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    • 25. 发明授权
    • Polyisocyanate adducts with apolar solvent compatibility and good
storage stability
    • 多异氰酸酯加合物具有非极性溶剂相容性和良好的储存稳定性
    • US4355138A
    • 1982-10-19
    • US282285
    • 1981-07-10
    • Peter MarkuschGeorge A. Hudson, deceasedby Richard L. White, administrator
    • Peter MarkuschGeorge A. Hudson, deceasedby Richard L. White, administrator
    • C07C275/62C08G18/80C08G18/78C07C127/24
    • C07C275/62C08G18/8064
    • The present invention is directed to light stable polyisocyanate adduct mixtures with an average functionality greater than 2.0 and an isocyanate content of between about 4 and 19 percent by weight based on solids, which has good compatibility with apolar solvents and good storage stability in a solution of polyisocyanate solvents. The polyisocyanate adduct mixtures are based on the reaction product of a polyisocyanate, preferably a biuret-containing polyisocyanate, with a first monohydroxy compound containing a saturated hydrocarbon chain of at least 8 carbon atoms and a second monohydroxy compound containing at least one polarity inducing group. Alternatively, both the saturated hydrocarbon chain and the polarity inducing group may be present in the same monohydroxy compound.The present invention is additionally directed to the use of the polyisocyanate adduct mixtures in the process of curing alkyd or acrylic resins and to compositions containing the adduct mixture and alkyd or acrylic resins.
    • 本发明涉及平均官能度大于2.0且异氰酸酯含量为约4至19重量%的基于固体的轻质稳定多异氰酸酯加合物混合物,其与非极性溶剂具有良好的相容性,并且在溶液中具有良好的储存稳定性 多异氰酸酯溶剂。 多异氰酸酯加合物混合物基于多异氰酸酯,优选含缩二脲的多异氰酸酯与含有至少8个碳原子的饱和烃链的第一单羟基化合物和含有至少一个极性诱导基团的第二单羟基化合物的反应产物。 或者,饱和烃链和极性诱导基团可以存在于相同的单羟基化合物中。 本发明另外涉及在固化醇酸树脂或丙烯酸树脂的方法中使用多异氰酸酯加合物混合物以及含有加合物混合物和醇酸树脂或丙烯酸树脂的组合物。
    • 28. 发明申请
    • Slow-release polyurethane(urea) encapsulated fertilizer
    • 缓释聚氨酯(尿素)包封肥料
    • US20050066697A1
    • 2005-03-31
    • US10675536
    • 2003-09-30
    • Robert ClinePeter MarkuschRalf Guether
    • Robert ClinePeter MarkuschRalf Guether
    • C05C9/00C05G3/00C05G5/00
    • C05G3/0029
    • This invention relates to polyurethane(urea) encapsulated fertilizer particles which exhibit slow-release properties and to a process for their production. In one embodiment, the process comprises a) applying a polyisocyanate component to fertilizer particles to form isocyanate coated fertilizer particles, b) mixing an inert inorganic filler with said isocyanate coated fertilizer, c) adding an isocyanate-reactive component to the mixture of step b) and d) allowing the reactive components to react to form filler containing polyurethane(urea) encapsulated fertilizer particles containing from about 1 to about 15 percent by weight of filled polyurethane(urea), said percent by weight based on the total weight of the encapsulated fertilizer, with the proviso that the weight ratio of polyurethane(urea) to filler is from about 80:20 to about 30:70.
    • 本发明涉及具有缓释特性的聚氨酯(脲)包封肥料颗粒及其生产方法。 在一个实施方案中,该方法包括a)将多异氰酸酯组分施用于肥料颗粒以形成异氰酸酯涂覆的肥料颗粒,b)将惰性无机填料与所述异氰酸酯涂覆的肥料混合,c)将异氰酸酯反应性组分加入到步骤b的混合物中 )和d)允许反应性组分反应以形成含有约1至约15重量%的填充聚氨酯(尿素)的含聚氨酯(脲)包封肥料颗粒的填料,所述重量百分比基于包封的 肥料,条件是聚氨酯(脲)与填料的重量比为约80:20至约30:70。
    • 29. 发明授权
    • Stable, colloidal, aqueous dispersions of cross-linked urea-urethane
polymers and their method of production
    • 交联尿素 - 氨基甲酸酯聚合物的稳定的胶态水分散体及其制备方法
    • US4408008A
    • 1983-10-04
    • US286493
    • 1981-07-24
    • Peter Markusch
    • Peter Markusch
    • C08G18/08C08G18/12C08G18/28C08G18/50C08G18/78C08L75/10C08L75/02
    • C08G18/7831C08G18/0804C08G18/12C08G18/283C08G18/5042Y10T428/31551Y10T428/31601Y10T428/31605
    • The present invention relates to a process for the preparation of stable, colloidal, aqueous dispersions of cross-linked urea-urethanes which comprises reacting(a) an aqueously dispersed, substantially linear, isocyanate-terminated prepolymer having a molecular weight of up to about 25,000 and containing(i) about 0 to 120 milliequivalents of ionic groups per 100 grams of prepolymer, and(ii) about 0.35 to 10% by weight, based on the weight of the prepolymer, of lateral and/or terminal, hydrophilic ethylene oxide units wherein components (i) and (ii) are present in an amount sufficient to provide a stable dispersion of the prepolymer in the aqueous medium, with(b) polyfunctional amine chain extenders having an average functionality between about 2.2 and 6.0.The present invention additionally relates to the aqueous dispersions produced by the above process and to the films, coatings or adhesives produced from these dispersions.
    • 本发明涉及一种用于制备交联尿素 - 氨基甲酸酯的稳定的胶体水性分散体的方法,其包括使(a)分子量大致为线性的异氰酸酯封端的预聚物与分子量高达约25,000 并且包含(i)每100克预聚物约0至120毫当量的离子基团,和(ii)基于预聚物重量的约0.35至10重量%的亲水性环氧乙烷单元和/或末端亲水性环氧乙烷单元 其中组分(i)和(ii)以足以提供预聚物在水性介质中的稳定分散体的量存在,(b)平均官能度在约2.2至6.0之间的多官能胺扩链剂。 本发明还涉及通过上述方法制备的水分散体和由这些分散体制备的薄膜,涂料或粘合剂。