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21. 发明授权

US4602021A Phenylbenzoylureas useful as pesticides 失效
标题翻译：苯甲酰脲可用作农药
公开(公告)号：US4602021A
公开(公告)日：1986-07-22
申请号：US745456
申请日：1985-06-17
申请人： Odd Kristiansen , Jozef Drabek
发明人： Odd Kristiansen , Jozef Drabek
IPC分类号： A01N47/36 , A01N20060101 , A01N47/34 , C07D20060101 , C07D213/00 , C07D239/00 , C07D309/00 , C07D309/14 , C07D405/12 , A01N43/16 , A01N43/40
CPC分类号： C07D405/12 , A01N47/36 , C07D309/14
摘要： The invention relates to novel substituted N-phenyl-N-tetrahydropyranyl-N'-benzoylureas of the formula ##STR1## wherein R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.3 haloalkyl containing 1 to 7 halogen atoms, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylthio, C.sub.1 -C.sub.3 haloalkoxy containing 1 to 7 halogen atoms, nitro, cyano, ethynyl or one of the groups ##STR2## wherein R.sub.5, R.sub.6 and R.sub.7 are C.sub.1 -C.sub.6 alkyl; R.sub.2, R.sub.3 and R.sub.4 are each independently hydrogen, halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.3 haloalkyl containing 1 to 7 halogen atoms, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylthio, C.sub.1 -C.sub.3 haloalkoxy containing 1 to 7 halogen atoms, nitro, cyano, ethynyl or one of the groups ##STR3## wherein R.sub.5, R.sub.6 and R.sub.7 are C.sub.1 -C.sub.6 alkyl, ##STR4## wherein --A-- is --O-- or --S--, R.sub.8 is halogen, methyl, nitro, CF.sub.3 or cyano and n is 0, 1, 2 or 3, or ##STR5## wherein each of R.sub.9 and R.sub.10 independently is hydrogen, chlorine, trifluoromethyl or an ethyl radical perhalogenated with fluorine and/or chlorine; andU, X, Y, Z and W are each independently hydrogen, halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkylthio,to the preparation of these compounds and to compositions containing them for controlling insects and representatives of the order Acarina. The novel compounds exhibit larvicidal activity, especially against plant-destructive insects.
摘要翻译：本发明涉及式IMA的新型取代的N-苯基-N-四氢吡喃基-N'-苯甲酰基，其中R 1是氢，卤素，C 1 -C 6烷基，含有1至7个卤素原子的C 1 -C 3卤代烷基，C 1 -C 6烷氧基，C 1 C 1-6烷硫基，含有1至7个卤素原子的C 1 -C 3卤代烷氧基，硝基，氰基，乙炔基或基团之一，其中R 5，R 6和R 7是C 1 -C 6烷基; R 2，R 3和R 4各自独立地为氢，卤素，C 1 -C 6烷基，含有1至7个卤素原子的C 1 -C 3卤代烷基，C 1 -C 6烷氧基，C 1 -C 6烷硫基，含有1至7个卤素原子的C 1 -C 3卤代烷氧基，硝基，氰基，乙炔基或其中R5，R6和R7是C1-C6烷基的组之一，其中-A-是-O-或-S-，R8是卤素，甲基，硝基，CF3或氰基，n是0， 1,2或3或者其中R 9和R 10各自独立地是氢，氯，三氟甲基或用氟和/或氯全卤化的乙基; 并且U，X，Y，Z和W各自独立地为氢，卤素，C 1 -C 3烷基，C 1 -C 3烷氧基或C 1 -C 3烷硫基，用于制备这些化合物，以及含有它们的用于控制昆虫和含有Acarina的代表的组合物。这些新型化合物具有杀幼体活性，特别是防止植物破坏性昆虫。

22. 发明授权

US5077412A Substituted thioureas, isothioureas and carbodiimides 失效
标题翻译：取代的硫酸盐，同位素和碳水化合物
公开(公告)号：US5077412A
公开(公告)日：1991-12-31
申请号：US414998
申请日：1989-09-29
申请人： Josef Ehrenfreund , Manfred Boger , Odd Kristiansen , Jozef Drabek , Haukur Kristinsson
发明人： Josef Ehrenfreund , Manfred Boger , Odd Kristiansen , Jozef Drabek , Haukur Kristinsson
IPC分类号： A01N47/30 , A01N47/32 , A01N47/40 , A01N47/42 , C07D207/34 , C07D209/32 , C07D231/20 , C07D233/70 , C07D235/26 , C07D249/12 , C07D257/04 , C07D263/38 , C07D263/58 , C07D271/10 , C07D271/113 , C07D277/20 , C07D277/34 , C07D277/68 , C07D285/08 , C07D285/12 , C07D285/13 , C07D307/58 , C07D333/32 , C07D333/34
CPC分类号： C07D271/113 , A01N47/30 , A01N47/32 , A01N47/40 , A01N47/42 , C07D233/70 , C07D249/12 , C07D277/34 , C07D277/68 , C07D285/08 , C07D285/13
摘要： The invention relates to novel substituted phenylthioureas, phenylisothioureas and phenylcarbodiimides of formula I ##STR1## wherein Z is ##STR2## or --N.dbd.C.dbd.N--; R.sub.1 is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.10 alkenyl, C.sub.3 -C.sub.10 alkynyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.3 alkyl substituted by 1 or 2 C.sub.3 -C.sub.6 cycloalkyl radicals, or is alkoxyalkyl containing a total of 3 to 10 carbon atoms, halogen-substituted C.sub.1 -C.sub.12 alkyl, polycyclic C.sub.7 -C.sub.10 cycloalkyl, or phenyl(C.sub.1 -C.sub.5)alkyl which may be substituted in the phenyl moiety by 1 or 2 identical or different members selected from the group consisting of halogen, methoxy, ethoxy and C.sub.1 -C.sub.5 alkyl,R.sub.2 is hydrogen or C.sub.1 -C.sub.5 alkyl,R.sub.3 is C.sub.1 -C.sub.5 alkyl or C.sub.3 -C.sub.6 cycloalkyl,R.sub.4 is hydrogen or C.sub.1 -C.sub.4 alkyl,R.sub.5 is a 5-membered heterocyclic radical containing 1 to 4 hetero atoms selected from the group consisting of N, O and S, which radical may be substituted at the carbon or nitrogen atoms by 1 to 3 of the substituents R.sub.6, R.sub.7 and R.sub.8, or is a 5-membered heterocyclic radical which may be fused with benzene nuclei and which contains 1 or 2 hetero atoms selected from the group consisting of N, O and S and can be substituted at the carbon or nitrogen atoms by 1 to 3 of the substituents R.sub.6, R.sub.7 and R.sub.8,R.sub.6 and R.sub.7 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, halogen-substituted C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy; halogen-substituted C.sub.1 -C.sub.4 alkoxy, phenyl, or C.sub.1 -C.sub.4 alkylthio,R.sub.8 is hydrogen or C.sub.1 -C.sub.4 alkyl, andR.sub.9 is C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.3 -C.sub.4 alkynyl, alkoxyalkyl containing a total of 10 carbon atoms, or alkylthioalkyl containing a total of 10 carbon atomsand to the salts thereof with acids and bases. The invention further relates to the preparation of these compounds and to the use thereof in pest control, and to novel intermediates.

23. 发明授权

US4262012A O-Methyl/ethyl-s-propyl/butyl-o-phenyl thiophosphates and dithiophosphates having an s-heterocyclic group on the phenyl ring 失效
标题翻译： O-甲基/乙基 - 正丙基/丁基邻苯基硫代磷酸酯和在苯环上具有s-杂环基的二硫代磷酸酯
公开(公告)号：US4262012A
公开(公告)日：1981-04-14
申请号：US751918
申请日：1976-12-17
申请人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
发明人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
IPC分类号： A01N57/10 , A01N57/14 , A01N57/16 , C07F9/12 , C07F9/18 , A61K31/385 , A61K31/39 , C07D327/04 , C07D339/08
CPC分类号： C07F9/18 , A01N57/10
摘要： The invention relates to O,S-dialkyl-O-phenyl-thiophosphates and dithiophosphates of the formula ##STR1## wherein R.sub.1 represents methyl or ethyl,R.sub.2 represents n-propyl, i-butyl or sec.-butyl,R.sub.3 and R.sub.4 each represents hydrogen, chlorine, bromine, methyl or ethyl,R.sub.5 represents a group of the formula ##STR2## X represents oxygen or sulfur, which compounds possess useful pesticidal, in particular acaricidal and insecticidal properties.
摘要翻译：本发明涉及下式的O，S-二烷基-O-苯基 - 硫代磷酸酯和二硫代磷酸酯，其中R 1表示甲基或乙基，R 2表示正丙基，异丁基或仲丁基，R 3和R 4各自代表氢，氯，溴，甲基或乙基，R 5表示下式的基团：X表示氧或硫，该化合物具有有用的杀虫剂，特别是杀螨和杀虫性质。

24. 发明授权

US4017612A Combatting insects and acarids with certain O-methyl/ethyl-S-propyl/butyl-O-phenyl-thiophosphates and -dithiophosphates 失效
标题翻译：用某些O-甲基/乙基-S-丙基/丁基-O-苯基 - 硫代磷酸酯和二硫代磷酸酯来防治昆虫和螨
公开(公告)号：US4017612A
公开(公告)日：1977-04-12
申请号：US578960
申请日：1975-05-19
申请人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
发明人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
IPC分类号： A01N57/10 , C07F9/18 , A01N9/36
CPC分类号： A01N57/10 , C07F9/18
摘要： Thiophosphoric and dithiophosphoric acid esters of the formula ##STR1## wherein R.sub.1 represents methyl or ethyl, R.sub.2 represents n-propyl, isobutyl or sec, butyl, R.sub.3 and R.sub.4 each represents chlorine, bromine, methyl or ethyl, R.sub.5 represents--OCOCH.sub.3, --O--C.sub.3 --C.sub.5 --alkenyl, --O--C.sub.3 --C.sub.5 --alkinyl, --O--C.sub.1 --C.sub.4 --alkylene-O--C.sub.1 --C.sub.4 --alkyl, --O--CH.sub.2 --CCl=CH.sub.2, --O--CH.sub.2 --CH=CHCl, ##STR2## --S--C.sub.3 --C.sub.5 --alkenyl, SCN, --CH.sub.2 --CCl=CH.sub.2, --CH.sub.2 CH=CHCl, --CHO, ##STR3## ##STR4## AND X represents oxygen or sulphur, processes for their manufacture and their use in pest control.
摘要翻译：其中R 1表示甲基或乙基，R 2表示正丙基，异丁基或仲丁基，R 3和R 4各自表示氯，溴，甲基或乙基，R 5表示-OCOCH 3，-O -C 3 -C 5 - 烯基，-O-C 3 -C 5 - 炔基，-O-C 1 -C 4亚烷基-O-C 1 -C 4烷基，-O-CH 2 -CCl = CH 2，-O-CH 2 -CH = CHCl ，图像-S-C3-C5-烯基，SCN，-CH2-CCl = CH2，-CH2CH = CHCl，-CHO，

25. 发明授权

US4963550A Substituted thioureas, isothioureas and carbodiimides and use as pesticide 失效
标题翻译：替代硫脲，异硫脲和碳二亚胺，用作农药
公开(公告)号：US4963550A
公开(公告)日：1990-10-16
申请号：US476200
申请日：1990-02-07
申请人： Manfred Boger , Jozef Drabek , Josef Ehrenfreund , Odd Kristiansen
发明人： Manfred Boger , Jozef Drabek , Josef Ehrenfreund , Odd Kristiansen
IPC分类号： A01N47/30 , A01N47/40 , A01N47/42 , C07D215/20 , C07D215/22 , C07D215/227 , C07D215/233 , C07D215/26 , C07D215/28 , C07D237/14 , C07D239/34 , C07D239/56 , C07D239/60 , C07D241/18 , C07D241/44 , C07D251/20 , C07D251/22 , C07D251/26 , C07D251/34 , C07D253/06 , C07D257/08
CPC分类号： C07D215/227 , A01N47/30 , A01N47/40 , A01N47/42 , C07D215/233 , C07D215/26 , C07D215/28 , C07D237/14 , C07D239/34 , C07D241/44 , C07D251/22
摘要： The invention relates to novel substituted N-phenylthioureas, N-phenylisothioureas and N-phenylcarbodiimides of formula ##STR1## wherein R.sub.1 to R.sub.5 and Z are as defined in the specification.The invention further relates to the preparation of said compounds and to compositions containing them for use in pest control, especially for controlling insects and representatives of the order Acarina that are pests of plants and animals, in particular plant-destructive sucking and eating pests.

26. 发明授权

US4539314A Phosphoryl-triazines 失效
标题翻译：磷酰三嗪
公开(公告)号：US4539314A
公开(公告)日：1985-09-03
申请号：US616371
申请日：1984-06-01
申请人： Odd Kristiansen , Jozef Drabek , Victor Fluck
发明人： Odd Kristiansen , Jozef Drabek , Victor Fluck
IPC分类号： A01N57/32 , C07F9/6521 , C07F9/65 , C07D251/70 , A01N43/68
CPC分类号： C07F9/65217 , A01N57/32
摘要： N-Phosphoryl- or thiophosphoryl-N'-s-triazinylformamidines of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of one another are each C.sub.1 -C.sub.20 -alkyl, or phenyl unsubstituted or substituted by halogen, andX and Y are each oxygen or sulfur.A process for producing these triazines and their use for controlling pests are described.
摘要翻译：其中R 1和R 2彼此独立地为C 1 -C 20 - 烷基或未被取代或被卤素取代的苯基的式（I）的N-磷酰基或硫代磷酰基-N'-三嗪基甲酰胺，X和Y 都是氧或硫。描述了制备这些三嗪的方法及其用于防治害虫的用途。

27. 发明授权

US4316908A Pesticidal sulfinylamides 失效
标题翻译：杀虫亚磺酰胺
公开(公告)号：US4316908A
公开(公告)日：1982-02-23
申请号：US200804
申请日：1980-10-27
申请人： Odd Kristiansen , Jozef Drabek
发明人： Odd Kristiansen , Jozef Drabek
IPC分类号： C07C303/00 , A01N47/24 , A01N51/00 , C07D317/24 , C07D339/06 , A01N43/28 , A01N41/02 , A01N43/30 , C07C125/067 , C07D317/12
CPC分类号： C07D317/24 , A01N47/24 , A01N51/00 , C07D339/06
摘要： Sulfinylamides of the formula ##STR1## wherein R.sub.1 is hydrogen or C.sub.1 -C.sub.6 -alkyl,R.sub.2 is C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxy, andR.sub.3 is phenyl which is unsubstituted or mono- or poly-substituted by identical or different substituents selected from the group comprising halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -alkylthio, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, nitro, ##STR2## processes for producing them, and their use in combating insect pests.
摘要翻译：其中R 1是氢或C 1 -C 6 - 烷基，R 2是C 1 -C 6 - 烷基或C 1 -C 6 - 烷氧基，和R 3是未被取代或被相同或不同的单取代或多取代的苯基的式选自卤素，C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基，C 1 -C 6 - 烷硫基，C 2 -C 6 - 链烯基，C 2 -C 6炔基，硝基，用于防治害虫。

28. 发明授权

US4291043A 1-N,N-dimethyl carbamoyl-3(5)-alkyl-5(3)-alkylthioalkylthio-1,2,4-triazoles, a process for their manufacture, compositions which contain them and their use in pest control 失效
标题翻译： 1-N，N-二甲基氨基甲酰基-3（5） - 烷基-5（3） - 烷硫基烷硫基-1,2,4-三唑，其制造方法，含有它们的组合物及其在害虫防治中的用途
公开(公告)号：US4291043A
公开(公告)日：1981-09-22
申请号：US70215
申请日：1979-08-27
申请人： Odd Kristiansen , Jozef Drabek
发明人： Odd Kristiansen , Jozef Drabek
IPC分类号： A01N47/38 , C07D249/12
CPC分类号： C07D249/12 , A01N47/38
摘要： Compounds of the formula IA and IB ##STR1## wherein R.sub.1 is i-propyl, s-butyl, t-butyl or optionally methyl-substituted cyclopropyl, R.sub.2 is hydrogen or methyl, R.sub.3 is C.sub.1 -C.sub.4 -alkyl and n is zero or the integer 1 posess valuable pesticidal, in particular insecticidal properties.
摘要翻译：式IA和IB的化合物其中R 1是异丙基，仲丁基，叔丁基或任选被甲基取代的环丙基，R 2是氢或甲基，R 3是C1- C4烷基，n为零或整数1为有价值的杀虫剂，特别是杀虫性质。

29. 发明授权

US4010227A O-alkyl-s-alkyl-o-(substituted phenyl)thiolphosphates 失效
标题翻译： O-烷基-S-烷基-O-（取代苯基）硫代磷酸酯
公开(公告)号：US4010227A
公开(公告)日：1977-03-01
申请号：US601886
申请日：1975-08-06
申请人： Jozef Drabek , Manfred Boger , Odd Kristiansen
发明人： Jozef Drabek , Manfred Boger , Odd Kristiansen
IPC分类号： A01N57/14 , C07F9/18
CPC分类号： A01N57/14 , C07F9/18
摘要： Thiolphosphoric acid esters of the formula ##STR1## wherein R.sub.1 represents methyl or ethyl,R.sub.2 represents n-propyl, isopropyl, isobutyl or sec.butyl,R.sub.3 represents nitro, cyano, allyl or methylthio,R.sub.4 represents hydrogen, chlorine, bromine, methyl or nitro, andR.sub.5, r.sub.6 and R.sub.7 each represent chlorine, bromine or methyl, processes for their preparation and their use in pest control.
摘要翻译：式中，R 1表示甲基或乙基，R 2表示正丙基，异丙基，异丁基或仲丁基的硫代磷酸酯。

30. 发明授权

US3991141A O-methyl/ethyl-S-propyl/butyl-O-phenyl thiphosphates and dithiophosphates having a thioether group on the phenyl ring 失效
标题翻译：在苯环上具有硫醚基的O-甲基/乙基-S-丙基/丁基-O-邻苯二磷酸酯和二硫代磷酸酯
公开(公告)号：US3991141A
公开(公告)日：1976-11-09
申请号：US534591
申请日：1974-12-20
申请人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
发明人： Ernst Beriger , Manfred Boger , Jozef Drabek , Odd Kristiansen
IPC分类号： A01N57/10 , C07F9/18 , C07F9/12
CPC分类号： C07F9/18 , A01N57/10
摘要： Thiophosphoric and dithiophosphoric acid esters of the formula ##SPC1##Wherein R.sub.1 represents methyl or ethyl, R.sub.2 represents n-propyl, isobutyl or sec, butyl, R.sub.3 and R.sub.4 each represents chlorine, bromine, methyl or ethyl, R.sub.5 represents--OCOCH.sub.3, --O--C.sub.3 --C.sub.5 -alkenyl, --O--C.sub.3 --C.sub.5 -alkinyl, --O--C.sub.1 --C.sub.4 -alkylene-O--C.sub.1 --C.sub.4 -alkyl, --O--CH.sub.2 --CCl=CH.sub.2, --O--CH.sub.2 --CH=CHCl, ##EQU1##--S--C.sub.3 --C.sub.5 -alkenyl, SCN, --CH.sub.2 --CCl=CH.sub.2, --CH.sub.2 CH=CHCl, --CHO, ##SPC2##--CH=N--C.sub.1 --C.sub.4 -alkyl, --CH=N--NH--C.sub.1 --C.sub.4 -alkyl or X represents oxygen or sulphur, processes for their manufacture and their use in pest control.
摘要翻译：式II的硫代磷酸和二硫代磷酸酯，其中R1表示甲基或乙基，R2表示正丙基，异丁基或仲丁基，R 3和R 4各自表示氯，溴，甲基或乙基，R 5表示-OCOCH 3，-O-C 3 - C5-烯基，-O-C3-C5-炔基，-O-C1-C4-亚烷基-O-C1-C4-烷基，-O-CH2-CCl = CH2，-O-CH2-CH = CHCl，-SCH2 -S-C 3 -C 5 - 烯基，SCN，-CH 2 -CCl = CH 2，-CH 2 CH = CHCl，-CHO，O -CH ANGLE，O -CH = N-C 1 -C 4烷基，-CH = C 1 -C 4 - 烷基或C 1 -C 4 - 烷基-CH = NN ANGLE和C 1 -C 4 - 烷基X代表氧或硫，其制备方法及其在害虫防治中的应用。

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