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    • 21. 发明授权
      US5248683A Benzo-1,2,3-thiadiazole derivatives 失效
    • Benzo-1,2,3-thiadiazole derivatives
    • 苯并-1,2,3-噻二唑衍生物
    • US5248683A
    • 1993-09-28
    • US893292
    • 1992-06-04
    • Hans-Georg Brunner , Walter Kunz , Rolf Schurter
    • Hans-Georg Brunner , Walter Kunz , Rolf Schurter
    • A01N43/82 , A01N43/828 , C07D285/14 , C07D405/06 , C07D409/06 , C07D417/06
    • C07D285/14 , A01N43/82 , C07D405/06 , C07D409/06 , C07D417/06
    • Compounds of the formula ##STR1## in which A.sub.1 and A.sub.2 independently of one another are CO--C.sub.1 -C.sub.4 alkyl, COO--C.sub.1 -C.sub.4 alkyl, CO--CF.sub.3, CO--N(R).sub.2 or cyano;A.sub.1 and A.sub.2 together are CO(X).sub.n --C.sub.1 -C.sub.3 alkylene-(X).sub.n CO, CO(X).sub.n --C.sub.1 -C.sub.3 alkylene-(X).sub.n CO which is substituted by C.sub.1 -C.sub.4 alkyl, COOR, CON(R).sub.2, cyano or phenyl, it being possible for the phenyl ring, in turn, to be substituted by halogen, methyl, trifluoromethyl, methoxy, nitro or cyano; CO--N(R)--CO--N(R)--CO;R is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyl or C.sub.3 -C.sub.6 alkynyl;X is oxygen, sulfur or N(CH.sub.3);X.sub.1, X.sub.2 and X.sub.3 independently of one another are hydrogen, halogen, methyl, methylthio, methoxy or nitro;n is 0 or 1;including the salts of the compounds of the formula I with agriculturally acceptable organic or inorganic bases, and including the metal complexes; have valuable microbicidal properties.The novel compounds can be used in crop protection for preventing the attack of crop plants by phytopathogenic microorganisms and for the control of these pests.
    • 其中A 1和A 2彼此独立的式“IMAGE”的化合物是CO-C 1 -C 4烷基，COO-C 1 -C 4烷基，CO-CF 3，CO-N（R）2或氰基; A1和A2一起是被C1-C4烷基，COOR，CON（R）2取代的CO（X）n-C1-C3亚烷基 - （X）nCO，CO（X）n-C1-C3亚烷基 - （X） 氰基或苯基，苯环可以被卤素，甲基，三氟甲基，甲氧基，硝基或氰基取代; CO-N（R）-CO-N（R）-CO; R是氢，C 1 -C 6烷基，C 3 -C 6烯基或C 3 -C 6炔基; X是氧，硫或N（CH 3）; X1，X2和X3彼此独立地是氢，卤素，甲基，甲硫基，甲氧基或硝基; n为0或1; 包括式I化合物与农业上可接受的有机或无机碱的盐，并包括金属络合物; 具有有价值的杀菌特性。 新型化合物可用于作物保护，以防止植物病原微生物侵袭作物和控制这些害虫。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 22. 发明授权
      US5180418A Herbicidally active thiadiazabicyclononanes and nonenes 失效
    • Herbicidally active thiadiazabicyclononanes and nonenes
    • US5180418A
    • 1993-01-19
    • US732988
    • 1991-07-19
    • Georg Pissiotas , Hans Moser , Hans-Georg Brunner , Eginhard Steiner
    • Georg Pissiotas , Hans Moser , Hans-Georg Brunner , Eginhard Steiner
    • A01N37/32 , A01N37/38 , A01N43/38 , A01N43/40 , A01N43/824 , A01N43/90 , A01N53/00 , C07C323/35 , C07C323/40 , C07C331/28 , C07D207/40 , C07D207/404 , C07D207/408 , C07D207/44 , C07D207/452 , C07D209/48 , C07D211/88 , C07D265/24 , C07D265/26 , C07D471/04 , C07D487/04 , C07D513/04 , C07F7/08
    • C07D207/408 , A01N37/38 , A01N43/90 , A01N53/00 , C07C323/35 , C07C323/40 , C07C331/28 , C07D207/452 , C07D209/48 , C07D211/88 , C07D265/26 , C07D471/04 , C07D487/04 , C07D513/04 , C07F7/0812
    • Cycloalkanecarboxylic acid derivatives of formula I ##STR1## wherein W is ##STR2## and A is CO--R.sub.3 or CN; R.sub.1 is hydrogen or fluorine; R.sub.2 is halogen or cyano; R.sub.3 is chlorine, X--R.sub.5, amino, C.sub.1 -C.sub.4 alkylamino, d-C.sub.1 -C.sub.4 alkylamino, C.sub.2 -C.sub.4 haloalkylamino, di-C.sub.2 -C.sub.4 haloalkylamino, C.sub.1 -C.sub.4 hydroxyalkylamino, di-C.sub.1 -C.sub.4 hydroxyalkylamino, C.sub.3 -C.sub.4 alkenylamino, diallylamino, --N-pyrrolidino, --N-piperidino, --N-morpholino, --N-thiomorpholino, --N-piperidazino, the group --O--N.dbd.C--(R.sub.9)R.sub.10 or the group --N--R.sub.6 (OR.sub.6); each of R.sub.4 and R.sub.14, independently of the other, is hydrogen, fluorine, chlorine, bromine, C.sub.1 -C.sub.4 alkyl or trifluoromethyl; R.sub.5 is hydrogen, C.sub.1 -C.sub.10 alkyl, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.10 alkylthio-C.sub.1 -C.sub.4 alkyl, di-C.sub.1 -C.sub.4 alkylamino-C.sub.1 -C.sub.4 alkyl, cyano-C.sub.1 -C.sub.8 alkyl, C.sub.3 -C.sub.8 alkenyl, halo-C.sub.3 -C.sub. 8 alkenyl, C.sub.3 -C.sub.8 alkynyl, C.sub.3 -C.sub.7 cycloalkyl, C.sub.3 -C.sub.7 cycloalkyl-C.sub.1 -C.sub.4 alkyl or halo-C.sub.3 -C.sub.7 cycloalkyl, or benzyl which is unsubstituted or substituted at the phenyl ring by up to three identical or different substituents selected from halogen, C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkoxy, or is an alkali metal ion, an alkaline earth metal ion or an ammonium ion, the group --[CHR.sub.6 --(CH.sub.2).sub.m ]--COOR.sub.7, or the group [CHR.sub.6 --(CH.sub.2).sub.t --Si(R.sub.8).sub.3 ]; R.sub.6 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sub.7 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.8 alkenyl, C.sub.3 -C.sub.8 alkynyl, C.sub.1 -C.sub.8 alkoxy-C.sub.2 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkylthio-C.sub.2 -C.sub.8 alkyl or C.sub.3 -C.sub.7 cycloalkyl; R.sub.8 is C.sub.1 - C.sub.4 alkyl; R.sub.9 is C.sub.1 -C.sub.4 alkyl; R.sub.10 is C.sub.1 -C.sub.4 alkyl or phenyl; or R.sub.9 and R.sub.10, together with the carbon atom to which they are bonded, form a cyclohexane ring; R.sub.11 is C.sub.1 -C.sub.8 alkyl; R.sub.12 is hydrogen or C.sub.1 -C.sub.8 alkyl; R.sub.13 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.7 cycloalkyl, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkylthio-C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.7 alkyl, C.sub.3 -C.sub.7 alkenyl or C.sub.3 -C.sub.7 alkynyl; X, Y, Y.sub.1, Y.sub.2, Y.sub.3, Y.sub.4, Z.sub.1 and Z.sub.2 are each independently oxygen or sulfur; n is 0, 1, 2, 3 or 4; m is 0, 1, 2, 3 or 4; q is 1 or 2; and t is 0, 1, 2, 3 or 4, have good pre- and post-emergence selective herbicidal and growth regulating properties.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 23. 发明授权
      US4872902A Cyclohexanediones and their use as plant growth regulators 失效
    • Cyclohexanediones and their use as plant growth regulators
    • 环己酮和它们作为植物生长调节剂的用途
    • US4872902A
    • 1989-10-10
    • US153376
    • 1988-02-08
    • Hans-Georg Brunner
    • Hans-Georg Brunner
    • A01N37/18 , A01N37/34 , A01N47/12 , A01N47/18 , A01N47/28 , A01N47/30 , A01N47/32 , A01N47/38 , A01N53/12 , C07C67/00 , C07C233/32 , C07C233/61 , C07C235/14 , C07C239/00 , C07C251/42 , C07C251/52 , C07C253/00 , C07C255/59 , C07C275/30 , C07C313/00 , C07C317/32 , C07C317/50 , C07C323/40 , C07C323/41 , C07C323/43 , C07C323/44 , C07D295/20 , C07D295/215
    • C07D295/215 , A01N37/18 , A01N47/18 , A01N47/32
    • The invention relates to the novel cyclohexanediones of formula I ##STR1## in which R is hydrogen or C.sub.1 -C.sub.6 -alkyl,A is R.sub.2, OR.sub.3 or NR.sub.3 R.sub.4,R.sub.2 is C.sub.1 -C.sub.6 -alkyl that is unsubstituted or is mono-substituted by C.sub.1 -C.sub.4 -alkoxy or mono- or poly-substituted by halogen, or is C.sub.3 -C.sub.6 -cycloalkyl,R.sub.3 is C.sub.1 -C.sub.6 -alkyl or C.sub.3 -C.sub.6 -cycloalkyl, or is phenyl or benzyl each of which is unsubstituted or is mono-, di- or tri-substituted by R.sub.5,R.sub.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.3 -C.sub.6 -cycloalkyl,R.sub.3 and R.sub.4 are, in addition, together with the nitrogen atom to which they are bonded, a pyrrolidine, morpholine or piperidine radical,B is one of the radicals ##STR2## m is 0, 1, 2 or 3, R.sub.5 is halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkylsulphinyl or C.sub.1 -C.sub.4 -alkylsulphonyl,R.sub.6 is C.sub.1 -C.sub.6 -alkyl or C.sub.3 -C.sub.6 -cycloalkyl, andR.sub.7 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -haloalkenyl or C.sub.3 -C.sub.6 -alkynyl, and to salts of the compounds of formula I with acids, bases or complex-formers, to processes for the preparation thereof and to novel intermediates. The compounds of formula I have herbicidal and growth-regulating action.
    • 本发明涉及式I的新型环己二酮，其中R是氢或C 1 -C 6 - 烷基，A是R 2，OR 3或NR 3 R 4，R 2是未被取代或是未取代的C 1 -C 6烷基， 被C1-C4-烷氧基取代或被卤素单取代或多取代，或为C3-C6-环烷基，R3为C1-C6-烷基或C3-C6-环烷基，或为苯基或苄基，各为未取代的或 是被R5，R4和R4独立地被R5，R4是氢，C1-C6-烷基，C1-C4-烷氧基或C3-C6-环烷基，R3和R4与氮原子一起， 它们是键合的，吡咯烷，吗啉或哌啶基，B是基团之一，m是0,1,2或3，R 5是卤素，硝基，氰基，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基 ，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4 - 烷基亚磺酰基或C 1 -C 4 - 烷基磺酰基，R 6是C 1 -C 6烷基或C 3 -C 6环烷基，R 7是氢，C 1 -C 6烷基， C 1 -C 6卤代烷基，C 3 -C 6烯基，C 3 -C 6卤代链烯基或C 3 -C 6炔基，以及式I化合物与酸的盐， 碱或复合物，其制备方法和新型中间体。 式I的化合物具有除草和生长调节作用。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 24. 发明授权
      US4851028A Method of combating undesirable plant growth and of regulating plant growth 失效
    • Method of combating undesirable plant growth and of regulating plant growth
    • 打击不良植物生长和调节植物生长的方法
    • US4851028A
    • 1989-07-25
    • US92252
    • 1987-09-02
    • Helmut Zondler , Wolfgang Eckhardt , Robert Nyfeler , Hans-Georg Brunner
    • Helmut Zondler , Wolfgang Eckhardt , Robert Nyfeler , Hans-Georg Brunner
    • A01N43/54 , A01N43/60 , C07D239/42 , C07D241/14 , C07D241/20 , C07D405/12
    • C07D239/42 , A01N43/54 , A01N43/60 , C07D241/20 , C07D405/12
    • A method of combating undesirable plant growth and of regulating plant growth, which comprises allowing a herbicidal or plant-regulating amount of a compound of the formula I ##STR1## in which R.sub.1 is SR.sub.2 ; OR.sub.2 ; O--CHR.sub.10 R.sub.2 ; N(R.sub.3) (CHR.sub.10 R.sub.4); N(R.sub.11)(CHR.sub.10 R.sub.4) or NR.sub.3 R.sub.4 ; R.sub.2 is optionally substituted C.sub.1 -C.sub.10 -alkyl C.sub.1 -C.sub.4 -haloalkyl; C.sub.3 -C.sub.8 -alkenyl; (3-methyloxetan-3-yl)methyl; C.sub.3 -C.sub.8 -alkynyl; or an optionally substituted radical from the group comprising phenyl, benzyl, C.sub.3 -C.sub.7 -cycloalkyl, furanyl or furfuryl R.sub.3 and R.sub.4 independently of one another are hydrogen; an optionally substituted phenyl or benzyl radical; C.sub.1 -C.sub.8 -alkyl; or C.sub.3 -C.sub.6 -cycloalkyl; or R.sub.3 and R.sub.4, together with the nitrogen atom, form a saturaated 5- or 6-membered heterocyclic ring which contains up to two heteroatoms from the group comprising N, O and S and can be mono- or disubstituted by C.sub.1 -C.sub.4 -alkyl; R.sub.5 is hydrogen; halogen; C.sub.1 -C.sub.8 -alkyl; C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl; nitro; cyano; C.sub.1 -C.sub.4 -haloalkoxy; phenylthio; di-C.sub.1 -C.sub.4 - alkylamino; phenyl; or is optionally substituted phenoxy; and R.sub.6 and R.sub.7 independently of one another are hydrogen; halogen; C.sub.1 -C.sub.8 -alkyl; C.sub.1 -C.sub.4 -haloalkyl; C.sub.1 -C.sub.4 -alkoxy; C.sub.1 -C.sub.4 -haloalkoxy; nitro; cyano; or di-C.sub.1 -C.sub.4 -alkylamino, and R.sub.10 and R.sub.11 independently of one another are C.sub.1 -C.sub.4 -alkyl; and salts of compounds of the formula I with acids and bases, to act on the plants or on the environment of the plants, and novel compounds of the formula I' ##STR2## process for their preparation and herbicidal or plant growth-regulating compositions containing these novel compounds.
    • 一种防治不期望的植物生长和调节植物生长的方法，其包括允许除草或植物调节量的其中R 1为SR 2的式I化合物（I）; OR2; O-CHR10R2; N（R3）（CHR10R4）; N（R11）（CHR10R4）或NR3R4; R2是任选取代的C 1 -C 10 - 烷基C 1 -C 4 - 卤代烷基; C3-C8-烯基; （3-甲基氧杂环丁烷-3-基）甲基; C3-C8-炔基; 或由苯基，苄基，C 3 -C 7 - 环烷基，呋喃基或糠基R3和R4彼此独立地选自任意取代的基团是氢; 任选取代的苯基或苄基; C 1 -C 8 - 烷基; 或C 3 -C 6 - 环烷基; 或R3和R4与氮原子一起形成饱和的5或6元杂环，其含有至多两个来自包含N，O和S的基团的杂原子，并且可被C1-C4烷基单或二取代 ; R5是氢; 卤素; C 1 -C 8 - 烷基; C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷基; 硝基 氰基; C 1 -C 4卤代烷氧基; 苯硫基 二-C 1 -C 4烷基氨基; 苯基; 或任选取代的苯氧基; 且R 6和R 7彼此独立地为氢; 卤素; C 1 -C 8 - 烷基; C 1 -C 4 - 卤代烷基; C1-C4-烷氧基; C 1 -C 4卤代烷氧基; 硝基 氰基; 或二-C 1 -C 4烷基氨基，R 10和R 11彼此独立地为C 1 -C 4 - 烷基; 和式I化合物与酸和碱的盐作用于植物或植物环境，以及式I'（I'）的新化合物，其制备和除草或植物生长过程 含有这些新化合物的调节组合物。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 25. 发明授权
      US4803268A Process for the preparation of cyclohexanedionecarboxylic acid derivatives 失效
    • Process for the preparation of cyclohexanedionecarboxylic acid derivatives
    • 环己二酸羧酸衍生物的制备方法
    • US4803268A
    • 1989-02-07
    • US008445
    • 1987-01-29
    • Hans-Georg Brunner , Urs Muller
    • Hans-Georg Brunner , Urs Muller
    • A01N37/42 , C07C51/00 , C07C51/347 , C07C62/00 , C07C62/38 , C07C67/00 , C07C67/22 , C07C69/757 , C07C201/00 , C07C205/43 , C07C231/00 , C07C231/12 , C07C233/12 , C07C235/82 , C07C253/00 , C07C255/55 , C07C255/60 , C07C313/00 , C07C323/12 , C07C323/40 , C07D295/18 , C07D295/185 , C07D279/10
    • C07D295/185 , C07C323/00 , C07C51/347
    • The present invention relates to a novel, optimized process for the preparation of cyclohexanedionecarboxylic acid derivatives of formula I which can be carried out in a single vessel affording a very good yield, which process comprises heating a reactive carboxylic acid derivative of formula III ##STR1## wherein X is a halide, an alkylsulfonic or arylsulfonic acid radical or the molecular radical ##STR2## which is necessary to form an anhydride and R.sub.1 is alkyl or cycloalkyl, with an alkali metal cyanide or copper cyanide, in an inert organic solvent, to give a mixture, then adding in succession to said mixture, at a temperature in the range from 0.degree. C. to room temperature, zinc chloride, an equimolar amount, with respect to the carboxylic acid derivative of formula III, of a 3,5-cyclohexanedione-1-carboxylic acid derivative of formula II ##STR3## wherein A is an ester or amide radical, and, dropwise, an amine, and, after acidifying the reaction mixture with an aqueous acid, isolating the resultant 4-acyl-3,5-cyclohexanedione-1-carboxylic acid derivative of formula I ##STR4## by extraction. Said cyclohexanedionecarboxylic acid derivatives have herbicidal and plant growth regulating properties.
    • 本发明涉及一种用于制备式I的环己二酸羧酸衍生物的新型优化方法，其可以在单一容器中进行，提供非常好的产率，该方法包括加热式III的反应性羧酸衍生物 （III）其中X是卤化物，烷基磺酸或芳基磺酸基团或在惰性有机溶剂中与碱金属氰化物或氰化铜形成酸酐而R1是烷基或环烷基所必需的分子基团 ，得到混合物，然后在0℃至室温的温度下连续加入所述混合物，相对于式III的羧酸衍生物，等摩尔量的氯化锌为3 （II）的5-环己二酮-1-羧酸衍生物其中A是酯或酰胺基，并逐滴加入胺，并且在用酸水溶液酸化反应混合物后， 通过萃取分离得到式I的所得4-酰基-3,5-环己二酮-1-羧酸衍生物（I）图像+ TR图像。 所述环己二酸羧酸衍生物具有除草和植物生长调节性质。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 26. 发明授权
      US4743296A Heterocyclically fused pyridine compounds as herbicides 失效
    • Heterocyclically fused pyridine compounds as herbicides
    • 杂环稠合吡啶化合物作为除草剂
    • US4743296A
    • 1988-05-10
    • US936214
    • 1986-12-01
    • Dieter Durr , Hans-Georg Brunner , Henry Szczepanski
    • Dieter Durr , Hans-Georg Brunner , Henry Szczepanski
    • A01N43/90 , C07D471/14 , A01N43/40 , A01N43/42
    • C07D471/14 , A01N43/90
    • This is a continuation in part application derived from our copending application Ser. No. 837,977 (filing date Mar. 10, 1986). This continuation in part is directed to novel pyridine compounds of formula I below have good selective herbicidal properties pre- and postemergence and also influence or inhibit plant growth. The compounds are of formula I ##STR1## wherein each of X, Y and Z independently of one another is hydrogen or a C.sub.1 -C.sub.4 alkyl group, or two adjacent substituents together also form a saturated or unsaturated 3- or 4-membered alkylene chain or alkenyl chain, each of which chains may in turn by substituted by one to four C.sub.1 -C.sub.4 alkyl groups, R is a C.sub.1 -C.sub.4 nitroalkyl group, a substituted C.sub.1 -C.sub.4 alkylthio group or C.sub.1 -C.sub.4 alkoxy group, an unsubstituted or substituted C.sub.3 -C.sub.4 alkenylthio or C.sub.3 -C.sub.4 alkynylthio group, the hydroxyamino group, a C.sub.1 -C.sub.4 alkoxyamino, C.sub.3 -C.sub.4 alkenyloxyamino or C.sub.3 -C.sub.4 alkynyloxyamino group, a --PO(C.sub.1 -C.sub.4 alkyl).sub.2 or --PO(CH.sub.3)OC.sub.1 -C.sub.4 -alkyl radical or an unsubstituted or substituted hydrazino radical.
    • 这是来自我们的共同未决申请Ser的部分申请的延续。 837,977号（1986年3月10日提交）。 这一延续部分涉及式I的新型吡啶化合物具有良好的选择性除草性能和芽后效应，并且还影响或抑制植物生长。 所述化合物具有式I（I）其中X，Y和Z各自独立地为氢或C 1 -C 4烷基，或两个相邻的取代基一起也形成饱和或不饱和的3-或4-元 亚烷基链或烯基链，其中每个链依次可被一至四个C 1 -C 4烷基取代，R是C 1 -C 4硝基烷基，取代的C 1 -C 4烷硫基或C 1 -C 4烷氧基，未取代或取代的C 3 -C 4烷氧基， C 4链烯基硫基或C 3 -C 4炔硫基，羟基氨基，C 1 -C 4烷氧基氨基，C 3 -C 4链烯氧基氨基或C 3 -C 4炔氧基氨基，-PO（C 1 -C 4烷基）2或-PO（CH 3）OC 1 -C 4烷基或未取代或未取代的 取代的肼基。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 28. 发明授权
      US4623382A Cyclohexanedionecarboxylic acid derivatives with herbicidal and plant growth regulating properties 失效
    • Cyclohexanedionecarboxylic acid derivatives with herbicidal and plant growth regulating properties
    • 具有除草和植物生长调节性质的环己烷二羧酸衍生物
    • US4623382A
    • 1986-11-18
    • US788176
    • 1985-10-16
    • Hans-Georg Brunner
    • Hans-Georg Brunner
    • C07D295/18 , A01N20060101 , A01N33/16 , A01N37/00 , A01N37/08 , A01N37/18 , A01N37/42 , A01N37/44 , A01N43/36 , A01N43/40 , A01N43/84 , C07C20060101 , C07C59/82 , C07C62/00 , C07C65/00 , C07C67/00 , C07C67/03 , C07C67/30 , C07C67/313 , C07C69/757 , C07C69/95 , C07C233/82 , C07C235/82 , C07C239/20 , C07C259/08 , C07C313/00 , C07C323/11 , C07C323/55 , C07C323/60 , C07D295/185 , C07C69/74
    • A01N37/42 , A01N37/44 , C07D295/185
    • Novel cyclohexanedionecarboxylic acid derivatives have herbicidal and plant growth regulating properties. The cyclohexanedionecarboxylic acid derivatives have the formula I ##STR1## wherein A is an --OR.sub.2 or --NR.sub.3 R.sub.4 radical,R is C.sub.1 -C.sub.6 alkyl or C.sub.3 -C.sub.6 cycloaklyl, each unsubstituted or substituted by halogen, C.sub.1 -C.sub.6 alkoxy or C.sub.2 -C.sub.4 alkylthio,R.sub.1 is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 haloalkenyl or C.sub.3 -C.sub.6 -alkynyl,R.sub.2, R.sub.3 and R.sub.4 are each independently hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.2 -C.sub.10 alkoxyalkyl, C.sub.2 -C.sub.10 alkylthioalkyl; C.sub.3 -C.sub.6 alkenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio; C.sub.3 -C.sub.6 alkynyl; phenyl or C.sub.1 -C.sub.6 aralkyl, wherein the phenyl nucleus is unsubstituted or substituted by halogen; C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, nitro or cyano; one of R.sub.3 and R.sub.4 is methoxy orR.sub.3 and R.sub.4, together with the nitrogen atom to which they are attached, form a 5- or 6-membered heterocyclic ring system which may contain an additional oxygen or sulfur atom in the ringor a metal or ammonium salt thereof.
    • 新型环己二酸羧酸衍生物具有除草和植物生长调节性质。 环己烷二羧酸衍生物具有式I（I）其中A为-OR 2或-NR 3 R 4基团，R为C 1 -C 6烷基或C 3 -C 6环烷基，各自未被取代或被卤素，C 1 -C 6烷氧基或C 2 -C 4烷硫基取代， R1是C1-C6烷基，C1-C6卤代烷基，C3-C6-烯基，C3-C6卤代烯基或C3-C6-炔基，R2，R3和R4分别独立地是氢，C1-C6烷基，C1-C6卤代烷基，C2-C10烷氧基烷基，C2- C10烷硫基烷基; 未被取代或被卤素，C 1 -C 4烷氧基或C 1 -C 4烷硫基取代的C 3 -C 6烯基; C 3 -C 6炔基; 苯基或C 1 -C 6烷基，其中所述苯基核未被取代或被卤素取代; C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷基，硝基或氰基; R 3和R 4中的一个是甲氧基或R 3和R 4与它们所连接的氮原子一起形成5-或6-元杂环体系，其可在环中含有另外的氧或硫原子或金属或 其铵盐。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
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