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21. 发明授权

US4857561A Novel neopentyladipate based prepolymers and reaction injection molded products made therefrom 失效
标题翻译：新型新戊二醇酯基预聚物和由其制备的反应注塑产品
公开(公告)号：US4857561A
公开(公告)日：1989-08-15
申请号：US238436
申请日：1988-08-30
申请人： Robson Mafoti , Neil H. Nodelman
发明人： Robson Mafoti , Neil H. Nodelman
IPC分类号： B29C45/00 , C08G18/10 , C08G18/42 , C08G18/72 , C08G18/76
CPC分类号： C08G18/7664 , C08G18/10 , C08G18/4238 , C08G2120/00 , C08G2410/00
摘要： The present invention is directed to a polyisocyanate comprising the reaction product of(a) an isocyanate selected from the group consisting of methylenebis(phenylisocyanate), polymethylenepoly(phenylisocyanate), and mixtures thereof, and(b) a polyester polyol having a hydroxyl functionality of from 2 to 3 and a molecular weight of from about 750 to about 3500, said polyester polyol prepared by reacting neopentyl glycol and adipic acid,the isocyanate group content of said reaction product from about 14% to about 28% by weight. The invention is also directed to a RIM process using such prepolymers.
摘要翻译：本发明涉及包含（a）选自亚甲基双（异氰酸苯酯），聚亚甲基聚（异氰酸苯酯）及其混合物的异氰酸酯的反应产物的多异氰酸酯，和（b）具有羟基官能度的聚酯多元醇 2至3，分子量为约750至约3500，所述聚酯多元醇通过新戊二醇和己二酸反应制备，所述反应产物的异氰酸酯基团含量为约14重量％至约28重量％。本发明还涉及使用这种预聚物的RIM方法。

22. 发明授权

US4544679A Polyol blend and polyisocyanurate foam produced therefrom 失效
标题翻译：由此产生的多元醇共混物和聚异氰脲酸酯泡沫
公开(公告)号：US4544679A
公开(公告)日：1985-10-01
申请号：US703849
申请日：1985-02-21
申请人： Richard B. Tideswell , Neil H. Nodelman , Barry A. Phillips
发明人： Richard B. Tideswell , Neil H. Nodelman , Barry A. Phillips
IPC分类号： C08G18/00 , C08G18/02 , C08G18/06 , C08G18/09 , C08G18/28 , C08G18/32 , C08G18/40 , C08G18/42 , C08G18/66 , C08G18/14 , C08G18/30 , C08G18/48 , C08G18/79
CPC分类号： C08G18/3221 , C08G18/092 , C08G18/283 , C08G18/4018 , C08G18/4247 , C08G18/6644 , C08G2101/00 , C08G2101/0025 , C08G2101/005 , C08G2105/02 , C08G2170/60 , Y10S521/902 , Y10T428/249991 , Y10T428/31547
摘要： The present invention is directed to a polyol blend comprising:(a) from about 30 to about 90 percent by weight of a polyester diol having an OH number of from about 50 to about 500 and having the structure: ##STR1## wherein each R may be the same or different and represents a radical of the formula: ##STR2## where R" represents H or CH.sub.3 with the proviso that both R"s cannot be CH.sub.3, and y represents a number of from 1 to 5,wherein R' represents an aromatic radical having from 6 to 12 carbon atoms, and wherein x represents a number of from 0 to 5,(b) from about 2 to about 40 percent by weight of an organic compound containing from 3 to 8 hydroxyl groups and being selected from the group consisting of(i) compounds having OH numbers of from about 250 to about 1830 and being free of carboxylic acid ester groups,(ii) compounds having OH numbers of from about 150 to about 1000 and containing at least one carboxylic acid ester group, and(iii) mixtures thereof,(c) from about 5 to about 30 percent by weight of a condensation product formed from 1 mole of a phenol and from 4 to 15 moles of ethylene oxide, and(d) from 0 to about 40 percent by weight of at least one diol of the structure: ##STR3## where R" and y are as defined above, and to an isocyanurate foam prepared therefrom.
摘要翻译：本发明涉及多元醇共混物，其包含：（a）约30至约90重量％的OH数为约50至约500的聚酯二醇，并具有以下结构：其中每个R可以相同或不同，表示下式的基团：其中R“表示H或CH 3，条件是两个R'不能为CH3，y表示1至5的数，其中R “表示具有6至12个碳原子的芳族基团，其中x表示0至5的数，（b）约2至约40重量％的含有3至8个羟基的有机化合物，并且为选自（i）具有约250至约1830的OH数的化合物和不含羧酸酯基的化合物，（ii）OH值为约150至约1000的化合物，并含有至少一种羧酸酯基，和（iii）它们的混合物，（c）约5至约3 0重量％由1摩尔酚和4至15摩尔环氧乙烷形成的缩合产物，和（d）0至约40重量％的至少一种以下结构的二醇：其中 R“和y如上所定义，和由其制备的异氰脲酸酯泡沫。

23. 发明授权

US5149458A Polyurea rim systems having improved flow properties and containing an organic cyclic carbonate 失效
标题翻译：具有改善的流动性并含有有机环状碳酸酯的聚脲轮辋系统
公开(公告)号：US5149458A
公开(公告)日：1992-09-22
申请号：US686555
申请日：1991-04-17
申请人： Neil H. Nodelman
发明人： Neil H. Nodelman
IPC分类号： C08G18/66 , C08K5/1565
CPC分类号： C08G18/6685 , C08K5/1565 , C08G2120/00
摘要： The present invention is directed to a RIM process and an isocyanate-reactive mixture useful therein. The mixture comprisesi) a polyether having at least two isocyanate-reactive groups and a molecular weight of from 1800 to 12,000 in which at least 50% of the isocyanate-reactive groups are primary and/or secondary amine groups,ii) an amine-terminated chain extender, andiii) from 2 to 20 parts by weight per 100 parts by weight of components b) and c) of propylene carbonate.
摘要翻译：本发明涉及可用于其中的RIM方法和异氰酸酯反应性混合物。该混合物包括i）具有至少两个异氰酸酯反应性基团和分子量为1800至12,000的聚醚，其中至少50％的异氰酸酯反应性基团是伯胺和/或仲胺基，ii）胺 - 并且iii）相对于每100重量份组分b）和c）碳酸亚丙酯为2至20重量份。

24. 发明授权

US5137966A Internal release agents, active hydrogen containing mixtures which contain such agents and the use thereof in a process for the production of molded products 失效
标题翻译：内部释放剂，含有这些化学物质的活性氢混合物及其在生产成型产品的过程中的用途
公开(公告)号：US5137966A
公开(公告)日：1992-08-11
申请号：US660759
申请日：1991-02-25
申请人： Neil H. Nodelman
发明人： Neil H. Nodelman
IPC分类号： B29C39/00 , B29C33/62 , B29C45/00 , B29C67/24 , C08G18/42 , C08L75/00 , C08L75/04
CPC分类号： C08G18/4288 , B29C33/62 , B29C67/246 , B29K2075/00 , C08G2120/00 , C08G2125/00
摘要： The present invention is directed to a novel internal mold release agent for use in a polyurethane(urea) RIM process. The release agent broadly consists of the transesterification product of a fatty acid and a lower alkyl acetoacetate.

25. 发明授权

US4963598A Gamma radiation resistant polycarbonate compositions 失效
标题翻译：耐辐射聚碳酸酯组合物
公开(公告)号：US4963598A
公开(公告)日：1990-10-16
申请号：US297264
申请日：1989-01-18
申请人： Sivaram Krishnan , Richard E. Keegan , Neil H. Nodelman , Charles E. Lundy
发明人： Sivaram Krishnan , Richard E. Keegan , Neil H. Nodelman , Charles E. Lundy
IPC分类号： C08K5/00 , C08K5/06 , C08K5/1545 , C08K5/54 , C08L69/00
CPC分类号： C08K5/1545 , C08K5/06 , C08K5/54 , C08L69/00
摘要： The invention relates to thermoplastic polycarbonate molding compositions which are rendered resistant to gamma-radiation by incorporating therewith about 0.1 to about 10 percent by weight of a stabilizing agent conforming to ##STR1## wherein R.sub.1 denotes a hydrogen atom or a C.sub.1 -C.sub.4 alkyl, R.sub.2 denotes a hydrogen atom, a C.sub.1 -C.sub.30 alkyl or acyl radical, silyl or pyranyl where said alkyl and acyl radicals may be either branched or linear, n is an integer of from 0 to 70, p is 0 or 1 and m is 1 to 4.

26. 发明授权

US4960537A Process and compositions for production of moldings 失效
公开(公告)号：US4960537A
公开(公告)日：1990-10-02
申请号：US480415
申请日：1990-02-15
申请人： Neil H. Nodelman
发明人： Neil H. Nodelman
IPC分类号： C08G18/38 , C08G18/67
CPC分类号： C08G18/3825 , C08G18/678 , C08G2120/00
摘要： The present invention relates to a novel chain extender for use in making moldings. The chain extender broadly comprises the reaction product of an aromatic diamine and a cyclic carboxylic acid anhydride.

27. 发明授权

US4937366A Process and compositions for production of moldings 失效
标题翻译：用于生产模制品的方法和组合物
公开(公告)号：US4937366A
公开(公告)日：1990-06-26
申请号：US310142
申请日：1989-02-13
申请人： Neil H. Nodelman
发明人： Neil H. Nodelman
IPC分类号： C08G18/65 , C08G18/38 , C08G18/67
CPC分类号： C08G18/3825 , C08G18/678 , C08G2120/00
摘要： The present invention relates to a novel chain extender for use in making moldings. The chain extender broadly comprises the reaction product of an aromatic diamine and a cyclic carboxylic acid anhydride.
摘要翻译：本发明涉及一种用于制造模制品的新型扩链剂。扩链剂广泛地包括芳族二胺和环状羧酸酐的反应产物。

28. 发明授权

US07750058B2 Process for preparing closed-cell water-blown rigid polyurethane foams having improved mechanical properties 失效
标题翻译：制备具有改进的机械性能的闭孔水喷硬质聚氨酯泡沫体的方法
公开(公告)号：US07750058B2
公开(公告)日：2010-07-06
申请号：US12241146
申请日：2008-09-30
申请人： Karl W. Haider , Neil H. Nodelman , John P. Forsythe , Brian R. Suddaby
发明人： Karl W. Haider , Neil H. Nodelman , John P. Forsythe , Brian R. Suddaby
IPC分类号： C08G18/28
CPC分类号： C08G18/409 , C08G18/10 , C08G18/4072 , C08G2101/0025 , C08G2101/0058 , C08G2101/0083 , Y10T428/31573 , Y10T428/31583 , Y10T428/31587 , Y10T428/31605 , C08G18/40
摘要： The present invention is directed to a process for preparing water-blown rigid polyurethane foams having at least an 80% closed-cell content which involves reacting a) at least one polyol mixture which is composed of (i) at least one polymer polyol; (ii) at least one polyol having a hydroxyl value within the range of from about 200 to about 800; and (iii) optionally, at least one polyol having a hydroxyl value within the range of from about 25 to about 115; with b) at least one polymeric isocyanate and/or a prepolymer thereof; in the presence of c) optionally, at least one catalyst; d) water; and e) optionally, at least one additive or auxiliary agent. The present invention is also directed to the closed-cell water blown rigid polyurethane foams produced by the process of the present invention. The invention is further directed to a polyurethane-foam forming mixture which is used to produce the water-blown rigid polyurethane foams of the present invention. Foams produced according to the present invention have reduced friability and acceptable adhesion to substrates as well as acceptable compressive strength.
摘要翻译：本发明涉及一种制备具有至少80％闭孔含量的水喷硬质聚氨酯泡沫体的方法，该方法包括使a）至少一种多元醇混合物，其由（i）至少一种聚合物多元醇组成; （ii）至少一种羟值在约200至约800范围内的多元醇; 和（iii）任选地，至少一种羟值在约25至约115范围内的多元醇; 其中b）至少一种聚合异氰酸酯和/或其预聚物; 在c）任选的情况下，至少一种催化剂; d）水; 和e）任选的至少一种添加剂或助剂。本发明还涉及通过本发明的方法生产的闭孔水喷硬质聚氨酯泡沫体。本发明还涉及用于生产本发明的水喷硬质聚氨酯泡沫的聚氨酯泡沫形成混合物。根据本发明生产的泡沫具有降低的脆性和对基材的可接受的粘合性以及可接受的抗压强度。

29. 发明申请

US20090156777A1 Freeze-stable aromatic diisocyanates and processes for the preparation of these freeze-stable products 审中-公开
标题翻译：冷冻稳定的芳族二异氰酸酯和制备这些冷冻稳定产物的方法
公开(公告)号：US20090156777A1
公开(公告)日：2009-06-18
申请号：US12002435
申请日：2007-12-17
申请人： Neil H. Nodelman , Ulrich B. Holeschovsky , Kurt E. Walter , Dennis F. Yajko
发明人： Neil H. Nodelman , Ulrich B. Holeschovsky , Kurt E. Walter , Dennis F. Yajko
IPC分类号： C08G18/72
CPC分类号： C08G18/7837 , C08G18/10 , C08G18/3206 , C08G18/4238 , C08G18/4841 , C08G18/7825 , C08G18/7831 , C08G18/7843 , C08G18/794 , C08G18/797 , C08G18/798
摘要： This invention relates to freeze-stable aromatic diisocyanates, an to processes for the preparation of these freeze-stable aromatic diisocyanates. The preferred aromatic diisocyanate is preferably diphenylmethane diisocyanate. These freeze-stable aromatic diisocyanates comprise a blend of an aromatic diisocyanate, with 2,2,4-trimethyl-1,3-pentanediol diisobutyrate, and have an NCO group content of from about 6% to about 29% by weight. Suitable aromatic diisocyanates contain one or more of the following modifying groups: allophanate groups, carbodiimide groups, uretonimine groups, biuret groups, dimer groups, isocyanurate groups, urea groups and/or urethane groups. Prepolymers of these modified aromatic diisocyanates are also suitable for the present invention.
摘要翻译：本发明涉及冷冻稳定的芳族二异氰酸酯，一种制备这些冷冻稳定的芳族二异氰酸酯的方法。优选的芳族二异氰酸酯优选为二苯基甲烷二异氰酸酯。这些冷冻稳定的芳族二异氰酸酯包括芳族二异氰酸酯与2,2,4-三甲基-1,3-戊二醇二异丁酸酯的共混物，并且具有约6重量％至约29重量％的NCO基团含量。合适的芳族二异氰酸酯含有一个或多个以下改性基团：脲基甲酸酯基，碳二亚胺基，脲酮亚胺基，缩二脲基，二聚体基，异氰脲酸酯基，脲基和/或氨基甲酸酯基。这些改性的芳族二异氰酸酯的预聚物也适用于本发明。

30. 发明申请

US20090036562A1 Process for preparing closed-cell water-blown rigid polyurethane foams having improved mechanical properties 失效
标题翻译：制备具有改进的机械性能的闭孔水喷硬质聚氨酯泡沫体的方法
公开(公告)号：US20090036562A1
公开(公告)日：2009-02-05
申请号：US12241146
申请日：2008-09-30
申请人： Karl W. Haider , Neil H. Nodelman , John P. Forsythe , Brian R. Suddaby
发明人： Karl W. Haider , Neil H. Nodelman , John P. Forsythe , Brian R. Suddaby
IPC分类号： C08L75/14 , C08L75/08
CPC分类号： C08G18/409 , C08G18/10 , C08G18/4072 , C08G2101/0025 , C08G2101/0058 , C08G2101/0083 , Y10T428/31573 , Y10T428/31583 , Y10T428/31587 , Y10T428/31605 , C08G18/40
摘要： The present invention is directed to a process for preparing water-blown rigid polyurethane foams having at least an 80% closed-cell content which involves reacting a) at least one polyol mixture which is composed of (i) at least one polymer polyol; (ii) at least one polyol having a hydroxyl value within the range of from about 200 to about 800; and (iii) optionally, at least one polyol having a hydroxyl value within the range of from about 25 to about 115; with b) at least one polymeric isocyanate and/or a prepolymer thereof; in the presence of c) optionally, at least one catalyst; d) water; and e) optionally, at least one additive or auxiliary agent. The present invention is also directed to the closed-cell water blown rigid polyurethane foams produced by the process of the present invention. The invention is further directed to a polyurethane-foam forming mixture which is used to produce the water-blown rigid polyurethane foams of the present invention. Foams produced according to the present invention have reduced friability and acceptable adhesion to substrates as well as acceptable compressive strength.
摘要翻译：本发明涉及一种制备具有至少80％闭孔含量的水喷硬质聚氨酯泡沫体的方法，该方法包括使a）至少一种多元醇混合物，其由（i）至少一种聚合物多元醇组成; （ii）至少一种羟值在约200至约800范围内的多元醇; 和（iii）任选地，至少一种羟值在约25至约115范围内的多元醇; 其中b）至少一种聚合异氰酸酯和/或其预聚物; 在c）任选的情况下，至少一种催化剂; d）水; 和e）任选的至少一种添加剂或助剂。本发明还涉及通过本发明的方法生产的闭孔水喷硬质聚氨酯泡沫体。本发明还涉及用于生产本发明的水喷硬质聚氨酯泡沫的聚氨酯泡沫形成混合物。根据本发明生产的泡沫具有降低的脆性和对基材的可接受的粘合性以及可接受的抗压强度。

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