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21. 发明申请

WO2012006264A1 POLYURETHANES MADE USING ZINC CATALYSTS 审中-公开
标题翻译：使用ZINC催化剂制备聚氨酯
公开(公告)号：WO2012006264A1
公开(公告)日：2012-01-12
申请号：PCT/US2011/042920
申请日：2011-07-05
申请人： DOW GLOBAL TECHNOLOGIES LLC , KEATON, Richard , MARGL, Peter , ROMER, Duane , WILMOT, Nathan , DUGGAL, Rajat , CHANSARKAR, Rashmi
发明人： KEATON, Richard , MARGL, Peter , ROMER, Duane , WILMOT, Nathan , DUGGAL, Rajat , CHANSARKAR, Rashmi
IPC分类号： C08G18/22 , C08G18/48 , C08G18/66 , C08G18/08
CPC分类号： C08G18/7671 , B01J31/2243 , B01J2231/14 , B01J2531/26 , C08G18/0885 , C08G18/18 , C08G18/222 , C08G18/3206 , C08G18/4841 , C08G18/4883 , C08G18/6674 , Y02P20/52
摘要： Polyisocyanate-based polymers are formed by curing a reaction mixture containing at least one polyisocyanate and at least one isocyanate-reactive compound having at least two isocyanate-reactive groups in the presence of a zinc catalyst that contains at least one zinc atom associated with a polydentate ligand that contains at least one nitrogen-containing complexing site.
摘要翻译：多异氰酸酯基聚合物通过在含有至少一个与多齿相关的锌原子的锌催化剂的存在下固化含有至少一种多异氰酸酯和至少一种具有至少两个异氰酸酯反应性基团的异氰酸酯反应性化合物的反应混合物而形成配体，其含有至少一个含氮络合位点。

22. 发明申请

WO2019218372A1 A POLYISOCYANATE COMPONENT, A POLYURETHANE FOAMING SYSTEM AND AN ARTICLE MADE THEREFROM 审中-公开
公开(公告)号：WO2019218372A1
公开(公告)日：2019-11-21
申请号：PCT/CN2018/087581
申请日：2018-05-18
申请人： DOW GLOBAL TECHNOLOGIES LLC , FENG, Yanli , ZHOU, Weijun , BERTUCELLI, Luigi , DUGGAL, Rajat , GU, Yibei , LIU, Wei , MICHELETTI, Davide
发明人： FENG, Yanli , ZHOU, Weijun , BERTUCELLI, Luigi , DUGGAL, Rajat , GU, Yibei , LIU, Wei , MICHELETTI, Davide
IPC分类号： C08G18/58 , C08G18/76
摘要： A polyisocyanate component, a polyurethane foaming system, and an article made therefrom, wherein the polyisocyanate component includes (a) a preformed mixture including an aromatic oxazolidone compound that is the reaction product of at least one aromatic epoxide and at least one first polyisocyanate having an average isocyanate functionality of no more than 2.7 and greater than 1.8, in the presence of at least one catalyst, the aromatic oxazolidone compound includes at least one free isocyanate group and at least one aromatic oxazolidone group, the aromatic oxazolidone group includes an aromatic group and an oxazolidone group, and (b) at least one second polyisocyanate has an average isocyanate functionality equal to or greater than 2.7 and less than 6.0. The second polyisocyanate is added to the preformed mixture to form the polyisocyanate component. The polyisocyanate component has a viscosity of no more than 4.0 Pa-sat 25°C, an aromatic oxazolidone group content of 2 weight percent to 10 weight percent based on a total weight of the polyisocyanate component, and an average isocyanate functionality of from 1.8 to 6.0.

23. 发明申请

WO2018097874A1 TOUGHENED URETHANE ACRYLATE COMPOSITIONS 审中-公开
公开(公告)号：WO2018097874A1
公开(公告)日：2018-05-31
申请号：PCT/US2017/050475
申请日：2017-09-07
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： QIAN, Huifeng , DUGGAL, Rajat , SHAFI, Muhammad A. , PELLACANI, Luigi , SHAH, Harshad M.
IPC分类号： C08G18/76 , C08G18/12 , C09D175/16 , C08G18/48 , C09J175/16
摘要： In various embodiments, a resin composition includes a urethane (meth)acrylate, a reactive diluent, and a urethane (meth)acrylate toughener. The urethane (meth)acrylate toughener includes at least one additional polyol having a number average molecular weight Mn of greater than 1,000 g/mol. Cured articles made from the resin composition have an average fracture toughness (K Ic ) value from 1 MPa*m 1/2 to 3 MPa*m 1/2 when measured in accordance with ASTM D5045. Processes for making the resin composition as well as processes using the resin composition are also provided.

24. 发明申请

WO2016069437A1 HYDROPHILIC PREPOLYMER FOR POLYURETHANE FOAMS 审中-公开
标题翻译：用于聚氨酯泡沫的水解制剂
公开(公告)号：WO2016069437A1
公开(公告)日：2016-05-06
申请号：PCT/US2015/057295
申请日：2015-10-26
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： SRIVASTAVA, Yasmin N. , GAMBOA, Rogelio , DUGGAL, Rajat
IPC分类号： C08G18/76 , C08G18/48 , C08G101/00
CPC分类号： C08G18/12 , A47C27/14 , A47G9/10 , A47G2009/1018 , C08G18/14 , C08G18/4804 , C08G18/4812 , C08G18/4833 , C08G18/4837 , C08G18/485 , C08G18/7671 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083 , C08G2350/00 , C08J9/00 , C08J2375/08 , C08G18/302
摘要： A polyurethane foam for comfort application, includes the reaction product of a first composition that includes from 20 wt% to 80 wt% of an aqueous component and from 20 wt% to 80 wt% of a hydrophilic isocyanate-terminated prepolymer component. The aqueous component includes at least 90 wt% of water based on the total weight of the aqueous component and the hydrophilic isocyanate-terminated prepolymer component has a free NCO content from 1 wt% to 15 wt% and is a reaction product of a second composition that includes an isocyanate component and an isocyanate-reactive component. The isocyanate component includes at least 90 wt% of methylenediphenyl diisocyanate (MDI) and a weight ratio of 4,4'-methylene diphenylisocyanate isomer to 2,4'- methylene diphenylisocyanate isomer greater than 1:1 and less than 10:1, the isocyanate-reactive component including polyethylene glycol and a polyoxypropylene-polyoxyethylene polyol having a molecular weight of from 3000 g/mole to 7500 g/mole and a polyoxyethylene content of at least 50 wt%, and the hydrophilic isocyanate terminated prepolymer component having an polyoxyethylene content from 45 wt% to 75 wt%, based on the total weight of the second composition.
摘要翻译：用于舒适应用的聚氨酯泡沫包括第一组合物的反应产物，其包含20重量％至80重量％的水性组分和20重量％至80重量％的亲水异氰酸酯封端的预聚物组分。含水组分包含至少90重量％的水，基于水性组分的总重量，亲水异氰酸酯封端的预聚物组分具有1重量％至15重量％的游离NCO含量，并且是第二组合物的反应产物其包括异氰酸酯组分和异氰酸酯反应性组分。异氰酸酯组分包括至少90重量％的亚甲基二苯基二异氰酸酯（MDI）和4,4'-亚甲基二苯基异氰酸酯异构体与2,4'-亚甲基二苯基异氰酸酯异构体的重量比大于1:1且小于10:1，异氰酸酯反应性成分，包括分子量为3000g / mol〜7500g / mol，聚氧乙烯含量为50重量％以上的聚乙二醇和聚氧丙烯 - 聚氧乙烯多元醇，亲水性异氰酸酯封端的预聚物成分的聚氧乙烯含量基于第二组合物的总重量从45重量％至75重量％。

25. 发明申请

WO2014099666A3 EPOXY COMPOSITION 审中-公开
公开(公告)号：WO2014099666A3
公开(公告)日：2014-06-26
申请号：PCT/US2013/075037
申请日：2013-12-13
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： CHANG, Kwanho , XIE, Jia , GE, Shouren , WILMOT, Nathan , DUGGAL, Rajat
IPC分类号： C08G59/06 , C08G59/64 , C08K5/56
摘要： An epoxy composition that includes an epoxy-terminated prepolymer, an alkanolamine hardener having at least one hydroxyl group and an organometallic compound, where amine groups of the alkanolamine hardener react with epoxy groups of the epoxy-terminated prepolymer in a stoichiometric ratio to form a cured epoxy composition. The epoxy-terminated prepolymer is formed from a reaction product of an amine terminated polymeric polyol and a molar excess of epoxy groups in an epoxy monomer, relative to a molar amount of amine groups in the amine terminated polymeric polyol.

26. 发明申请

WO2014031181A1 POLYURETHANES MADE USING BISMUTH THIOCARBAMATE OR THIOCARBONATE SALTS AS CATALYSTS 审中-公开
标题翻译：使用硼酸三甲酯或碳酸氢钠作为催化剂制备的聚氨酯
公开(公告)号：WO2014031181A1
公开(公告)日：2014-02-27
申请号：PCT/US2013/033832
申请日：2013-03-26
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： KEATON, Richard, J. , MARGL, Peter, M. , BOELTER, Scott, D. , ROMER, Duane, R. , WILMOT, Nathan , DUGGAL, Rajat
IPC分类号： C08G18/65 , C08G18/76 , C08G18/22
CPC分类号： C08G18/227 , C08G18/10 , C08G18/14 , C08G18/3206 , C08G18/4883 , C08G18/6564 , C08G18/7664 , C08G18/7671 , C08G2101/005 , C08G2101/0058
摘要： Polyisocyanate-based polymers are formed by curing a reaction mixture containing at least one polyisocyanate and at least one isocyanate-reactive compound having at least two isocyanate-reactive groups in the presence of a bismuth mono- or dithiocarbamate or mono- or dithiocarbonate salt.
摘要翻译：基于聚异氰酸酯的聚合物是通过在含有铋或二硫代氨基甲酸铋或单 - 或二硫代碳酸盐的存在下固化含有至少一种多异氰酸酯和至少一种具有至少两个异氰酸酯反应性基团的异氰酸酯反应性化合物的反应混合物形成的。

27. 发明申请

WO2013048806A1 IMPROVING COMPRESSION SET PROPERTY IN SILYLATED POLYMERS 审中-公开
标题翻译：改进硅胶聚合物的压缩性能
公开(公告)号：WO2013048806A1
公开(公告)日：2013-04-04
申请号：PCT/US2012/055748
申请日：2012-09-17
申请人： DOW GLOBAL TECHNOLOGIES LLC , VYAKARANAM, Kamesh R. , ZHANG, Ling , MINNIKANTI, Venkat S. , LATHAM, Dwight D. , ARSHAD, Sara , DUGGAL, Rajat , KOONCE, William A.
发明人： VYAKARANAM, Kamesh R. , ZHANG, Ling , MINNIKANTI, Venkat S. , LATHAM, Dwight D. , ARSHAD, Sara , DUGGAL, Rajat , KOONCE, William A.
IPC分类号： C08G65/336 , C08L101/10 , C08L71/00
CPC分类号： C08L71/00 , C08G65/336 , C08K5/0025 , C08L71/02 , C08L75/04 , C08L75/08 , C08L83/00 , C08L83/06 , C08L101/10
摘要： Moisture curable compositions including silylated polymers and methods for producing the same are provided. A two component moisture curable system for producing a cured or cross-linked silylated polymer having improved compression set properties is provided. The two component system comprises a first formulation and a second formulation. The first formulation comprises a silylated polymer, water, and filler and the second formulation comprises the silylated polymer, a curing catalyst comprising at least one Brønsted acid, and a moisture scavenger. The final cured formulation may have a compression set, determined by ASTM D395 or ISO 815-1, of less than 100%, and in some examples less than 50% and in some examples less than 15%. This demonstrated improvement in compression set not only allows the silylated polymers to be used in applications where cyclic loads are applied but also enhances product durability.
摘要翻译：提供了包含甲硅烷基化聚合物的水溶性组合物及其制备方法。提供了用于制备具有改进的压缩永久变形特性的固化或交联的甲硅烷基化聚合物的双组分湿气可固化体系。双组分体系包括第一制剂和第二制剂。第一制剂包含甲硅烷基化聚合物，水和填料，第二制剂包含甲硅烷基化聚合物，包含至少一种布朗斯台德酸的固化催化剂和除湿剂。最终固化的制剂可以具有通过ASTM D395或ISO 815-1测定的压缩永久变形小于100％，在一些实例中小于50％，在一些实例中小于15％。这表明压缩变形的改进不仅允许将甲硅烷基化的聚合物用于应用循环载荷的应用中，而且可以提高产品的耐久性。

28. 发明申请

WO2012030969A1 ELASTOMERIC EPOXY MATERIALS AND THE USE THEREOF 审中-公开
标题翻译：弹性体环氧材料及其用途
公开(公告)号：WO2012030969A1
公开(公告)日：2012-03-08
申请号：PCT/US2011/049978
申请日：2011-08-31
申请人： DOW GLOBAL TECHNOLOGIES LLC , WILMOT, Nathan , DUGGAL, Rajat , MEDINA, Juan Carlos , SHAH, Harshad, M. , SCHROCK, Alan, K.
发明人： WILMOT, Nathan , DUGGAL, Rajat , MEDINA, Juan Carlos , SHAH, Harshad, M. , SCHROCK, Alan, K.
IPC分类号： C08G59/18
CPC分类号： C08G59/50 , C08G59/066 , C08G2650/50
摘要： Thermoset elastomer compositions are disclosed. Such elastomers are the reaction product of (a) an ambient temperature liquid epoxy-terminated prepolymer formed by reacting a polyoxyalkyleneamine having a molecular weight of from 3000 to 20,000 with an excess of epoxide, wherein the polyoxyalkyleneamine has at least 3 active hydrogen atoms and (b) a curing agent comprising at least one amine or polyamine having an equivalent weight of less than 200 and having 2 to 5 active hydrogen atoms. Such elastomers can be used in applications such as for sealants, adhesives, coatings, gaskets, jointing and cast elastomers.
摘要翻译：公开了热固性弹性体组合物。这样的弹性体是（a）通过使分子量为3000-20,000的聚氧亚烷基胺与过量的环氧化物反应形成的常温液体环氧端基预聚物的反应产物，其中聚氧亚烷基胺具有至少3个活性氢原子和（ b）固化剂，其包含至少一种当量小于200且具有2至5个活性氢原子的胺或多胺。这类弹性体可用于密封胶，粘合剂，涂料，垫片，连接和浇铸弹性体等应用。

29. 发明申请

WO2012003212A1 TIN FREE SILYL-TERMINATED POLYMERS 审中-公开
公开(公告)号：WO2012003212A1
公开(公告)日：2012-01-05
申请号：PCT/US2011/042355
申请日：2011-06-29
申请人： DOW GLOBAL TECHNOLOGIES LLC , VYAKARANAM, Kameswara , ZHANG, Ling , KOONCE, William , MEDINA, Juan , KAILASAM, Ganesh , DUGGAL, Rajat , WILMOT, Nathan
发明人： VYAKARANAM, Kameswara , ZHANG, Ling , KOONCE, William , MEDINA, Juan , KAILASAM, Ganesh , DUGGAL, Rajat , WILMOT, Nathan
IPC分类号： C08G18/18 , C08G18/20 , C08G18/22 , C08G18/28 , C08G18/71 , C08G18/76 , C08G18/83 , C08G77/46 , C08G18/48
CPC分类号： C08G18/222 , C08G18/18 , C08G18/20 , C08G18/289 , C08G18/3893 , C08G18/4825 , C08G18/718 , C08G18/7621 , C08G18/7671 , C08G18/837
摘要： Embodiments of the invention provide for methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The method comprises providing a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polyoxyalkylene polymers, reacting the hydrosilylated polyoxyalkylene polymers with at least one isocyanate in the presence of a first tin-free catalyst to form an isocyanate reacted hydrosilylated polymer, and optionally reacting the isocyanate reacted hydrosilylated polymer with a polyol having a nominal functionality of at least 2 to form a polyol reacted crosslinkable silane-terminated polymer.
摘要翻译：本发明的实施方案提供了制备包含在每个分子中具有至少一个可交联甲硅烷基的可交联的硅烷封端的聚合物的组合物的方法。该方法包括提供在每个分子中具有至少一个不饱和基团和至少一个醇羟基的聚合物，向该聚合物中加入每个分子中具有氢 - 硅键和交联性甲硅烷基的化合物和氢化硅烷化催化剂从而携带排出氢化硅烷化反应以形成包含氢化硅烷化的聚氧化烯聚合物的组合物，在第一无锡催化剂存在下使氢化硅烷化聚氧化烯聚合物与至少一种异氰酸酯反应，以形成异氰酸酯反应的氢化硅烷化聚合物，并任选地使异氰酸酯反应的硅烷化聚合物与具有至少2的标称官能度的多元醇，以形成多元醇反应的可交联的硅烷封端的聚合物。

30. 发明授权

EP2900725B1 ADDUCT COMPOSITIONS 有权
公开(公告)号：EP2900725B1
公开(公告)日：2020-05-13
申请号：EP13773526.2
申请日：2013-09-24
申请人： Dow Global Technologies LLC
发明人： PADILLA-ACEVEDO, Angela I. , WILMOT, Nathan , DUGGAL, Rajat , SHAH, Harshad, M. , CHANG, Kwanho
IPC分类号： C08G59/06 , C08G59/18 , C08G65/26

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