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21. 发明授权

US5210084A Fungicidal substituted amino acid amides 失效
标题翻译：杀真菌剂替代氨基酸
公开(公告)号：US5210084A
公开(公告)日：1993-05-11
申请号：US514919
申请日：1990-04-25
申请人： Detlef Wollweber , Thomas Seitz , Wilhelm Brandes
发明人： Detlef Wollweber , Thomas Seitz , Wilhelm Brandes
IPC分类号： C07D295/00 , A01N47/10 , A01N47/12 , A01N47/18 , C07C269/06 , C07C271/22 , C07C271/24 , C07C271/34 , C07C271/36 , C07C323/41 , C07D213/40 , C07D265/30 , C07D295/18 , C07D295/185 , C07D521/00
CPC分类号： C07D295/185 , A01N47/12 , A01N47/18 , C07C271/22 , C07C323/41 , C07C2101/14
摘要： Combating fungi with substituted amine acid derivatives of the formula ##STR1## in which R.sup.1 represents alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, cycloalkyl or cycloalkenyl,R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are identical or different and represent hydrogen, cycloalkyl or alkyl, orR.sup.3 and R.sup.4, together with the carbon atom to which they are bonded, form a cycloalkyl ring, andR.sup.6 represents hydrogen, alkyl, alkenyl, alkinyl, cyanoalkyl, unsubstituted or substituted phenylalkyl, unsubstituted or substituted phenyl or unsubstituted or substituted cycloalkyl, or represents unsubstituted or substituted heterocyclyl or heterocyclylalkyl, orR.sup.5 and R.sup.6, together with the nitrogen atom to which they are bonded, represent a heterocyclyl radical, which can contain further hetero atoms.
摘要翻译：用式（I）的取代的胺酸衍生物与R1代表烷基，烯基，炔基，卤代烷基，卤代烯基，卤代链烯基，环烷基或环烯基，R2，R3，R4和R5相同或不同，代表氢，环烷基或烷基，或R 3和R 4与它们所键合的碳原子一起形成环烷基环，R 6表示氢，烷基，烯基，炔基，氰基烷基，未取代或取代的苯基烷基，未取代或取代的苯基或未取代的或取代的环烷基，或表示未取代或取代的杂环基或杂环基烷基，或者R 5和R 6与它们所键合的氮原子一起表示可含有其它杂原子的杂环基。

22. 发明授权

US5015757A Substituted fluorocinnamonnitriles 失效
标题翻译：取代氟肉桂腈
公开(公告)号：US5015757A
公开(公告)日：1991-05-14
申请号：US526363
申请日：1990-05-21
申请人： Detlef Wollweber , Wilhelm Brandes
发明人： Detlef Wollweber , Wilhelm Brandes
IPC分类号： A01N43/36 , C07D207/34
CPC分类号： A01N43/36 , C07D207/34
摘要： 3-cyano-4-phenyl-pyrroles of the formula ##STR1## in which R stands for halogen, alkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy or halogenoalkylthio,have been found. These compounds are useful as fungicides.

23. 发明授权

US5158962A Fungicidal substituted amino acid amides 失效
标题翻译：杀真菌剂替代氨基酸
公开(公告)号：US5158962A
公开(公告)日：1992-10-27
申请号：US591912
申请日：1990-10-02
申请人： Thomas Seitz , Detlef Wollweber , Wilhelm Brandes
发明人： Thomas Seitz , Detlef Wollweber , Wilhelm Brandes
IPC分类号： C07D307/06 , A01N47/22 , A01N53/00 , C07C269/06 , C07C271/22 , C07C271/50 , C07C271/54 , C07C271/56 , C07C317/32 , C07D213/40 , C07D521/00
CPC分类号： C07C271/54 , A01N47/22 , A01N53/00
摘要： Fungicidal substituted amino acid amides of the formula ##STR1## in which Ar and Ar' are identical or different and represent unsubstituted or substituted aryl, unsubstituted or substituted aralkyl, unsubstituted or substituted heteroaryl and unsubstituted or substituted heteroarylalkyl, andR.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are identical or different and represent hydrogen or alkyl orR.sup.3 and R.sup.4, together with the carbon atom to which they are bonded, form a cycloalkyl ring.
摘要翻译：其中Ar和Ar'相同或不同并且表示未取代或取代的芳基，未取代或取代的芳烷基，未取代或取代的杂芳基和未取代或取代的杂芳基烷基的式（I）的杀真菌取代的氨基酸酰胺，和R1，R2 ，R 3，R 4，R 5和R 6相同或不同，表示氢或烷基或R 3和R 4与它们所键合的碳原子一起形成环烷基环。

24. 发明授权

US4973350A Fungicidal 1-aminomethyl-3-(2-fluoro-3-chlorophenyl)-4-cyanopyrrole derivatives 失效
标题翻译：杀真菌剂1-氨基甲基-3-（2-氟-3-氯苯基）-4-氰基吡咯衍生物
公开(公告)号：US4973350A
公开(公告)日：1990-11-27
申请号：US307390
申请日：1989-02-06
申请人： Detlef Wollweber , Wilhelm Brandes
发明人： Detlef Wollweber , Wilhelm Brandes
IPC分类号： A01N43/36 , A01N43/40 , C07D207/34 , C07D401/12 , C07D403/06 , C07D405/12 , C07D409/12
CPC分类号： C07D401/12 , A01N43/36 , A01N43/40 , C07D207/34 , C07D405/12
摘要： Fungicidal 1-aminomethyl-3-(2-fluoro-3-chlorophenyl)-4-cyano-pyrrole derivatives of the formula ##STR1## in which R stands for a ##STR2## wherein R.sup.1 stands for optionally substituted alkyl, for alkenyl, alkinyl or cycloalkyl, or for in each case optionally substituted aralkyl or aryl,R.sup.2 stands for in each case optionally substituted heterocyclylalkyl, heterocyclylalkenyl, heterocyclylalkinyl or heterocyclyl, for dialkylaminoalkyl or for in each case optionally substituted cycloalkylalkyl or phenethyl,R.sup.3 stands for hydrogen or alkyl andR.sup.4 stands for cyano, alkanoyl, alkoxycarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, for alkylsulphinyl, for alkylsulphonyl, for phenylsulphinyl or for phenylsulphonyl.The compound where R is replaced by an election-withdrawing leaving group is a novel intermediate.
摘要翻译：式（I）的杀真菌剂1-氨基甲基-3-（2-氟-3-氯苯基）-4-氰基 - 吡咯衍生物，其中R代表一个，其中R1代表任选取代的烷基，对于链烯基，炔基或环烷基，或者在每种情况下均为任选取代的芳烷基或芳基，R 2在每种情况下表示任选取代的杂环基烷基，杂环基烯基，杂环基炔基或杂环基，对于二烷基氨基烷基或在每种情况下任选取代的环烷基烷基或苯乙基，R 3 代表氢或烷基，R4代表氰基，烷酰基，烷氧基羰基，烷基氨基羰基，二烷基氨基羰基，烷基亚磺酰基，烷基磺酰基，苯基亚磺酰基或苯基磺酰基。其中R由选举撤离离去基团代替的化合物是新的中间体。

25. 发明授权

US4904687A Fungicidal substituted 3-arylpyrroles 失效
标题翻译：杀真菌剂取代的3-芳基吡咯
公开(公告)号：US4904687A
公开(公告)日：1990-02-27
申请号：US220055
申请日：1988-07-15
申请人： Detlef Wollweber , Wilhelm Brandes
发明人： Detlef Wollweber , Wilhelm Brandes
IPC分类号： A01N43/36 , A01N43/40 , C07D207/32 , C07D207/337 , C07D401/04 , C07D405/04
CPC分类号： C07D207/337 , A01N43/36 , A01N43/40 , C07D401/04 , C07D405/04
摘要： Fungicidally active substituted 3-arylpyrroles of the formula ##STR1## in which Ar represents optionally substituted aryl or optionally substituted heteroaryl.
摘要翻译：式（I）的杀真菌活性取代的3-芳基吡咯，其中Ar表示任选取代的芳基或任选取代的杂芳基。

26. 发明申请

US20050009839A1 Novel azoles having an insecticidal action 有权
标题翻译：具有杀虫作用的新型唑类
公开(公告)号：US20050009839A1
公开(公告)日：2005-01-13
申请号：US10474947
申请日：2002-04-10
申请人： Peter Jeshcke , Michael Beck , Wolfgang Kramer , Detlef Wollweber , Christoph Erdelen , Angelika Lubos-Erdelen , Andreas Turberg , Olaf Hansen , Hans-Dieter Martin , Piet Sauer
发明人： Peter Jeshcke , Michael Beck , Wolfgang Kramer , Detlef Wollweber , Christoph Erdelen , Angelika Lubos-Erdelen , Andreas Turberg , Olaf Hansen , Hans-Dieter Martin , Piet Sauer
IPC分类号： A01N43/78 , A01N47/40 , A01N51/00 , A61K31/426 , A61K31/427 , A61K31/4436 , A61K31/4439 , A61P33/00 , C07D277/20 , C07D277/36 , C07D277/38 , C07D277/42 , C07D401/12 , C07D409/12 , C07D417/12 , A01N43/50 , A01N43/40 , A01N43/76 , C07D413/02 , C07D417/02 , C07
CPC分类号： C07D277/20 , A01N47/40 , A01N51/00 , C07D277/38 , C07D417/12
摘要： The present application relates to novel heterocyclic compounds, to processes for their preparation, and to their use as crop protection agents, particularly for controlling animal pests.
摘要翻译：本申请涉及新型杂环化合物，其制备方法及其作为作物保护剂的用途，特别是用于防治动物害虫。

27. 发明授权

US06528651B1 Method for production of 1,3-disubtituted 2-nitroguanidines 有权
标题翻译：生产1,3-二取代的2-硝基胍的方法
公开(公告)号：US06528651B1
公开(公告)日：2003-03-04
申请号：US10149891
申请日：2002-06-14
申请人： Kai van Laak , Wolfram Sirges , Detlef Wollweber
发明人： Kai van Laak , Wolfram Sirges , Detlef Wollweber
IPC分类号： C07D21302
CPC分类号： C07D277/32 , C07D213/61 , C07D307/14
摘要： The present invention relates to a process for the preparation of compounds of the formula (I) by reacting compounds of the formula (II) in which Het, R1, R2 and R4 are as defined in the description, with anhydrous hydrogen chloride or compounds which generate hydrogen chloride.
摘要翻译：本发明涉及通过使式（II）化合物（其中Het，R 1，R 2和R 4如说明书中所定义）与无水氯化氢反应制备式（I）化合物的方法或产生氯化氢。

28. 发明授权

US4912229A Process for the preparation of 3-cyano-4-aryl-pyrroles 失效
标题翻译： 3-氰基-4-芳基吡咯的制备方法
公开(公告)号：US4912229A
公开(公告)日：1990-03-27
申请号：US197065
申请日：1988-05-19
申请人： Detlef Wollweber
发明人： Detlef Wollweber
IPC分类号： C07B61/00 , C07D207/22 , C07D207/34
CPC分类号： C07D207/22 , C07D207/34
摘要： A process for the preparation of a 3-cyano-4-aryl-pyrrole of the formula ##STR1## in which Ar is optionally substituted heteroaryl or aryl, which comprises (a) reacting an .alpha.-cyanoacrylic acid derivative of the formula ##STR2## in which R.sup.1 is amino or alkoxy, with an isocyanoacetic acid ester of the formula ##STR3## in which R.sup.2 is alkyl, in the presence of a base thereby to produce a .DELTA..sup.2 -pyrroline-2-carboxylic acid derivative of the formula ##STR4## in which X represents hydrogen or an equivalent of an inorganic or organic cation,and (b) oxidatively decarboxylating the .DELTA..sup.2 -pyrroline-2-carboxylic acid. The end products are known fungicides and the intermediates IVa are new and themselves fungicidally active.
摘要翻译：制备式（I）的3-氰基-4-芳基吡咯的方法，其中Ar是任选取代的杂芳基或芳基，其包括（a）使式（I）的α-氰基丙烯酸衍生物与式其中R 1是氨基或烷氧基，与式（III）的异氰酸乙酸酯（其中R 2是烷基）在碱的存在下反应，生成DELTA 2-吡咯啉-2 （IVa）的羧酸衍生物，其中X表示氢或当量的无机或有机阳离子，和（b）使DELTA 2-吡咯啉-2-羧酸氧化脱羧。最终产品是已知的杀真菌剂，中间体IVa是新的并且其本身具有杀真菌活性。

29. 发明授权

US06444667B1 Synergistic insecticidal mixtures 有权
标题翻译：协同杀虫混合物
公开(公告)号：US06444667B1
公开(公告)日：2002-09-03
申请号：US09700675
申请日：2000-11-17
申请人： Wolfram Andersch , Hans-Jürgen Schnorbach , Detlef Wollweber
发明人： Wolfram Andersch , Hans-Jürgen Schnorbach , Detlef Wollweber
IPC分类号： A61K31535
CPC分类号： A01N43/22 , A01N51/00 , A01N47/40 , A01N2300/00
摘要： The invention relates to insecticidal mixtures of spinosyns and agonists or antagonists of nicotinic acetylcholine receptors for protecting plants against attack by pests.
摘要翻译：本发明涉及多杀菌素和烟酸乙酰胆碱受体的激动剂或拮抗剂的杀虫混合物，用于保护植物免受害虫袭击。

30. 发明授权

US06297195B1 Substituted triazoloazine sulphonamides 失效
标题翻译：取代的三唑啉磺酰胺
公开(公告)号：US06297195B1
公开(公告)日：2001-10-02
申请号：US09214773
申请日：1999-05-10
申请人： Ernst Rudolf F. Gesing , Mark Wilhelm Drewes , Johannes R. Jansen , Rolf Kirsten , Joachim Kluth , Klaus-Helmut Müller , Ulrich Philipp , Hans-Jochem Riebel , Otto Schallner , Detlef Wollweber , Markus Dollinger , Klaus Stenzel , Christoph Erdelen
发明人： Ernst Rudolf F. Gesing , Mark Wilhelm Drewes , Johannes R. Jansen , Rolf Kirsten , Joachim Kluth , Klaus-Helmut Müller , Ulrich Philipp , Hans-Jochem Riebel , Otto Schallner , Detlef Wollweber , Markus Dollinger , Klaus Stenzel , Christoph Erdelen
IPC分类号： A01N4388
CPC分类号： C07D487/04 , A01N43/90
摘要： The invention concerns novel substituted triazoloazine sulphonamides of formula (I) in which Q1 stands for nitrogen or a CH group: Q2 stands for nitrogen or a CH group; R1 stands for hydrogen or halogen, or for C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, C1-C4 alkylamino or di(C1-C4 alkyl)amino, in each case optionally substituted by hydroxy, halogen or C1-C4 alkoxy; R2 stands for hydrogen or halogen, or for C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, C1-C4 alkylamino or di(C1-C4 alkyl)amino, in each case optionally substituted by halogen; and Ar stands for 4-cyano-2,5-difluoro-phenyl, 2,6-dimethoxy-phenyl, 2-bromo-3-trifluoro-methyl-phenyl, 2-bromo-5-trifluoromethyl-phenyl, 6-chloro-pyridine-3-yl-methyl or one of the 5- or 6-member (hetero)cyclic groups mentioned in the description. The invention also concerns salts of these substances, a process for preparing the novel compounds, and their use as plant-treatment agents.
摘要翻译：本发明涉及式（I）的新型取代的三唑并乙酰胺，其中Q 1代表氮或CH基：Q 2代表氮或CH基; R1代表氢或卤素，或C1-C4烷基，C1-C4烷氧基，C1-C4烷硫基，C1-C4烷基氨基或二（C1-C4烷基）氨基，各自任选被羟基，卤素或C1- C4烷氧基; R2代表氢或卤素，或C1-C4烷基，C1-C4烷氧基，C1-C4烷硫基，C1-C4烷基氨基或二（C1-C4烷基）氨基，各自任选被卤素取代; Ar代表4-氰基-2,5-二氟 - 苯基，2,6-二甲氧基 - 苯基，2-溴-3-三氟 - 甲基 - 苯基，2-溴-5-三氟甲基 - 苯基，6-氯 - 吡啶-3-基 - 甲基或说明书中提到的5-或6-元（杂）环基之一。本发明还涉及这些物质的盐，一种制备新化合物的方法及其作为植物处理剂的用途。

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