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21. 发明授权

US4525468A Olefin polymerization catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US4525468A
公开(公告)日：1985-06-25
申请号：US489687
申请日：1983-04-28
申请人： Mark P. Mack , Mark L. Shannon
发明人： Mark P. Mack , Mark L. Shannon
IPC分类号： C08F4/64 , C08F10/00
CPC分类号： C08F10/00
摘要： High activity catalysts for the polymerization of ethylene and other .alpha.-olefins are made by contacting a soluble magnesium compound of the general formula Mg(OSiR.sup.1 R.sup.2 R.sup.3).sub.2, wherein each of R.sup.1, R.sup.2, and R.sup.3 is, independently, alkyl, alkoxy or aryl with a metal alkoxide, or a mixture of a titanium tetraalkoxide with an alkoxide of another transition metal, in a saturated aliphatic hydrocarbon solution, followed by chlorination and precipitation by a suitable chlorinating agent. These catalysts show high activity for the polymerization of ethylene, especially under slurry polymerization conditions.
摘要翻译：通过使通式Mg（OSiR1R2R3）2的可溶性镁化合物与其中R1，R2和R3各自独立地为烷基，烷氧基或芳基与通式Mg（OSiR 2 R 3）2的可溶性镁化合物接触而制备用于乙烯和其它α-烯烃聚合的高活性催化剂，金属醇盐或四烷氧基钛与另一过渡金属的醇盐的混合物，在饱和脂族烃溶液中，然后氯化并通过合适的氯化剂沉淀。这些催化剂对于乙烯的聚合显示出高的活性，特别是在淤浆聚合条件下。

22. 发明授权

US4371455A Supported catalyst for olefin polymerization 失效
标题翻译：用于烯烃聚合的负载催化剂
公开(公告)号：US4371455A
公开(公告)日：1983-02-01
申请号：US332417
申请日：1981-12-21
申请人： Mark P. Mack , Charles T. Berge
发明人： Mark P. Mack , Charles T. Berge
IPC分类号： C08F10/00 , C08F4/02 , C08F4/64
CPC分类号： C08F10/00
摘要： A method for the preparation of supported Ziegler-Natta catalysts comprising the reduction of a transition metal compound with a magnesium containing reducing agent. The reducing agent is prepared in the presence of a magnesium chloride support utilizing an anhydrous and oxygen-free mixture of magnesium halide and magnesium metal, slurried in a hydrocarbon solvent. A halogenated hydrocarbon is added to activate the magnesium-containing reducing agent. Thereafter the transition metal compound is mixed with the slurry. The resulting solid is washed with a hydrocarbon solvent to eliminate residual transition metal compounds. The resulting washed solid is an active supported Ziegler-Natta olefin polymerization catalyst.
摘要翻译：一种制备负载齐格勒 - 纳塔催化剂的方法，包括用含镁还原剂还原过渡金属化合物。在氯化镁载体的存在下，使用卤化镁和镁的金属的无水和无氧混合物在烃溶剂中成浆形成还原剂。加入卤代烃以活化含镁还原剂。然后将过渡金属化合物与浆料混合。所得固体用烃溶剂洗涤以除去残留的过渡金属化合物。所得洗涤的固体是活性负载齐格勒 - 纳塔烯烃聚合催化剂。

23. 发明授权

US4358572A Method for the preparation of non-crystalline polymers of high molecular weight 失效
标题翻译：制备高分子量非晶态聚合物的方法
公开(公告)号：US4358572A
公开(公告)日：1982-11-09
申请号：US261339
申请日：1981-05-07
申请人： Mark P. Mack , Lewis B. Decker, Jr. , Adrian L. Wallace
发明人： Mark P. Mack , Lewis B. Decker, Jr. , Adrian L. Wallace
IPC分类号： C08F2/00 , C08F20060101 , C08F2/04 , C08F2/06 , C08F4/00 , C08F4/60 , C08F4/64 , C08F8/00 , C08F10/00 , C08F210/00 , C08F10/14
CPC分类号： C08F10/00 , Y10S526/907 , Y10T137/0391
摘要： A process for the preparation of a drag reducing substance which comprises:(a) a transition metal catalyst slurry containing:1. crystalline titanium halide having the general formula TiXn where n=2.5 to 3.0 and X is halogen,2. a hydrocarbon diluent, and3. an ether;(b) a co-catalyst;(c) alpha-monoolefinic hydrocarbons containing from 2 to 30 carbon atoms under suitable polymerization conditions providing for an ultrahigh molecular weight polymer that is soluble in hydrocarbons; and(d) ceasing the polymerization at a polymer content of 20 percent by weight or less.
摘要翻译：一种制备减阻物质的方法，包括：（a）过渡金属催化剂浆料，其含有：1.具有通式TiXn的结晶卤化钛，其中n = 2.5至3.0，X为卤素，2.烃稀释剂，和一个乙醚; （b）助催化剂; （c）在合适的聚合条件下含有2至30个碳原子的α-单烯烃，提供可溶于烃的超高分子量聚合物; 和（d）以聚合物含量为20重量％以下停止聚合。

24. 发明授权

US4311571A Rapid phase transformation for poly(butene-1) 失效
标题翻译：聚（丁烯-1）的快速相变
公开(公告)号：US4311571A
公开(公告)日：1982-01-19
申请号：US195822
申请日：1980-10-10
申请人： Mark P. Mack
发明人： Mark P. Mack
IPC分类号： C08J7/02 , C08F6/00 , C08F8/00
CPC分类号： C08J7/02 , C08J2323/20 , Y10S204/90
摘要： Poly(butene-1) in type II form can be accelerated to its stable type I form by applying a volatile solvent such as an olefinic hydrocarbon and allowing the solvent to evaporate. The phase transformation can be accelerated by additional treatment with heat below the melt temperature of about 90.degree. C. and/or ultrasonic sound.
摘要翻译： II型形式的聚（丁烯-1）可通过施加诸如烯烃的挥发性溶剂并使溶剂蒸发而加速至其稳定的I型形式。可以通过在低于约90℃的熔体温度和/或超声波的温度下进行额外处理来加速相变。

25. 发明授权

US07855255B2 Preparation of multimodal polyethylene 有权
标题翻译：多峰聚乙烯的制备
公开(公告)号：US07855255B2
公开(公告)日：2010-12-21
申请号：US12315552
申请日：2008-12-04
申请人： Venki Chandrashekar , Mark P. Mack , Charles H. Gates, Jr. , Charles S. Holland , Natalia Nagy , Sandor M. Nagy , Edward S. Vargas , Jean A. Merrick-Mack
发明人： Venki Chandrashekar , Mark P. Mack , Charles H. Gates, Jr. , Charles S. Holland , Natalia Nagy , Sandor M. Nagy , Edward S. Vargas , Jean A. Merrick-Mack
IPC分类号： C08L23/04
CPC分类号： C08L23/04 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/06 , C08L23/0807 , C08F2/001 , C08F4/65904 , C08L23/00 , C08L2666/06 , C08F2500/05 , C08F2500/09 , C08F210/08
摘要： Disclosed is a polyethylene composition. The composition comprises single-site multimodal resin A and single-site multimodal resin B, wherein resin A differs from resin B in molecular weight, in monomeric composition, in density, in long chain branch concentration or distribution, or in combinations thereof. Disclosed is also a method for making the polyethylene composition. The method comprises polymerizing, in the presence of two or more single-site catalysts, ethylene or its mixture with a C3-C10 α-olefin to form a first multimodal resin and continuing the polymerization in the presence of the same catalysts but in a different hydrogen concentration, in a different monomer composition, or at a different temperature to form a second multimodal resin.
摘要翻译：公开了一种聚乙烯组合物。该组合物包含单体多峰树脂A和单体多峰树脂B，其中树脂A的分子量，单体组成，密度，长链分支浓度或分布或其组合不同于树脂B. 还公开了制备聚乙烯组合物的方法。该方法包括在两个或多个单中心催化剂存在下，将乙烯或其混合物与C 3 -C 10α-烯烃聚合以形成第一多峰树脂，并在相同催化剂存在下继续进行聚合反应氢浓度，以不同的单体组成，或在不同的温度下形成第二多峰树脂。

26. 发明授权

US07473745B2 Preparation of multimodal polyethylene 失效
标题翻译：多峰聚乙烯的制备
公开(公告)号：US07473745B2
公开(公告)日：2009-01-06
申请号：US11218888
申请日：2005-09-02
申请人： Venki Chandrashekar , Mark P. Mack , Charles H. Gates, Jr. , Charles S. Holland , Natalia Nagy , Sandor M. Nagy , Edward S. Vargas , Jean A. Merrick-Mack
发明人： Venki Chandrashekar , Mark P. Mack , Charles H. Gates, Jr. , Charles S. Holland , Natalia Nagy , Sandor M. Nagy , Edward S. Vargas , Jean A. Merrick-Mack
IPC分类号： C08F4/06
CPC分类号： C08L23/04 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/06 , C08L23/0807 , C08F2/001 , C08F4/65904 , C08L23/00 , C08L2666/06 , C08F2500/05 , C08F2500/09 , C08F210/08
摘要： Disclosed is a polyethylene composition. The composition comprises single-site multimodal resin A and single-site multimodal resin B, wherein resin A differs from resin B in molecular weight, in monomeric composition, in density, in long chain branch concentration or distribution, or in combinations thereof. Disclosed is also a method for making the polyethylene composition. The method comprises polymerizing, in the presence of two or more single-site catalysts, ethylene or its mixture with a C3-C10 α-olefin to form a first multimodal resin and continuing the polymerization in the presence of the same catalysts but in a different hydrogen concentration, in a different monomer composition, or at a different temperature to form a second multimodal resin.
摘要翻译：公开了一种聚乙烯组合物。该组合物包含单体多峰树脂A和单体多峰树脂B，其中树脂A的分子量，单体组成，密度，长链分支浓度或分布或其组合不同于树脂B. 还公开了制备聚乙烯组合物的方法。该方法包括在两个或多个单中心催化剂存在下，将乙烯或其与C 3 -C 10α-烯烃的混合物聚合以形成第一多峰树脂并在相同催化剂存在下继续进行聚合反应氢浓度，以不同的单体组成，或在不同的温度下形成第二多峰树脂。

27. 发明授权

US07273914B2 Olefin polymerization methods 失效
标题翻译：烯烃聚合方法
公开(公告)号：US07273914B2
公开(公告)日：2007-09-25
申请号：US11196639
申请日：2005-08-03
申请人： Shaotian Wang , Barbara M. Tsuie , Mark P. Mack , Edward S. Vargas , Debra L. Beran
发明人： Shaotian Wang , Barbara M. Tsuie , Mark P. Mack , Edward S. Vargas , Debra L. Beran
IPC分类号： C08F4/52 , C08F4/76
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F210/16 , C08F4/65916 , C08F210/08 , C08F2500/03 , C08F210/14
摘要： Methods for making polyolefins are disclosed. One method comprises polymerizing an olefin in the presence of a catalyst system comprising a single-site complex, an agglomerated metal oxide/clay support-activator, and an ionic borate. Including an ionic borate with the support-activator provides an unexpected boost in catalyst activity and gives polyolefins with high molecular weight and improved comonomer incorporation. In another method of the invention, an olefin is polymerized in the presence of an indenoindolyl metal alkylated complex and an agglomerated metal oxide/clay support-activator. Use of alkylated indenoindolyl complexes with the support-activators provides improved activity compared with metal halides.
摘要翻译：公开了制备聚烯烃的方法。一种方法包括在包含单位点络合物，附聚金属氧化物/粘土载体活化剂和离子硼酸盐的催化剂体系存在下聚合烯烃。包括离子硼酸盐与载体 - 活化剂提供催化剂活性的意想不到的增加，并提供具有高分子量和改进的共聚单体掺入的聚烯烃。在本发明的另一种方法中，烯烃在茚并吲哚基金属烷基化络合物和聚集的金属氧化物/粘土载体 - 活化剂的存在下聚合。与金属卤化物相比，使用烷基化茚并吲哚基配合物与载体活化剂相比提供了更好的活性。

28. 发明授权

US07144964B2 Solution polymerization process utilizing preassembled bimetallic Ziegler-Natta catalyst 失效
标题翻译：溶液聚合法利用预组装的双金属齐格勒 - 纳塔催化剂
公开(公告)号：US07144964B2
公开(公告)日：2006-12-05
申请号：US10921687
申请日：2004-08-19
申请人： Sandor Nagy , Mark P. Mack
发明人： Sandor Nagy , Mark P. Mack
IPC分类号： C08F4/68 , C08F4/72 , C08F4/52
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F2410/03 , C08F4/685 , C08F4/68 , C08F2/06 , C08F4/64079 , C08F4/68198 , C08F4/69
摘要： A high-temperature solution process for polymerizing ethylene is disclosed. The polymerization is performed in the presence of a preassembled bimetallic Ziegler-Natta catalyst and an aluminum compound. Molecular modeling calculations predict that the bimetallic Ziegler-Natta catalyst will have good activity and improved stability versus traditional Ziegler-Natta catalysts. This makes the catalyst especially suitable for solution polymerization processes, which require a thermally robust catalyst.
摘要翻译：公开了用于聚合乙烯的高温溶液方法。在预组装的双金属齐格勒 - 纳塔催化剂和铝化合物的存在下进行聚合。分子模拟计算预测，与传统的齐格勒 - 纳塔催化剂相比，双金属齐格勒 - 纳塔催化剂具有良好的活性和改进的稳定性。这使得催化剂特别适用于需要热稳定催化剂的溶液聚合方法。

29. 发明授权

US07094723B2 Catalysts containing at least one heterocyclic ligand for improving the catalysts' performance of olefin polymerization 失效
公开(公告)号：US07094723B2
公开(公告)日：2006-08-22
申请号：US10124991
申请日：2002-04-18
申请人： Shaotian Wang , Clifford C. Lee , Mark P. Mack
发明人： Shaotian Wang , Clifford C. Lee , Mark P. Mack
IPC分类号： B01J31/16 , C08F4/42 , C08F4/64
CPC分类号： C08F10/00 , B01J31/2204 , B01J31/2295 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F2420/04 , C08F4/65925
摘要： The present invention provides a non-metallocene catalyst comprising a complex having one or more ligands coordinated a transition metal. The catalyst contains substituents bonded to the transition metal through a heteroatom such as oxygen or sulfur. Furthermore, the complex includes a Group 3 to 10 transition or lanthanide metal and one or more anionic or neutral ligands in an amount that satisfies the valency of the metal such that the complex has a net zero charge. The present invention also discloses a method for preparing the catalyst and polymerizing olefins utilizing the catalyst of the present invention.

30. 发明授权

US06265504B1 Preparation of ultra-high-molecular-weight polyethylene 有权
标题翻译：制备超高分子量聚乙烯
公开(公告)号：US06265504B1
公开(公告)日：2001-07-24
申请号：US09401472
申请日：1999-09-22
申请人： Jia-Chu Liu , Mark P. Mack , Clifford C. Lee
发明人： Jia-Chu Liu , Mark P. Mack , Clifford C. Lee
IPC分类号： C08F442
CPC分类号： C08F110/02 , Y10S526/943 , C08F2500/01 , C08F2500/03 , C08F2500/07
摘要： An ultra-high-molecular-weight polyethylene (UHMWPE) is disclosed. The UHMWPE has a weight average molecular weight (Mw) greater than about 3,000,000 and molecular weight distribution less than about 5. A process for making the UHMWPE is also disclosed. The process is performed with a heteroatomic ligand-containing single-site catalyst in the presence of a non-alumoxane activator, but in the absence of an &agr;-olefin, an aromatic solvent, and hydrogen.
摘要翻译：公开了一种超高分子量聚乙烯（UHMWPE）。 UHMWPE的重均分子量（Mw）大于约3,000,000，分子量分布小于约5.制备UHMWPE的方法也被公开。该方法在非铝氧烷激活剂存在下，但不存在α-烯烃，芳族溶剂和氢气的情况下，用含杂原子配体的单中心催化剂进行。

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