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21. 发明公开

EP3049458A1 METHOD FOR MAKING POLY (BUTYLENE OXIDE) POLYOLS 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG VON POLY（BUTYLENOXID）POLYOLEN
公开(公告)号：EP3049458A1
公开(公告)日：2016-08-03
申请号：EP14758230.8
申请日：2014-08-16
申请人： Dow Global Technologies LLC
发明人： MASY, Jean-Paul , LINKE, Myriam , BABB, David A. , WESTON, John W.
IPC分类号： C08G65/26
CPC分类号： C08G65/12 , C08G65/2606 , C08G65/2609 , C08G65/2663 , C08G65/2696
摘要： 1,2-butylene oxide is homopolymerized or randomly copolymerized in the presence of a double metal cyanide catalyst such as a zinc hexacyanocobaltate catalyst complex. The polymers unexpectedly contain significant amounts of monofunctional impurities, which can be partially controlled through selection of polymerization conditions.
摘要翻译：在双金属氰化物催化剂如六氰基钴酸锌催化剂络合物的存在下，1,2-环氧丁烷均聚或无规共聚。聚合物意外地含有大量的单官能杂质，其可以通过选择聚合条件来部分控制。

22. 发明公开

EP2691440A1 METHOD FOR PRODUCING SHORT-CHAIN POLYFUNCTIONAL POLYETHER POLYOLS UTILIZING SUPERACID AND DOUBLE-METAL CYANIDE CATALYSIS 有权
标题翻译：生产具有超酸，双金属催化短链多官能聚醚多元醇
公开(公告)号：EP2691440A1
公开(公告)日：2014-02-05
申请号：EP12711522.8
申请日：2012-03-19
申请人： Dow Global Technologies LLC
发明人： SHUTOV, Pavel, L. , VAN DER WAL, Hanno, R. , MASY, Jean-Paul , BABB, David, A.
IPC分类号： C08G65/00
CPC分类号： C08G65/2609 , C08G18/3206 , C08G65/2678 , C08G65/2684 , C08G65/2696
摘要： A two stage alkoxlyation process for preparing a short-chain polyether polyol from a starter compound comprising from 3 to 9 hydroxyl groups and at least one alkylene oxide, wherein said starter compound has a hydroxy equivalent weight of from 22 to 90 Da. Said process comprises a first stage alkoxlyation using a superacid catalyst to prepare an oligomeric alkoxylated starter compound that is further alkoxylated to the short-chain polyether polyol of the invention in a second stage using a DMC catalyst. The process of the present invention may be performed continuously, in a batch, or semi-batch process.

23. 发明授权

EP2513192B1 METHOD FOR CONTINUOUSLY PRODUCING LOW EQUIVALENT WEIGHT POLYOLS USING DOUBLE METAL CYANIDE CATALYSTS 有权
标题翻译：法的双金属度的多元醇低当量重量为基础连续生产
公开(公告)号：EP2513192B1
公开(公告)日：2014-01-22
申请号：EP10788205.2
申请日：2010-12-06
申请人： Dow Global Technologies LLC
发明人： WESTON, John, W. , VILLA, Carlos, M. , MASY, Jean-Paul , SEAVEY, Kevin, C.
IPC分类号： C08G65/00
CPC分类号： C08G65/2663 , C08G65/2609 , C08G65/2696

24. 发明公开

EP2510043A1 POLYETHER DERIVATIVES OF SECONDARY HYDROXY FATTY ACIDS AND DERIVATIVES THEREOF 审中-公开
标题翻译：次生羟基脂肪酸及其衍生物的聚醚衍生物
公开(公告)号：EP2510043A1
公开(公告)日：2012-10-17
申请号：EP09795613.0
申请日：2009-12-09
申请人： Dow Global Technologies LLC
发明人： THOEN, Johan , MASY, Jean-Paul
IPC分类号： C08G65/26
CPC分类号： C08G65/2663 , C08G65/2615 , C08G65/3311
摘要： A compound that is a polyether of a saturated monobasic secondary hydroxyl fatty acid, preferably 12-hydroxy stearate, or a reaction product of the polyether with a polyhydric alcohol, a capping agent or a combination of both. Prepare the compound by contacting a saturated hydroxy monobasic fatty acid or derivative thereof with an alkoxide in the presence of a double metal cyanide catalyst such that a polyether of the fatty acid is formed. Optionally, preparation also includes a step of capping the polyether, or alternatively, contacting the polyether with a polyhydric alcohol.

25. 发明公开

EP4423168A1 POLYETHER POLYMERIZATION PROCESS 审中-实审
公开(公告)号：EP4423168A1
公开(公告)日：2024-09-04
申请号：EP22797563.8
申请日：2022-09-30
申请人： Dow Global Technologies LLC
发明人： STEELMAN, David K. , NIKBIN, Nima , RAGHURAMAN, Arjun , ZIEBARTH, Robin P. , WESTON, John W. , MASY, Jean-Paul
IPC分类号： C08G65/26 , B01J27/26 , C08G65/40
CPC分类号： C08G65/2663 , B01J27/26 , C08G65/2696 , B01J37/0036 , B01J37/036 , B01J35/40

26. 发明公开

EP3898768A1 POLYETHER POLYMERIZATION PROCESS 有权
公开(公告)号：EP3898768A1
公开(公告)日：2021-10-27
申请号：EP19832257.0
申请日：2019-12-11
申请人： Dow Global Technologies LLC
发明人： BABB, David A. , MASY, Jean-Paul , STEELMAN, David Keith
IPC分类号： C08G65/26 , B01J27/26

27. 发明授权

EP3359582B1 HIGH RESILIENCY POLYURETHANE FOAMS MADE WITH HIGH FUNCTIONALITY, HIGH EQUIVALENT WEIGHT POLYOLS WITH MAINLY SECONDARY HYDROXYL GROUPS 有权
公开(公告)号：EP3359582B1
公开(公告)日：2020-07-29
申请号：EP16770640.7
申请日：2016-09-15
申请人： Dow Global Technologies, LLC
发明人： BABB, David, A. , MASY, Jean-Paul
IPC分类号： C08G18/48 , C08G18/66 , C08G18/76 , C08G65/26

28. 发明公开

EP3209706A1 DUAL CATALYST SYSTEM FOR HIGH PRIMARY HYDROXYL POLYOLS 有权
标题翻译：双原料羟基多元醇催化剂体系
公开(公告)号：EP3209706A1
公开(公告)日：2017-08-30
申请号：EP15791819.4
申请日：2015-10-19
申请人： Dow Global Technologies LLC
发明人： RAGHURAMAN, Arjun , SCHAEFER, Matthias , MASY, Jean-Paul , LAITAR, David S.
IPC分类号： C08G65/26 , B01J27/26
CPC分类号： C08G65/269 , B01J23/75 , B01J27/26 , C08G65/2654 , C08G65/266 , C08G65/2663 , C08G65/2696
摘要： A method of producing a high primary hydroxyl group content and a high number average molecular weight polyol includes preparing a mixture that includes a double metal cyanide catalyst and a low molecular weight polyether polyol having a number average molecular weight of less than 1,000 g/mol, the polyether polyol is derived from propylene oxide, ethylene oxide, or butylene oxide, setting the mixture to having a first temperature, adding at least one selected from propylene oxide, ethylene oxide, and butylene oxide to the mixture at the first temperature, allowing the mixture to react to form a reacted mixture, adding a Lewis acid catalyst to the reacted mixture, setting the reaction mixture including the second catalyst to have a second temperature that is less than the first temperature, and adding additional at least one selected from propylene oxide, ethylene oxide, and butylene oxide to the reacted mixture at the second temperature such that a resultant polyol having a primary hydroxyl group content of at least 60% and a number average molecular weight greater than 2,500 g/mol is formed.
摘要翻译：产生高伯羟基含量和高数均分子量多元醇的方法包括制备包含双金属氰化物催化剂和数均分子量小于1,000g / mol的低分子量聚醚多元醇的混合物，聚醚多元醇衍生自环氧丙烷，环氧乙烷或环氧丁烷，使混合物具有第一温度，在第一温度下将至少一种选自环氧丙烷，环氧乙烷和环氧丁烷的混合物加入混合物中，使得混合物反应以形成反应混合物，向反应混合物中加入路易斯酸催化剂，使包含第二催化剂的反应混合物具有小于第一温度的第二温度，并加入另外的选自环氧丙烷，环氧乙烷和环氧丁烷在第二温度下加入到反应后的混合物中，形成至少60％的droxyl基含量和大于2,500g / mol的数均分子量。

29. 发明公开

EP2904027A1 MACROMER AND PROCESS FOR MAKING POLYMER POLYOLS 有权
标题翻译：大分子单体和方法，用于制备聚合物多元醇
公开(公告)号：EP2904027A1
公开(公告)日：2015-08-12
申请号：EP13779654.6
申请日：2013-09-23
申请人： Dow Global Technologies LLC
发明人： BORELLA, Ricco, B. , CLAUSSSENS, Sven , MASY, Jean-Paul , DE LOOS, Stijn
IPC分类号： C08G18/63 , C08G18/40
CPC分类号： C08L25/12 , C08G18/4072 , C08G18/632 , C08G18/636 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08G2650/58 , C08J9/0061 , C08J9/12 , C08J2375/08 , C08J2425/12
摘要： Polymer polyols are made by polymerizing an ethylenically unsaturated monomer in a continuous polyol phase. The polymerization is stabilized with a macromer or a pre-formed polymer made by polymerizing or copolymerizing the macromer. The macromer is a random polymer of propylene oxide and ethylene oxide in defined ratios, which also contains polymerization carbon-carbon double or triple bond. Polymer polyols made in the process exhibit little viscosity rise when blended with water. Flexible polyurethane foam made from the polymer polyol exhibits excellent hardness, have good surface characteristics and, when pigmented, exhibit good, uniform coloration.

30. 发明授权

EP3478744B1 PROCESS FOR MAKING POLYETHER DIOLS 有权
公开(公告)号：EP3478744B1
公开(公告)日：2020-05-13
申请号：EP17731760.9
申请日：2017-06-12
申请人： Dow Global Technologies, LLC
发明人： MASY, Jean-Paul , TÜRÜNÇ, Oguz
IPC分类号： C08G65/26 , C08G65/334

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