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21. 发明申请

US20050234253A1 Ferrocenyl ligands and the use thereof in catalysis 失效
标题翻译：二茂铁基配体及其在催化中的应用
公开(公告)号：US20050234253A1
公开(公告)日：2005-10-20
申请号：US10506255
申请日：2003-03-10
申请人： Paul Knochel , Matthias Lotz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Juan Almena Perea
发明人： Paul Knochel , Matthias Lotz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Juan Almena Perea
IPC分类号： B01J31/24 , C07B53/00 , C07B61/00 , C07C67/31 , C07C69/73 , C07C69/732 , C07C231/12 , C07C233/51 , C07C233/82 , C07C241/02 , C07C243/38 , C07C269/06 , C07C271/22 , C07C303/36 , C07C311/16 , C07F1/08 , C07F9/50 , C07F15/00 , C07F15/04 , C07F15/06 , C07F17/02 , C07F19/00
CPC分类号： C07F17/02
摘要： The invention relates to bidentate organophosphorous ferrocenyl ligands containing ligands of formula (I), to their complex compounds and to their utilization in catalytic processes.
摘要翻译：本发明涉及含有式（I）配位体的双齿有机亚磷酸二茂铁基配体，其复合化合物及其在催化过程中的应用。

22. 发明授权

US07763739B2 Cycloolefin phosphine ligands and their use in catalysis 失效
标题翻译：环烯烃膦配体及其在催化中的应用
公开(公告)号：US07763739B2
公开(公告)日：2010-07-27
申请号：US11579626
申请日：2005-04-14
申请人： Renat Kadyrov , Juan José Almena Perea , Axel Monsees , Thomas Riermeier , Ilias Ilaldinov
发明人： Renat Kadyrov , Juan José Almena Perea , Axel Monsees , Thomas Riermeier , Ilias Ilaldinov
IPC分类号： C07D333/04 , C07D333/02
CPC分类号： C07F9/655345 , B01J31/188 , B01J31/2414 , B01J2231/645 , B01J2531/822 , C07B2200/07 , C07C29/145 , C07C45/505 , C07C67/283 , C07C67/303 , C07C231/18 , C07D333/16 , C07D333/28 , C07F9/5027 , C07F9/5532 , C07F9/572 , C07F9/5728 , C07F9/59 , C07F9/60 , C07F9/65031 , C07F9/6506 , C07F9/65335 , C07F9/6547 , C07F9/65515 , C07F9/65517 , C07F9/655354 , C07F9/655372 , C07F9/6561 , C07F17/02 , C07C69/007 , C07C69/34 , C07C233/05 , C07C233/47 , C07C69/157 , C07C33/22
摘要： The present invention concerns novel bidentante optionally N-containing P-ligands of general formula (I) embracing a two-ring-system and processes for synthesizing them, transition metal complexes of these compounds and their use as catalysts.
摘要翻译：本发明涉及包含双环体系的通式（I）的任意含N的P-配位体及其合成方法，这些化合物的过渡金属配合物及其用作催化剂的新型二异氰酸酯。

23. 发明申请

US20050240007A1 Ferrocenyl ligands and method for the production of such ligands 失效
标题翻译：二茂铁基配体及其制备方法
公开(公告)号：US20050240007A1
公开(公告)日：2005-10-27
申请号：US10511439
申请日：2003-04-17
申请人： Paul Knochel , Matthias Lotz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Juan Almena Perea
发明人： Paul Knochel , Matthias Lotz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Juan Almena Perea
IPC分类号： C07B35/02 , C07B53/00 , C07B61/00 , C07C67/303 , C07C69/34 , C07C69/67 , C07C231/12 , C07C231/18 , C07C233/05 , C07C233/47 , C07F17/02
CPC分类号： C07F17/02 , C07B53/00 , C07C67/303 , C07C231/18 , C07C233/47 , C07C69/67 , C07C69/34
摘要： The invention relates to ferrocenyl ligands of general formula (II), the Sfc,S-enantiomer or the Rfc,R-enantiomer of the ferrocenyl ligands of formula (II) being enriched, and a method for producing such ligands.
摘要翻译：本发明涉及通式（II）的二茂铁基配体，式（II）的二茂铁基配体的S-对映异构体或RΨC，），以及这种配体的制造方法。

24. 发明申请

US20090253907A1 CYCLOPENTADIENYL, INDENYL OR FLUORENYL SUBSTITUTED PHOSPHINE COMPOUNDS AND THEIR USE IN CATALYTIC REACTIONS 审中-公开
标题翻译：环戊二烯基，茚基或氟代替膦酸酯化合物及其在催化反应中的应用
公开(公告)号：US20090253907A1
公开(公告)日：2009-10-08
申请号：US12375869
申请日：2007-08-14
申请人： Herbert Plenio , Christoph Fleckenstein , Renat Kadyrov , Juan Almena , Axel Monsees , Thomas Riermeier
发明人： Herbert Plenio , Christoph Fleckenstein , Renat Kadyrov , Juan Almena , Axel Monsees , Thomas Riermeier
IPC分类号： C07D295/155 , C07D401/04 , C07C209/68 , C07F9/54 , C07F9/50 , C07C45/61
CPC分类号： C07C2/88 , B01J31/2404 , B01J31/2447 , B01J2231/321 , B01J2231/4227 , B01J2231/4266 , B01J2231/4283 , B01J2531/824 , C07C17/26 , C07C41/30 , C07C45/62 , C07C201/12 , C07C209/68 , C07C253/30 , C07D213/16 , C07D213/22 , C07D213/73 , C07D265/30 , C07F9/5022 , C07F9/5442
摘要： A phosphine compound represented by general formula (1) wherein R′ and R″ independently are selected from alkyl, cycloalkyl and 2-furyl radicals, or R′ and R″ are joined together to form with the phosphorous atom a carbon-phosphorous monocycle including at least 3 carbon atoms or a carbon-phosphorous bicycle; the alkyl radicals, cycloalkyl radicals, and carbon-phosphorous monocycle being unsubstituted or substituted by at least one radical selected from the group of alkyl, cycloalkyl, aryl, alkoxy, and aryloxy radicals; Cps is a partially substituted or completely substituted cyclopentadien-1-yl group, including substitutions resulting in a fused ring system, and wherein a substitution at the 1-position of the cyclopentadien-1-yl group is mandatory when the cyclopentadien-1-yl group is not part of a fused ring system or is part of an indenyl group. These phosphines can be used as ligands in catalytic reactions.
摘要翻译：由通式（1）表示的膦化合物，其中R'和R“独立地选自烷基，环烷基和2-呋喃基，或者R'和R”连接在一起，与磷原子一起形成碳 - 磷包含至少3个碳原子的单环或碳磷自行车; 烷基，环烷基和碳 - 磷单环未被取代或被至少一个选自烷基，环烷基，芳基，烷氧基和芳氧基的基团取代; Cps是部分取代的或完全取代的环戊二烯-1-基，包括导致稠环系统的取代，并且其中当环戊二烯-1-基的1-位上的取代是必需的，当环戊二烯-1-基基团不是稠环体系的一部分或是茚基基团的一部分。这些膦可以用作催化反应中的配体。

25. 发明申请

US20090036713A1 PROCESS FOR THE HYDROGENATION OF IMINES 审中-公开
标题翻译：加氢方法
公开(公告)号：US20090036713A1
公开(公告)日：2009-02-05
申请号：US12282189
申请日：2007-02-09
申请人： Juan Almena , Thomas Riermeier , Axel Monsees , Renat Kadyrov
发明人： Juan Almena , Thomas Riermeier , Axel Monsees , Renat Kadyrov
IPC分类号： C07C231/10
CPC分类号： C07C209/52 , C07B2200/07 , C07C211/48
摘要： The present invention relates to a process for the hydrogenation of imines with hydrogen in the presence of iridium catalysts. In particular the present invention relates to a process for the hydrogenation of imines with hydrogen under elevated pressure in the presence of an iridium catalysts and with or without an inert solvent, wherein the reaction mixture comprises a phosphonium chloride, bromide or iodide in the presence or in the absence of an acid, which can be an organic or inorganic acid, soluble or insoluble in the reaction mixture. Suitable imines are especially those that contain at least one (Formula I) group. If the groups are substituted asymmetrically and are thus compounds having a prochiral ketimine group, it is possible in the process according to the invention for mixtures of optical isomers or pure optical isomers to be formed if enantioselective or diastereoselective iridium catalysts are used.
摘要翻译：本发明涉及在铱催化剂存在下用氢氢化亚胺的方法。特别地，本发明涉及在铱催化剂存在下，在惰性溶剂存在下，在高压下用氢气氢化亚胺的方法，其中反应混合物包含氯化鏻，溴化物或碘化鏻，在不存在酸的情况下，其可以是可溶于或不溶于反应混合物的有机或无机酸。合适的亚胺特别是含有至少一个（式I）基团的亚胺。如果这些基团被不对称取代并且因此是具有前手性酮亚胺基团的化合物，则在本发明的方法中，如果使用对映选择性或非对映异构选择性铱催化剂，则可以形成光学异构体或纯光学异构体的混合物。

26. 发明授权

US06884887B1 Method for producing amines by homogeneously catalyzed reductive amination of carbonyl compounds 失效
标题翻译：通过羰基化合物的均匀催化还原胺化制备胺的方法
公开(公告)号：US06884887B1
公开(公告)日：2005-04-26
申请号：US10030946
申请日：2000-06-29
申请人： Thomas Riermeier , Karl-Josef Haack , Uwe Dingerdissen , Armin Boerner , Vitali Tararov , Renat Kadyrov
发明人： Thomas Riermeier , Karl-Josef Haack , Uwe Dingerdissen , Armin Boerner , Vitali Tararov , Renat Kadyrov
IPC分类号： C07D295/02 , B01J31/18 , B01J31/24 , C07B53/00 , C07B61/00 , C07C209/26 , C07C211/08 , C07C211/27 , C07C213/02 , C07C215/50 , C07C227/08 , C07C229/08 , C07C229/14 , C07C229/36 , C07D295/023 , C07D295/14 , C07D295/15 , C07D265/30
CPC分类号： C07D295/15 , B01J31/1875 , B01J31/2404 , B01J31/2409 , B01J2231/341 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , C07C209/26 , C07C227/08 , C07D295/023 , C07C211/27 , C07C229/14
摘要： The invention relates to the preparation of chiral or achiral amines by reaction of aldehydes or ketones with ammonia or primary or secondary amines in the presence of hydrogen and in the presence of homogeneous metal catalysts under mild conditions. Metal catalysts which can be used are complexes of late transition metals with chiral or achiral phosphorus-containing ligands.
摘要翻译：本发明涉及通过醛或酮与氨或伯胺或仲胺在氢气存在下和在温和条件下在均相金属催化剂存在下反应来制备手性或非手性胺。可以使用的金属催化剂是后过渡金属与手性或非手性含磷配体的络合物。

27. 发明授权

US07230134B2 Method for the production of amines by reductive amination of carbonyl compounds under transfer-hydrogenation conditions 失效
标题翻译：通过羰基化合物在转移氢化条件下还原胺化制备胺的方法
公开(公告)号：US07230134B2
公开(公告)日：2007-06-12
申请号：US10484900
申请日：2002-08-06
申请人： Armin Borner , Uwe Dingerdissen , Renat Kadyrov , Thomas Riermeier , Vitali Tararov
发明人： Armin Borner , Uwe Dingerdissen , Renat Kadyrov , Thomas Riermeier , Vitali Tararov
IPC分类号： C07C209/28
CPC分类号： C07C231/08 , C07C209/28 , C07C213/02 , C07C231/02 , C07C2601/14 , C07C2602/08 , C07D213/38 , C07C211/03 , C07C211/27 , C07C211/29 , C07C211/35 , C07C211/42 , C07C215/50 , C07C217/58 , C07C237/22
摘要： This application claims the benefit of German priority Application No. 10138140.9, filed on Aug. 9, 2001, and International Application No. PCT/EP02/08748, filed on Aug. 6, 2002. The invention relates to the production of amines by the reaction of aldehydes or ketones with ammonia or primary or secondary amines in the presence of a hydrogen-donor and the presence of homogeneous metal catalysts of the eighth sub-group under mild conditions.
摘要翻译：本申请要求于2001年8月9日提交的德国优先权申请号10138140.9和2002年8月6日提交的国际申请号PCT / EP02 / 08748的优先权。本发明涉及由在氢供体存在下，醛或酮与氨或伯胺或仲胺的反应，以及在温和条件下第八子基团的均相金属催化剂的存在。

28. 发明授权

US07217828B2 Phosphinine compounds and metal complexes thereof 失效
标题翻译：膦化合物及其金属络合物
公开(公告)号：US07217828B2
公开(公告)日：2007-05-15
申请号：US10911499
申请日：2004-08-05
申请人： Detlef Selent , Armin Boerner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Roettger
发明人： Detlef Selent , Armin Boerner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Roettger
IPC分类号： C07F9/02
CPC分类号： C07F15/06 , B01J31/185 , B01J31/187 , B01J31/1885 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F9/65846 , C07F15/0046 , C07F15/0073 , C07F15/0086 , C07C47/02
摘要： Phosphinines of formula (I) can be combined with metal salts to prepare hydroformylation catalysts. The phosphinine complexes have two phosphorus centers that may be substituted with a variety of hetero atoms or alkyl substituents to modify the ligand characteristics of the phosphinine. Phosphinine metal complexes are employed under normal hydroformylation reaction conditions. The preparatory routes to the phosphinine ligands of formula (I) allow for their convenient synthesis.
摘要翻译：式（I）的膦可以与金属盐组合以制备加氢甲酰化催化剂。次膦酸络合物具有可以被各种杂原子或烷基取代基取代的两个磷中心，以改变次膦酸的配体特性。在正常加氢甲酰化反应条件下使用膦酸金属络合物。通式（I）的次膦酸配体的准备途径允许其方便的合成。

29. 发明申请

US20050043279A1 Novel phosphinine compounds and metal complexes thereof 失效
标题翻译：新型次膦化合物及其金属配合物
公开(公告)号：US20050043279A1
公开(公告)日：2005-02-24
申请号：US10911499
申请日：2004-08-05
申请人： Detlef Selent , Armin Boerner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Roettger
发明人： Detlef Selent , Armin Boerner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Roettger
IPC分类号： B01J31/22 , B01J31/18 , C07B61/00 , C07C45/50 , C07C47/02 , C07F9/6564 , C07F9/6584 , C07F15/00 , C07F15/06 , C07F9/547 , A61K31/66
CPC分类号： C07F15/06 , B01J31/185 , B01J31/187 , B01J31/1885 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F9/65846 , C07F15/0046 , C07F15/0073 , C07F15/0086 , C07C47/02
摘要： Phosphinines of formula (I) can be combined with metal salts to prepare hydroformylation catalysts. The phosphinine complexes have two phosphorus centers that may be substituted with a variety of hetero atoms or alkyl substituents to modify the ligand characteristics of the phosphinine. Phosphinine metal complexes are employed under normal hydroformylation reaction conditions. The preparatory routes to the phosphinine ligands of formula (I) allow for their convenient synthesis.
摘要翻译：式（I）的膦可以与金属盐组合以制备加氢甲酰化催化剂。次膦酸络合物具有可以被各种杂原子或烷基取代基取代的两个磷中心，以改变次膦酸的配体特性。在正常加氢甲酰化反应条件下使用膦酸金属络合物。通式（I）的次膦酸配体的准备途径允许其方便的合成。

30. 发明申请

US20060089469A1 Hydroxy diphosphines and their use in catalysis 审中-公开
标题翻译：羟基二膦及其在催化中的应用
公开(公告)号：US20060089469A1
公开(公告)日：2006-04-27
申请号：US10514241
申请日：2003-05-20
申请人： Igor Komarov , Armin Boerner , Renat Kadyrov
发明人： Igor Komarov , Armin Boerner , Renat Kadyrov
IPC分类号： C08F4/44 , C07F9/30 , C07F15/00
CPC分类号： C07C231/18 , C07B53/00 , C07C45/505 , C07C51/36 , C07C67/303 , C07C231/12 , C07F9/5027 , C07F15/0073 , C07C55/02 , C07C69/34 , C07C233/47
摘要： The invention relates to novel asymmetrical, chiral hydroxy diphosphines and to derivatives of general formula (I), in addition to their use as catalysts, in particular for enantioselective syntheses.
摘要翻译：本发明涉及新颖的不对称手性羟基二膦和通式（I）的衍生物，除了它们用作催化剂，特别是对映选择性合成之外。

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