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    • 24. 发明授权
    • Light-sensitive mixed diazonium condensate printing plate for waterless
offset printing
    • 光敏混合重氮冷凝印版,用于无水胶版印刷
    • US4775607A
    • 1988-10-04
    • US943034
    • 1986-12-17
    • Hans-Joachim Schlosser
    • Hans-Joachim Schlosser
    • G03F7/00G03F7/021G03F7/075G03C1/54G03C1/60G03C1/76G03F7/08
    • G03F7/021G03F7/0752
    • A light-sensitive printing plate for waterless offset printing is comprised of a layer carrier, a light-sensitive layer containing a diazonium salt polycondensation product, and of an ink-repellent crosslinked silicone elastomer layer superimposed on the light-sensitive layer, wherein the diazonium salt polycondensation product comprises recurrent A-N.sub.2 X and B units which are mutually linked by bridge members, preferably methylene groups, derived from carbonyl compounds capable of condensation, A being the radical of an aromatic diazonium compound capable of condensation with formaldehyde and B being the radical of a compound, in particular an aromatic amine, a phenol, a phenol ether, an aromatic thioether, an aromatic hydrocarbon, an aromatic heterocyclic compound or an organic acid amide, that is free of diazonium groups and that is capable of condensation with formaldehyde. The printing plate can be readily developed with developers which contain organic solvents, to give printing forms with good resolution, good ink repellency in the background areas, and long print runs.
    • 用于无水胶版印刷的感光印版由层载体,含有重氮盐缩聚产物的感光层和叠加在感光层上的拒墨交联硅氧烷弹性体层组成,其中重氮 盐缩聚产物包括由能够缩合的羰基化合物衍生的桥连构件,优选亚甲基相互连接的复原A-N2X和B单元,A是能够与甲醛缩合的芳族重氮化合物的基团,B是基团 的化合物,特别是芳族胺,苯酚,苯酚醚,芳香族硫醚,芳香族烃,芳香族杂环化合物或有机酸酰胺,其不含重氮基并且能够与甲醛缩合。 印刷版可以容易地与包含有机溶剂的显影剂一起显影,以得到具有良好分辨率的印刷形式,在背景区域中具有良好的拒油性,以及长的印刷运行。