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21. 发明授权

EP3274086B1 KATALYSATORFORMKÖRPER FÜR DIE KATALYTISCHE OXIDATION VON SO2 ZU SO3 有权
公开(公告)号：EP3274086B1
公开(公告)日：2019-01-30
申请号：EP16713761.1
申请日：2016-03-16
申请人： BASF SE
发明人： GRÜNE, Philipp , WALSDORFF, Christian , SCHUBERT, Markus , BORCHERT, Holger , VAN DORLAND, Jacob Cornelis , ZÜHLKE, Jürgen , LIPP, Stefan , KRÄMER, Michael
IPC分类号： B01J23/22 , B01J27/055 , B01J35/02 , B01J37/00 , C01B17/79 , B01D53/86 , B01J35/00 , B01J35/10

22. 发明授权

EP2013144B1 METALLOXIDE AUS METALLORGANISCHEN GERÜSTMATERIALIEN 有权
标题翻译：金属氧化物金属有机骨架材料
公开(公告)号：EP2013144B1
公开(公告)日：2012-10-03
申请号：EP07728038.6
申请日：2007-04-12
申请人： BASF SE
发明人： SCHUBERT, Markus , MUELLER, Ulrich , TRUKHAN, Natalia
IPC分类号： C01G1/02 , C04B35/486 , C01G25/02 , C01G23/053 , C01F7/02 , C01F5/02 , C01F7/30 , C04B35/111 , C04B35/053 , C04B38/00 , C04B35/10 , C04B35/04 , C04B35/48
CPC分类号： B01J20/0211 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/28042 , B01J20/28057 , C01F5/02 , C01F7/30 , C01G1/02 , C01G9/02 , C01G23/047 , C01G25/00 , C01G25/02 , C01P2002/72 , C01P2004/03 , C01P2006/12 , C01P2006/13 , C07C51/418 , Y10T428/2982 , C07C63/38 , C07C63/26 , C07C57/15

23. 发明授权

EP2089157B1 MAGNESIUMBUTYLISOPHTHALAT ALS PORÖSES METALLORGANISCHES GERÜSTMATERIAL 有权
标题翻译： MAGNESIUMBUTYLISOPHTHALAT ALS多孔金属有机骨架材料
公开(公告)号：EP2089157B1
公开(公告)日：2012-09-05
申请号：EP07822192.6
申请日：2007-11-05
申请人： BASF SE
发明人： TRUKHAN, Natalia , MÜLLER, Ulrich , SCHUBERT, Markus
IPC分类号： B01J31/16 , B01J20/00
CPC分类号： B01J31/1691 , B01D53/02 , B01D2253/204 , B01J20/226 , B01J2531/22 , C01B3/0015 , C01B6/003 , C01B7/00 , C01B13/0281 , C01B21/0455 , C01B23/0057 , C07C63/24 , C07F3/003 , F17C11/005 , Y02C10/08 , Y02E60/328

24. 发明授权

EP1917228B1 MESOPORÖSES METALLORGANISCHES GERÜSTMATERIAL 有权
标题翻译：中孔金属 - 有机骨架
公开(公告)号：EP1917228B1
公开(公告)日：2010-11-24
申请号：EP06792831.7
申请日：2006-08-16
申请人： BASF SE
发明人： SCHUBERT, Markus , MÜLLER, Ulrich , MATTENHEIMER, Hendrick , TONIGOLD, Markus
IPC分类号： C07C51/41 , C07F5/06 , C01B3/00
CPC分类号： C07F5/069 , C01B3/001 , C01B3/0015 , C01B3/0026 , C07C51/418 , Y02E60/327 , Y02E60/328 , C07C63/307
摘要： The invention relates to porous metal-organic framework comprising Al'' and at least one at least bidentate compound. The at least one at least bidentate compound is a six-membered aromatic hydrocarbon ring A, wherein one ore more ring carbon atoms may be replaced by nitrogen and the three substituents X and optionally one or more substituents selected from the group including R, NRR', OR, SR, F, Cl, and Br, wherein R, R' independently represent hydrogen, methyl which is optionally substituted by one or more fluorine atoms or ethyl which is optionally substituted by one or more fluorine atoms and every X independently represents C(=O)O-, C(=S)O-, C(=O)S-, C(=S)S- or the protonized form thereof. The invention also relates to methods for producing said framework and to the use of the novel metal-organic framework.

25. 发明授权

EP1984378B1 VERFAHREN ZUR HERSTELLUNG PORÖSER ORGANISCHER GERÜSTMATERIALIEN 有权
标题翻译：用于生产多孔有机骨架材料
公开(公告)号：EP1984378B1
公开(公告)日：2010-07-28
申请号：EP07712171.3
申请日：2007-02-08
申请人： BASF SE
发明人： SCHUBERT, Markus , MÜLLER, Ulrich , MATTENHEIMER, Hendrick
IPC分类号： C07F3/00 , C07F19/00
CPC分类号： C07F3/003 , C07F19/005

26. 发明公开

EP2176201A1 PROCESS FOR THE SEPARATION OF UNBRANCHED HYDROCARBONS FROM THEIR BRANCHED ISOMERS 有权
标题翻译：方法用于分离的支链烃不会从支化异构
公开(公告)号：EP2176201A1
公开(公告)日：2010-04-21
申请号：EP08774533.7
申请日：2008-06-30
申请人： BASF SE
发明人： SCHUBERT, Markus , MÜLLER, Ulrich , KIENER, Christoph , RICHTER, Ingo , WILLIAM, Dolan , POPLOW, Frank
IPC分类号： C07C7/135 , C07C7/12
CPC分类号： C07C7/12 , B01J20/22 , B01J20/226 , B01J2220/56 , C07C7/135 , C10G25/003 , C07C9/00
摘要： The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of-contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.

27. 发明公开

EP2019874A1 PORÖSES METALLORGANISCHES GERÜSTMATERIAL BASIEREND AUF PYRROLEN UND PYRIDINONEN 有权
标题翻译： PORÖSESMETALLORGANISCHESGERÜSTMATERIALBASIEREND AUF PYRROLEN UND PYRIDINONEN
公开(公告)号：EP2019874A1
公开(公告)日：2009-02-04
申请号：EP07729020.3
申请日：2007-05-11
申请人： BASF SE
发明人： RICHTER, Ingo , SCHUBERT, Markus , MÜLLER, Ulrich
IPC分类号： C25B3/12 , C07D233/54 , C07D235/22
CPC分类号： C07D233/54 , B01J20/226 , C07D235/22 , C25B3/12
摘要： The present invention relates to a process for preparing a porous metal organic framework containing at least one organic compound coordinated to at least one metal ion, which comprises the step of oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of the at least one organic compound, where the at least one organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived at least from one of the heterocycles selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens, where the ring system is unsubstituted or has one or more substituents selected independently from the group consisting of halogen, C1-6-alkyl, phenyl, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OC1-6-alkyl, where the substituents C1-6-alkyl and phenyl are unsubstituted or have one or more substituents selected independently from the group consisting of halogen, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OC1-6-alkyl.
摘要翻译：本发明涉及制备含有至少一种与至少一种金属离子配位的有机化合物的多孔金属有机骨架的方法，该方法包括以下步骤：将至少一种含金属的阳极与对应于在所述至少一种有机化合物存在下的反应介质，其中所述至少一种有机化合物是单环，双环或多环体系，其衍生自至少一种选自以下的杂环化合物：吡咯，吡啶酮和γ-吡啶酮并且具有至少两个环氮，其中环系未被取代或具有一个或多个独立选自卤素，C 1-6 - 烷基，苯基，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，Ophenyl和OC 1-6 - 烷基，其中取代基C 1-6 - 烷基和苯基未被取代或具有一个或多个独立选自下列的取代基：卤素 O 2，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，Ophenyl和OC 1-6 - 烷基。

28. 发明公开

EP2004589A1 VERFAHREN ZUR HERSTELLUNG PORÖSER METALLORGANISCHER GERÜSTMATERIALIEN 有权
标题翻译： VERFAHREN ZUR HERSTELLUNGPORÖSERMETALLORGANISCHERGERÜSTMATERIALIEN
公开(公告)号：EP2004589A1
公开(公告)日：2008-12-24
申请号：EP07704355.2
申请日：2007-02-05
申请人： BASF SE
发明人： SCHUBERT, Markus , MÜLLER, Ulrich , HESSE, Michael , DIEHLMANN, Uwe
IPC分类号： C07C51/41 , C07C63/307 , C07F3/00 , B01J20/26
CPC分类号： C07C51/418 , C07C63/307
摘要： The present invention relates to processes for preparing a porous metal-organic framework material that comprise the step of reacting in the liquid phase a reaction mixture composed of at least one copper compound with at least one at least bidentate organic compound able to coordinate to the copper, in the presence of a non-aqueous solvent, said at least one at least bidentate organic compound deriving from a polycarboxylic acid having at least three carboxyl groups, and the reaction taking place under atmospheric pressure at more than 80°C.
摘要翻译：本发明涉及多孔金属 - 有机骨架材料的制造方法，该方法包括使具有至少一种至少二齿的有机化合物的至少一种铜化合物的液相中的反应混合物反应，该有机化合物可通过配位与铜在非水溶剂的存在下，所述至少一种至少二齿的有机化合物衍生自具有至少三个羧基的多元羧酸，并且所述反应在大气压下高于80℃进行。

29. 发明公开

EP1968746A1 SAUER FUNKTIONALISIERTE METALLORGANISCHE GERÜSTMATERIALIEN 有权
标题翻译： SAUER官能化金属有机骨架
公开(公告)号：EP1968746A1
公开(公告)日：2008-09-17
申请号：EP06830534.1
申请日：2006-12-12
申请人： BASF SE
发明人： SCHUBERT, Markus , MÜLLER, Ulrich , BOSCH, Marco , TRILLER, Michael , HATSCHER, Stephan
IPC分类号： B01J31/16 , B01J20/26
CPC分类号： B01J31/1691 , B01J20/226 , B01J39/26 , B01J45/00 , B01J2231/49 , C07C51/418 , C07F5/069 , C07C63/28
摘要： The invention relates to porous organometallic framework materials containing at least one at least ambident organic compound L which is coordinatively bound to at least one metal ion M and is provided with at least one functional group G that binds non-coordinatively to M and is selected among the group comprising -SO3H, -PO3H2, and the analogues thereof. The invention further relates to method for the production thereof and the use thereof.

30. 发明公开

EP3107654A1 KATALYSATORSYSTEM ZUR OXIDATION VON O-XYLOL UND/ODER NAPHTHALIN ZU PHTHALSÄUREANHYDRID 审中-公开
标题翻译： ON ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID ID
公开(公告)号：EP3107654A1
公开(公告)日：2016-12-28
申请号：EP15706733.1
申请日：2015-02-17
申请人： BASF SE
发明人： FISCHER, Nico, Frederik , GALEANO NUNEZ, Diana, Carolina , KRÄMER, Michael , SCHUBERT, Markus , ZÜHLKE, Jürgen , ALLMANN, Hans-Martin
IPC分类号： B01J23/18 , B01J23/22 , B01J27/198 , B01J35/00 , B01J35/02 , C07C15/24
CPC分类号： C07D307/89 , B01J8/06 , B01J23/18 , B01J23/22 , B01J27/198 , B01J35/0006 , B01J35/023 , B01J2208/06 , B01J2523/00 , C01G30/005 , C01P2002/60 , B01J2523/15 , B01J2523/47 , B01J2523/53 , B01J2523/55 , B01J2523/51
摘要： The invention relates to a catalyst system for oxidizing o-xylol and/or naphthalene into phthalic anhydride (PA), which catalyst system comprises a plurality of catalyst layers arranged one after the other in the reaction tube, for the production of which catalyst system an antimony trioxide was used, which contains an appreciable fraction of senarmontite, some of the primary crystallites of which have a size of less than 200 nm. The present invention further relates to a method for gas-phase oxidation, wherein a gas flow, which comprises at least one hydrocarbon and molecular oxygen, is conducted through a catalyst system, which comprises a plurality of catalyst layers arranged one after the other in the reaction tube and for the production of which an antimony trioxide was used, which contains an appreciable fraction of senarmontite, some of the primary crystallites of which have a size of less than 200 nm.
摘要翻译：本发明涉及一种用于将邻二甲苯和/或萘氧化成邻苯二甲酸酐（PA）的催化剂体系，其包括在反应管中连续布置的多个催化剂区域，其使用包含显着比例的三氧化锑生产其中一些初级微晶具有小于200nm的尺寸。本发明还涉及一种用于气相氧化的方法，其中包含至少一种烃和分子氧的气流通过催化剂体系，该催化剂体系包括连续排列在反应管中的多个催化剂区，使用包含显着比例的三钠的三氧化锑生产，其中一些主晶体具有小于200nm的尺寸。

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