会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 28. 发明申请
    • PREPARATION OF ISOBUTENE BY DISSOCIATION OF MTBE
    • 通过MTBE的分离制备ISOBUTEN
    • US20120142985A1
    • 2012-06-07
    • US13381680
    • 2010-06-16
    • Markus WinterbergDirk RoettgerArmin RixReiner BukohlWalter LuhHolger WiederholdGunnar SchillingChristian Boeing
    • Markus WinterbergDirk RoettgerArmin RixReiner BukohlWalter LuhHolger WiederholdGunnar SchillingChristian Boeing
    • C07C1/20F28F1/00
    • C07C11/09C07C1/20
    • The invention relates to a method for producing isobutene by cracking MTBE, wherein the following steps are carried out: a) MTBE synthesis; reacting isobutene-containing hydrocarbon mixtures (II) with methanol (III), contained in one or more methanol-containing streams (VIII, IX), on acidic ion exchangers obtaining a stream (IV) containing MTBE and TBA, b) MTBE separation; separating a stream (V) containing MTBE and TBA from stream (IV) by means of distillation, c) MTBE cracking; cracking the stream (V) on a heterogenic catalyst in the gas phase, thus obtaining a stream (VI) which contains at least isobutene, methanol, MTBE, water, and optionally TBA, d) isobutene separation; separating the stream (VI) by means of distillation, thus obtaining a stream (VII) containing more than 50 mass % of the amounts of methanol, TBA, and water contained in stream (VI), and a stream (XVII) containing isobutene, e) water separation; separating, water from the stream (VII) to below 1 mass % by means of distillation, thus obtaining a stream (VIII), f) recirculating; complete or partial recirculation of the methanol-containing stream (VIII) into the MTBE synthesis. The invention further relates to a tube bundle device comprising the following elements: i) tube bundle, ii) tube bottom, iii) deflection plates, iv) inner shell, iv) pressure bearing outer shell, comprising at least one inlet and outlet, vi) shell chamber, comprising a fluid releasing or absorbing heat, characterized in that the inner shell is connected to the deflection plates attached over the length of the tube bundle without a gap, or with a small gap, and is connected to the tube bottom, wherein the fluid present in the shell chamber encloses the inner shell on both sides.
    • 本发明涉及通过裂解MTBE生产异丁烯的方法,其中进行以下步骤:a)MTBE合成; 使含异丁烯的烃混合物(II)与含有一种或多种含甲醇的物流(VIII,IX)中的甲醇(III)在酸性离子交换剂上反应,得到含有MTBE和TBA的物流(Ⅳ),b)MTBE分离; 通过蒸馏从流(IV)分离含有MTBE和TBA的物流(V); c)MTBE裂解; 在气相中的异源催化剂上裂解物流(V),从而获得至少含有异丁烯,甲醇,MTBE,水和任选的TBA的流(VI),d)异丁烯分离; 通过蒸馏分离料流(VI),从而获得含有大于50质量%的流(VI)中所含的甲醇,TBA和水量的流(VII)和含有异丁烯的料流(XVII) e)水分离; 通过蒸馏从水(VII)中将水分离成低于1质量%,从而获得流(VIII),f)再循环; 将含甲醇的物流(VIII)完全或部分再循环到MT​​BE合成中。 本发明还涉及一种管束装置,其包括以下元件:i)管束,ii)管底,iii)偏转板,iv)内壳,iv)承压外壳,包括至少一个入口和出口,vi )壳体,其包括释放或吸收热量的流体,其特征在于,所述内壳连接到在所述管束的长度上连接的所述偏转板,而没有间隙或具有小间隙,并且连接到所述管底部, 其中存在于壳室中的流体在两侧封闭内壳。
    • 29. 发明申请
    • PROCESS FOR PREPARING ISOBUTENE BY CLEAVING MTBE-CONTAINING MIXTURES
    • 通过清除含MTBE的混合物制备ISOBUTEN的方法
    • US20110118523A1
    • 2011-05-19
    • US13054115
    • 2009-05-19
    • Markus WinterbergDirk RoettgerRainer BukohlHolger WiederholdWalter Luh
    • Markus WinterbergDirk RoettgerRainer BukohlHolger WiederholdWalter Luh
    • C07C1/20
    • C07C1/20C07C7/04C07C2521/12C07C2523/02C07C11/09
    • A process for preparing isobutene from MTBE-containing mixtures, including: a) in a reactor, cleaving a mixture obtained from an MTBE-containing feedstock and/or an MTBE-containing stream, affording a stream of reaction products including isobutene, methanol, MTBE, and by-products, which are a1) high boilers having a boiling range above 55° C. at a pressure of 0.1 MPa, a2) medium boilers having a boiling range of 12 to 55° C. at a pressure of 0.1 MPa, and a3) low boilers having a boiling range below 12° C. at a pressure of 0.1 MPa; b) distillatively separating stream into a stream which contains the isobutene product and low boilers, and a stream which contains MTBE, methanol, medium boilers and high boilers; c) distillatively separating stream to obtain an MTBE-containing stream and a methanol-containing high boiler stream; and d) recycling an MTBE-containing stream into a) of the process, the medium boilers being removed completely or partially before d) from the streams rich in medium boilers.
    • 一种从含MTBE的混合物制备异丁烯的方法,包括:a)在反应器中,裂解从含有MTBE的原料和/或含MTBE的料流获得的混合物,得到包括异丁烯,甲醇,MTBE ,副产物,a1)沸点范围在55℃以上,压力为0.1MPa的高锅炉,a2)沸点范围为12〜55℃,压力为0.1MPa的中等锅炉, 和a3)在0.1MPa的压力下沸点低于12℃的低锅炉; b)蒸馏分离成含有异丁烯产物和低锅炉的料流,以及含有MTBE,甲醇,中等锅炉和高锅炉的料流; c)蒸馏分离料流以获得含MTBE的料流和含甲醇的高锅炉料流; 和d)将含MTBE的流再循环到该方法的一个步骤中,在d)从富含中等锅炉的物流中完全或部分地去除中等锅炉。