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    • 22. 发明申请
    • OLEFIN FUNCTIONALIZATION BY METATHESIS REACTION
    • 烯烃反应的烯烃功能化
    • WO2009155517A2
    • 2009-12-23
    • PCT/US2009/047953
    • 2009-06-19
    • ExxonMobil Chemical Patent Inc.HAGADORN, John, R.HOLTCAMP, Matthew, W.NARVAEZ, Andrew, G.CROWTHER, Donna, J.BRANT, Patrick
    • HAGADORN, John, R.HOLTCAMP, Matthew, W.NARVAEZ, Andrew, G.CROWTHER, Donna, J.BRANT, Patrick
    • C08F210/06C08F210/16C08F2500/20C08F2500/02
    • This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol% propylene and 10 to 90 mol% of ethylene, wherein the oligomer has at least X% allyl chain ends, where: 1) X = (-0.94 (mole% ethylene incorporated) + 100), when 10 to 60 mole% ethylene is present in the co-oligomer, and 2) X = 45, when greater than 60 and less than 70 mole% ethylene is present in the co-oligomer, and 3) X = (1.83* (mole% ethylene incorporated) -83), when 70 to 90 mole% ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8: 1 to 1.2: 1.0, and less than 100 ppm aluminum.
    • 本发明涉及官能化丙烯共聚低聚物的方法,包括使烯烃复分解催化剂与含杂原子的烯烃接触,以及丙烯,共聚低聚物,其Mn为300至30,000g / mol,包含10至90mol%的丙烯和10 至90mol%的乙烯,其中所述低聚物具有至少X%的烯丙基链端,其中:1)X =( - 0.94(摩尔%乙烯掺入)+ 100),当共聚物中存在10至60摩尔%的乙烯时 - 低聚物,和2)X = 45,当共聚物中存在大于60且小于70摩尔%的乙烯时,和3)X =(1.83 *(摩尔%乙烯加入)-83),当70〜 共聚低聚物中存在90摩尔%的乙烯。 本发明还涉及使丙烯均聚物低聚物官能化的方法,包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触,其中低聚物具有:至少93%的烯丙基链端,Mn 约500至约20,000g / mol,异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0,低于100ppm的铝。