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    • 29. 发明公开
    • PROCESS FOR PREPARING 2,3,3,3-TETRAFLUOROPROPENE
    • 制备2,3,3,3-四氟丙烯的方法
    • EP2349958A2
    • 2011-08-03
    • EP09741475.9
    • 2009-10-13
    • Daikin Industries, Ltd.
    • NOSE, MasatoshiTAKAHASHI, KazuhiroKOMATSU, YuzoSUGIYAMA, AkinariSHIBANUMA, Takashi
    • C07C17/087C07C17/25C07C17/383C07C21/18
    • C07C17/25C07C17/087C07C17/383C07C21/18Y02P20/582C07C21/22
    • The present invention provides a process for preparing 2,3,3,3-tetrafluoropropene comprising the steps of: (a) reacting 3,3,3-trifluoropropyne with hydrogen fluoride while heating to obtain a product containing 2,3,3,3-tetrafluoropropene; (b) separating the product obtained in Step (a) into Component A containing 2,3,3,3-tetrafluoropropene and 3,3,3-trifluoropropyne, and Component B containing 1,3,3,3-tetrafluoropropene; (c) separating 2,3,3,3-tetrafluoropropene and 3,3,3-trifluoropropyne contained in Component A obtained in Step (b) into each compound; (d) conducting a dehydrofluorination reaction by heating Component B obtained in Step (b) in the presence of a catalyst; (e) separating the product obtained in Step (d) into Component C containing 2,3,3,3-tetrafluoropropene and 3,3,3-trifluoropropyne, and Component D containing 1,3,3,3-tetrafluoropropene; (f) separating 2,3,3,3-tetrafluoropropene and 3,3,3-trifluoropropyne contained in Component C obtained in Step (e) into each compound; and (g) conducting a dehydrofluorination reaction by heating Component D obtained in Step (e) in the presence of a catalyst. The present invention provides an effective and industrially applicable process for preparing 2,3,3,3-tetrafluoropropene.
    • 本发明提供了制备2,3,3,3-四氟丙烯的方法,该方法包括以下步骤:(a)在加热下使3,3,3-三氟丙炔与氟化氢反应,得到含2,3,3,3-三氟丙烯 -tetrafluoropropene; (b)将步骤(a)中得到的产物分离成含有2,3,3,3-四氟丙烯和3,3,3-三氟丙炔的组分A和含有1,3,3,3-四氟丙烯的组分B; (c)将步骤(b)中得到的组分A中所含的2,3,3,3-四氟丙烯和3,3,3-三氟丙炔分离成每种化合物; (d)通过在催化剂存在下加热步骤(b)中获得的组分B进行脱氟化氢反应; (e)将步骤(d)中得到的产物分离成含有2,3,3,3-四氟丙烯和3,3,3-三氟丙炔的组分C和含有1,3,3,3-四氟丙烯的组分D; (f)将步骤(e)中获得的组分C中所含的2,3,3,3-四氟丙烯和3,3,3-三氟丙炔分离成每种化合物; 和(g)通过在催化剂存在下加热步骤(e)中获得的组分D来进行脱氟化氢反应。 本发明提供了一种有效的和工业上可用的制备2,3,3,3-四氟丙烯的方法。