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21. 发明申请

US20140364628A1 PROCESS FOR THE PREPARATION OF BENZODITHIOPHENE COMPOUNDS 审中-公开
标题翻译：制备苯二酚化合物的方法
公开(公告)号：US20140364628A1
公开(公告)日：2014-12-11
申请号：US14362738
申请日：2012-12-19
申请人： Eni S.p.A.
发明人： Gabriele Bianchi , Giuliana Schimperna
IPC分类号： C07D495/04
CPC分类号： C07D495/04
摘要： Process for the preparation of a benzodithiophene compound which comprises reacting at least one monohalogenated dithiophene compound with at least one internal alkyne. Said benzodithiophene compound, after suitable functionalization and polymerization, can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photo-voltaic modules, solar cells, solar modules, on both rigid and flexible supports. Furthermore said benzodithiophene compound can be advantageously used as spectrum converter in luminescent solar concentrators (LSC). Said benzodithiophene compound can also be advantageously used as precursor of monomeric units in the preparation of semiconductor polymers.
摘要翻译：制备苯并二噻吩化合物的方法，其包括使至少一种一卤代二噻吩化合物与至少一种内炔反应。所述苯并二噻吩化合物在适当的官能化和聚合之后可以有利地用于在刚性和柔性载体两者上构建诸如光伏电池，光伏电池模块，太阳能电池，太阳能电池组件的光伏器件。此外，所述苯并二噻吩化合物可以有利地用作发光太阳能集中器（LSC）中的光谱转换器。所述苯并二噻吩化合物也可有利地用作制备半导体聚合物中单体单元的前体。

22. 发明授权

US11930705B2 Diaryloxybenzoheterodiazole compounds di-substituted with thienothiophenic groups 有权
公开(公告)号：US11930705B2
公开(公告)日：2024-03-12
申请号：US17775900
申请日：2020-11-12
申请人： ENI S.P.A.
发明人： Giuliana Schimperna , Luigi Abbondanza , Antonio Alfonso Proto , Stefano Zanardi
IPC分类号： H10K85/60 , C07D495/04 , H10K30/87
CPC分类号： H10K85/6576 , C07D495/04 , H10K30/87 , H10K85/657
摘要： There is a diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia):

The diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia) can be advantageously used as a spectrum converter in luminescent solar concentrators (LSCS) capable, in turn, of improving the performance of photovoltaic devices (or solar devices), selected for example, between photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support. More particularly, said photovoltaic devices (or solar devices) can be advantageously used in the construction of greenhouses.

23. 发明授权

US11713314B2 Disubstituted diaryloxybenzoheterodiazole compounds 有权
公开(公告)号：US11713314B2
公开(公告)日：2023-08-01
申请号：US17506183
申请日：2021-10-20
申请人： Eni S.p.A.
发明人： Giuliana Schimperna , Antonio Alfonso Proto
IPC分类号： C07D417/14 , C09K11/06 , H01L31/055 , C09K11/02 , H01L31/0232 , H01L27/146 , H02S40/22 , H10K30/87 , H10K30/00 , H10K39/10 , H10K85/10 , H10K85/60
CPC分类号： C07D417/14 , C09K11/06 , H01L31/055 , C09K11/02 , C09K2211/1007 , C09K2211/1011 , C09K2211/1051 , C09K2211/1092 , H01L27/14663 , H01L31/02322 , H02S40/22 , H10K30/451 , H10K30/87 , H10K39/10 , H10K85/141 , H10K85/626 , H10K85/655 , H10K85/657 , Y02E10/52 , Y02E10/549
摘要： A process for the preparation of a disubstituted diaryloxybenzoheterodiazole compound having general formula (XII):

wherein:

Z represents a sulfur atom, an oxygen atom, a selenium atom; or a group NR6 wherein R6 is selected from linear or branched C1-C20 alkyl groups, or from optionally substituted aryl groups;
R2 and R3, identical or different, represent a hydrogen atom, provided that R1 does not represent a hydrogen atom; or R1, R2 and R3 are selected from linear or branched C1-C20 alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted, linear or branched C1-C20 alkoxy groups, optionally substituted phenoxy groups, or a cyano group;
or R1 and R2, may optionally be bound together so as to form, together with carbon atoms to which R1 and R2 are bound, a saturated, unsaturated, or aromatic, cyclic or a polycyclic system containing from 3 to 14 carbon atoms, optionally containing one or more heteroatoms selected from oxygen, sulfur, nitrogen, silicon, phosphorus, or selenium;
or R2 and R3 may optionally be bound together so as to form, together with carbon atoms to which R2 and R3 are bound, a saturated, unsaturated, or aromatic, cyclic or a polycyclic system containing from 3 to 14 carbon atoms, saturated, unsaturated, or aromatic, optionally containing one or more heteroatoms selected from oxygen, sulfur, nitrogen, silicon, phosphorus, or selenium;

wherein Ra and Rb, which are different, represent a hydrogen atom; or are selected from linear or branched C1-C20 alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20 alkoxy groups, optionally substituted phenoxy groups, —COORc groups wherein Rc is selected from linear or branched C1-C20 alkyl groups, —CON(Rc)2, wherein Rc has the same meanings described above, or —N(Rc)2 groups wherein Rc has the same meanings described above.

24. 发明申请

US20220399509A1 DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS DI-SUBSTITUTED WITH THIENOTHIOPHENIC GROUPS 有权
公开(公告)号：US20220399509A1
公开(公告)日：2022-12-15
申请号：US17775900
申请日：2020-11-12
申请人： ENI S.P.A.
发明人： Giuliana Schimperna , Luigi Abbondanza , Antonio Alfonso Proto , Stefano Zanardi
IPC分类号： H01L51/00 , C07D495/04 , H01L51/44
摘要： There is a diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia): The diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia) can be advantageously used as a spectrum converter in luminescent solar concentrators (LSCS) capable, in turn, of improving the performance of photovoltaic devices (or solar devices), selected for example, between photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support. More particularly, said photovoltaic devices (or solar devices) can be advantageously used in the construction of greenhouses.

25. 发明授权

US09624212B2 Process for the preparation of benzohetero [1,3]—diazole compounds disubstituted with heteoaryl groups 有权
公开(公告)号：US09624212B2
公开(公告)日：2017-04-18
申请号：US15167285
申请日：2016-05-27
申请人： Eni S.P.A.
发明人： Giuliana Schimperna , Gabriele Bianchi
IPC分类号： C07D409/14 , C07D495/04 , C07D519/00 , C07D417/14 , C07D413/14
CPC分类号： C07D417/14 , C07D409/14 , C07D413/14 , C07D495/04 , C07D519/00
摘要： Process for the preparation of a benzohetero[1,3]diazole compound disubstituted with heteroaryl groups which comprises reacting at least one benzohetero[1,3]diazole compound disubstituted with at least one heteroaryl compound.Said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of luminescent solar concentrators (LSC). Furthermore, said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both a rigid and flexible support. Said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can also be advantageously used as a precursor of monomeric units in the preparation of semiconductor polymers.

26. 发明授权

US09567321B2 Aromatic monomers deriving from glycerol units, process for their preparation and use thereof for the preparation of water-soluble conjugated polymers 有权
标题翻译：衍生自甘油单元的芳族单体，其制备方法及其用于制备水溶性共轭聚合物的方法
公开(公告)号：US09567321B2
公开(公告)日：2017-02-14
申请号：US14880645
申请日：2015-10-12
申请人： ENI S.p.A.
发明人： Giuliana Schimperna , Riccardo Po′ , Andrea Pellegrino , Maria Caldararo
IPC分类号： C08G65/26 , C08G65/04 , C07D317/22 , C07D409/12 , C07D405/12 , C08G61/12 , H01L51/00 , C08G75/06 , H01L51/42
CPC分类号： C07D405/12 , C07D317/22 , C07D409/12 , C08G61/123 , C08G61/124 , C08G61/126 , C08G75/06 , C08G2261/124 , C08G2261/1422 , C08G2261/1424 , C08G2261/3142 , C08G2261/3223 , C08G2261/3241 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , H01L51/0036 , H01L51/0039 , H01L51/0043 , H01L51/0068 , H01L51/0072 , H01L51/42
摘要： Monomers having formula (I) and process for their synthesis which comprises the etherification reaction of a halogen-derivative (Z═Cl, Br, I) having formula (III) with the hydroxyl group of the glycerol derivative (IV), according to the following scheme:
摘要翻译：具有式（I）的单体及其合成方法，其包括具有式（III）的卤素衍生物（Z = Cl，Br，I）与甘油衍生物（IV）的羟基的醚化反应，根据（式III，IV＆I）（III）（IV）（I）

27. 发明申请

US20160272629A1 PROCESS FOR THE PREPARATION OF BENZOHETERO [1,3] - DIAZOLE COMPOUNDS DISUBSTITUTED WITH HETEOARYL GROUPS 审中-公开
标题翻译：制备苯并[1,3] - 二苯并噻唑化合物的方法
公开(公告)号：US20160272629A1
公开(公告)日：2016-09-22
申请号：US15167285
申请日：2016-05-27
申请人： Eni S.P.A.
发明人： Giuliana Schimperna , Gabriele Bianchi
IPC分类号： C07D417/14 , C07D413/14 , C07D409/14 , C07D495/04
CPC分类号： C07D417/14 , C07D409/14 , C07D413/14 , C07D495/04 , C07D519/00
摘要： Process for the preparation of a benzohetero[1,3]diazole compound disubstituted with heteroaryl groups which comprises reacting at least one benzohetero[1,3]diazole compound disubstituted with at least one heteroaryl compound.Said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of luminescent solar concentrators (LSC). Furthermore, said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both a rigid and flexible support. Said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can also be advantageously used as a precursor of monomeric units in the preparation of semiconductor polymers.
摘要翻译：用杂芳基二取代的所述苯并[1,3]二唑化合物可有利地用于发光太阳能集中器（LSC）的构建。此外，用杂芳基二取代的所述苯并[1,3]二唑化合物可有利地用于在刚性和柔性载体上构建光伏器件，例如光伏电池，光伏模块，太阳能电池，太阳能电池组件。用杂芳基二取代的所述苯并[1,3]二唑化合物也可有利地用作半导体聚合物制备中单体单元的前体。

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