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    • 24. 发明申请
    • POLYCARBAZOLYL(METH)ACRYLATE LIGHT EMISSIVE COMPOSITIONS
    • 聚甲基丙烯酸(甲基)丙烯酸酯光敏组合物
    • US20080262184A1
    • 2008-10-23
    • US11736214
    • 2007-04-17
    • Qing YeJie LiuKyle Erik Litz
    • Qing YeJie LiuKyle Erik Litz
    • C08G79/00
    • C08F230/04C07F15/0033C09K11/06C09K2211/1007C09K2211/1011C09K2211/1029C09K2211/1044C09K2211/1092C09K2211/185H01L51/004H01L51/0042H01L51/0043H01L51/0085H01L51/5016H05B33/14
    • The present invention provides polymer derived from a monomer of formula I and a polymerizable phosphorescent organometallic compound of formula L′2MZ′, wherein R1 is H or CH3; R2 is H or C1-C5 alkyl; R3 is H or CH3; R4 and R5 are independently H, CH3, t-butyl, triarylsilyl, trialkylsilyl, diphenyl phosphine oxide, or diphenyl phosphine sulfide; m ranges from 1 to about 20; n ranges from 1 to about 20; L′ and Z′ are independently bidentate ligands; at least one of L′ and Z′ comprises at least one substituent selected from C2-20 alkenyl, C2-20 alkynyl, C2-20 substituted alkenyl, C2-20 substituted alkynyl, C2-20 alkenyloxy, C2-20 alkynyloxy, styryl, acryloyl, and methacryloyl; and M is Ga, Al, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Lr, Rf, Db, Sg, Bbh, Hs, Mt, Ds, Rg, Uub, Eu, Tb, La, Po, or a combination thereof. The polymers of the invention are useful as light emissive layers in light emitting devices. Thus. the present invention also provides an organic light emitting device comprising a light emissive layer comprising a polymer derived from a monomer of formula I, and a polymerizable phosphorescent organometallic compound of formula L′2MZ′.
    • 本发明提供衍生自式I单体的聚合物和式L'2 MZ'的可聚合磷光有机金属化合物,其中R 1是H或CH 2, 3 R 2是H或C 1 -C 5烷基; R 3是H或CH 3 N; R 4和R 5独立地为H,CH 3,叔丁基,三芳基甲硅烷基,三烷基甲硅烷基,二苯基氧化膦或二苯基硫化膦; m范围从1到大约20; n范围从1到约20; L'和Z'独立为二齿配体; L'和Z'中的至少一个包含至少一个选自C 2-20 - 烯基,C 2-20炔基,C 2-20环烷基, 取代的烯基,C 2-20取代的炔基,C 2-20链烯氧基,C 2-20炔氧基,苯乙烯基,丙烯酰基, 和甲基丙烯酰基; 并且M是Ga,Al,Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,Y,Zr,Nb,Mo,Tc,Ru,Rh,Pd,Ag,Cd,Lu,Hf ,Ta,W,Re,Os,Ir,Pt,Au,Hg,Lr,Rf,Db,Sg,Bbh,Hs,Mt,Ds,Rg,Uub,Eu,Tb,La,Po或其组合。 本发明的聚合物可用作发光器件中的发光层。 从而。 本发明还提供了一种有机发光器件,其包括包含衍生自式I单体的聚合物的光发射层和式L'2 MZ'的可聚合磷光有机金属化合物。