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21. 发明授权

US5387359A Alkaline earth metal potassium acetate, a process for its preparation and its use 失效
标题翻译：碱土金属乙酸钾，其制备方法及其用途
公开(公告)号：US5387359A
公开(公告)日：1995-02-07
申请号：US161777
申请日：1993-12-02
申请人： Johannes Himmrich , Gunther Schimmel , Klaus Pollmannn
发明人： Johannes Himmrich , Gunther Schimmel , Klaus Pollmannn
IPC分类号： C07C51/41 , C07C53/10 , C09K3/00 , C09K3/18
CPC分类号： C09K3/185
摘要： The alkaline earth metal potassium acetate according to the invention comprises14 to 19 % by weight of calcium (Ca.sup.++),0 to 1% by weight of magnesium (Mg.sup.++),11 to 16 % by weight of potassium (K.sup.+),62 to 71% by weight of acetate (CH.sub.3 COO.sup.-),0 to 7 % by weight of waterand0 to 2 % by weight of water-insoluble componentsFor its preparation, a calcium oxide containing at least 85% of CaO, acetic acid and potassium hydroxide solution are reacted with one another and the reaction product is granulated to give particles of 0.5 to 5 mm. The alkaline earth metal potassium acetate according to the invention can be used as an environment-friendly deicing agent causing little corrosion.
摘要翻译：本发明的碱土金属乙酸钾含有14〜19重量％的钙（Ca ++），0〜1重量％的镁（Mg ++），11〜16重量％的钾（K +），62〜71 乙酸酯（CH 3 COO-），0〜7重量％的水和0〜2重量％的水不溶性组分的重量％制备其中含有至少85％的CaO，乙酸和氢氧化钾的氧化钙溶液彼此反应，将反应产物造粒，得到0.5至5mm的颗粒。根据本发明的碱土金属乙酸钾可以用作几乎不腐蚀的环保除冰剂。

22. 发明授权

US5183651A Process for the preparation of crystalline sodium silicates 失效
标题翻译：制备晶体硅酸钠的方法
公开(公告)号：US5183651A
公开(公告)日：1993-02-02
申请号：US635933
申请日：1990-12-28
申请人： Gunther Schimmel , Michael Kotzian , Reinhard Gradl
发明人： Gunther Schimmel , Michael Kotzian , Reinhard Gradl
IPC分类号： C01B33/32 , C01B33/38
CPC分类号： C01B33/38
摘要： To prepare crystalline sodium silicates having a layer structure and the formula Na.sub.2 Si.sub.x O.sub.2x+1, in which x is between 2 and 3, sand and soda are first fused in a molar ratio of SiO.sub.2 /Na.sub.2 O of 2 to 3.5 at temperature of 1200.degree. to 1400.degree. C. The water-glass obtained in pieces after the melt has cooled is ground to particle sizes of less than 2 mm before it is treated at temperatures of 600.degree. to 800.degree. C. for 10 to 120 minutes in an elongated reaction zone with mechanical circulation. Finally, the material leaving the reaction zone is ground to a particle fineness of less than 1 mm.
摘要翻译：为了制备具有层结构的结晶硅酸钠和其中x在2和3之间的式Na2SixO2x + 1，首先在1200至1400的温度下以SiO 2 / Na 2 O的摩尔比2至3.5熔融砂和苏打将熔融物冷却后的片状水玻璃研磨至小于2mm的粒度，然后在600℃至800℃的温度下在延长的反应区域中处理10至120分钟，机械循环。最后，将离开反应区的材料研磨成小于1mm的颗粒细度。

23. 发明授权

US4834960A Process for purifying phosphorous acid 失效
标题翻译：纯化亚磷酸的方法
公开(公告)号：US4834960A
公开(公告)日：1989-05-30
申请号：US182871
申请日：1988-04-18
申请人： Jurgen Grosse , Gunther Schimmel , Bernhard Hofmann
发明人： Jurgen Grosse , Gunther Schimmel , Bernhard Hofmann
IPC分类号： C01B25/163
CPC分类号： C01B25/163
摘要： The purification of phosphorous acid which is formed in halogenations of hydrocarbon derivatives using phosphorus trihalides is carried out in the context of preparing phosphorous acid in a reaction zone by reacting a mixture of phosphorus trichloride and water which has been finely divided by means of steam at temperatures between 150.degree. and 200.degree. C. in the gas phase. In this process, the liquid reaction product drains into a concentrating evaporation zone which has a downstream first separation zone. Inert gas is introduced to the lower part of the first separation zone. A melt is withdrawn from the first separation zone into a crystallizing zone. The waste gases from the reaction zone are treated with a washing liquid in a second separation zone before being passed into the atmosphere. The washing liquid used is an aqueous solution of never-purified phosphorous acid, which can have been prepurified by hydrolysis and stripping.
摘要翻译：通过使用三卤化磷在烃衍生物的卤化中形成的亚磷酸的纯化是在反应区中通过使三氯化磷和水分混合物在蒸气中分解的温度反应在反应区中进行的在气相中为150〜200℃。在该方法中，液体反应产物排入具有下游第一分离区的浓缩蒸发区。惰性气体被引入第一分离区的下部。将熔体从第一分离区取出成结晶区。来自反应区的废气在通入大气中之前用洗涤液在第二分离区中处理。所使用的洗涤液是未经纯化的亚磷酸的水溶液，其可以通过水解和汽提进行预净化。

24. 发明授权

US4806324A Process for making phosphoric acid free from titanium 失效
标题翻译：制备不含钛的磷酸的方法
公开(公告)号：US4806324A
公开(公告)日：1989-02-21
申请号：US152751
申请日：1988-02-05
申请人： Gunther Schimmel , Reinhard Gradl , Klaus Schrodter
发明人： Gunther Schimmel , Reinhard Gradl , Klaus Schrodter
IPC分类号： C01B25/234 , C01B25/46 , C01B25/16
CPC分类号： C01B25/462 , C01B25/461
摘要： Phosphoric acid substantially free from titanium is made from the organic extract obtained by subjecting crude phosphoric acid containing titanium to extractive purification with an organic solvent immiscible or only partially miscible with water. To this end, the organic extract is scrubbed in a scrubbing zone with a stage number of n>4 by introducing the crude extract into stage 1 and scrubbing it countercurrently with an aqueous alkaline solution in one of stages 2 to n-2 and with pure scrubbing water in stage n.
摘要翻译：基本上不含钛的磷酸由有机提取物制得，所述有机提取物通过用不溶混或仅与水部分混溶的有机溶剂对含有钛的粗磷酸进行萃取纯化而获得。为此，通过将粗提取物引入阶段1并将其与阶段2至n-2之一中的碱性水溶液逆流洗涤，并且纯化到具有阶段数n> 4的洗涤区中，有机萃取物被洗涤在阶段n洗涤水。

25. 发明授权

US6036733A Process for the preparation of crystalline sodium silicates 失效
标题翻译：制备结晶硅酸钠的方法
公开(公告)号：US6036733A
公开(公告)日：2000-03-14
申请号：US027531
申请日：1998-02-23
申请人： Josef Holz , Gunther Schimmel , Alexander Tapper , Volker Thewes
发明人： Josef Holz , Gunther Schimmel , Alexander Tapper , Volker Thewes
IPC分类号： C01B33/32 , C01B33/38 , C11D3/08 , C11D3/12 , B01D9/00 , C01B33/00 , C01B33/20 , C01D1/30
CPC分类号： C11D3/1273 , C01B33/38
摘要： The invention relates to a process for the preparation of crystalline sodium silicates having a sheet structure and high .delta. phase content from water glass, which has been prepared predominantly hydrothermally, by dehydration of the water glass and subsequent crystallization at elevated temperature, wherein the water glass is a mixture of water glass prepared hydrothermally and tank furnace water glass, and also to its use.
摘要翻译：本发明涉及通过水玻璃的脱水和随后的高温结晶，制备具有主要水热制备的片状结构和高δ相含量的结晶硅酸钠的方法，其中水玻璃是水热玻璃和水箱玻璃水玻璃的混合物，也是它的用途。

26. 发明授权

US5520860A Process for preparing granular sodium silicates 失效
标题翻译：制备颗粒状硅酸钠的方法
公开(公告)号：US5520860A
公开(公告)日：1996-05-28
申请号：US297227
申请日：1994-08-29
申请人： Alexander Tapper , Gunther Schimmel , Hans-Peter Rieck , Gerhard Noltner
发明人： Alexander Tapper , Gunther Schimmel , Hans-Peter Rieck , Gerhard Noltner
IPC分类号： B01J2/22 , B01J2/28 , C01B33/32 , C11D3/08 , C11D3/12 , C11D11/00 , C11D17/00 , B29B9/16
CPC分类号： C01B33/325 , B01J2/22 , C11D11/0088 , C11D17/0039 , C11D3/08 , C11D3/1273
摘要： To prepare a compacted, granular sodium silicate having an SiO.sub.2 /Na.sub.2 O molar ratio of 1.7:1 to 4.1:1, sodium silicate having a median particle diameter of
摘要翻译：为了制备SiO 2 / Na 2 O摩尔比为1.7:1至4.1:1的压实的粒状硅酸钠，首先将中值粒径<500μm的硅酸钠与增加其硬度的材料混合，然后再转化成压制通过压实，粉碎和筛选，粒径为0.1至5mm的颗粒。

27. 发明授权

US5236682A Process for producing crystalline sodium silicates having a layered structure 失效
标题翻译：具有层状结构的结晶硅酸钠的制造方法
公开(公告)号：US5236682A
公开(公告)日：1993-08-17
申请号：US846758
申请日：1992-03-05
申请人： Gunther Schimmel , Michael Kotzian , Herbert Panter , Alexander Tapper
发明人： Gunther Schimmel , Michael Kotzian , Herbert Panter , Alexander Tapper
IPC分类号： C01B33/32 , C01B33/38
CPC分类号： C01B33/325 , C01B33/32 , C01B33/38
摘要： For producing crystalline sodium silicates having a layer structure, an SiO.sub.2 /Na.sub.2 O molar ratio of (1.9 to 2.1):1 and a water content of less than 0.3% by weight from a waterglass solution containing at least 20% by weight of solids, the waterglass solution is obtained by reacting quartz sand with sodium hydroxide solution at an SiO.sub.2 /Na.sub.2 O molar ratio of (2.0 to 2.3):1 at temperatures of 180.degree. to 240.degree. C. and pressures of 10 to 30 bar. This waterglass solution is treated in a spray-drying zone with hot air at 200.degree. to 300.degree. C. for a residence time of 10 to 25 seconds and at a temperature of the exit gas leaving the spray-drying zone of 90.degree. to 130.degree. C., to form a pulverulent amorphous sodium silicate having a water content (determined as the loss on ignition at 700.degree. C.) of 15 to 23% by weight and a bulk density of more than 300 g/l. The pulverulent, amorphous, water-containing sodium silicate is introduced into an obliquely arranged rotary kiln fitted with devices for moving solids and treated therein with flue gas in countercurrent at temperatures from more than 500.degree. up to 850.degree. C. for 1 to 60 minutes to form crystalline soidium silicate. The rotary kiln is here insulated in such a way that its outside wall temperature is less than 60.degree. C. Finally, the crystalline sodium silicate emerging from the rotary kiln is comminuted by means of a mechanical crusher to grain sizes of 0.1 to 12 mm.
摘要翻译：为了生产具有层状结构的结晶硅酸钠，SiO 2 / Na 2 O摩尔比为（1.9-2.1）：1，水含量小于含有至少20重量％固体的水玻璃溶液的0.3重量％通过使SiO 2 / Na 2 O摩尔比为（2.0〜2.3）：1的石英砂与氢氧化钠溶液在180〜240℃的温度和10〜30巴的压力下反应获得水玻璃溶液。该水玻璃溶液在200℃至300℃的热空气的喷雾干燥区中处理，停留时间为10至25秒，并且在离开喷雾干燥区的出口气体的温度为90°至130° 以形成具有15至23重量％的含水量（以700℃测定的点火损失确定）的粉末状无定形硅酸钠，堆积密度大于300g / l。将粉末状，无定形含水硅酸钠引入倾斜布置的回转窑中，该回转窑装有固体移动装置，并在大于500℃至850℃的温度下逆流处理烟气1至60分钟以形成硅酸的结晶硅酸盐。回转窑的外壁温度低于60℃，最后将回转窑中出现的结晶硅酸钠粉碎成0.1〜12mm的粒度粉碎机。

28. 发明授权

US5211930A Process for the preparation of crystalline sodium silicates having a sheet structure 失效
标题翻译：制备具有片状结构的结晶硅酸钠的方法
公开(公告)号：US5211930A
公开(公告)日：1993-05-18
申请号：US693782
申请日：1991-04-26
申请人： Gunther Schimmel , Reinhard Gradl , Martin Schott
发明人： Gunther Schimmel , Reinhard Gradl , Martin Schott
IPC分类号： C01B33/38
CPC分类号： C01B33/38
摘要： For the preparation of crystalline sodium silicates having a sheet structure and an SiO.sub.2 /Na.sub.2 O molar ratio of 1.9:1 to 3.5:1 from waterglass solutions having a solids content of 20 to 65% by weight, the waterglass solutions are first treated in a spray-drying zone. This gives a pulverulent amorphous sodium silicate having a maximum ignition loss of 20% by weight, while the waste gas leaving the spray-drying zone is at a temperature of at least 140.degree. C. Thereafter, the spray-dried sodium silicate is heated in an ignition zone containing an agitated solid bed at temperatures of 500.degree. to 800.degree. C. for 1 to 60 minutes in the presence of at least 10% by weight of recycled material. This recycled material was obtained by mechanical comminution of crystalline sodium silicate discharged from the ignition zone.
摘要翻译：对于具有固体含量为20至65重量％的水玻璃溶液，具有片状结构和SiO 2 / Na 2 O摩尔比为1.9:1至3.5:1的结晶硅酸钠的制备，先将水玻璃溶液以喷雾干燥区这产生了具有20重量％的最大灼烧损失的粉状无定形硅酸钠，而离开喷雾干燥区的废气处于至少140℃的温度。此后，将喷雾干燥的硅酸钠加热在至少10重量％的再循环材料的存在下，在500℃至800℃的温度下含有搅拌的固体床1分钟至60分钟的点火区域。该回收材料通过从点火区域排出的结晶硅酸钠的机械粉碎获得。

29. 发明授权

US5124137A Process for the preparation of alkali metal phosphate solutions 失效
标题翻译：制备碱金属磷酸盐溶液的方法
公开(公告)号：US5124137A
公开(公告)日：1992-06-23
申请号：US676862
申请日：1991-03-28
申请人： Gunther Schimmel , Thomas Staffel , Reinhard Gradl
发明人： Gunther Schimmel , Thomas Staffel , Reinhard Gradl
IPC分类号： C01B25/30
CPC分类号： C01B25/308
摘要： Alkali metal phosphate solutions having a fluorine content of less than 20 ppm, based on P.sub.2 O.sub.5, are prepared by first digesting crude phosphate using sulfuric acid, and separating the calcium sulfate from the crude phosphoric acid. An alkali metal compound is then added to the crude phosphoric acid, and the precipitated solid is filtered off. The prepurified crude phosphoric acid is neutralized to a pH of at least 7, and the solid produced during this operation is separated off. The resultant alkali metal phosphate solutions having a P.sub.2 O.sub.5 content of from 10 to 30% by weight are adjusted to a pH of between 4.8 and 6.0 using phosphoric acid. The solutions are heated to from 60.degree. to 120.degree. C., and from 1 to 6% by weight, based on the weight of the solution, of an alkaline earth metal oxygen compound are added to the alkali metal phosphate solutions with stirring. Finally, the precipitated solid is filtered off from the alkali metal phosphate solutions after a residence time of from 0.5 to 4 hours.
摘要翻译：通过首先使用硫酸消化粗磷酸酯，并从粗磷酸中分离硫酸钙，制备基于P 2 O 5的氟含量小于20ppm的碱金属磷酸盐溶液。然后向粗磷酸中加入碱金属化合物，滤出沉淀的固体。将预纯化的粗磷酸中和至至少7的pH，并且在该操作期间产生的固体被分离出来。使用磷酸将所得的具有10-30重量％的P2O5含量的碱金属磷酸盐溶液调节至4.8至6.0的pH。在搅拌下将溶液加热至60〜120℃，以溶液重量为1〜6重量％的碱土金属氧化合物加入到碱金属磷酸盐溶液中。最后，在0.5-4小时的停留时间后，将沉淀的固体从碱金属磷酸盐溶液中滤出。

30. 发明授权

US5078895A Washing agent with storage-stabilized bleach system 失效
标题翻译：洗涤剂与储存稳定的漂白系统
公开(公告)号：US5078895A
公开(公告)日：1992-01-07
申请号：US627884
申请日：1990-12-13
申请人： Franz-Josef Dany , Werner Gohla , Gunther Schimmel , Hans P. Rieck , Ingrid Czeslik
发明人： Franz-Josef Dany , Werner Gohla , Gunther Schimmel , Hans P. Rieck , Ingrid Czeslik
IPC分类号： C11D3/395 , C11D3/08 , C11D3/12 , C11D3/39 , D06L1/12 , D06L3/02
CPC分类号： C11D3/1273 , C11D3/3917
摘要： The invention relates to a washing agent with a storage-stabilized bleach system and 2 to 20% by weight of detergents and conventional washing auxiliaries, including fillers, the washing agent containing 10 to 50% by weight of a crystalline layered silicate as a builder as well as 1 to 5% by weight of tetraacetylethylenediamine (TAED) and a bleach, the quantity of bleach being such that 0.5 to 4% by weight of washing-active oxygen (AVOX) is present in the washing agent.
摘要翻译：本发明涉及具有储存稳定的漂白系统和2至20重量％的洗涤剂和常规洗涤助剂（包括填料）的洗涤剂，洗涤剂含有10至50重量％的作为助洗剂的结晶层状硅酸盐，以及1-5重量％的四乙酰乙二胺（TAED）和漂白剂，洗涤剂中存在漂白剂的量为0.5-4重量％的洗涤活性氧（AVOX）。

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