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    • 23. 发明申请
    • MAGNESIUM-BASED ENERGY STORAGE SYSTEMS AND METHODS HAVING IMPROVED ELECTROLYTES
    • 基于镁的能源储存系统和具有改进电解质的方法
    • WO2014168671A1
    • 2014-10-16
    • PCT/US2014/013371
    • 2014-01-28
    • BATTELLE MEMORIAL INSTITUTE
    • LIU, TianbiaoLI, GuoshengLIU, JunSHAO, Yuyan
    • H01M10/056H01M10/054
    • H01M10/0568H01M10/054
    • Electrolytes for Mg-based energy storage devices can be formed from non-nucleophilic Mg 2+ sources to provide outstanding electrochemical performance and improved electrophilic susceptibility compared to electrolytes employing nucleophilic sources. The instant electrolytes are characterized by high oxidation stability (up to 3.4 V vs Mg), improved electrophile compatibility and electrochemical reversibility (up to 100% coulombic efficiency). Synthesis of the Mg 2+ electrolytes utilizes inexpensive and safe magnesium dihalides as non-nucleophilic Mg 2+ sources in combination with Lewis acids, MR a X 3-a (for 3≥ a≥ 1). Furthermore, addition of free-halide-anion donors can improve the coulombic efficiency of Mg electrolytes from nucleophilic or non-nucleophilic Mg 2+ sources.
    • 用于Mg基能量储存装置的电解质可以由非亲核Mg 2+源形成,以提供与使用亲核源的电解质相比优异的电化学性能和改善的亲电子敏感性。 瞬时电解质的特征在于高氧化稳定性(高达3.4V vs镁),改善的亲电子相容性和电化学可逆性(高达100%的库仑效率)。 Mg2 +电解质的合成使用廉价和安全的二卤化镁作为非亲核Mg2 +源与路易斯酸MRaX3-a(3≥a≥1)的组合。 此外,添加游离卤化物 - 阴离子供体可以提高Mg电解质从亲核或非亲核Mg2 +来源的库仑效率。
    • 25. 发明申请
    • ELECTROSYNTHESIS OF NANOFIBERS AND NANO-COMPOSITE FILMS
    • 纳米纤维和纳米复合薄膜的电合成
    • WO2004048644A2
    • 2004-06-10
    • PCT/US2003/016273
    • 2003-05-21
    • BATTELLE MEMORIAL INSTITUTE
    • LIN, YueheLIANG, LiangLIU, Jun
    • C25D
    • B82Y30/00C09D5/4476C25D9/00
    • A method of producing an array of oriented nanofibers that involves forming a solution that includes at least one electroactive species. An electrode substrate is brought into contact with the solution. A current density is applied to the electrode substrate that includes at least a first step of applying a first substantially constant current density for a first time period and a second step of applying a second substantially constant current density for a second time period. The first and second time periods are of sufficient duration to electrically deposit on the electrode substrate an array of oriented nanofibers produced from the electroactive species. Also disclosed are films that include arrays or networks of oriented nanofibers and a method for amperometrically detecting or measuring at least one analyte in a sample.
    • 生产取向纳米纤维阵列的方法,其涉及形成包含至少一种电活性物质的溶液。 使电极基板与溶液接触。 向电极基板施加电流密度,该电流密度至少包括在第一时间段施加第一基本上恒定的电流密度的第一步骤和在第二时间段施加第二基本上恒定的电流密度的第二步骤。 第一和第二时间段具有足够的持续时间以在电极基板上电沉积由电活性物质产生的取向纳米纤维的阵列。 还公开了包含取向纳米纤维的阵列或网络的膜以及用于安培检测或测量样品中的至少一种分析物的方法。
    • 29. 发明申请
    • MAGNESIUM ENERGY STORAGE DEVICE HAVING A SEMI-SOLID POSITIVE ELECTRODE
    • 具有半固体电极的镁能量储存装置
    • WO2014168672A1
    • 2014-10-16
    • PCT/US2014/013373
    • 2014-01-28
    • BATTELLE MEMORIAL INSTITUTE
    • SHAO, YuyanLIU, JunLI, GuoshengLIU, Tianbiao
    • H01M10/056H01M10/054
    • H01M8/20H01M8/188H01M8/225Y02E60/528
    • Magnesium energy storage devices that take advantage of magnesium-based anodes while maintaining practical energy densities can be useful for large-scale energy storage as well as other applications. One such device can include a negative electrode having magnesium and a positive electrode material that can flow in a batch or continuous manner. The flowable positive electrode material can result in an increased practical energy density because the fresh active material can be flowed to the positive electrode, and as a result can be theoretically infinite in size. The positive electrode can include a cathode suspension contacting a positive current collector and having particulates of a cathode magnesium intercalation compound, a cathode magnesium conversion compound, a redox active species, or combinations thereof.
    • 利用镁基阳极同时保持实际能量密度的镁储能装置对于大规模储能以及其它应用是有用的。 一种这样的装置可以包括具有镁的负极和可以分批或连续流动的正电极材料。 可流动的正极材料可以导致增加的实际能量密度,因为新鲜的活性材料可以流到正极,结果在理论上可以是无限大小的。 正极可以包括与正极集电器接触并具有阴极镁插入化合物,阴极镁转化化合物,氧化还原活性物质或其组合的微粒的阴极悬浮液。