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    • 21. 发明授权
    • Alkylbenzenesulfonate surfactants
    • 烷基苯磺酸盐表面活性剂
    • US06306817B1
    • 2001-10-23
    • US09479365
    • 2000-01-07
    • Kevin Lee KottJeffrey John ScheibelThomas Anthony CripeDaniel Stedman ConnorPhillip Kyle Vinson
    • Kevin Lee KottJeffrey John ScheibelThomas Anthony CripeDaniel Stedman ConnorPhillip Kyle Vinson
    • C11D1700
    • C11D1/22
    • A surfactant composition comprising: alkylarylsulfonate surfactant system comprising at least two isomers of the alkylarylsulfonate surfactant of the formula:  wherein: L is an acyclic aliphatic hydrocarbyl of from 6 to 18 carbon atoms in total; M is a cation or cation mixture and q is the valence thereof; and b are numbers selected such that said composition is electroneutral; R′ is selected from H and C1 to C3 alkyl; R″ is selected from H and C1 to C3 alkyl; R′″ is selected from H and C1 to C3 alkyl; any of R′ and R″ is nonterminally attached to L and at least one of R′ and R″ is C1 to C3 alkyl; and A is aryl; and wherein: said alkylarylsulfonate surfactant system comprises two or more isomers with respect to positions of attachment of R′, R″ and A to L; in at least about 60% of said composition, A is attached to L in the position which is selected from positions alpha- and beta- to either of the two terminal carbon atoms thereof; and wherein further said alkylarylsulfonate surfactant system has at least one (preferably both) of the following properties: said alkylarylsulfonate surfactant system has a ratio of nonquatemary to quaternary carbon atoms in L of at least about 10:1 by weight, when said quaternary carbon atoms are present; and there is no more than 40% by weight loss as measured by Hardness Tolerance Test.
    • 一种表面活性剂组合物,其包含:烷基芳基磺酸盐表面活性剂体系,其包含下式的烷基芳基磺酸盐表面活性剂的至少两种异构体:其中:L是总共6至18个碳原子的无环脂族烃基; M是阳离子或阳离子混合物,q是 b为选择为所述组成为电中性的数字; R'选自H和C 1至C 3烷基; R“选自H和C 1至C 3烷基; R”'选自H和C 1 至C3烷基; R'和R“中的任一个非离子地连接到L,R'和R”中的至少一个是C 1至C 3烷基; A是芳基; 并且其中:所述烷基芳基磺酸盐表面活性剂体系包含两个或多个相对于R',R“和A至L的连接位置的异构体;在所述组合物的至少约60%中,A在所选择的位置附着于L 从位于其两个末端碳原子的α-和β-位置; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有至少一种(优选两者)以下性质:所述烷基芳基磺酸盐表面活性剂体系具有至少约10:1重量比的至少约10:1重量比的非季铵碳原子比,当所述季碳原子为 当下; 并且通过耐硬度测试测量不超过40重量%的损失。