，箔，纤维或泡沫的用途，用于模制品，箔，纤维或泡沫，其包括本发明的组合物，以及本发明组合物用作电子部件的包装，例如集成电路（微芯片）（“电子包装”），用于化学工程，家用产品，浴室用品中的应用，例如牙刷滚筒，化妆品保持器等，作为外壳，作为管，用作医疗用品或医疗装置的型材，以及玩具。

24. 发明申请

US20120061287A1 PHASE-SEPARATING BLOCK OR GRAFT COPOLYMERS COMPRISING INCOMPATIBLE HARD BLOCKS AND MOULDING COMPOSITIONS HAVING A HIGH STIFFNESS 有权
标题翻译：包含不合适硬块的相分离块或共聚物和具有高刚度的成型组合物
公开(公告)号：US20120061287A1
公开(公告)日：2012-03-15
申请号：US13141870
申请日：2009-12-14
申请人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
发明人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
IPC分类号： B65D85/86 , C08L53/02 , C08F12/08
CPC分类号： C08L25/10 , C08F257/02 , C08F279/02 , C08F297/04 , C08F297/044 , C08L25/06 , C08L51/003 , C08L51/06 , C08L53/02 , C08L2666/24 , C08L2666/02 , C08L2666/04 , C08L2666/06
摘要： A block copolymer or graft copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block copolymer or graft copolymer, and also mixtures thereof, and their use.
摘要翻译：包含重量平均摩尔质量Mw至少为100 000g / mol的嵌段共聚物或接枝共聚物，其包含a）至少一种由95至100重量％的乙烯基芳族单体和0至5重量％的组分的二烯，和b）至少一种由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的共聚物嵌段（S / B）A，玻璃化转变温度TgA为5 至30℃，其中基于嵌段共聚物或接枝共聚物，所有嵌段S的总重量的比例为50至70重量％，以及它们的混合物及其用途。

25. 发明申请

US20120053284A1 THERMOPLASTIC LINOLEUM 失效
标题翻译：热塑性LINOLEUM
公开(公告)号：US20120053284A1
公开(公告)日：2012-03-01
申请号：US13216391
申请日：2011-08-24
申请人： Konrad Knoll , Michel Pepers
发明人： Konrad Knoll , Michel Pepers
IPC分类号： C08L35/02 , C08F8/00 , C08F22/14
CPC分类号： C08F8/46 , C08F22/14 , C08L25/06 , C08L25/12 , C09F7/06 , C08F242/00 , C08L51/006 , C08L53/02
摘要： The present invention relates to a thermoplastic molding composition at least comprising particles made of nonoxidatively polymerized vegetable oil which has been crosslinked by way of functional groups, as component (A), at least one thermoplastic polymer, as component (B), optionally at least one resin, as component (C), optionally at least one filler, as component (D), and optionally further additives, use thereof and a process for production thereof.
摘要翻译：本发明涉及一种热塑性模塑组合物，其至少包含通过官能团交联的非氧化聚合植物油，作为组分（A），至少一种热塑性聚合物作为组分（B），任选地至少一种树脂，作为组分（C），任选的至少一种填料，作为组分（D），以及任选的其它添加剂，其用途及其制备方法。

26. 发明授权

US08097669B2 Flame-retardant elastic block copolymer 失效
标题翻译：阻燃弹性嵌段共聚物
公开(公告)号：US08097669B2
公开(公告)日：2012-01-17
申请号：US12668286
申请日：2008-07-08
申请人： Konrad Knoll , Maarten Staal , Piyada Charoensirisomboon , Volker Warzelhan
发明人： Konrad Knoll , Maarten Staal , Piyada Charoensirisomboon , Volker Warzelhan
IPC分类号： C08K5/49 , C08K5/34
CPC分类号： C08L53/025 , C08K3/04 , C08K3/32 , C08K5/34928 , C08L53/02 , C08L2666/04 , C08L2666/02
摘要： The invention relates to a flameproofed resilient block polymer comprising polymerized units of at least one vinylaromatic monomer and at least one diene monomer with at least one flameproofing agent B) which comprises a compound comprising phosphorus, in particular a phosphorus-containing melamine compound, a process for the preparation and the use for the production of moldings.
摘要翻译：本发明涉及一种包含至少一种乙烯基芳族单体和至少一种二烯单体与至少一种二烯单体的聚合单元和至少一种防火剂B）的隔爆弹性嵌段聚合物，其包含含磷化合物，特别是含磷三聚氰胺化合物，用于制备和用于生产模制品。

27. 发明申请

US20110065819A1 ELASTIC MOLDED FOAM BASED ON POLYOLEFIN/STYRENE POLYMER MIXTURES 审中-公开
标题翻译：基于聚烯烃/苯乙烯聚合物混合物的弹性模制泡沫
公开(公告)号：US20110065819A1
公开(公告)日：2011-03-17
申请号：US12921526
申请日：2009-03-12
申请人： Carsten Schips , Klaus Hahn , Georg Grässel , Daniela Longo-Schedel , Jens Assmann , Andreas Gietl , Konrad Knoll , Holger Ruckdäschel , Maximilian Hofmann , Christof Zylla , Jürgen Lambert , Geert Janssens
发明人： Carsten Schips , Klaus Hahn , Georg Grässel , Daniela Longo-Schedel , Jens Assmann , Andreas Gietl , Konrad Knoll , Holger Ruckdäschel , Maximilian Hofmann , Christof Zylla , Jürgen Lambert , Geert Janssens
IPC分类号： C08J9/16
CPC分类号： C08J9/232 , C08J9/0061 , C08J2201/036 , C08J2203/14 , C08J2325/04 , C08J2423/00 , C08J2453/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L25/04 , C08L25/06 , C08L53/02 , C08L53/025 , C08L2203/14 , C08L2205/02 , C08L2205/035 , C08L2666/02
摘要： Expandable, thermoplastic polymer bead material, comprising A) from 45 to 98.8 percent by weight of a styrene polymer, B1) from 1 to 45 percent by weight of a polyolefin whose melting point is in the range from 105 to 140° C., B2) from 0 to 25 percent by weight of a polyolefin whose melting point is below 105° C., C1) from 0.1 to 9.9 percent by weight of a styrene-butadiene block copolymer, C2) from 0.1 to 9.9 percent by weight of a styrene-ethylene-butylene block copolymer, D) from 1 to 15 percent by weight of a blowing agent, E) from 0 to 5 percent by weight of a nucleating agent where the entirety of A) to E) gives 100% by weight, and also processes for production of the same, and use for the production of elastic molded-foam moldings.
摘要翻译：可膨胀的热塑性聚合物珠粒材料，其包含A）45至98.8重量％的苯乙烯聚合物，B1）1至45重量％的熔点为105-140℃的聚烯烃，B2 ）0至25重量％的熔点低于105℃的聚烯烃，C1）0.1至9.9重量％的苯乙烯 - 丁二烯嵌段共聚物C2）0.1至9.9重量％的苯乙烯乙烯 - 丁烯嵌段共聚物，D）1至15重量％的发泡剂，E）0至5重量％的成核剂，其中A）至E）的总量为100重量％，以及也用于生产它们的方法，并且用于生产弹性模制泡沫模制品。

28. 发明授权

US07470746B2 Transparent mixtures of linear styrene-butadiene block copolymers 有权
标题翻译：线性苯乙烯 - 丁二烯嵌段共聚物的透明混合物
公开(公告)号：US07470746B2
公开(公告)日：2008-12-30
申请号：US11297470
申请日：2005-12-09
申请人： Konrad Knoll , Daniel Wagner , Jürgen Koch , Peter Merkel
发明人： Konrad Knoll , Daniel Wagner , Jürgen Koch , Peter Merkel
IPC分类号： C08L53/02
CPC分类号： C08L53/025 , C08F297/04 , C08L51/003 , C08L53/02 , C08L2666/24 , C08L2666/02 , C08L53/00
摘要： Mixtures comprising linear block copolymers composed of vinylaromatic monomers and dienes of the structure (I) S1-B1-S2 and (II) B2-S3, where S1 is a block composed of vinylaromatic monomers whose number-average molar mass Mn is in the range from 40 000 to 100 000 g/mol, each of S2 and S3 is a block composed of vinylaromatic monomers whose number-average molar mass Mn is in the range from 5000 to 20 000 g/mol, each of B1 and B2 is one or more blocks composed of dienes or is copolymer blocks composed of dienes and vinylaromatic monomers whose number-average molar mass Mn is in the range from 15 000 to 100 000 g/mol, and the ratio of block copolymers (I)/(II) is in the range from 0.5 to 10, and their use for impact-modification of blends using polystyrene.
摘要翻译：包含由乙烯基芳族单体和结构（I）S1-B1-S2和（II）B2-S3组成的二烯的线性嵌段共聚物的混合物，其中S1是由数均摩尔质量Mn在该范围内的乙烯基芳族单体组成的嵌段从40000至100000g / mol，S2和S3各自为数均摩尔质量Mn为5000〜200000g / mol的乙烯基芳族单体的组成，B1和B2各为1或由二烯构成的更多嵌段或由二烯和乙烯基芳族单体组成的共聚物嵌段，其数均摩尔质量Mn在15000至100000g / mol的范围内，嵌段共聚物（I）/（II）的比例为在0.5至10的范围内，以及它们用于使用聚苯乙烯的共混物的冲击改性的用途。

29. 发明申请

US20080269414A1 Styrol/Butadiene Block Copolymer Mixtures for Shrink Films 有权
标题翻译：用于收缩膜的苯乙烯/丁二烯嵌段共聚物混合物
公开(公告)号：US20080269414A1
公开(公告)日：2008-10-30
申请号：US11813742
申请日：2005-12-31
申请人： Konrad Knoll , Helmut Steininger , Michael Schuster , Daniel Wagner , Peter Merkel
发明人： Konrad Knoll , Helmut Steininger , Michael Schuster , Daniel Wagner , Peter Merkel
IPC分类号： C08L53/02
CPC分类号： C08L53/02 , C08L2666/24
摘要： A mixture which comprises a) from 5 to 50% by weight of a block copolymer A which comprises one or more oopolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transtion temperature TgA in the range from 40° to 90° C. b) from 95 to 50% by weight of a block copolymer B which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0°C. c) from 0 to 45% by weight of polystyrene or of a block copolymer C other than A and B, and d) from 0 to 6% by weight of a plasticizer, and its use for production of shrink films.
摘要翻译：一种混合物，其包含a）5至50重量％的嵌段共聚物A，其包含一种或多种聚合物嵌段（B / S）A A，各自由65至95重量％的乙烯基芳族单体和35至5重量％的二烯，玻璃化转变温度Tg A A在40℃至90℃的范围内。b）95至50重量％的嵌段共聚物 B，其包含至少一个由乙烯基芳族单体组成的硬块S，并且包含一个或多个共聚物嵌段（B / S）B，每个由20至60重量％的乙烯基芳族单体组成，80至 40重量％的二烯和玻璃化转变温度Tg B 在-70℃至0℃的范围内。 c）0至45重量％的聚苯乙烯或除A和B之外的嵌段共聚物C，以及d）0至6重量％的增塑剂，以及其用于生产收缩膜的用途。

30. 发明授权

US07355084B2 Method for hydrogenating organic compounds by means of Ru/SiO2 catalysts 失效
标题翻译：通过Ru / SiO2催化剂氢化有机化合物的方法
公开(公告)号：US07355084B2
公开(公告)日：2008-04-08
申请号：US10480196
申请日：2002-06-07
申请人： Arnd Böttcher , Dominic Vanoppen , Jan-Dirk Arndt , Jochem Henkelmann , Konrad Knoll
发明人： Arnd Böttcher , Dominic Vanoppen , Jan-Dirk Arndt , Jochem Henkelmann , Konrad Knoll
IPC分类号： C07C5/00
CPC分类号： C07D295/023 , B01J21/08 , B01J23/462 , B01J37/18 , C07B2200/09 , C07C5/10 , C07C29/141 , C07C29/172 , C07C29/19 , C07C29/20 , C07C51/36 , C07C209/48 , C07C209/72 , C07C2523/46 , C07C2601/14 , C08F8/04 , C07C13/18 , C07C211/03 , C07C211/11 , C07C211/35 , C07C211/36 , C07C31/12 , C07C31/20 , C07C35/08 , C07C35/21 , C07C31/1355 , C07C29/175
摘要： In a process for hydrogenating at least one organic compound, the organic compound or compounds is/are brought into contact with a hydrogen-containing gas in the presence of a catalyst which comprises, as active metal, ruthenium either alone or together with at least one further metal of transition group I, VII or VIII of the Periodic Table applied to a support material based on amorphons silicon dioxide and is obtainable by: i) a single or multiple treatment of a support material based on amorphous silicon dioxide with a halogen-free aqueous solution of a low molecular weight ruthenium compound and subsequent drying of the treated support material at below 200° C., ii) reduction of the solid obtained in i) by means of hydrogen at from 100 to 350° C., with step ii) being carried out directly after step i).
摘要翻译：在使至少一种有机化合物氢化的方法中，有机化合物与含氢气体在催化剂的存在下进行接触，所述催化剂单独或与至少一种作为活性金属包含钌应用于基于无定形二氧化硅的载体材料的周期表的过渡组I，VII或VIII的进一步金属，可通过以下步骤获得：i）单独或多次处理基于无卤素的无定形二氧化硅的载体材料低分子量钌化合物的水溶液，随后在低于200℃下干燥经处理的载体材料，ii）通过在100至350℃的氢气使i）中获得的固体还原，步骤ii ）在步骤i）之后直接进行。

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