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21. 发明授权

US5876890A Electrophotographic photosensitive member and apparatus and process cartridge provided with the same 失效
标题翻译：电子照相感光元件及其设备和处理盒
公开(公告)号：US5876890A
公开(公告)日：1999-03-02
申请号：US863046
申请日：1997-05-23
申请人： Wataru Kitamura , Hidetoshi Hirano , Kimihiro Yoshimura
发明人： Wataru Kitamura , Hidetoshi Hirano , Kimihiro Yoshimura
IPC分类号： G03G5/05 , G03G5/06 , G03G5/147
CPC分类号： G03G5/0564 , G03G5/0614 , G03G5/0668 , G03G5/14756
摘要： A surface layer of a photosensitive layer contains a resin comprising a structural unit represented by the following general formula (1), and at least one compound of a triarylamine compound represented by the following general formula (2) and a styryl compound represented by the following general formula (3): ##STR1## wherein, X is --CR.sub.13 R.sub.14 --, substituted or unsubstituted cycloalkylidene, substituted or unsubstituted .alpha.,.omega.-alkylene, single bond, --O--, --S--, --SO-- or --SO.sub.2 --, wherein R.sub.13 and R.sub.14 are each hydrogen, trifluoromethyl, or substituted or unsubstituted alkyl or aryl, and R.sub.1 to R.sub.12 are each hydrogen, halogen, or substituted or unsubstituted alkyl or aryl; ##STR2## wherein Y is hydrogen, halogen, substituted or unsubstituted alkyl or alkoxy, or ##STR3## wherein R.sub.15 ' to R.sub.24 ' are each hydrogen, halogen, substituted or unsubstituted alkyl or alkoxy, R.sub.15 to R.sub.27 are each hydrogen, halogen, substituted or unsubstituted alkyl or alkoxy, and R.sub.28 and R.sub.29 are each hydrogen or substituted or unsubstituted alkyl, aralkyl or aryl; ##STR4## wherein Z is --CH.sub.2 CH.sub.2 -- or --CH.dbd.CH--, R.sub.30 and R.sub.31 are each substituted or unsubstituted alkyl, aralkyl, aryl or heterocyclic, R.sub.32 to R.sub.39 are each hydrogen, substituted or unsubstituted alkyl or alkoxy, and Ar is substituted or unsubstituted arylene or heterocyclic.
摘要翻译：感光层的表面层含有包含由以下通式（1）表示的结构单元的树脂和至少一种由以下通式（2）表示的三芳基胺化合物和由下列通式（2）表示的苯乙烯基化合物（3）：其中X为-CR 13 R 14 - ，取代或未取代的亚环烷基，取代或未取代的α，ω-亚烷基，单键，-O - ， - S - ， - SO-或 - SO 2 - ，其中R 13和R 14各自为氢，三氟甲基或取代或未取代的烷基或芳基，R 1至R 12各自为氢，卤素或取代或未取代的烷基或芳基; （2）其中Y是氢，卤素，取代或未取代的烷基或烷氧基，或者其中R 15'至R 24'各自为氢，卤素，取代或未取代的烷基或烷氧基，R 15至R 27各自为氢，卤素，取代或未取代的烷基或烷氧基，R28和R29各自为氢或取代或未取代的烷基，芳烷基或芳基; （3）其中Z是-CH 2 CH 2 - 或-CH = CH-，R 30和R 31各自是取代或未取代的烷基，芳烷基，芳基或杂环，R 32至R 39各自为氢，取代或未取代的烷基或烷氧基， Ar是取代或未取代的亚芳基或杂环基。

22. 发明授权

US08481254B2 Substrate probe for use in measuring enzyme activity 有权
标题翻译：用于测量酶活性的底物探针
公开(公告)号：US08481254B2
公开(公告)日：2013-07-09
申请号：US12675511
申请日：2008-09-08
申请人： Fumio Yamauchi , Kimihiro Yoshimura , Katsuaki Kuge , Tetsuya Yano , Masahiro Shirakawa , Yasuhiro Aoyama , Shinsuke Sando
发明人： Fumio Yamauchi , Kimihiro Yoshimura , Katsuaki Kuge , Tetsuya Yano , Masahiro Shirakawa , Yasuhiro Aoyama , Shinsuke Sando
IPC分类号： C12Q1/00
CPC分类号： C12Q1/54 , C12Q1/32 , C12Q1/34 , G01N24/088 , G01R33/281 , G01R33/4633 , G01R33/465 , G01R33/483 , G01R33/5601 , Y02P20/582
摘要： Substrate probe capable of detecting enzyme activity with high accuracy and a method for detecting the enzyme activity by a multi nuclear magnetic resonance method using the substrate probe. Multi-dimensional nuclear magnetic resonance is performed by using a substrate probe, which is used for measuring enzyme activity by a multi-dimensional nuclear magnetic resonance method and characterized by containing a enzyme recognition site that is selectively recognized by an active-state enzyme, as at least one constitutional unit, and a group to which at least three nuclear magnetic resonance active nuclei each having a nuclear spin and a different resonance frequency are connected, being present specifically to the enzyme recognition, thereby detecting presence of the substrate probe and the enzyme activity. Alternatively, imaging of the enzyme activity is performed by a multi-dimensional nuclear resonance imaging method.
摘要翻译：能够高精度地检测酶活性的底物探针和使用底物探针的多核磁共振法检测酶活性的方法。通过使用用于通过多维核磁共振法测定酶活性的底物探针进行多维核磁共振，其特征在于含有被活性酶选择性识别的酶识别位点作为至少一个结构单元和至少三个具有核自旋和不同共振频率的核磁共振活性核连接的基团，其特异性地存在于酶识别中，从而检测底物探针和酶的存在活动。或者，通过多维核共振成像方法进行酶活性的成像。

23. 发明授权

US08217340B2 Mass spectrometry substrate and mass spectrometry method 有权
标题翻译：质谱底物和质谱法
公开(公告)号：US08217340B2
公开(公告)日：2012-07-10
申请号：US12427583
申请日：2009-04-21
申请人： Kimihiro Yoshimura , Manabu Komatsu , Hiroyuki Hashimoto , Yohei Murayama
发明人： Kimihiro Yoshimura , Manabu Komatsu , Hiroyuki Hashimoto , Yohei Murayama
IPC分类号： H01J49/26
CPC分类号： H01J49/0418 , Y10T436/24 , Y10T436/25 , Y10T436/25875
摘要： A mass spectrometry method that makes it possible to perform high-sensitivity detection of a desorbed/ionized object substance to be measured in mass spectrometry in which the object substance to be measured is desorbed and ionized. The method includes placing at least an ionizing agent having two or more functional groups represented by Formula (1) below in a molecule: —(CF2)COOH (1) wherein the ionizing agent has a boiling point of equal to or higher than 150° C. and an object molecule to be measured on a substrate and irradiating the ionizing agent and the object molecule to be measured with a primary beam selected from ions, neutral particles, electrons, and a laser beam.
摘要翻译：能够对被测定对象物质进行离子化和离子化的质谱法进行高灵敏度地检测待测量的解吸/电离对象物质的质谱法。该方法包括在分子中至少放置一个具有两个或多个由式（1）表示的官能团的电离剂： - （CF 2）COOH（1）其中电离剂的沸点等于或高于150℃ 和待测量的物体分子，并用从离子，中性粒子，电子和激光束中选择的一次束照射被测量的电离剂和待测物体。

24. 发明申请

US20090045332A1 SUBSTRATE FOR MASS SPECTROMETRY, MASS SPECTROMETRY, AND MASS SPECTROMETER 失效
标题翻译：质谱分析仪，质谱仪，质谱仪等
公开(公告)号：US20090045332A1
公开(公告)日：2009-02-19
申请号：US12133654
申请日：2008-06-05
申请人： Kimihiro Yoshimura , Kazuya Miyazaki , Kazuhiro Yamada
发明人： Kimihiro Yoshimura , Kazuya Miyazaki , Kazuhiro Yamada
IPC分类号： B01D59/44
CPC分类号： H01J49/0418
摘要： Provided is a substrate for mass spectrometry, which enables a detection of a high molecular weight compound to be conducted at a high sensitivity, and can avoid the fragmentation so that there is substantially no obstacle to the analysis of a low molecular weight region. The substrate is a substrate for mass spectrometry for use in laser desorption/ionization mass spectrometry, containing a metal and having a porous structure on a surface thereof, wherein at least one functional group selected from the group consisting of a carboxyl group, a sulfonic group and an ammonium chloride group is covalently bonded to the surface of the substrate.
摘要翻译：提供了一种用于质谱的基质，其能够以高灵敏度检测高分子量化合物，并且可以避免片段化，从而基本上不存在低分子量区域的分析的障碍。基板是用于激光解吸/电离质谱的质谱用基板，含有金属，在其表面具有多孔结构，其中，选自羧基，磺酸基中的至少一种官能团并且氯化铵基团共价结合到基材的表面。

25. 发明授权

US07141343B2 Toner, method for forming image using the toner, and process cartridge 失效
标题翻译：调色剂，使用调色剂形成图像的方法和处理盒
公开(公告)号：US07141343B2
公开(公告)日：2006-11-28
申请号：US10418215
申请日：2003-04-18
申请人： Tsuyoshi Takiguchi , Yosuke Morikawa , Takashige Kasuya , Kimihiro Yoshimura , Katsuhisa Yamazaki , Kaori Hiratsuka
发明人： Tsuyoshi Takiguchi , Yosuke Morikawa , Takashige Kasuya , Kimihiro Yoshimura , Katsuhisa Yamazaki , Kaori Hiratsuka
IPC分类号： G03G9/08
CPC分类号： G03G9/09725 , G03G9/0819 , G03G9/0821 , G03G9/08755 , G03G9/09708 , G03G15/0241
摘要： A toner exhibits excellent image characteristics, and also has an excellent charging property even if the toner is used in a cleaning-simultaneous-with-developing system having a direct injection charging mechanism. The toner includes toner particles and non-magnetic metallic-compound fine particles. The weight average particle diameter of the toner is 3.0 μm to 12.0 μm. The metallic-compound fine particles are conductive metallic-compound fine particles having a specific surface area (cm2/cm3) of 5×105 to 100×105; a medium diameter (D50) of 0.4 μm to 4.0 μm with respect to a volume-based particle diameter distribution, the medium diameter (D50) being smaller than the weight average particle diameter of the toner; and a 90% particle diameter D90 of 6.0 μm or less with respect to a volume-based particle diameter.
摘要翻译：调色剂表现出优异的图像特性，并且即使将调色剂用于具有直接注入充电机构的同时显影清洗系统中也具有优异的充电特性。调色剂包括调色剂颗粒和非磁性金属化合物细颗粒。调色剂的重均粒径为3.0μm〜12.0μm。金属化合物微粒是具有5×10 5以上的比表面积（cm 2以上/ cm 3以下）的导电性金属化合物微粒〜 100×10 5; 相对于基于体积的粒径分布为0.4μm至4.0μm的中等直径（D≤50），中等直径（D≤50<）小于重量调色剂的平均粒径; 和相对于基于体积的粒径为6.0μm或更小的90％粒径D 90 N。

26. 发明授权

US07022446B2 Electrophotographic photosensitive member, process cartridge and electrophotographic apparatus 有权
标题翻译：电子照相感光构件，处理盒和电子照相设备
公开(公告)号：US07022446B2
公开(公告)日：2006-04-04
申请号：US10616944
申请日：2003-07-11
申请人： Kimihiro Yoshimura , Yosuke Morikawa , Tatsuya Ikezue , Kouichi Nakata , Daisuke Tanaka
发明人： Kimihiro Yoshimura , Yosuke Morikawa , Tatsuya Ikezue , Kouichi Nakata , Daisuke Tanaka
IPC分类号： G03G5/047 , G03G5/147
CPC分类号： G03G5/14747 , G03G5/0564 , G03G5/0567 , G03G5/0575 , G03G5/0592 , G03G5/14791
摘要： An electrophotographic photosensitive member having a surface layer containing at least one of a charge-transporting material and conductive particles and a polymer obtained by polymerizing at least one selected from the group consisting of a polyhydroxymethylbisphenol monomer having a specific structure, a polyhydroxymethylbisphenol oligomer having a specific structure, a polyhydroxymethyltrisphenol monomer having a specific structure and a polyhydroxymethyltrisphenol oligomer having a specific structure; and a process cartridge and an electrophotographic apparatus which have the electrophotographic photosensitive member.
摘要翻译：一种电子照相感光构件，其具有包含电荷输送材料和导电颗粒中的至少一种的表面层和通过聚合选自具有特定结构的多羟基甲基双酚单体，具有特定结构的多羟基甲基双酚低聚物的至少一种而获得的聚合物结构，具有特定结构的多羟基甲基三苯酚单体和具有特定结构的多羟甲基三苯酚低聚物; 以及具有电照相感光构件的处理盒和电子照相设备。

27. 发明授权

US06806009B2 Electrophotographic photosensitive member, process cartridge and electrophotographic apparatus 有权
标题翻译：电子照相感光构件，处理盒和电子照相设备
公开(公告)号：US06806009B2
公开(公告)日：2004-10-19
申请号：US10314354
申请日：2002-12-09
申请人： Daisuke Tanaka , Yosuke Morikawa , Tatsuya Ikezue , Kouichi Nakata , Kimihiro Yoshimura
发明人： Daisuke Tanaka , Yosuke Morikawa , Tatsuya Ikezue , Kouichi Nakata , Kimihiro Yoshimura
IPC分类号： G03G5147
CPC分类号： G03G15/751 , G03G5/147
摘要： In an electrophotographic photosensitive member comprising a cylindrical support, and provided thereon a photosensitive layer and a protective layer in this order, which cylindrical support has an outer diameter of less than 30 mm, the difference between a coefficient of thermal expansion &agr;1 measured from the top of the protective layer and a coefficient of thermal expansion &agr;2 measured after the protective layer has been removed, |&agr;1−&agr;2|, is more than 5.0×10−7° C.−1 to less than 1.0×10−4° C.−1, and the modulus of elastic deformation We % measured from the top of the protective layer is more than 30% to less than 60%. Also disclosed are a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member.
摘要翻译：在包括圆柱形支撑件并且在其上设置有感光层和保护层的电子照相感光构件中，该圆柱形支撑件的外径小于30mm，从顶部测量的热膨胀系数α1之间的差异的保护层和在保护层被去除之后测量的热膨胀系数α2，|α1-α2|大于5.0×10-7。<-1>小于1.0×10 -4 >°C <1>，从保护层顶部测量的弹性变形量We％大于30％至小于60％。还公开了具有这种电子照相感光构件的处理盒和电子照相设备。

28. 发明授权

US06697591B2 Electrophotographic apparatus and process cartridge 有权
标题翻译：电子照相设备和处理盒
公开(公告)号：US06697591B2
公开(公告)日：2004-02-24
申请号：US10173161
申请日：2002-06-18
申请人： Yosuke Morikawa , Kouichi Nakata , Kimihiro Yoshimura , Daisuke Tanaka
发明人： Yosuke Morikawa , Kouichi Nakata , Kimihiro Yoshimura , Daisuke Tanaka
IPC分类号： G03G1500
CPC分类号： G03G5/14704 , G03G5/147 , G03G2215/021
摘要： An electrophotographic apparatus, includes: an electrophotographic photosensitive member and a charging device. The charging device includes a conductor particle-carrying member having an electroconductive and elastic surface, and conductor particles having a particle size of 10 nm-10 &mgr;m and carried on the carrying member so as to be disposed in contact with the photosensitive member, thereby directly injecting charges to the photosensitive member to charge the photosensitive member. The photosensitive member includes a photosensitive layer and a charge injection layer as a surface layer disposed in this order on a support, the charge-injection layer having a thickness d (&mgr;m) and an elastic deformation percentage We (OCL) (%) satisfying a relationship of formula (1) below with an elastic deformation percentage We (CTL) (%) of the photosensitive layer: −0.71×d+We(CTL)≦We(OCL)≦0.03×d3−0.89×d2+8.43×d+We(CTL) (1).
摘要翻译：一种电子照相设备，包括：电子照相感光构件和充电装置。充电装置包括具有导电和弹性表面的导体颗粒承载构件和粒径为10nm-10μm的导体颗粒，并承载在承载构件上以便与感光构件接触，从而直接向感光构件注入电荷以对感光构件充电。感光构件包括感光层和作为表面层的电荷注入层，其依次设置在载体上，电荷注入层的厚度d（母）和弹性变形百分比We（OCL）（％）满足关系式（1）与弹性变形百分比We（CTL）（％）感光层：

29. 发明授权

US06562530B2 Electrophotographic photosensitive member, and process cartridge and electrophotographic apparatus having the electrophotographic photosensitive member 有权
标题翻译：电子照相感光构件，以及具有电照相感光构件的处理盒和电子照相设备
公开(公告)号：US06562530B2
公开(公告)日：2003-05-13
申请号：US09883396
申请日：2001-06-19
申请人： Yosuke Morikawa , Kouichi Nakata , Kimihiro Yoshimura , Daisuke Tanaka
发明人： Yosuke Morikawa , Kouichi Nakata , Kimihiro Yoshimura , Daisuke Tanaka
IPC分类号： G03G514
CPC分类号： G03G5/14791 , G03G5/147 , G03G5/14704 , G03G5/14726 , G03G5/1476
摘要： An electrophotographic photosensitive member has, in this order, a support, a photosensitive layer and a protective layer. The thickness d (&mgr;m) of the protective layer, the universal hardness Hu-1 (N/mm2) of the protective layer, and the universal hardness Hu-2 (N/mm2) of the photosensitive layer after peeling off the protective layer satisfy the following expression (1): 5.8×d+Hu-2≦Hu-1≦−2.45×d2+44.4×d+Hu-2 (1). Also disclosed are a process cartridge and an electrophotographic apparatus which have the above electrophotographic photosensitive member.
摘要翻译：电子照相感光构件依次具有载体，感光层和保护层。保护层的厚度d（mum），保护层的通用硬度Hu-1（N / mm2）以及剥离保护层后的感光层的通用硬度Hu-2（N / mm2）满足以下表达式（1）：还公开了具有上述电子照相感光构件的处理盒和电子照相设备。

30. 发明授权

US07078140B2 Electrophotographic photosensitive member, electrophotographic apparatus, and process cartridge 有权
标题翻译：电子照相感光构件，电子照相设备和处理盒
公开(公告)号：US07078140B2
公开(公告)日：2006-07-18
申请号：US10618628
申请日：2003-07-15
申请人： Kimihiro Yoshimura , Yosuke Morikawa , Tatsuya Ikezue , Kouichi Nakata , Shuji Ishii , Daisuke Tanaka
发明人： Kimihiro Yoshimura , Yosuke Morikawa , Tatsuya Ikezue , Kouichi Nakata , Shuji Ishii , Daisuke Tanaka
IPC分类号： G03G5/047
CPC分类号： G03G5/0542 , G03G5/0535 , G03G5/0539 , G03G5/0567 , G03G5/0596 , G03G5/14717 , G03G5/14747 , G03G5/14795
摘要： According to the present invention, there is provided: an electrophotographic photosensitive member having a photosensitive layer on a support in which a surface layer of the electrophotographic photosensitive member comprises an acrylic polymer having a polyfluoroolefin unit and an alkylene oxide unit, and having a number-average molecular weight in a range of 2,000 to 20,000; a process cartridge and an electrophotographic apparatus both comprising the electrophotographic photosensitive member.
摘要翻译：根据本发明，提供了一种电子照相感光构件，其在载体上具有感光层，其中电子照相感光构件的表面层包含具有聚氟烯烃单元和烯化氧单元的丙烯酸类聚合物，平均分子量在2,000至20,000的范围内; 一个处理盒和一个电子照相设备，它们都包括电子照相感光构件。

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