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    • 22. 发明授权
    • Herbicidal oxazolidines and methods of use
    • 除草剂恶唑烷及其使用方法
    • US4824468A
    • 1989-04-25
    • US107196
    • 1987-10-13
    • Eugene G. Teach
    • Eugene G. Teach
    • A01N43/76A01N47/16A01N47/38C07D263/04C07D263/06
    • C07D263/04A01N43/76A01N47/16A01N47/38
    • An oxazolidine having the formula ##STR1## wherein R is selected from the group consisting of alkyl, substituted alkyl, alkenyl, cycloalkyl, benzyl, alkoxyalkyl, carboalkoxyalkyl, alkylthioalkyl, phenyl, substituted phenyl, furanyl, phenoxyalkyl, carboalkoxy, substituted phenoxyalkyl, alkylamino, alkoxy, chloroethylamino, alkylthio, cycloalkylalkyl, cycloalkenylalkyl, phenylamino, substituted phenylamino, alkenylamino, and benzylamino; Z is selected from the group consisting of oxygen or sulfur; R.sub.1 is selected from the group consisting of alkyl or halosubstituted alkyl wherein the alkyl group has from 1 to 4 carbon atoms; and X and Y are the same or different and are selected from the group consisting of trifluoromethyl, chloro, bromo, fluoro, hydrogen, cyano, alkyl, thioalkyl, halothioalkyl, alkoxy and sulfonylalkyl, wherein the alkyl groups in each alkyl-containing moiety have from 1 to 4 carbon atoms. Also disclosed is a method of use.
    • 具有式的恶唑烷,其中R选自烷基,取代的烷基,烯基,环烷基,苄基,烷氧基烷基,烷氧基烷基,烷硫基烷基,苯基,取代的苯基,呋喃基,苯氧基烷基,烷氧羰基,取代的苯氧基烷基,烷基氨基, 烷氧基,氯乙基氨基,烷硫基,环烷基烷基,环烯基烷基,苯基氨基,取代的苯基氨基,烯基氨基和苄基氨基; Z选自氧或硫; R1选自烷基或卤代烷基,其中烷基具有1至4个碳原子; 并且X和Y相同或不同,并且选自三氟甲基,氯,溴,氟,氢,氰基,烷基,硫代烷基,卤代烷基,烷氧基和磺酰基烷基,其中每个含烷基部分中的烷基具有 1至4个碳原子。 还公开了一种使用方法。
    • 26. 发明授权
    • 1-(Substituted phenylthiocarbamyl) 3,3-disubstituted formamidines and
their use as pharmaceutical agents
    • 1-(取代的苯基硫代氨基甲酰基)3,3-二取代的甲酰胺及其作为药剂的用途
    • US4532348A
    • 1985-07-30
    • US169350
    • 1980-07-16
    • Ferenc M. PallosJack R. DeBaunEugene G. Teach
    • Ferenc M. PallosJack R. DeBaunEugene G. Teach
    • C07C335/18C07C157/09
    • C07C335/18
    • 1-(Substituted phenylthiocarbamyl) 3,3-disubstituted formamidine compounds having the structural formula ##STR1## wherein n is 1, 2 or 3,R is alkyl having 1 to 6 carbon atoms, alkoxy having 1 to 6 carbon atoms, alkylthio having 1 to 4 carbon atoms, halogen, nitro, acyl having 1 to 4 carbon atoms, hydroxyl and ##STR2## wherein R.sup.3 and R.sup.4 have the same meaning as R.sup.1 and R.sup.2 defined below,R.sup.1 and R.sup.2 are the same or different and are alkyl having 1 to 6 carbon atoms, or taken together represent the chain --(CH.sub.2).sub.p --(X).sub.m --(CH.sub.2).sub.q and forming a ring structure with the nitrogen to which they are bound wherein p is 1, 2 or 3, q is 2 or 3, X represents --O--, --S--, --SO--, --SO.sub.2 --, --NR.sup.3 --, R.sup.3 is hydrogen or alkyl having 1 to 6 carbon atoms, and m is 0 or 1 and their use as pharmaceutical agents.
    • 1-(取代的苯基硫代氨基甲酰基)3,3-二取代的甲脒化合物,其结构式为:其中n为1,2或3,R为具有1至6个碳原子的烷基,具有1至6个碳原子的烷氧基, 至4个碳原子,卤素,硝基,具有1至4个碳原子的酰基,羟基和其中R 3和R 4具有与下面定义的R 1和R 2相同的含义,R 1和R 2相同或不同, 或者一起代表链 - (CH 2)p - (X)m - (CH 2)q,并与它们所键合的氮形成环结构,其中p是1,2或3,q是 2或3,X表示-O - , - S - , - SO - , - SO 2 - , - NR 3 - ,R 3是氢或具有1至6个碳原子的烷基,m是0或1,并且它们作为药剂 。
    • 30. 发明授权
    • 5-Phenoxymethyl substituted oxazolidine herbicide antidotes
    • 5-苯氧基甲基取代的恶唑烷除草剂解毒剂
    • US4249932A
    • 1981-02-10
    • US49814
    • 1979-06-18
    • Eugene G. Teach
    • Eugene G. Teach
    • A01N25/32C07C323/25C07D263/04C07D263/06C07D303/34
    • C07D263/04A01N25/32C07C323/25C07D263/06C07D303/34
    • Substituted N-haloacyl oxazolidines as new compositions of matter useful as active herbicidal antidotes to protect against and decrease crop injury when used with thiolcarbamate herbicides when applied in various methods; improved herbicidal compositions and utility of said compositions to protect against and decrease phytotoxic crop injury when employing thiolcarbamate herbicides, and a two-part herbicide system consisting essentially of a first-part of one or more thiolcarbamate herbicides and a second-part of an effective antidote compound therefor, said antidote compounds of the class 5-substituted 3-haloacyl oxazolidines having the formula ##STR1## wherein XR.sub.1 is phenoxy, R is selected from the group consisting of haloalkyl, where halo is chloro or bromo, and p-methyl phenylsulfonylamido; and R.sub.2 and R.sub.3 are independently selected from lower alkyl.
    • 取代的N-卤代酰基恶唑烷作为用作活性除草剂的新物质组合物,用于当以各种方法施用时用于硫代氨基甲酸酯除草剂时防止和减少作物损伤; 改进的除草组合物和所述组合物在使用硫代氨基甲酸酯除草剂时防止和减少植物毒性作物损伤的效用,以及基本上由一种或多种硫代氨基甲酸酯除草剂的第一部分组成的两部分除草剂系统和有效解毒剂的第二部分 具有下式的化合物:具有式“IMAGE”的5-取代的3-卤代酰基恶唑烷的解毒剂化合物,其中XR1是苯氧基,R选自卤代烷基,其中卤素是氯或溴,和对甲基苯基磺酰氨基; 并且R 2和R 3独立地选自低级烷基。