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21. 发明授权

US4340507A Preparation of electrically conductive polyaromatics, and their use in the electrical industry and for rendering plastics antistatic 失效
标题翻译：导电多芳族化合物的制备及其在电气工业中的应用以及使塑料抗静电
公开(公告)号：US4340507A
公开(公告)日：1982-07-20
申请号：US204639
申请日：1980-11-06
申请人： Herbert Naarmann , Dieter Naegele , Klaus Penzien , Johannes Schlag
发明人： Herbert Naarmann , Dieter Naegele , Klaus Penzien , Johannes Schlag
IPC分类号： C08K3/08 , C08K3/28 , C08L65/00 , C08L65/02 , H01B1/12 , H01L51/30 , H01B1/02
CPC分类号： H01B1/128 , C08K3/08 , C08K3/28 , C08L65/00 , C08L65/02 , H01L51/0035 , C08G2261/312 , Y02E10/549
摘要： A process for the preparation of electrically conductive polyaromatics having conductivities greater than 10.sup.-2 S/cm., wherein from 0.5 to 5% by weight, based on the polyaromatics, of sodium, potassium, rubidium, cesium or their amides, preferably in tetrahydrofuran, dimethoxyglycol, anthracene, naphthalene or 2-methylstyrene, are incorporated into polyaromatics, in the absence of moisture and of oxygen. The conductive polyaromatics obtained may be used in the electrical industry for the manufacture of solar cells, for the conversion of radiation and for the manufacture of electrical and magnetic switches, and may also be used to render plastics antistatic.
摘要翻译：制备电导率大于10-2S / cm的导电多芳族化合物的方法，其中基于多元芳族化合物的钠，钾，铷，铯或它们的酰胺，优选在四氢呋喃中的0.5至5重量％二甲氧基二醇，蒽，萘或2-甲基苯乙烯，在没有水分和氧气的情况下加入到多芳族化合物中。获得的导电多芳族化合物可用于制造太阳能电池的电气工业中，用于辐射转换和用于制造电气和磁性开关，并且还可用于使塑料抗静电。

22. 发明授权

US4277588A Preparation of acetylene copolymers 失效
标题翻译：制备乙炔共聚物
公开(公告)号：US4277588A
公开(公告)日：1981-07-07
申请号：US129828
申请日：1980-03-13
申请人： Herbert Naarmann , Klaus Penzien , Helmut Doerfel , Albrecht Eckell
发明人： Herbert Naarmann , Klaus Penzien , Helmut Doerfel , Albrecht Eckell
IPC分类号： C08F238/00 , C08F4/64 , C08F4/68 , C08F38/02 , C08F38/04
CPC分类号： C08F238/00
摘要： A process for the preparation of acetylene copolymers by catalytic polymerization of a mixture of acetylene and dialkynes or polyalkynes, using Ziegler catalysts. The novel polymers may be used as colored pigments, as colored coatings for metal, glass or plastics, and for the production of electrical or magnetic components.
摘要翻译：使用齐格勒催化剂通过乙炔和二炔烃或多炔烃的混合物的催化聚合制备乙炔共聚物的方法。新型聚合物可用作有色颜料，作为金属，玻璃或塑料的着色涂料，以及用于制造电或磁性组分。

23. 发明授权

US4158097A Polymerizable compounds containing tribromomethyl groups 失效
标题翻译：含有三溴甲基的可聚合化合物
公开(公告)号：US4158097A
公开(公告)日：1979-06-12
申请号：US782613
申请日：1977-03-30
申请人： Herbert Naarmann , Klaus Penzien
发明人： Herbert Naarmann , Klaus Penzien
IPC分类号： C08F20/24 , C07C69/54
CPC分类号： C08F20/24
摘要： New compounds containing tribromomethyl groups, of the general formula ##STR1## WHEREIN X is chlorine or bromine, R is hydrogen or methyl and R.sup.1 is hydrogen or a group of the formula --COO--CHX--CBr.sub.3 and a process for their preparation. The compounds may be used for the manufacture of homopolymers or copolymers which find diverse uses, eg. for the manufacture of moldings, coatings or adhesives. The compounds are manufactured by reacting the corresponding acid chlorides or acid bromides with equivalent amounts of tribromoacetaldehyde. The acid chlorides and bromides have the formula ##STR2## wherein X is chlorine or bromine, R is hydrogen or methyl and R.sup.2 is hydrogen or --COX. The reaction is carried out in the presence of from 0.1 to 10 per cent by weight of a Lewis acid, preferably AlBr.sub.3 or FeBr.sub.3, at from 0 to 80.degree. C., generally with reaction times of from 1 to 10 hours, preferably from 2 to 3 hours. The reaction is carried out without solvents or, with particular advantage, in a solution, of about 50 per cent strength, in an inert aliphatic, cycloaliphatic or aromatic solvent, eg. hexane mixtures, octane mixtures, cyclohexane or toluene. From 0.1 to 10 per cent by weight of magnesium oxide is added to the reaction mixture, prior to the distillation to achieve good yields and compound purity.
摘要翻译：含有三溴甲基的新化合物，通式为：其中X为氯或溴，R为氢或甲基，R 1为氢或式-COO-CHX-CBr 3基团及其制备方法。这些化合物可以用于制造均聚物或共聚物，其可以找到不同的用途，例如。用于制造模制品，涂料或粘合剂。该化合物通过使相应的酰氯或酸性溴化物与等量的三溴乙醛反应制备。酰氯和溴化物具有式“其中X是氯或溴，R是氢或甲基，R 2是氢或-COX”。反应在0.1至10重量百分比的路易斯酸，优选AlBr 3或FeBr 3存在下进行，在0至80℃下，通常反应时间为1至10小时，优选2 至3小时。该反应在惰性脂族，脂环族或芳族溶剂（例如）中没有溶剂或特别有利的是在约50％的强度溶液中进行。己烷混合物，辛烷混合物，环己烷或甲苯。在蒸馏之前，将0.1至10重量％的氧化镁加入到反应混合物中以获得良好的收率和化合物纯度。

24. 发明授权

US4058508A Polymers containing urethane groups 失效
标题翻译：含聚氨酯基团的聚合物
公开(公告)号：US4058508A
公开(公告)日：1977-11-15
申请号：US632641
申请日：1975-11-17
申请人： Herbert Naarmann , Heinz Pohlemann
发明人： Herbert Naarmann , Heinz Pohlemann
IPC分类号： C08F20/36 , C08F22/22 , C08F22/38 , C08F18/24 , C08F20/26 , C08G63/00
CPC分类号： C08F20/36 , C08F22/22 , C08F22/38
摘要： Polymers of which the side chains contain urethane groups and which have the reactivity of a urethane but can, in addition, contain other reactive groups. The new polymers may be used to produce moldings, coatings or adhesives.
摘要翻译：侧链含有氨基甲酸酯基并且具有氨基甲酸酯的反应性的聚合物，而且还可以含有其它反应性基团。新的聚合物可用于生产模制品，涂料或粘合剂。

25. 发明授权

US4038311A Production of N-(1-alkenyl)-carbamyl chlorides 失效
标题翻译： N-（1-烷基） - 氨基甲酰氯的生产
公开(公告)号：US4038311A
公开(公告)日：1977-07-26
申请号：US533143
申请日：1974-12-16
申请人： Hans Kiefer , Herbert Naarmann
发明人： Hans Kiefer , Herbert Naarmann
IPC分类号： C07C271/02 , C07C271/06 , C08F26/02 , C08F226/02 , E04H17/14 , C07C125/03
CPC分类号： C08F226/02 , C07C271/02 , C07C271/06 , C08F26/02 , E04H17/14
摘要： The production of N-(1-alkenyl)-carbamyl chlorides by reaction of a Schiff base with phosgene, and the new N-(1-alkenyl)-carbamyl chlorides themselves. The new compounds which can be prepared by the process of the invention are valuable starting materials for the production of coating intermediates, plastics, paints and plant protection agents.One preferred group of compounds available from said process are the N-vinyl compounds of the formula ##STR1## in which R.sup.1 is cyclohexyl, cyclooctyl, norbornyl, tetrahydrodicyclopentadienyl, n-hexyl, n-octyl, 2-ethylhexyl or phenyl. Another preferred group of compounds are the N-vinyl-N-t-alkylcarbamyl chlorides of 4 to 6 carbon atoms in the tertiary alkyl group, especially N-vinyl-N-t-butylcarbamyl chloride.

26. 发明授权

US4012366A Polymers containing hydroxamic acid-o-sulfonyl groups 失效
标题翻译：含有异羟肟酸-O-磺酰基的聚合物
公开(公告)号：US4012366A
公开(公告)日：1977-03-15
申请号：US632642
申请日：1975-11-17
申请人： Herbert Naarmann , Heinz Pohlemann
发明人： Herbert Naarmann , Heinz Pohlemann
IPC分类号： C08F20/58 , C08F22/38 , C08G75/00
CPC分类号： C08F22/38 , C08F20/58 , Y10S260/17
摘要： Polymers which contain hydroxamic acid-O-sulfonyl groups in the side chains and which accordingly can undergo important substitution reactions. The polymers may also contain other reactive groups and may be used for the manufacture of moldings, coatings or adhesives.
摘要翻译：在侧链中含有异羟肟酸-O-磺酰基的聚合物，因此可以进行重要的取代反应。聚合物还可以含有其它反应性基团，并可用于制造模制品，涂料或粘合剂。

27. 发明授权

US3983268A Process for surface sizing paper 失效
标题翻译：表面施胶纸的工艺
公开(公告)号：US3983268A
公开(公告)日：1976-09-28
申请号：US522631
申请日：1974-11-11
申请人： Emil Scharf , Herbert Naarmann , Fritz Reichel
发明人： Emil Scharf , Herbert Naarmann , Fritz Reichel
IPC分类号： C09J123/02 , D21H17/07 , D21H17/35 , D21H17/43 , B05D3/02
CPC分类号： D21H17/43 , C08K3/30 , C08K5/20 , C09J123/02 , D21H17/07 , D21H17/35
摘要： Process for the manufacture of surface-sized papers by impregnating a paper with a solution containing a water-soluble salt of a random polymer based on .alpha.-olefins and ethylenically unsaturated acids and a compound of the formula: ##EQU1## wherein R is alkyl, aryl or a radical of the formula: ##EQU2## and R.sup.1 and R.sup.2 each independently denotes H, R or a radical of the formula:R -- O-- CH.sub.2 --and drying the impregnated paper. Very well sized papers are obtained which show alkali resistance and filler compatibility.
摘要翻译：通过用包含基于α-烯烃和烯键式不饱和酸的无规聚合物的水溶性盐的溶液浸渍纸而制备表面尺寸纸的方法和下式化合物：R1R-CO-N ANGLE R2 其中R是烷基，芳基或下式的基团：R1 ANGLEN-R2和R1和R2各自独立地表示H，R或下式的基团：

28. 发明授权

US3943195A Self-extinguishing thermoplastic molding material 失效
标题翻译：自熄性热塑性成型材料
公开(公告)号：US3943195A
公开(公告)日：1976-03-09
申请号：US525822
申请日：1974-11-21
申请人： Herbert Naarmann , Klaus Penzien
发明人： Herbert Naarmann , Klaus Penzien
IPC分类号： C08L23/00 , C08K5/00 , C08K5/02 , C08L7/00 , C08L21/00 , C08L23/02 , C08L25/00 , C08L25/04 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L59/00 , C08L65/00 , C08L101/00 , C08L25/06
CPC分类号： C08L23/02 , C08L25/04 , C08L65/00 , Y10S260/24
摘要： Thermoplastic molding material based on styrene polymers and olefin polymers which have been flameproofed with an organic bromine compound. Brominated oligomers or polymers of dialkylbenzenes, trialkylbenzenes or tetraalkylbenzenes serve as flameproofing agents. The molding material may be processed into self-extinguishing moldings.
摘要翻译：基于苯乙烯聚合物和烯烃聚合物的热塑性成型材料已被有机溴化合物隔爆。溴化低聚物或二烷基苯，三烷基苯或四烷基苯的聚合物用作防火剂。成型材料可以被加工成自熄模制品。

29. 发明申请

US20060099510A1 Electrically conductive bonding agent 审中-公开
标题翻译：导电粘合剂
公开(公告)号：US20060099510A1
公开(公告)日：2006-05-11
申请号：US10521664
申请日：2003-07-16
申请人： Herbert Naarmann , Franz Kruger , Michael Stolzenberg
发明人： Herbert Naarmann , Franz Kruger , Michael Stolzenberg
IPC分类号： H01B1/20 , H01B1/24 , H01M4/62
CPC分类号： H01M4/621 , H01M4/0404 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/139 , H01M4/623
摘要： The invention relates to an electrically conductive bonding agent, an electrode, and a secondary battery comprising such a bonding agent, and a method for the production of such an electrode. The inventive bonding agent is characterized by the fact that it comprises an aqueously dispersed fluoride polymer and an amine salt or ammonium salt of a perfluorcarboxylic acid
摘要翻译：本发明涉及导电粘合剂，电极和包含这种粘合剂的二次电池，以及这种电极的制造方法。本发明的粘结剂的特征在于它包括一个分散的氟化物聚合物和全氟羧酸的胺盐或铵盐

30. 发明授权

US4640749A Electrically conductive pyrrole copolymers and their preparation 失效
标题翻译：导电吡咯共聚物及其制备方法
公开(公告)号：US4640749A
公开(公告)日：1987-02-03
申请号：US731458
申请日：1985-05-07
申请人： Herbert Naarmann , Gernot Koehler , Johannes Schlag
发明人： Herbert Naarmann , Gernot Koehler , Johannes Schlag
IPC分类号： H01M4/60 , C08F38/00 , C08G61/00 , C08G61/10 , C08G61/12 , C08J7/02 , C08L65/00 , H01B1/12 , H01L21/331 , H01L29/73 , H01L51/05 , H01L51/30 , H01L51/40 , C25C1/00
CPC分类号： H01B1/127 , C08G61/124 , Y10T428/31855 , Y10T428/8305
摘要： Highly electrically conductive copolymers of pyrroles and alkynes and/or aromatics, which possess good mechanical properties coupled with a well-balanced spectrum of properties, are prepared by anodic polymerization of the pyrroles and alkynes and/or aromatics in a polar solvent in the presence of a suitable conductive salt.
摘要翻译：通过吡咯和炔和/或芳族化合物在极性溶剂中的存在下阳极聚合，制备具有良好机械性能与良好平衡的性质光谱的吡咯和炔和/或芳族化合物的高度导电的共聚物合适的导电盐。

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