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21. 发明授权

US07915464B2 Process for the conversion of natural gas to hydrocarbon liquids 有权
公开(公告)号：US07915464B2
公开(公告)日：2011-03-29
申请号：US12684385
申请日：2010-01-08
申请人： Sean C. Gattis , Edward R. Peterson
发明人： Sean C. Gattis , Edward R. Peterson
IPC分类号： C07C2/78
CPC分类号： C10G50/00 , Y10S585/943
摘要： A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.

22. 发明授权

US07915461B2 Process for the conversion of natural gas to hydrocarbon liquids 有权
公开(公告)号：US07915461B2
公开(公告)日：2011-03-29
申请号：US12684213
申请日：2010-01-08
申请人： Sean C. Gattis , Edward R. Peterson
发明人： Sean C. Gattis , Edward R. Peterson
IPC分类号： C07C2/78
CPC分类号： C10G50/00 , Y10S585/943
摘要： A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.

23. 发明申请

US20100167137A1 PROCESS FOR THE CONVERSION OF NATURAL GAS TO HYDROCARBON LIQUIDS 有权
公开(公告)号：US20100167137A1
公开(公告)日：2010-07-01
申请号：US12684385
申请日：2010-01-08
申请人： Sean C. Gattis , Edward R. Peterson
发明人： Sean C. Gattis , Edward R. Peterson
IPC分类号： F01D15/10 , C07C2/00 , H01M8/06 , F02C7/22
CPC分类号： C10G50/00 , Y10S585/943
摘要： A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.

24. 发明申请

US20100167136A1 PROCESS FOR THE CONVERSION OF NATURAL GAS TO HYDROCARBON LIQUIDS 有权
公开(公告)号：US20100167136A1
公开(公告)日：2010-07-01
申请号：US12684373
申请日：2010-01-08
申请人： Sean C. Gattis , Edward R. Peterson
发明人： Sean C. Gattis , Edward R. Peterson
IPC分类号： H01M8/06 , C07C2/00 , C10G57/00 , F01D15/10 , F02C7/22 , F01K7/16
CPC分类号： C10G50/00 , Y10S585/943
摘要： A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.

25. 发明授权

US07667085B2 Process for the conversion of natural gas to hydrocarbon liquids 有权
标题翻译：将天然气转化为烃类液体的方法
公开(公告)号：US07667085B2
公开(公告)日：2010-02-23
申请号：US11669451
申请日：2007-01-31
申请人： Sean C. Gattis , Edward R. Peterson
发明人： Sean C. Gattis , Edward R. Peterson
IPC分类号： C07C11/28
CPC分类号： C10G50/00 , Y10S585/943
摘要： A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.
摘要翻译：一种将天然气转化为液体烃的方法，包括将气体在选定的温度范围内加热足够的时间和/或在足够的温度和适当的条件下燃烧气体以使反应时间足以转化一部分气流反应性烃产物，主要是乙烯或乙炔。可以分离含乙炔的气体，使乙炔转化为乙烯。乙烯产物可以在酸性催化剂的存在下反应以产生液体，其中一部分主要是石脑油或汽油。在该过程中产生的一部分进入的天然气或氢气可用于将剩余的天然气加热到所选择的温度范围。反应性气体组分用于催化液化步骤和/或用于替代化学处理。

26. 发明授权

US07408091B2 Process for liquid phase hydrogenation 有权
标题翻译：液相氢化方法
公开(公告)号：US07408091B2
公开(公告)日：2008-08-05
申请号：US11383325
申请日：2006-05-15
申请人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
发明人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
IPC分类号： G07C5/02 , G07C5/08
CPC分类号： B01J37/08 , B01J21/04 , B01J23/44 , B01J23/50 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/008 , B01J35/08 , B01J37/18 , C07C7/167 , C07C2523/56 , C07C2523/60 , C07C2523/62 , C07C2523/64
摘要： A process and catalyst for the liquid phase selective hydrogenation of alkynes to alkenes with high selectivity to alkenes relative to alkanes, high alkyne conversion, and sustained catalytic activity comprising a reactant comprising an alkyne and a non-hydrocarbon solvent/absorbent, contacting the reactant stream with a hydrogen-containing stream in the presence of a supported, promoted, Group VIII catalyst, removing the solvent/absorbent, and recovering the alkene product.
摘要翻译：一种用于相对于烷烃对烯烃具有高选择性的烯烃至烯烃的液相选择性氢化的方法和催化剂，高炔转化率和持续的催化活性，其包含含有炔烃和非烃溶剂/吸收剂的反应物，使反应物流在含有载体的促进的VIII族催化剂的存在下，将含氢的物流除去溶剂/吸收剂，并回收烯烃产物。

27. 发明授权

US5759486A Apparatus and method for sterilization of instruments 失效
标题翻译：仪器灭菌仪器及方法
公开(公告)号：US5759486A
公开(公告)日：1998-06-02
申请号：US622163
申请日：1996-03-27
申请人： Edward R. Peterson
发明人： Edward R. Peterson
IPC分类号： A61L2/12 , A61L2/00
CPC分类号： A61L2/12
摘要： The present invention reveals an apparatus and method for sterilizing instruments at atmospheric pressure in a microwave oven. The apparatus is made of a tray for holding medical, surgical, dental, veterinary, or other instruments, a receiver for holding the tray, three containers, where one container holds a sterilization chemical and a second container holds sterile water, a cover for placement over the tray, and two pumps for transferring the liquids. The method requires a sterilization chemical that has a boiling point of greater than 100.degree. C. and that is at least slightly soluble or is rinsable in water. In addition, the entire microwave sterilization process is completed in less than six minutes.
摘要翻译：本发明揭示了在微波炉中在大气压下对仪器进行灭菌的装置和方法。该装置由用于保持医疗，手术，牙科，兽医或其他器械的托盘，用于保持托盘的容器，三个容器，其中一个容器容纳灭菌化学品，第二容器容纳无菌水的容器，用于放置的盖子在纸盘上，以及两个用于传送液体的泵。该方法需要沸点大于100℃的灭菌化学品，并且其至少是微溶的或可在水中冲洗。此外，整个微波消毒过程在不到六分钟内完成。

28. 发明授权

US08460937B2 Catalyst formulation for hydrogenation 有权
标题翻译：用于氢化的催化剂配方
公开(公告)号：US08460937B2
公开(公告)日：2013-06-11
申请号：US13431964
申请日：2012-03-27
申请人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
发明人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
IPC分类号： G01N31/10 , B01J31/00 , B01J31/40 , B01J37/00 , B01J38/72 , B01J23/00 , C08F4/02 , C08F4/60
CPC分类号： B01J23/50 , B01J23/44 , B01J23/48 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/002 , B01J37/0036 , B01J37/009 , B01J37/0205 , B01J37/18 , C10G45/34 , C10G45/40 , C10G2400/20
摘要： A method of screening catalysts for liquid-phase selective hydrogenation by preparing a test catalyst by adding a promoter to a reference catalyst; preparing a liquid reactant stream comprising C2H2 dissolved in n-methyl-2-pyrrolidone; testing the test and reference catalysts by contacting the reactant stream and gas mixture comprising hydrogen and carbon monoxide in continuous flow with the test catalyst and reference catalyst, respectively, at selective hydrogenation reaction conditions to produce a product stream, condensing substantially all of the n-methyl-2-pyrrolidone from the product stream; measuring the concentrations of products comprising C2H2, C2H4, and C2H6 in the product stream at steady state; determining performance parameters for the test catalyst and the reference catalyst comprising the respective C2H2 conversion Sc and C2H4 selectivity relative to C2H6 Ss; and comparing the test catalyst performance parameters to those for the reference catalyst.
摘要翻译：一种筛选用于液相选择性氢化的催化剂的方法，通过向参考催化剂中加入助催化剂制备试验催化剂; 制备包含溶解在正甲基-2-吡咯烷酮中的C2H2的液体反应物流; 通过在选择性氢化反应条件下分别使包含氢气和一氧化碳的反应物流和连续流动的气体混合物与测试催化剂和参考催化剂分别接触来测试测试和参考催化剂，以产生产物流，基本上将所有的n- 甲基-2-吡咯烷酮; 在稳定状态下测量产物流中包含C2H2，C2H4和C2H6的产物的浓度; 确定测试催化剂和参考催化剂的性能参数，其包含相对于C 2 H 6 S的相应的C 2 H 2转化率Sc和C 2 H 4选择性; 并将试验催化剂性能参数与参考催化剂的参数进行比较。

29. 发明授权

US08247340B2 Catalyst formulation for hydrogenation 有权
标题翻译：用于氢化的催化剂配方
公开(公告)号：US08247340B2
公开(公告)日：2012-08-21
申请号：US13045346
申请日：2011-03-10
申请人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
发明人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
IPC分类号： B01J23/00 , B01J21/00 , B01J31/00 , B01J37/00
CPC分类号： B01J23/50 , B01J23/44 , B01J23/48 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/002 , B01J37/0036 , B01J37/009 , B01J37/0205 , B01J37/18 , C10G45/34 , C10G45/40 , C10G2400/20
摘要： A composition and method for preparation of a catalyst for the liquid phase selective hydrogenation of alkynes to alkenes with high selectivity to alkenes relative to alkanes, high alkyne conversion, and sustained catalytic activity comprising a Group VIII metal and a Group IB, Group IIB, Group IIIA, and/or Group VIIB promoter on a particulate support.
摘要翻译：一种用于制备用于相对于烷烃对烯烃具有高选择性的炔烃至烯烃的液相选择性氢化的催化剂的组合物和方法，具有高炔烃转化率和持续催化活性的组合物和方法，其包含VIII族金属和IB族，IIB族， IIIA和/或VIIB族促进剂。

30. 发明申请

US20120190117A1 CATALYST FORMULATION FOR HYDROGENATION 有权
标题翻译：催化剂用于氢化反应
公开(公告)号：US20120190117A1
公开(公告)日：2012-07-26
申请号：US13431964
申请日：2012-03-27
申请人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
发明人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
IPC分类号： G01N31/10 , B01J23/08 , B01J23/34 , B01J23/06 , B01J23/44
CPC分类号： B01J23/50 , B01J23/44 , B01J23/48 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/002 , B01J37/0036 , B01J37/009 , B01J37/0205 , B01J37/18 , C10G45/34 , C10G45/40 , C10G2400/20
摘要： A method of screening catalysts for liquid-phase selective hydrogenation by preparing a test catalyst by adding a promoter to a reference catalyst; preparing a liquid reactant stream comprising C2H2 dissolved in n-methyl-2-pyrrolidone; testing the test and reference catalysts by contacting the reactant stream and gas mixture comprising hydrogen and carbon monoxide in continuous flow with the test catalyst and reference catalyst, respectively, at selective hydrogenation reaction conditions to produce a product stream, condensing substantially all of the n-methyl-2-pyrrolidone from the product stream; measuring the concentrations of products comprising C2H2, C2H4, and C2H6 in the product stream at steady state; determining performance parameters for the test catalyst and the reference catalyst comprising the respective C2H2 conversion Sc and C2H4 selectivity relative to C2H6 Ss; and comparing the test catalyst performance parameters to those for the reference catalyst.
摘要翻译：一种筛选用于液相选择性氢化的催化剂的方法，通过向参考催化剂中加入助催化剂制备试验催化剂; 制备包含溶解在正甲基-2-吡咯烷酮中的C2H2的液体反应物流; 通过在选择性氢化反应条件下分别使包含氢气和一氧化碳的反应物流和连续流动的气体混合物与测试催化剂和参考催化剂分别接触来测试测试和参考催化剂，以产生产物流，基本上将所有的n- 甲基-2-吡咯烷酮; 在稳定状态下测量产物流中包含C2H2，C2H4和C2H6的产物的浓度; 确定测试催化剂和参考催化剂的性能参数，其包含相对于C 2 H 6 S的相应的C 2 H 2转化率Sc和C 2 H 4选择性; 并将试验催化剂性能参数与参考催化剂的参数进行比较。

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