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    • 26. 发明授权
    • Nonaqueous electrolytic solution and nonaqueous electrolyte battery
    • 非水电解液和非水电解质电池
    • US08962192B2
    • 2015-02-24
    • US12525188
    • 2008-03-17
    • Minoru KotatoShinichi Kinoshita
    • Minoru KotatoShinichi Kinoshita
    • H01M6/18H01M10/0567H01M10/052H01M10/0568
    • H01M10/0567H01M10/052H01M10/0568Y02E60/122
    • A nonaqueous electrolytic solution that can provide a battery that is low in gas generation, has a large capacity, and is excellent in storage characteristics and cycle characteristics contains an electrolyte and a nonaqueous solvent dissolving the electrolyte and further contains 0.001 vol % or more and less than 1 vol % of a compound represented by Formula (1) in the nonaqueous solvent. Alternatively, the nonaqueous electrolytic solution contains 0.001 vol % or more and less than 5 vol % of a compound represented by Formula (1) in the nonaqueous solvent and further contains at least one compound selected from the group consisting of cyclic carbonate compounds having carbon-carbon unsaturated bonds, cyclic carbonate compounds having fluorine atoms, monofluorophosphates, and difluorophosphates. In Formula (1), R1 to R3 each independently represent an alkyl group of 1 to 12 carbon atoms, which may be substituted by a halogen atom; and n represents an integer of 0 to 6.
    • 能够提供气体发生量低的电池的非水电解液容量大,储存特性和循环特性优异,含有电解质和溶解电解质的非水溶剂,进一步含有0.001体积%以上 在非水溶剂中的1体积%以下的式(1)表示的化合物。 或者,非水电解液在非水溶剂中含有0.001体积%以上且小于5体积%的式(1)表示的化合物,并且还含有选自碳酸酯化合物的环状碳酸酯化合物中的至少一种, 碳不饱和键,具有氟原子的环状碳酸酯化合物,单氟磷酸盐和二氟磷酸盐。 式(1)中,R 1〜R 3各自独立地表示可被卤素原子取代的碳原子数1〜12的烷基, n表示0〜6的整数。