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    • 25. 发明申请
    • WATERBASED BINDER FOR TWO-COMPONENT COATING COMPOSITION
    • WO2022112042A1
    • 2022-06-02
    • PCT/EP2021/081712
    • 2021-11-15
    • BASF SE
    • ROLLER, SebastianKAINZ, Quirin MaximilianPATEL, Chintankumar JayantilalAL-HELLANI, Rabie
    • C08F2/38C08F265/06C09D151/00C09D175/04
    • The present invention relates process for preparing an aqueous polymer dispersion by radically initiated aqueous emulsion polymerization, which comprises polymerizing, in an aqueous polymerization medium a) in a first polymerization stage ≥ 0.5 and ≤ 15 wt% of at least one α,β-monoethylenically unsaturated C3 to C6 monocarboxylic or dicarboxylic acid (monomers A1), ≥ 5 and ≤ 40 wt% of at least one monoethylenically unsaturated compound having at least one hydroxyl group (monomers B1), ≥ 0 - ≤ 40 wt% of carboxyl-free (meth)acrylic esters with a cycloaliphatic structure (monomers C1), ≥ 15 and ≤ 94.5 wt% of at least one ethylenically unsaturated compound which is different from the monomers A1, B1 and C1 (monomers D1), the amounts of the monomers A1 to D1 adding up to 100 wt%, in the presence of at least one radical initiator and at least one chain transfer agent, and also, optionally, in the presence of a dispersing assistant, with the provisos that • the amount of chain transfer agent is selected such that the polymer 1 obtained from the first polymerization stage has a weight-average molecular weight in the range of ≥ 5000 and ≤ 40000 g/mol, • the nature and amounts of the monomers A1 to D1 are selected such that the resulting polymer 1 has a glass transition temperature Tg1 as measured to DIN EN ISO 11357-2 (2013-09) ≥ 15°C, and thereafter polymerizing, in the presence of the polymer 1 b) in a second polymerization stage ≥ 0 and ≤ 1.0 wt% of at least one α,β-monoethylenically unsaturated C3 to C6 monocarboxylic or dicarboxylic acid (monomers A2), ≥ 0.1 and ≤ 40 wt% of at least one monoethylenically unsaturated compound having at least one hydroxyl group (monomers B2), ≥ 0 - ≤ 40 wt% of carboxyl-free (meth)acrylic esters with a cycloaliphatic structure (monomers C2) ≥ 30 and ≤ 99.9 wt% of at least one ethylenically unsaturated compound which is different from the monomers A2, B2 and C2 (monomers D2), the amounts of the monomers A2 to D2 adding up to 100 wt%, in the presence of at least one radical initiator and at least one chain transfer agent, and also, optionally, in the presence of a dispersing assistant, with the provisos that • the weight ratio of the sum of the total amounts of monomers A1 to D1 (total monomer amount 1) to the sum of the total amounts of monomers A2 to D2 (total monomer amount 2) is in the range 25:75 to 50:50, • the amount of chain transfer agent in the second polymerization stage is selected such that the overall polymer obtained after the second polymerization stage has a weight-average molecular weight ≥ 5000 and ≤ 75000 /mol, and • the amount of the dispersing assistant is ≤ 3.0 wt%, based on the sum of total monomer amount 1 and total monomer amount 2 (total monomer amount), • that the sum of the total amounts of monomers C1 and C2 is 7 to 40 wt% based on the sum of total monomer amount 1 and total monomer amount 2; the aqueous polymer dispersion itself, its use and coating compositions comprising the aqueous polymer dispersion.
    • 26. 发明申请
    • HYPERBRANCHED POLYESTER POLYOLS SUITABLE FOR USE IN ORGANIC SOLVENT-BASED TWO-COMPONENT POLYURETHANE COATING COMPOSITIONS
    • WO2021165122A1
    • 2021-08-26
    • PCT/EP2021/053245
    • 2021-02-10
    • BASF SE
    • GEYER, Florian LudwigROLLER, SebastianNEU, Oliver
    • C09D175/06C08G18/42C08G18/46C08G18/62C08G18/73C08G18/79C08G63/137C08G63/685C09D5/00C08G18/24
    • The present invention relates to polyester polyols comprising units derived from a) at least one COOH group or derivative thereof carrying component or mixture of components (A) comprising at least one compound carrying two COOH groups or derivatives thereof (A1), b) at least one OH group carrying component or mixture of components (B) comprising (i) at least one compound carrying three OH groups selected from the group consisting of 1,3,5-tris(hydroxymethyl)isocyanurate, 1,3,5-tris(2-hydroxyethyl) isocyanurate, 1,3,5-tris(2-hydroxyisopropyl)isocyanurate, 1,3,5-tris(2- hydroxypropyl)isocyanurate and 1,3,5-tris(2-hydroxybutyl)isocyanurate (B1), (ii) at least one compound carrying two OH groups selected from the group consisting of 1,1-bis(hydroxymethyl)-cyclohexane, 1,2-bis(hydroxymethyl)- cyclohexane, 1,3-bis(hydroxymethyl)-cyclohexane, 1,4-bis(hydroxymethyl)- cyclohexane, 1,1-bis(hydroxyethyl)-cyclohexane, 1,2-bis(hydroxyethyl)- cyclohexane, 1,3-bis(hydroxyethyl)-cyclohexane and 1,4-bis(hydroxyethyl)- cyclohexane (B2), (iii) optionally at least one compound or polymer carrying at least three OH groups, which is different from B1 (B3), and (iv) optionally at least one compound or polymer carrying two OH groups, which is different from B2 (B4), and c) optionally at least one compound carrying at least one OH group and at least one COOH group or a derivative thereof (C), and to organic-solvent based two-component coating compositions comprising a) a first component (K1) comprising (i) at least one polyester polyol of the present invention and (ii) optionally at least one polymer carrying more than one OH group, which is different from the polyester polyol of the present invention (D), and b) a second component (K2) comprising (i) at least one compound, oligomer or polymer carrying more than one N=C=O group or blocked N=C=O group (F).