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    • 21. 发明授权
    • Molybdenum-tungsten-containing catalyst for methane conversion process
    • 用于甲烷转化过程的含钼钨催化剂
    • US4808563A
    • 1989-02-28
    • US87534
    • 1987-08-19
    • Louis J. Velenyi
    • Louis J. Velenyi
    • B01J23/00B01J23/30B01J23/32B01J23/887C07C2/84B01J21/08B01J23/02B01J23/28
    • C07C2/84B01J23/002B01J23/30B01J23/32B01J23/8871B01J23/8872B01J2523/00C07C2521/04C07C2521/06C07C2521/08C07C2521/10C07C2521/16C07C2521/18C07C2523/04C07C2523/14C07C2523/22C07C2523/28C07C2523/30C07C2523/36C07C2523/75C07C2527/224C07C2529/04
    • A catalyst is disclosed which comprises a molybdenum-tungsten-containing complex represented by the formulaMo.sub.a W.sub.b M.sub.c A.sub.d O.sub.ewherein M is selected from the group consisting of one or more metals selected from any of Groups IB, IIB, IVB, VB or VIII of the Periodic Table and/or one or more of Y, Cr, Mn, Re, B, In, Ge, Sn, Pb, Th or U, or a mixture of two or more of the metals in said group; A is at least one metal selected from the group consisting of alkali metals, alkaline earth metals, Lanthanide series metals, La, T1, or a mixture or two or more of the metals in said group; a is a number in the range of from about 1 to about 200; b is a number in the range of from about 1 to about 200; with the proviso that either Mo or W is in excess of the other, the ratio of a:b being about 4:1 or greater, or about 1:4 or less; c is a number such that the ratio of c:(a+b) is in the range of from 0:100 to about 10:100; d is a number such that the ratio of d:(a+b) is in the range of from 0:100 to about 75:100; and e is the number of oxygens needed to fulfill the valence requirements of the other elements. A process for converting gaseous reactants comprising methane and oxygen to higher order hydrocarbons using the foregoing catalyst is also disclosed.
    • 公开了一种催化剂,其包括由式MoaWbMcAdOe表示的含钼钨络合物,其中M选自一种或多种选自元素周期表IB,IIB,IVB,VB或VIII族中的任何一种的金属,以及 /或Y,Cr,Mn,Re,B,In,Ge,Sn,Pb,Th或U中的一种或多种,​​或所述组中的两种或更多种金属的混合物; A是选自碱金属,碱土金属,镧系金属,La,T1中的至少一种金属或所述基团中的一种或多种金属的混合物; a为约1至约200的数值; b是约1至约200的范围内的数; 条件是Mo或W超过另一个,a:b的比例为约4:1或更大,或约1:4或更小; c是使得c:(a + b)的比例在0:100至约10:100的范围内的数字; d是使d:(a + b)的比例在0:100至约75:100的范围内的数字; e是满足其他元素的化合价要求所需的氧数。 还公开了使用上述催化剂将包含甲烷和氧气的气态反应物转化为更高级烃的方法。
    • 27. 发明授权
    • Process for converting light hydrocarbons and/or natural gas to liquid
hydrocarbons
    • 将轻烃和/或天然气转化为液态烃的方法
    • US4822940A
    • 1989-04-18
    • US86097
    • 1987-08-17
    • Alan A. LeffJoseph E. MetcalfeLouis J. VelenyiChristos Paparizos
    • Alan A. LeffJoseph E. MetcalfeLouis J. VelenyiChristos Paparizos
    • C07C2/00
    • C07C2/00Y10S585/943
    • The present invention provides for a process for converting a feedstock comprising ethylene and/or acetylene to a product comprising liquid hydrocarbons. The process comprises maintaining said feedstock at a temperature in the range of about 700.degree. C. to about 1000.degree. C. for about 100 to about 1000 milliseconds to provide for said conversion. In one embodiment, the feedstock further comprises hydrogen. In another embodiment the feedstock comprises the product made by the process comprising heating a gaseous mixture comprising (i) hydrogen and (ii) natural gas and/or at least one light hydrocarbon at a temperature of at least about 1250.degree. C. for an effective period of time to provide said feedstock. In still another embodiment, the feedstock further comprises natural gas and/or at least one light hydrocarbon in addition to said ethylene and/or acetylene.
    • 本发明提供了将包含乙烯和/或乙炔的原料转化成包含液体烃的产物的方法。 该方法包括将所述原料维持在约700℃至约1000℃的温度范围内约100至约1000毫秒以提供所述转化。 在一个实施方案中,原料还包含氢。 在另一个实施方案中,原料包括通过该方法制备的产物,其包括在至少约1250℃的温度下加热包含(i)氢和(ii)天然气和/或至少一种轻质烃的气态混合物,以获得有效的 提供所述原料的一段时间。 在另一个实施方案中,除了所述乙烯和/或乙炔之外,原料还包含天然气和/或至少一种轻质烃。