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    • 22. 发明授权
    • Method for the control of excessive corrosion in phosphoric acid circuits
    • 控制磷酸回路过度腐蚀的方法
    • US4367197A
    • 1983-01-04
    • US238061
    • 1981-03-02
    • Gary L. LongRoger B. Humberger
    • Gary L. LongRoger B. Humberger
    • C01B25/225C01B25/226C23F11/04
    • C01B25/226C01B25/225C23F11/04
    • Methods for control of excessive corrosion in wet process phosphoric circuits are effected by oxidation of reduced ion species in the acid with maintenance of EMF value of the acid above about 190 millivolts (S.C.E. reference) through the digestion circuit. Supplementary monitoring is by a ceric red-ox titration procedure. In one embodied form, the present invention is utilized to control corrosion in a phosphoric acid plant digestion system (and subsequent processing equipment) operating by a dihydrate (gypsum) process even when such a process employs a calcined western U.S. phosphate ore feed from a relatively highly carbonaceous ore. The invention is also applicable for treating wet process phosphoric acid in phosphoric acid plants having a digester system operating by a hemihydrate process. In a presently preferred embodiment, additions of manganese dioxide to a primary digester in a sufficient amount effective to achieve an EMF value over about 190 millivolts will significantly control the occurrence of excessive corrosion in phosphoric acid circuits. In yet another preferred embodiment, an oxygen autoclave oxidation is used to oxidize the reduced ion species present in the acid to inhibit corrosion.
    • 用于控制湿法磷酸回路中过度腐蚀的方法是通过在酸中氧化还原的离子物质来实现的,其中通过消化回路维持高于约190毫伏(S.C.E.参考)的酸的EMF值。 补充监测是通过氧化铈滴定法。 在一个实施形式中,本发明用于控制在二水合物(石膏)方法中操作的磷酸设备消化系统(和随后的加工设备)中的腐蚀,即使这种方法使用来自相对的 高含碳矿石。 本发明也适用于在具有通过半水合法处理的蒸煮器系统的磷酸设备中处理湿法磷酸。 在目前优选的实施方案中,以足以实现大约190毫伏的EMF值的足够量的一次蒸煮器添加二氧化锰将显着控制磷酸回路中过度腐蚀的发生。 在另一个优选的实施方案中,使用氧气高压釜氧化来氧化存在于酸中的还原离子种类以抑制腐蚀。
    • 27. 发明授权
    • Electroporation ablation apparatus, system, and method
    • 电穿孔消融装置,系统及方法
    • US08449538B2
    • 2013-05-28
    • US12694452
    • 2010-01-27
    • Gary L. Long
    • Gary L. Long
    • A61B18/14
    • A61B18/1492A61B1/018A61B1/04A61B1/06A61B18/1482A61B2018/00482A61B2018/00577A61B2018/00613A61N1/306A61N1/327
    • A surgical instrument, such as an endoscopic or laparoscopic instrument, includes an ablation device. The ablation device includes an elongate relatively flexible member having a proximal end and a distal end, the flexible member includes at least a first working channel. A first and second electrode extends from a working channel at the distal end of the flexible member. The first and second electrodes are adapted to be endoscopically located in a tissue treatment region. The first and second electrodes are adapted to couple to an electrical waveform generator to receive an irreversible electroporation electrical waveform sufficient to ablate tissue located between the first and second electrodes. The waveform parameters of the irreversible electroporation electrical waveform are determined based on image information received from the tissue treatment region.
    • 诸如内窥镜或腹腔镜仪器的手术器械包括消融装置。 消融装置包括具有近端和远端的细长相对柔性的构件,所述柔性构件至少包括第一工作通道。 第一和第二电极从柔性构件的远端处的工作通道延伸。 第一和第二电极适于内窥镜地位于组织治疗区域中。 第一和第二电极适于耦合到电波形发生器以接收足以消融位于第一和第二电极之间的组织的不可逆电穿孔电波形。 基于从组织处理区域接收的图像信息确定不可逆电穿孔电波形的波形参数。
    • 28. 发明授权
    • Electroporation ablation apparatus, system, and method
    • 电穿孔消融装置,系统及方法
    • US08425505B2
    • 2013-04-23
    • US13218221
    • 2011-08-25
    • Gary L. Long
    • Gary L. Long
    • A61B18/04A61B1/00
    • A61B18/1492A61B1/018A61B1/04A61B1/06A61B18/1482A61B2018/00482A61B2018/00577A61B2018/00613A61N1/306A61N1/327
    • A surgical instrument, such as an endoscopic or laparoscopic instrument, includes an ablation device. The ablation device includes an elongate member having first and second channels. First and second probes are disposed within the respective first and second channels. The first and second probes each define a central axis. The first and second probes each have substantially straight distal ends protruding from the distal ends of the respective first and second channels. The substantially straight distal ends define an outer surface. First and second electrodes are attached to a portion of the outer surface of the substantially straight distal ends of the respective first and second probes. The first and second electrodes are positioned in juxtaposed relationship with the central axis of the first and second probes. A distance between the first and second electrodes is adjustable by rotating at least one of the first and second probes about the respective central axis of the at least one of the first and second probes.
    • 诸如内窥镜或腹腔镜仪器的手术器械包括消融装置。 消融装置包括具有第一和第二通道的细长构件。 第一和第二探针设置在相应的第一和第二通道内。 第一和第二探针均限定中心轴。 第一和第二探头各自具有从相应的第一和第二通道的远端突出的基本上直的远端。 基本上直的远端限定外表面。 第一和第二电极附接到相应的第一和第二探针的基本上直的远端的外表面的一部分。 第一和第二电极与第一和第二探针的中心轴线并置放置。 第一和第二电极之间的距离可通过使第一和第二探针中的至少一个围绕第一和第二探针中的至少一个探针的相应中心轴旋转来调节。