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21. 发明授权

US06579643B1 Separator having a plasticizer coating for use in electrochemical cell devices 失效
标题翻译：具有用于电化学电池器件的增塑剂涂层的分离器
公开(公告)号：US06579643B1
公开(公告)日：2003-06-17
申请号：US09447772
申请日：1999-11-23
申请人： Antoni S. Gozdz
发明人： Antoni S. Gozdz
IPC分类号： H01M216
CPC分类号： H01G9/155 , H01G9/02 , H01M2/1653 , H01M4/02 , Y02E60/13
摘要： A separator for use in laminated multi-layer electrochemical cell device structures. The devices comprise positive and negative electrode layer members of polymeric matrix composition having the microporous polyolefin membrane separator member interposed therebetween wherein the separator membrane includes a polymer coating layer. The separator is treated to provide a deposited coating of a primary plasticizer for the polymer coating layer. The device electrode and separator members are then assembled and laminated at a compressive force and temperature at which the plasticizer film softens the polymer coating of the separator member sufficiently to establish a strong interfacial bond with the matrix polymers of the electrode members and thereby form a laminated unitary cell structure. In another embodiment, the primary plasticizer comprises a component of the electrode polymeric matrix compositions. In either embodiment, the plasticizer subsequently volatilizes from the structure to further strengthen the interfacial bond, yet its temporary presence in the interfacial region of the multi-layer cell structure enables lamination of the cell members at a temperature below the pore-collapse temperature of the separator membrane, thereby preserving the thermal shut-down protection feature of the microporous separator.
摘要翻译：用于层压多层电化学电池器件结构的隔板。这些装置包括聚合物基质组合物的正电极层和负极层构件，其中介于其间的微孔聚烯烃隔膜构件，其中隔膜包括聚合物涂层。处理分离器以提供用于聚合物涂层的初级增塑剂的沉积涂层。然后将装置电极和分隔件组件以压缩力和温度层压，在该压缩力和温度下，增塑膜充分地软化隔板构件的聚合物涂层，以与电极构件的基质聚合物形成强界面结合，从而形成层压单体电池结构。在另一个实施方案中，主增塑剂包含电极聚合物基质组合物的组分。在任一实施方案中，增塑剂随后从该结构挥发，以进一步加强界面结合，但其暂时存在于多层电池结构的界面区域中，可使电池构件在低于隔膜，从而保留微孔隔膜的热关闭保护功能。

22. 发明授权

US06413667B1 Flat, bonded-electrode rechargeable electrochemical cell and method of making same 有权
标题翻译：扁平键合电极可充电电化学电池及其制造方法
公开(公告)号：US06413667B1
公开(公告)日：2002-07-02
申请号：US09538574
申请日：2000-03-29
申请人： Antoni S. Gozdz
发明人： Antoni S. Gozdz
IPC分类号： H01M1050
CPC分类号： H01M10/38 , B29C65/4895 , B29C66/1122 , B29C66/45 , B29C66/71 , B29C66/723 , B29C66/72321 , B29C66/727 , B29L2009/00 , B29L2031/3468 , B32B7/10 , B32B37/00 , B32B2305/026 , B32B2457/00 , H01M2/1653 , H01M4/13 , H01M4/139 , H01M4/622 , H01M10/04 , H01M10/0525 , H01M10/0565 , H01M10/0585 , Y02E60/122 , Y02P70/54 , B29K2033/20 , B29K2033/12 , B29K2027/16 , B29K2027/08 , B29K2027/06
摘要： A Li-ion battery cell comprising a polymeric matrix positive electrode layer member, a polymeric matrix negative electrode layer member, and an interposed microporous polyolefin separator layer member is laminated into a unitary, flexible cell structure by means of heat and pressure without necessity of applied interlayer adhesive. A volatile vehicle solution of a primary plasticizer for the electrode member polymer matrix is applied to the microporous separator member where it is absorbed into the porous structure. Evaporation of the volatile vehicle solvent deposits the plasticizer upon and within the pores of the separator member. During the lamination operation the plasticizer is forced into contact with the electrode member polymer where it softens the polymer into a thermoplastic adhesive in the region of the electrode/separator interface, thereby enabling the electrode polymer alone to form a strong bond to the separator upon cooling.
摘要翻译：包含聚合物基质正电极层构件，聚合物基质负极层构件和插入的微孔聚烯烃隔离层构件的锂离子电池单元通过热和压力层压到单一的柔性电池结构中，而不需要施加夹层粘合剂。将用于电极构件聚合物基质的主要增塑剂的挥发性载体溶液施加到微孔隔板构件，其中它被吸收到多孔结构中。挥发性载体溶剂的蒸发将增塑剂沉积在分离器构件的孔隙中和内部。在层压操作期间，增塑剂被迫与电极构件聚合物接触，其中它将聚合物软化成电极/分离器界面区域中的热塑性粘合剂，从而使电极聚合物单独在冷却时与隔板形成牢固的结合。

23. 发明授权

US5554459A Material and method for low internal resistance LI-ion battery 失效
标题翻译：低内阻锂离子电池的材料和方法
公开(公告)号：US5554459A
公开(公告)日：1996-09-10
申请号：US589944
申请日：1996-01-23
申请人： Antoni S. Gozdz , Paul C. Warren
发明人： Antoni S. Gozdz , Paul C. Warren
IPC分类号： H01M4/58 , H01M4/62 , H01M4/66 , H01M4/74 , H01M4/64
CPC分类号： H01M4/623 , H01M4/66 , H01M4/667 , H01M2300/0025 , H01M4/587 , H01M4/625 , H01M4/661 , H01M4/74 , Y10T29/49115
摘要： An electrically-conductive collector element (23) in a polymeric laminate lithium ion rechargeable battery is cleaned of surface oxides and coated with an adherent conductive polymer film (34) which is substantially inert to battery electrolyte components and prevents recurrent formation of insulative collector surface oxides, thereby maintaining effective electrode/collector electrical conductivity and significantly reducing internal battery resistance.
摘要翻译：在聚合层压锂离子可再充电电池中的导电集电器元件（23）被清洁表面氧化物并涂覆有对电池电解质组分基本上惰性的粘附导电聚合物膜（34），并防止绝缘集电体表面氧化物的复发形成从而保持有效的电极/集电极导电性并显着降低内部电池电阻。

24. 发明授权

US5540741A Lithium secondary battery extraction method 失效
标题翻译：锂二次电池提取方法
公开(公告)号：US5540741A
公开(公告)日：1996-07-30
申请号：US373143
申请日：1995-01-17
申请人： Antoni S. Gozdz , Caroline N. Schmutz , Jean-Marie Tarascon , Paul C. Warren
发明人： Antoni S. Gozdz , Caroline N. Schmutz , Jean-Marie Tarascon , Paul C. Warren
IPC分类号： C08J9/28 , H01M2/16 , H01M6/18 , H01M6/32 , H01M10/40 , H01M10/38
CPC分类号： C08J9/28 , H01M10/0431 , H01M10/05 , H01M10/052 , H01M10/0565 , H01M2/1653 , H01M6/181 , H01M6/32 , H01M6/46 , C08J2327/16 , H01M2300/0085 , H01M6/30 , H01M6/42 , Y02P70/54 , Y10T29/49115
摘要： The present invention is a method of fabricating a rechargeable battery structure by extracting plasticizer from plastic battery preforms to render them insensitive to water while maintaining the homogeneous characteristics of the plastic materials to allow subsequent activation of the batteries through the introduction of an electrolyte solution. These battery preforms need not be maintained under anhydrous conditions and can be activated immediately preceding use thereof.
摘要翻译：本发明是一种通过从塑料电池预制件中提取增塑剂来制造可再充电电池结构的方法，以使它们对水不敏感，同时保持塑料材料的均匀特性，从而允许通过引入电解质溶液随后激活电池。这些电池预制件不需要保持在无水条件下，并且可以在其使用之前立即被激活。

25. 发明授权

US5460904A Electrolyte activatable lithium-ion rechargeable battery cell 失效
标题翻译：电解液可激活的锂离子可充电电池
公开(公告)号：US5460904A
公开(公告)日：1995-10-24
申请号：US160018
申请日：1993-11-30
申请人： Antoni S. Gozdz , Jean-Marie Tarascon , Paul C. Warren
发明人： Antoni S. Gozdz , Jean-Marie Tarascon , Paul C. Warren
IPC分类号： C08J9/26 , C08J9/28 , H01M2/02 , H01M2/16 , H01M4/64 , H01M6/18 , H01M6/30 , H01M6/32 , H01M6/42 , H01M6/46 , H01M10/04 , H01M10/05 , H01M10/052 , H01M10/0565
CPC分类号： H01M10/05 , C08J9/28 , H01M10/0431 , H01M10/052 , H01M10/0565 , H01M2/1653 , H01M6/181 , H01M6/32 , H01M6/46 , C08J2327/16 , H01M2300/0085 , H01M6/30 , H01M6/42 , Y02P70/54 , Y10T29/4911 , Y10T29/49114
摘要： Li-ion rechargeable battery cell electrode and electrolyte/separator elements formulated as layers of plasticized polymeric matrix compositions are laminated to form a unitary battery cell structure. The structure may be stored indefinitely, since it is essentially devoid of electrolyte solution which typically comprises a moisture-sensitive lithium salt. Prior to the battery's being put into service, the plasticizer of the polymeric composition is removed by leaching with a selective solvent and is replaced with a lithium salt electrolyte solution by simple imbibition. The battery thus activated may then be charged and recharged in the usual manner.
摘要翻译：配制为增塑聚合物基质组合物层的锂离子可再充电电池单元电极和电解质/隔膜元件被层压以形成单体电池单元结构。结构可以无限期地存储，因为它基本上不含通常包含湿敏锂盐的电解质溶液。在电池投入使用之前，通过用选择性溶剂浸出除去聚合物组合物的增塑剂，并通过简单的吸入被锂盐电解质溶液代替。然后由此激活的电池可以以通常的方式进行充电和再充电。

26. 发明申请

US20140291886A1 THREE DIMENSIONAL PRINTING 审中-公开
标题翻译：三维打印
公开(公告)号：US20140291886A1
公开(公告)日：2014-10-02
申请号：US14222318
申请日：2014-03-21
申请人： Gregory Thomas Mark , Antoni S. Gozdz
发明人： Gregory Thomas Mark , Antoni S. Gozdz
IPC分类号： B29C47/00
CPC分类号： B29C64/106 , B29B15/14 , B29C48/05 , B29C48/154 , B29C48/2528 , B29C48/92 , B29C64/118 , B29C69/001 , B29C70/384 , B29C2948/92076 , B29C2948/92571 , B29C2948/92704 , B29C2948/92904 , B29K2101/12 , B29K2105/08 , B33Y10/00 , B33Y30/00 , B33Y40/00 , B33Y70/00
摘要： Various embodiments related to three dimensional printers, and reinforced filaments, and their methods of use are described. In one embodiment, a void free reinforced filament is fed into an extrusion nozzle. The reinforced filament includes a core, which may be continuous or semi-continuous, and a matrix material surrounding the core. The reinforced filament is heated to a temperature greater than a melting temperature of the matrix material and less than a melting temperature of the core prior to extruding the filament from the extrusion nozzle.
摘要翻译：描述了与三维打印机和增强长丝相关的各种实施例及其使用方法。在一个实施例中，将无空隙的增强长丝进料到挤出喷嘴中。增强长丝包括可以是连续或半连续的芯和围绕芯的基体材料。在从挤出喷嘴挤出细丝之前，将增强的长丝加热到大于基体材料的熔融温度的温度并小于芯的熔化温度。

27. 发明授权

US08617745B2 Lithium secondary cell with high charge and discharge rate capability and low impedance growth 有权
标题翻译：具有高充放电能力和低阻抗增长的锂二次电池
公开(公告)号：US08617745B2
公开(公告)日：2013-12-31
申请号：US11518974
申请日：2006-09-11
申请人： Antoni S. Gozdz , Andrew C. Chu , Ricardo Fulop , Yet-Ming Chiang , Gilbert N. Riley, Jr. , Roger Lin
发明人： Antoni S. Gozdz , Andrew C. Chu , Ricardo Fulop , Yet-Ming Chiang , Gilbert N. Riley, Jr. , Roger Lin
IPC分类号： H01M4/133 , H01M4/136
CPC分类号： H01M10/0569 , H01M4/133 , H01M4/136 , H01M4/5825 , H01M10/0525 , Y02E60/122 , Y02T10/7011
摘要： A lithium-ion battery is provided that has a fast charge and discharge rate capability and low rate of capacity fade during high rate cycling. The battery can exhibit low impedance growth and other properties allowing for its use in hybrid electric vehicle applications and other applications where high power and long battery life are important features.
摘要翻译：提供了一种锂离子电池，具有快速的充放电速率能力和高速率循环期间低容量的褪色率。电池可以表现出低阻抗增长和其他性能，允许其用于混合电动车辆应用和其中高功率和长电池寿命是重要特征的其它应用。

28. 发明授权

US08323832B2 Nanoscale ion storage materials 有权
标题翻译：纳米级离子储存材料
公开(公告)号：US08323832B2
公开(公告)日：2012-12-04
申请号：US11672931
申请日：2007-02-08
申请人： Yet-Ming Chiang , Antoni S. Gozdz , Martin W. Payne
发明人： Yet-Ming Chiang , Antoni S. Gozdz , Martin W. Payne
IPC分类号： H01M4/58 , H01M10/44 , C01B25/45
CPC分类号： C01B25/45 , H01M4/136 , H01M4/5825 , H01M10/0525 , H01M2004/021 , Y02E60/122 , Y02T10/7011
摘要： Nanoscale ion storage materials are provided that exhibit unique properties measurably distinct from their larger scale counterparts. For example, the nanoscale materials can exhibit increased electronic conductivity, improved electromechanical stability, increased rate of intercalation, and/or an extended range of solid solution. Useful nanoscale materials include alkaline transition metal phosphates, such as LiMPO4, where M is one or more transition metals. The nanoscale ion storage materials are useful for producing devices such as high energy and high power storage batteries, battery-capacitor hybrid devices, and high rate electrochromic devices.
摘要翻译：提供纳米级离子存储材料，其显示出与其较大规模的对应物可测量不同的独特性质。例如，纳米尺度材料可以表现出增加的电子导电性，改善的机电稳定性，增加的嵌入速率和/或扩展的固溶体范围。有用的纳米尺度材料包括碱金属过渡金属磷酸盐，例如LiMPO4，其中M是一种或多种过渡金属。纳米级离子存储材料可用于制造诸如高能量和高功率蓄电池，电池 - 电容器混合器件和高速率电致变色器件的器件。

29. 发明授权

US08088512B2 Self organizing battery structure method 有权
标题翻译：自组织电池结构方法
公开(公告)号：US08088512B2
公开(公告)日：2012-01-03
申请号：US12140058
申请日：2008-06-16
申请人： Antoni S. Gozdz , Richard K. Holman , Andrew L. Loxley , Ronnie Wilkins
发明人： Antoni S. Gozdz , Richard K. Holman , Andrew L. Loxley , Ronnie Wilkins
IPC分类号： H01M10/02 , H01M4/04
CPC分类号： H01M10/0565 , H01G11/06 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/405 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/587 , H01M10/0525 , Y02E60/13
摘要： An electrochemical device includes a first electrode in electrical communication with a first current collector, a second electrode in electrical communication with a second current collector and a crosslinked solid polymer in contact with the first and second electrodes. At least one of the first and second electrodes includes a network of electrically connected particles comprising an electroactive material, and the particles of one electrode exert a repelling force on the other electrode when the first and second electrodes are combined with an uncrosslinked precursor to the solid polymer.
摘要翻译：电化学装置包括与第一集电器电连通的第一电极，与第二集电器电连通的第二电极和与第一和第二电极接触的交联固体聚合物。第一和第二电极中的至少一个包括包含电活性材料的电连接的颗粒的网络，并且当第一和第二电极与未交联的前体与固体组合时，一个电极的颗粒在另一个电极上施加排斥力聚合物。

30. 发明授权

US08057936B2 Nanoscale ion storage materials including co-existing phases or solid solutions 有权
公开(公告)号：US08057936B2
公开(公告)日：2011-11-15
申请号：US13086883
申请日：2011-04-14
申请人： Yet-Ming Chiang , Antoni S. Gozdz , Martin W. Payne
发明人： Yet-Ming Chiang , Antoni S. Gozdz , Martin W. Payne
IPC分类号： H01M4/58
CPC分类号： C01B25/45 , H01M4/136 , H01M4/5825 , H01M10/0525 , H01M2004/021 , Y02E60/122 , Y02P70/54
摘要： Nanoscale ion storage materials are provided that exhibit unique properties measurably distinct from their larger scale counterparts. For example, the nanoscale materials can exhibit increased electronic conductivity, improved electromechanical stability, increased rate of intercalation, and/or an extended range of solid solution. Useful nanoscale materials include alkaline transition metal phosphates, such as LiMPO4, where M is one or more transition metals. The nanoscale ion storage materials are useful for producing devices such as high energy and high power storage batteries, battery-capacitor hybrid devices, and high rate electrochromic devices.

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