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21. 发明申请

US20110265689A1 HIGH-GLOSS MULTILAYER EFFECT PIGMENTS HAVING A CHROMATIC INTERFERENCE COLOR AND A NARROW SIZE DISTRIBUTION, AND METHOD FOR THE PRODUCTION THEREOF 有权
标题翻译：具有色度干涉色和高分辨率分布的高光泽多层效应色素及其生产方法
公开(公告)号：US20110265689A1
公开(公告)日：2011-11-03
申请号：US13143378
申请日：2010-08-09
申请人： Dirk Schumacher , Michael Grüner , Günter Kaupp
发明人： Dirk Schumacher , Michael Grüner , Günter Kaupp
IPC分类号： C04B14/20 , B05D5/06 , C04B14/04
CPC分类号： C09C1/0024 , C01P2004/51 , C01P2006/65 , C09C1/003 , C09C1/0039 , C09C2200/1004 , C09C2200/102 , C09C2200/301 , C09C2200/302 , C09C2200/303 , C09C2200/304 , C09C2200/401 , C09C2200/407 , C09C2200/408
摘要： Multilayer pearlescent pigments comprising platelet-shaped transparent substrates provided with an optically active coating, where the optically active coating includes at leasta) an absorbing high-index layer A having a refractive index n≧1.8 b) a low-index layer B having a refractive index n
摘要翻译：多层珠光颜料包括设置有光学活性涂层的片状透明基板，其中光学活性涂层至少包括a）具有折射率n≥1.8b的吸收性高折射率层A）低折射率层B，具有折射率n <1.8c）折射率n≥1.8的高折射率层C，以及d）任选的至少一个外保护层D，其中多层珠光颜料具有体积平均尺寸分布的累积频率分布功能，其指数为D10，D50，D90，跨度和Dgr; D在0.7-1.4的范围内，跨度＆Dgr; D根据公式（I）＆Dgr计算; D =（D90-D10）/ D50 一世）。本发明进一步涉及一种生产这些多层珠光颜料的方法，以及它们的用途。

22. 发明授权

US08980976B2 Pearlescent pigments coated with mixed inorganic/organic layers and method for the production thereof 有权
标题翻译：涂有混合无机/有机层的珠光颜料及其制备方法
公开(公告)号：US08980976B2
公开(公告)日：2015-03-17
申请号：US12280398
申请日：2007-02-22
申请人： Frank Henglein , Stefan Trummer , Ulrich Schmidt , Günter Kaupp , Peter Krüger
发明人： Frank Henglein , Stefan Trummer , Ulrich Schmidt , Günter Kaupp , Peter Krüger
IPC分类号： C08K9/00 , C08K3/08 , C09B67/00 , C09C1/00
CPC分类号： C09C1/0021 , C01P2006/66 , C09B67/0098 , C09C1/0015 , C09C1/0024 , C09C2200/1004 , C09C2200/102 , C09C2200/301 , C09C2200/307 , C09C2200/409 , C09C2220/10
摘要： The invention relates to platelet-shaped pearlescent pigments that are coated with at least one mixed inorganic/organic layer for improving their application properties, and of these, particularly their mechanical properties, and to methods for the production thereof and to the use thereof. The said mixed inorganic/organic layer comprises at least one at least partially crosslinked inorganic metal-oxide component and an organic component. The organic component is at least one organic oligomer and/or polymer, which is covalently bonded, at least in part, to the inorganic network via network formers, wherein the coating comprises at least one mixed inorganic/organic layer, which mixed layer comprises, at least in part, an inorganic network having one or more inorganic oxide component(s) and at least one organic component, the organic component being, at least in part, an organic oligomer and/or polymer covalently bonded, at least in part, to the inorganic network via one or more organic network formers.The invention also relates to a method for the production of such pearlescent pigments.
摘要翻译：本发明涉及涂覆有至少一种混合无机/有机层以提高它们的应用性能，特别是其机械性能的片状珠光颜料及其生产方法及其应用。所述混合无机/有机层包含至少一种至少部分交联的无机金属氧化物组分和有机组分。有机组分是至少一种有机低聚物和/或聚合物，其至少部分地通过网络成型体与无机网络共价键合，其中涂层包含至少一种混合的无机/有机层，该混合层包含，至少部分是具有一种或多种无机氧化物组分和至少一种有机组分的无机网络，所述有机组分至少部分是至少部分共价键合的有机低聚物和/或聚合物，通过一个或多个有机网络建立者到无机网络。本发明还涉及一种生产这种珠光颜料的方法。

23. 发明申请

US20090249979A1 PEARLESCENT PIGMENTS HAVING A SECONDARY COATING COMPRISING ALPHA-SILANES AND METHOD FOR THE PRODUCTION THEREOF 失效
标题翻译：具有包含ALPHA-硅烷的二次涂层的珍珠粉及其生产方法
公开(公告)号：US20090249979A1
公开(公告)日：2009-10-08
申请号：US12280378
申请日：2007-02-23
申请人： Günter Kaupp , Ulrich Schmidt
发明人： Günter Kaupp , Ulrich Schmidt
IPC分类号： C09D5/29 , B05D7/00
CPC分类号： C09C1/0015 , C01P2004/84 , C09C2200/401 , C09C2200/407 , C09C2200/408 , C09C2200/409 , C09D5/36 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T428/2996
摘要： The invention relates to a pearlescent pigment comprising a metal oxide-containing, platelet-shaped substrate and having a first and a second protective layer, wherein the metal oxide has a refractive index greater than 1.8, and in which the first protective layer comprises cerium oxide and/or hydrated cerium oxide and/or cerium hydroxide, the second protective layer consists substantially, preferably completely, of SiO2, wherein the second protective layer is disposed on top of the first protective layer, and between the first and second protective layers there can be disposed metal oxide layers which differ from cerium oxide and/or hydrated cerium oxide and/or cerium hydroxide and SiO2, wherein the second protective layer has an organochemical aftercoat and the organochemical aftercoat comprises at least one silane bonded to the second protective layer by means of at least one oxygen atom, said α-silane having the formula —O(4−n−m)—Si(—R1)m(—CH2—Y)n (I), in which 1≦n+m≦3; m=0 to 2; n=1 to 3 and R1 is a hydrogen atom or an Si—C-bonded C1-C20-hydrocarbon radical or a C1-C15-hydrocarbonoxy radical, in which in each case one or more methylene units not adjacent to one another can be replaced by the groups —O—, —CO—, —COO—, —OCO—, or —OCOO—, —S—, or —NRx— and in which one or more methine units not adjacent to one another can be replaced by the groups —N═, —N═N—, or —P═, wherein R1 can independently be the same or different, Rx can be a hydrogen atom or a linear, branched and/or cyclic C1-C15-hydrocarbon radical or aryl radical, and Y is a functional binding group reactive with a binder system.
摘要翻译：本发明涉及包含含金属氧化物的片状基材并具有第一和第二保护层的珠光颜料，其中金属氧化物的折射率大于1.8，其中第一保护层包含氧化铈和/或水合氧化铈和/或氢氧化铈，所述第二保护层基本上优选完全由SiO 2组成，其中所述第二保护层设置在所述第一保护层的顶部上，并且在所述第一和第二保护层之间可以设置与氧化铈和/或水合氧化铈和/或氢氧化铈和SiO 2不同的金属氧化物层，其中第二保护层具有有机化学后涂层，有机化学后涂层包含通过装置结合到第二保护层的至少一个硅烷的至少一个氧原子，所述α-硅烷具有式-O（4-nm）-Si（-R1）m（-CH2-Y）n（I），其中1 <= n + m <= 3 ; m = 0〜2; n = 1〜3，R 1为氢原子或Si-C键合的C 1 -C 20烃基或C 1 -C 15烃氧基，其中在各种情况下，一个或多个彼此不相邻的亚甲基可以是被-O - ， - CO - ， - COO-，-OCO-或-OCOO-，-S-或-NRx-基团取代，并且其中不相邻的一个或多个次甲基单元可以被基团-N-，-NN-或-P-，其中R 1可以独立地相同或不同，R x可以是氢原子或直链，支链和/或环状C 1 -C 15 - 烃基或芳基， Y是与粘合剂体系反应的功能性结合基团。

24. 发明申请

US20100095868A1 PEARLESCENT PIGMENTS WITH A CROSS-LINKABLE BINDING AGENT COATING, COATING COMPOSITION, METHOD FOR PRODUCING THE COATED PERLESCENT PIGMENTS AND USE THEREOF 审中-公开
标题翻译：具有交联粘合剂涂料的涂料组合物，涂料组合物，用于生产涂覆后的颜料的方法及其用途
公开(公告)号：US20100095868A1
公开(公告)日：2010-04-22
申请号：US11993867
申请日：2006-06-23
申请人： Günter Kaupp , Ulrich Schmidt , Burkhard Schreiber , Alexander Albrecht
发明人： Günter Kaupp , Ulrich Schmidt , Burkhard Schreiber , Alexander Albrecht
IPC分类号： C09C1/00 , B05D7/00 , C04B14/20 , C09C1/02 , C04B14/04 , C09C1/34 , C09C1/04 , C09C1/36 , C09C1/22
CPC分类号： C09D5/035 , C01P2004/61 , C09C1/0015 , C09C1/0024 , C09C1/0039 , C09C1/0042 , C09C2200/1004 , C09C2200/102 , C09C2200/1025 , C09C2200/1087 , C09C2200/401 , C09C2200/402 , C09C2200/405 , C09C2200/406 , C09D5/36
摘要： The invention relates to coated pearlescent pigments, whereby the coating covers the pearlescent pigments and comprises uncured, however, chemically cross-linkable and/or oligomeric and/or polymeric binding agents that can be cross-linked by heat, IR radiation, UV radiation and/or electron rays. The invention also relates to a method for producing the coated pearlescent pigments and to the use thereof. The invention additionally relates to a coating composition and to a coated article.
摘要翻译：本发明涉及涂覆的珠光颜料，其中涂层覆盖珠光颜料，并且包括未固化的，但是化学上可交联和/或低聚和/或聚合的粘合剂，其可以通过热，IR辐射，UV辐射和 /或电子射线。本发明还涉及一种生产涂层珠光颜料的方法及其用途。本发明还涉及涂料组合物和涂覆制品。

25. 发明授权

US07413599B2 Coated pearlescent pigments with SiO2 and cerium oxide 有权
标题翻译：涂有珠光颜料的SiO2和氧化铈
公开(公告)号：US07413599B2
公开(公告)日：2008-08-19
申请号：US11213234
申请日：2005-08-26
申请人： Frank Henglein , Ulrich Schmidt , Peter Krüger , Günter Kaupp
发明人： Frank Henglein , Ulrich Schmidt , Peter Krüger , Günter Kaupp
IPC分类号： C09C1/00
CPC分类号： C09C1/0015 , C01P2004/88 , C09C1/0021 , C09C2200/102 , C09C2200/401 , C09C2200/407 , C09C2200/408
摘要： The invention relates to pearlescent pigments with a platelet-shaped substrate comprising metal oxide and having a first and a second protective layer, said metal oxide having a refractive index of greater than 1.8, there being on the platelet-shaped substrate a first protective layer comprising cerium oxide and/or cerium hydroxide and a second protective layer of SiO2, applied to which is an organic chemical aftercoat comprising at least one silane having at least one functional bond group and at least one silane without a functional bond group, it being possible for metal oxide layers other than cerium oxide and SiO2 to be disposed between the first and the second protective layer. The invention further relates to a process for preparing these pigments, and to the use thereof.
摘要翻译：本发明涉及具有包含金属氧化物并具有第一和第二保护层的片状基底的珠光颜料，所述金属氧化物的折射率大于1.8，在该片状基底上具有第一保护层，该第一保护层包含氧化铈和/或铈氢氧化物和SiO 2的第二保护层，其中施加有有机化学后涂层，其包含至少一种具有至少一个官能键基团的硅烷和至少一种不含功能性键合基团，除了氧化铈和SiO 2以外的金属氧化物层可以设置在第一和第二保护层之间。本发明还涉及制备这些颜料的方法及其用途。

26. 发明授权

US08735461B2 Printing ink, in particular ink-jet ink, containing pearlescent pigments based on fine and thin substrates 有权
标题翻译：印刷油墨，特别是喷墨油墨，其含有基于细小基材的珠光颜料
公开(公告)号：US08735461B2
公开(公告)日：2014-05-27
申请号：US13381404
申请日：2010-06-22
申请人： Michael Grüner , Günter Kaupp , Stefan Engel , Barbara Mendler , Ulrich Schmidt
发明人： Michael Grüner , Günter Kaupp , Stefan Engel , Barbara Mendler , Ulrich Schmidt
IPC分类号： C08F2/46 , C08G61/04
CPC分类号： C09C1/0021 , C01P2004/51 , C09C2200/102 , C09C2200/30 , C09C2200/301 , C09C2200/302 , C09C2200/304 , C09C2200/308 , C09D5/36 , C09D11/00 , C09D11/101 , C09D11/322 , C09D11/40
摘要： A printing ink, preferably ink-jet ink, containing pearlescent pigments and at least one of at least one solvent, at least one radiation-curable component and at least one binder, wherein the pearlescent pigments comprise a substantially transparent platelet-shaped substrate having a density ρS and at least one optically active coating having a density ρM, and the pearlescent pigments have a d90 value for a cumulative frequency distribution of a volume-averaged size distribution function with a range from 3.5 to 15 μm. The invention further relates to a process for producing the printing ink.
摘要翻译：包含珠光颜料和至少一种溶剂，至少一种可辐射固化组分和至少一种粘合剂中的至少一种的印刷油墨，优选喷墨油墨，其中珠光颜料包括基本上透明的片状基材，其具有密度和至少一种具有密度的光学活性涂层，并且珠光颜料对于体积平均尺寸分布函数的累积频率分布具有d90值，范围为3.5至15μm。本发明还涉及一种用于生产印刷油墨的方法。

27. 发明申请

US20090252772A1 PEARLESCENT PIGMENTS COATED WITH MIXED INORGANIC/ORGANIC LAYERS AND METHOD FOR THE PRODUCTION THEREOF 有权
标题翻译：涂有混合无机/有机层的珍珠粉及其生产方法
公开(公告)号：US20090252772A1
公开(公告)日：2009-10-08
申请号：US12280398
申请日：2007-02-22
申请人： Frank Henglein , Stefan Trummer , Ulrich Schmidt , Günter Kaupp , Peter Krüger
发明人： Frank Henglein , Stefan Trummer , Ulrich Schmidt , Günter Kaupp , Peter Krüger
IPC分类号： C09B67/08 , C09D11/00 , A61K8/02
CPC分类号： C09C1/0021 , C01P2006/66 , C09B67/0098 , C09C1/0015 , C09C1/0024 , C09C2200/1004 , C09C2200/102 , C09C2200/301 , C09C2200/307 , C09C2200/409 , C09C2220/10
摘要： The invention relates to platelet-shaped pearlescent pigments that are coated with at least one mixed inorganic/organic layer for improving their application properties, and of these, particularly their mechanical properties, and to methods for the production thereof and to the use thereof. The said mixed inorganic/organic layer comprises at least one at least partially crosslinked inorganic metal-oxide component and an organic component. The organic component is at least one organic oligomer and/or polymer, which is covalently bonded, at least in part, to the inorganic network via network formers, wherein the coating comprises at least one mixed inorganic/organic layer, which mixed layer comprises, at least in part, an inorganic network having one or more inorganic oxide component(s) and at least one organic component, the organic component being, at least in part, an organic oligomer and/or polymer covalently bonded, at least in part, to the inorganic network via one or more organic network formers.The invention also relates to a method for the production of such pearlescent pigments.
摘要翻译：本发明涉及涂覆有至少一种混合无机/有机层以提高它们的应用性能，特别是其机械性能的片状珠光颜料及其生产方法及其应用。所述混合无机/有机层包含至少一种至少部分交联的无机金属氧化物组分和有机组分。有机组分是至少一种有机低聚物和/或聚合物，其至少部分地通过网络成型体与无机网络共价键合，其中涂层包含至少一种混合的无机/有机层，该混合层包含，至少部分是具有一种或多种无机氧化物组分和至少一种有机组分的无机网络，所述有机组分至少部分是至少部分共价键合的有机低聚物和/或聚合物，通过一个或多个有机网络建立者到无机网络。本发明还涉及一种生产这种珠光颜料的方法。

28. 发明授权

US08197591B2 Pearlescent pigments having a secondary coating comprising α-silanes and method for the production thereof 失效
公开(公告)号：US08197591B2
公开(公告)日：2012-06-12
申请号：US12280378
申请日：2007-02-23
申请人： Günter Kaupp , Ulrich Schmidt
发明人： Günter Kaupp , Ulrich Schmidt
IPC分类号： C09C1/36 , C09C1/00 , C04B14/04 , C23C16/00 , C23C16/40 , B32B15/02 , B32B9/00 , B32B19/00 , B32B23/02 , B32B5/16 , C08K5/00
CPC分类号： C09C1/0015 , C01P2004/84 , C09C2200/401 , C09C2200/407 , C09C2200/408 , C09C2200/409 , C09D5/36 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T428/2996
摘要： The invention relates to a pearlescent pigment comprising a metal oxide-containing, platelet-shaped substrate and having a first and a second protective layer, wherein the metal oxide has a refractive index greater than 1.8, and in which the first protective layer comprises cerium oxide and/or hydrated cerium oxide and/or cerium hydroxide, the second protective layer consists substantially, preferably completely, of SiO2, wherein the second protective layer is disposed on top of the first protective layer, and between the first and second protective layers there can be disposed metal oxide layers which differ from cerium oxide and/or hydrated cerium oxide and/or cerium hydroxide and SiO2, wherein the second protective layer has an organochemical aftercoat and the organochemical aftercoat comprises at least one silane bonded to the second protective layer by means of at least one oxygen atom, said α-silane having the formula —O(4-n-m)—Si(—R1)m(—CH2—Y)n (I), in which 1≦n+m≦3; m=0 to 2; n=1 to 3 and R1 is a hydrogen atom or an Si—C-bonded C1-C20-hydrocarbon radical or a C1-C15-hydrocarbonoxy radical, in which in each case one or more methylene units not adjacent to one another can be replaced by the groups —O—, —CO—, —COO—, —OCO—, or —OCOO—, —S—, or —NRx— and in which one or more methine units not adjacent to one another can be replaced by the groups —N═, —N═N—, or —P═, wherein R1 can independently be the same or different, Rx can be a hydrogen atom or a linear, branched and/or cyclic C1-C15-hydrocarbon radical or aryl radical, and Y is a functional binding group reactive with a binder system.

29. 发明申请

US20120125229A1 PRINTING INK, IN PARTICULAR INK-JET INK, CONTAINING PEARLESCENT PIGMENTS BASED ON FINE AND THIN SUBSTRATES 有权
标题翻译：印刷油墨，特别是喷墨墨水，包含基于精细和薄基材的珍珠色
公开(公告)号：US20120125229A1
公开(公告)日：2012-05-24
申请号：US13381404
申请日：2010-06-22
申请人： Michael Grüner , Günter Kaupp , Stefan Engel , Barbara Mendler , Ulrich Schmidt
发明人： Michael Grüner , Günter Kaupp , Stefan Engel , Barbara Mendler , Ulrich Schmidt
IPC分类号： C09D11/02 , C08K5/101
CPC分类号： C09C1/0021 , C01P2004/51 , C09C2200/102 , C09C2200/30 , C09C2200/301 , C09C2200/302 , C09C2200/304 , C09C2200/308 , C09D5/36 , C09D11/00 , C09D11/101 , C09D11/322 , C09D11/40
摘要： A printing ink, preferably ink-jet ink, containing pearlescent pigments and at least one of at least one solvent, at least one radiation-curable component and at least one binder, wherein the pearlescent pigments comprise a substantially transparent platelet-shaped substrate having a density ρS and at least one optically active coating having a density ρM, and the pearlescent pigments have a d90 value for a cumulative frequency distribution of a volume-averaged size distribution function with a range from 3.5 to 15 μm. The invention further relates to a process for producing the printing ink.
摘要翻译：包含珠光颜料和至少一种溶剂，至少一种可辐射固化组分和至少一种粘合剂中的至少一种的印刷油墨，优选喷墨油墨，其中珠光颜料包括基本上透明的片状基材，其具有密度和至少一种具有密度的光学活性涂层，并且珠光颜料对于体积平均尺寸分布函数的累积频率分布具有d90值，范围为3.5至15μm。本发明还涉及一种用于生产印刷油墨的方法。

30. 发明授权

US09051471B2 Weather-resistant pearlescent pigments, process for the production and use thereof 有权
标题翻译：耐候珠光颜料，其生产和使用的方法
公开(公告)号：US09051471B2
公开(公告)日：2015-06-09
申请号：US14007383
申请日：2012-03-28
申请人： Michael Grüner , Thomas Schneider , Günter Kaupp
发明人： Michael Grüner , Thomas Schneider , Günter Kaupp
IPC分类号： C09C1/28 , C09C1/00 , C09D5/36 , C09D11/037 , A61Q1/02 , A61K8/02 , A61K8/19 , C09C1/40
CPC分类号： C09C1/28 , A61K8/0258 , A61K8/19 , A61K2800/436 , A61Q1/02 , C01P2004/20 , C01P2004/60 , C01P2004/61 , C01P2006/60 , C09C1/0021 , C09C1/0024 , C09C1/405 , C09C2200/1004 , C09C2200/102 , C09C2200/1087 , C09C2200/40 , C09C2200/408 , C09C2220/106 , C09D5/36 , C09D11/037
摘要： The present invention relates to a weather-resistant pearlescent pigment which consists of a platelet-shaped substrate coated with one or more highly refractive metal oxides, the platelet-shaped substrate being selected from the group consisting of synthetic mica flakes, glass flakes, SiO2 flakes, Al2O3 flakes, synthetic boehmite flakes, BiOCl flakes and mixtures thereof, and a top layer, wherein the top layer consists of the following layers: a) a cerium-containing layer, selected from the group consisting of cerium oxide, cerium hydroxide, hydrated cerium oxide, and mixtures thereof, the cerium-containing layer being applied directly to the highly refractive metal oxide layer, and b) an organic-chemical compatibilizing layer, which comprises the reaction products of oligomeric silanes, wherein the oligomeric silanes have one or more amino groups, the organic-chemical compatibilizing layer being applied directly to the cerium-containing layer a).
摘要翻译：本发明涉及耐候珠光颜料，其由涂覆有一种或多种高折射性金属氧化物的片状基材组成，所述片状基材选自合成云母片，玻璃片，SiO 2片 Al2O3薄片，合成勃姆石薄片，BiOCl薄片及其混合物，以及顶层，其中顶层由以下层组成：a）含铈层，选自氧化铈，氢氧化铈，水合氧化铈及其混合物，所述含铈层直接施加到高折射性金属氧化物层，以及b）有机化学相容化层，其包含低聚硅烷的反应产物，其中所述低聚硅烷具有一个或多个氨基，有机化学相容层直接施加到含铈层a）上。

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