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    • 21. 发明授权
    • Green strength of elastomers
    • 弹性体的绿色强度
    • US4124546A
    • 1978-11-07
    • US692267
    • 1976-06-03
    • Diego C. Rubio, Jr.Richard G. BauerRichard M. Scriver, Jr.
    • Diego C. Rubio, Jr.Richard G. BauerRichard M. Scriver, Jr.
    • C08F36/04C08L21/00C08L7/00C08L9/00
    • C08F36/045C08L21/00
    • Improved green strength of elastomers made from monomers selected from the class consisting of at least one conjugated diene having from 4 to 10 carbon atoms, olefins having from 2 to 14 carbon atoms along with a diene having from 4 to 6 carbon atoms, and combinations thereof, is achieved by adding an amount of a polydimethylbutadiene compound to form a blend having a glass transition temperature of from about 0.degree. C to about -100.degree. C. The polydimethylbutadiene compound may be merely the homopolymer of dimetylbutadiene, the copolymer, the terpolymer or the tetrapolymer of dimethylbutadiene in various combinations with monomers such as butadiene, isoprene, piperylene, acrylonitrile, vinylidene chloride, vinyl pyridine, methacrylic acid and vinyl substituted aromatic compounds.
    • 由选自至少一种具有4至10个碳原子的共轭二烯,具有2至14个碳原子的烯烃以及具有4至6个碳原子的二烯的单体制成的弹性体的改善的生坯强度,以及其组合 通过加入一定量的聚二甲基丁二烯化合物以形成玻璃化转变温度为约0℃至约-100℃的共混物来实现。聚二甲基丁二烯化合物可以仅仅是二甲基丁二烯的均聚物,共聚物,三元共聚物或 与丁二烯,异戊二烯,戊间二烯,丙烯腈,偏二氯乙烯,乙烯基吡啶,甲基丙烯酸和乙烯基取代的芳族化合物等单体的各种组合的二甲基丁二烯的四元共聚物。
    • 25. 发明授权
    • Comb polymers having a halobutyl rubber backbone
    • 具有卤代丁基橡胶主链的梳理聚合物
    • US5342896A
    • 1994-08-30
    • US47638
    • 1993-06-10
    • George JalicsRichard G. Bauer
    • George JalicsRichard G. Bauer
    • C08G81/02C08F236/16C08F236/18
    • C08G81/021
    • The subject invention relates to comb polymers having a halobutyl rubber backbone and to techniques for synthesizing such polymers. The comb polymers of this invention can be thermoplastic elastomers. For instance, halobutyl rubbers having sidechains which are derived from vinyl aromatic monomers are thermoplastic elastomers which can be made by a technique of the subject invention. Such thermoplastic elastomers typically have a chlorobutyl rubber backbone and side chains which are comprised of polystyrene. The subject invention more specifically discloses a process for grafting a lithium terminated vinyl aromatic polymer onto a halobutyl rubber which comprises: (1) capping the lithium terminated vinyl aromatic polymer with a diene monomer to produce a lithium terminated diene capped vinyl aromatic polymer, and (2) reacting the lithium terminated diene capped vinyl aromatic polymer with the halobutyl rubber to produce a halobutyl rubber having vinyl aromatic sidechains grafted thereto.
    • 本发明涉及具有卤代丁基橡胶骨架的梳形聚合物和用于合成这种聚合物的技术。 本发明的梳状聚合物可以是热塑性弹性体。 例如,具有衍生自乙烯基芳族单体的侧链的卤代丁基橡胶是可通过本发明的技术制备的热塑性弹性体。 这种热塑性弹性体通常具有氯丁基橡胶骨架和由聚苯乙烯组成的侧链。 本发明更具体地公开了一种将锂封端的乙烯基芳族聚合物接枝到卤代丁基橡胶上的方法,其包括:(1)用二烯单体封端锂封端的乙烯基芳族聚合物以制备锂封端的二烯封端的乙烯基芳族聚合物,和 2)使锂封端的二烯封端的乙烯基芳族聚合物与卤代丁基橡胶反应,以制备接枝有乙烯基芳族侧链的卤代丁基橡胶。