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21. 发明专利

JP2013110006A Electrolyte 有权
标题翻译：电解液
公开(公告)号：JP2013110006A
公开(公告)日：2013-06-06
申请号：JP2011254939
申请日：2011-11-22
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： FUJITA SATORU , HASEGAWA NAOKI , KAWAKADO MASAYA
IPC分类号： H01B1/06 , C01B33/12 , H01M8/02 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide an electrolyte having a high EW (or a low IEC), and exhibiting a high proton conductivity even in non-humidified conditions.SOLUTION: The electrolyte includes a silica layer formed by condensation polymerization of a hydrophilic group consisting of a silanol group or a precursor thereof, and an organic sulfonate group modifying the internal surface of the silica layer and not having pores derived from the removal of a surfactant internally. The electrolyte is obtained by adding an SiOsource having a hydrophilic group, as required, into a solution containing amphipathic molecules including a silanol group or a hydrophilic group consisting of a precursor thereof and a hydrophobic group consisting of a precursor of an organic sulfonate group, self-assembling the amphipathic molecules in the solution, and condensing and polymerizing the hydrophilic group.
摘要翻译：要解决的问题：提供具有高EW（或低IEC）的电解质，即使在非加湿条件下也表现出高的质子传导性。解决方案：电解质包括通过由硅烷醇基或其前体组成的亲水基团的缩聚形成的二氧化硅层和改性二氧化硅层的内表面并且不具有来自除去的孔的有机磺酸盐基团的表面活性剂。电解质是通过将根据需要将具有亲水基团的SiO 2原料添加到含有两亲性分子的溶液中而获得的，所述两亲分子包括硅烷醇基或由其前体组成的亲水基团，由有机磺酸盐基团的前体组成的疏水基团，在溶液中自组装两亲性分子，并使亲水基团缩合和聚合。版权所有（C）2013，JPO＆INPIT

22. 发明专利

JP2012158726A Solid polymer electrolyte membrane and method for manufacturing the same 有权
标题翻译：固体聚合物电解质膜及其制造方法
公开(公告)号：JP2012158726A
公开(公告)日：2012-08-23
申请号：JP2011021235
申请日：2011-02-02
申请人： Nitto Denko Corp , Toyota Central R&D Labs Inc , 日東電工株式会社 , 株式会社豊田中央研究所
发明人： TSUSAKA KYOKO , KITANO NAOKI , HASEGAWA NAOKI , KAWAKADO MASAYA , SUGITANI TORU , NISHII HIROYUKI , MATSUDA YASUSO
IPC分类号： C08J5/22 , H01B1/06 , H01B13/00 , H01M8/02 , H01M8/10
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a solid polymer electrolyte membrane with a high electric conductivity capable of being mass-produced while reaction control being comparatively easy, and to provide a method for manufacturing the same.SOLUTION: The method for manufacturing solid polymer electrolyte membrane includes: a membrane forming step of forming a precursor film using a prepolymer solution in which a prepolymer is dissolved or dispersed in a solvent or a prepolymer melt in which the prepolymer is melted; and a crosslinking step of crosslinking directly among the prepoymers in the precursor film or through a crosslinking agent introduced in the precursor film at a time of forming film or after forming film. The solid polymer electrolyte membrane obtained by such the method is also provided.
摘要翻译：要解决的问题：提供具有高导电性的固体聚合物电解质膜，其能够大量生产，同时反应控制相对容易，并提供其制造方法。固体高分子电解质膜的制造方法包括：使用预聚物溶解或分散在预聚物熔融的溶剂或预聚物熔体中的预聚物溶液形成前体膜的膜形成步骤; 以及直接在前体膜中的预浸料之间交联或者在形成膜时或者在形成膜之后通过在前体膜中引入的交联剂交联的交联步骤。还提供了通过这种方法获得的固体聚合物电解质膜。版权所有（C）2012，JPO＆INPIT

23. 发明专利

JP2012158725A Prepolymer and prepolymer solution, and catalyst layer 有权
标题翻译：制备和预处理溶液和催化剂层
公开(公告)号：JP2012158725A
公开(公告)日：2012-08-23
申请号：JP2011021234
申请日：2011-02-02
申请人： Nitto Denko Corp , Toyota Central R&D Labs Inc , 日東電工株式会社 , 株式会社豊田中央研究所
发明人： KITANO NAOKI , TSUSAKA KYOKO , HASEGAWA NAOKI , KAWAKADO MASAYA , SUGITANI TORU , NISHII HIROYUKI , MATSUDA YASUSO
IPC分类号： C08G75/30 , H01M4/86 , H01M8/02 , H01M8/10 , H01M10/0565
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a prepolymer and a prepolymer solution, and a catalyst layer, suitable for a raw material of a solid polymer electrolyte membrane that has a high electrical conductivity and in which a reaction can be controlled comparatively easily, and a mass production can be performed.SOLUTION: The prepolymer is obtained by reacting one or two or more raw monomers and/or raw polymers in a prescribed condition, in which types and the numbers of a reactive terminal group A and a reactive terminal group B by which a bissulfonimide group (-SONHSO-), a sulfone carbonyl imide group (-SONHCO-) or a biscarbonyl imide group (-CONHCO-) can be formed satisfies a prescribed condition, wherein the prepolymer has a high solvent-solubility. In addition, the prepolymer solution is formed by dissolving or dispersing such a prepolymer in a solvent, and the catalyst layer can be obtained using the same.
摘要翻译：待解决的问题：为了提供一种适合于具有高导电性并且可以相对容易地控制反应的固体聚合物电解质膜的原料的预聚物和预聚物溶液和催化剂层，并且可以进行批量生产。解决方案：预聚物是通过使一种或两种以上的原料单体和/或原料聚合物在规定的条件下反应得到的，其中反应性末端基团A和反应性末端基团B的类型和数目是通过其将双磺酰亚胺基团（-SO 2 - ），砜羰基酰亚胺基（-SO

24. 发明专利

JP2012046775A Material coated with metal single atomic layer and manufacturing method therefor 审中-公开
标题翻译：材料涂覆金属单原子层及其制造方法
公开(公告)号：JP2012046775A
公开(公告)日：2012-03-08
申请号：JP2010187632
申请日：2010-08-24
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： UETAKA YUJI , TAKESHITA TOMOHIRO , JINNAI AKINORI , HATANAKA TATSUYA , KAWAKADO MASAYA , MORIMOTO TOMO
IPC分类号： C23C14/14
摘要： PROBLEM TO BE SOLVED: To provide a material coated with a metal single atomic layer where the surface of the substrate is coated with a metal single atomic layer, and manufacturing method therefor.SOLUTION: The method includes: a sealing step of sealing a first substrate and a coating metal which satisfy a predetermined relationship among affinity, a melting point and an evaporation temperature, in a sealed container so as to form the metal single atomic layer; and a coating step of coating a surface of the first substrate with the metal single atomic layer comprising the coating metal after the sealed container is heated at a maximum value Tor higher of the evaporation temperature in a vacuum of each coating metal, and at a lower temperature or below between a minimum value of the temperature at which each first substrate and coating metal react and a heat resistant temperature of the sealed container, and the sealed container is then cooled.
摘要翻译：要解决的问题：提供涂覆有金属单原子层的材料，其中基底的表面被金属单原子层涂覆，及其制造方法。解决方案：该方法包括：在密封容器中密封在亲和力，熔点和蒸发温度之间满足预定关系的第一基底和涂层金属的密封步骤，以形成金属单原子层 ; 以及在密封容器被加热到最大值T Mb 以上之后，将包含涂层金属的金属单原子层涂覆在第一基板的表面上的涂布步骤在每个涂覆金属的真空中的蒸发温度以及在每个第一基底和涂覆金属反应的温度的最小值与密封容器的耐热温度之间的较低温度或更低温度下，然后将密封容器冷却。版权所有（C）2012，JPO＆INPIT

25. 发明专利

JP2011225494A Production method of sugar or its derivative 有权
标题翻译：糖或其衍生物的生产方法
公开(公告)号：JP2011225494A
公开(公告)日：2011-11-10
申请号：JP2010098302
申请日：2010-04-21
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： FUJITA SATORU , INAGAKI SHINJI , FUKUSHIMA HIDEOKI , KAWAKADO MASAYA
IPC分类号： C07H3/02 , B01J27/12 , C07B61/00
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method of carrying out decomposition/saccharification of a cellulosic material more efficiently to produce sugar or its derivative.SOLUTION: The production method of sugar or its derivative includes a process which makes a cellulosic material contact with a porous body which includes two or more pores consisting of a polysiloxane-containing skeleton, and a perfluoro sulfonic acid group expressed by the formula (1): -[C(H, F)]-X-(CF)-SOH (wherein X is O or a direct bond; and n and m are each an integer of 1 to 3) on inner surfaces of the pores under irradiation of a microwave to saccharify the cellulosic material.
摘要翻译：要解决的问题：提供一种更有效地进行纤维素材料的分解/糖化以产生糖或其衍生物的方法。糖或其衍生物的制造方法包括使纤维素材料与包含由含聚硅氧烷的骨架构成的两个以上的多孔的多孔体接触的方法和由式（1）： - [C（H，F） 2 ] n -X-（CF 2 ）其中X是O或直接键;并且n和 m为1〜3的整数），在微波照射下，在纤维素材料糖化的情况下。版权所有（C）2012，JPO＆INPIT

26. 发明专利

JP2009062343A Noncrosslinked type layered phosphonic acid metal compound and its manufacturing method 审中-公开
标题翻译：非交联型层状磷酸金属化合物及其制造方法
公开(公告)号：JP2009062343A
公开(公告)日：2009-03-26
申请号：JP2007233625
申请日：2007-09-10
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： OGATA SHINICHI , FUKUSHIMA YOSHIAKI , KAWAKADO MASAYA
IPC分类号： C07F9/38 , C07F7/00 , C07F7/28
摘要： PROBLEM TO BE SOLVED: To provide a new noncrosslinked type layered phosphonic acid metal compound which has high crystallizability and a uniformly introduced multi-component phosphonic acid and does not contain a fluorine atom and its manufacturing method. SOLUTION: The method for manufacturing a noncrosslinked type layered phosphonic acid metal compound comprises a reaction step of reacting at least two types of monophosphonic acids or derivatives thereof having predetermined conditions with a metal source forming a 6 coordination metal atom ion which comes to the central atom (M) of a metal oxide octahedron at the time of reaction in the presence of a sulfuric acid catalyst. The noncrosslinked type layered phosphonic acid metal compound can be obtained by such a method. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供具有高结晶性和均匀引入的多组分膦酸并且不含氟原子的新型非交联型层状膦酸金属化合物及其制造方法。解决方案：非交联型层状膦酸金属化合物的制造方法包括使至少两种具有预定条件的单膦酸或其衍生物与形成6配位金属原子离子的金属源反应的反应步骤，在硫酸催化剂存在下反应时金属氧化物八面体的中心原子（M）。可以通过这种方法得到非交联型层状膦酸金属化合物。版权所有（C）2009，JPO＆INPIT

27. 发明专利

JP2008159343A Solid polymer fuel cell 有权
标题翻译：固体聚合物燃料电池
公开(公告)号：JP2008159343A
公开(公告)日：2008-07-10
申请号：JP2006345275
申请日：2006-12-22
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： HASEGAWA NAOKI , MUTO JUNKO , TOYODA EIJIRO , ASANO TAKASHI , MIURA FUSAYOSHI , KAWAKADO MASAYA
IPC分类号： H01M8/02 , H01M4/86 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide a solid polymer fuel cell with little degradation of electrolyte and excellent in durability. SOLUTION: The solid polymer fuel cell comprises a membrane electrode assembly with an electrode containing catalyst jointed to an electrolyte membrane, and one or two kinds or more compounds containing W and/or Mo and transition metal (except W and Mo) added to either the electrolyte membrane or the electrode, and that, includes a degradation inhibitor with a ratio of the transition metal to the W and or the Mo expressed in formula (1): transition metal/(W+Mo)(mol/mol)=0.01 to 0.6. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供固体聚合物燃料电池，其电解质的降解很小，耐久性优异。固体聚合物燃料电池包括具有连接到电解质膜的催化剂电极的膜电极组件，并且添加含有W和/或Mo和过渡金属（W和Mo除外）的一种或两种以上的化合物并且包括具有过渡金属与W的比例的降解抑制剂和/或式（1）表示的Mo：过渡金属/（W + Mo）（mol / mol） = 0.01〜0.6。版权所有（C）2008，JPO＆INPIT

28. 发明专利

JP2009259793A Strong acid crosslinking type compound electrolyte 审中-公开
标题翻译：强酸交联型复合电解质
公开(公告)号：JP2009259793A
公开(公告)日：2009-11-05
申请号：JP2009062881
申请日：2009-03-16
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： TSUSAKA KYOKO , KAMIYA ATSUSHI , HASEGAWA NAOKI , KAWAKADO MASAYA
IPC分类号： H01B1/06 , C08F2/44 , C08F283/00 , C08G75/30 , H01M8/02
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To provide a strong acid crosslinking type compound electrolyte capable of providing compatibility between strength and electric conductivity. SOLUTION: The strong acid crosslinking type compound electrolyte includes a high polymer electrolyte containing imide crosslinking type electrolyte provided by a reaction of one or more types of first monomers having two or more reactive functional groups A, B, and one or more types of second monomers having three or more of the reactive functional groups A, B, and a different type of polymer combined with the imide crosslinking type electrolyte. At least one reactive functional group A, and at least one reactive functional group B are included in either one of the first monomer or the second monomer. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供能够提供强度和电导率之间的相容性的强酸交联型复合电解质。解决方案：强酸交联型复合电解质包括通过一种或多种具有两个或更多个反应性官能团A，B和一种或多种类型的第一单体的反应提供的含有酰亚胺交联型电解质的高分子电解质的具有三个或更多个反应性官能团A，B的第二单体和与酰亚胺交联型电解质组合的不同类型的聚合物。至少一个反应性官能团A和至少一个反应性官能团B包括在第一单体或第二单体中的任一个中。版权所有（C）2010，JPO＆INPIT

29. 发明专利

JP2008243511A Composite electrolyte, and its manufacturing method 有权
标题翻译：复合电解质及其制造方法
公开(公告)号：JP2008243511A
公开(公告)日：2008-10-09
申请号：JP2007080720
申请日：2007-03-27
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： HOSOKAWA YOICHI , TSUSAKA KYOKO , HASEGAWA NAOKI , KAWAKADO MASAYA
IPC分类号： H01B13/00 , C08J9/36 , H01B1/06 , H01M8/02 , H01M8/10
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a composite electrolyte suppressing elution and swell of the electrolyte, high in electric conductivity, and excelling in chemical durability, and also to provide its manufacturing method. SOLUTION: This composite electrolyte manufacturing method comprises: a modification process of introducing a reactive functional group A comprising a sulfonamide group or its derivative, or a sulfonyl halide group or its derivative into a surface of a hydrocarbon-based porous base material; and a compounding process of filling an electrolyte monomer and/or an electrolyte polymer having a reactive functional group B producing a sulfonimide group by reacting with the reactive functional group A in the hydrocarbon-based porous base material to react the reactive functional group A with the reactive functional group B. This composite electrolyte is provided by such a method. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供抑制电解质的洗脱和膨胀的复合电解质，高导电性和优异的化学耐久性，并且还提供其制造方法。解决方案：该复合电解质制造方法包括：将包含磺酰胺基团或其衍生物或磺酰卤基团或其衍生物的反应性官能团A引入烃类多孔基材的表面的改性方法; 以及填充电解质单体和/或具有反应性官能团B的电解质聚合物的复合方法，通过与烃类多孔基材中的反应性官能团A反应，使反应性官能团A与反应性官能团B.这种复合电解质是通过这种方法提供的。版权所有（C）2009，JPO＆INPIT

30. 发明专利

JP2007294408A Polyparaphenylene hydrocarbon electrolyte, manufacture method therefor, polyparaphenylene, and electrolyte membrane, catalyst layer and polymer electrolyte fuel cell using polyparaphenylene hydrocarbon electrolyte 审中-公开
标题翻译：聚苯醚烯烃电解质，其制备方法，聚苯乙烯和电解质膜，催化层和聚合物电解质燃料电池使用聚苯醚烯烃电解液
公开(公告)号：JP2007294408A
公开(公告)日：2007-11-08
申请号：JP2007034296
申请日：2007-02-15
申请人： Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： HOSHIKAWA HISAHIRO , HASEGAWA NAOKI , KAWAKADO MASAYA , AOKI YOSHIFUMI , TAKAMI MASAYOSHI , KAWAHARA MITSUYASU
IPC分类号： H01B1/06 , C08G61/10 , H01B13/00 , H01M8/02 , H01M8/10
CPC分类号： H01B1/122 , C08G61/10 , C08J5/2256 , C08J2365/00 , H01M8/1004 , H01M8/1023 , H01M8/1067 , H01M8/1072 , H01M2300/0082 , Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide an electrolyte excellent in chemical durability, a manufacturing method therefor, polyparaphenylene (PPP), and an electrolyte membrane, a catalyst layer, and a polymer electrolyte fuel cell using the same. SOLUTION: A polyparaphenylene hydrocarbon electrolyte having a specific structure, a manufacture method therefor, and a polyparaphenylene usable as a raw material for manufacturing the polyparaphenylene hydrocarbon electrolyte, as well as an electrolyte membrane, a catalyst layer and a polymer electrolyte fuel cell that employ the polyparaphenylene hydrocarbon-based electrolyte. In the structural formula, phenyl group has a direct bond or an oxygen atom, which is arbitrarily assignable in repetitions. A branch from the phenyl group has a hydrogen atom or a proton-conducting site, which is arbitrarily assignable in repetitions. The proton-conducting site is made up of -SO 3 H, -COOH, -PO 3 H 2 or -SO 2 NHSO 2 R (R is an alkyl chain or a perfluoroalkyl chain). COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供化学耐久性优异的电解液，其制造方法，聚对亚苯基（PPP）和电解质膜，催化剂层和使用该电解质的固体高分子型燃料电池。解决方案：具有特定结构的聚对亚苯基碳氢化合物电解质及其制造方法和可用作制备聚对亚苯基烃电解质的原料的聚对亚苯基，以及电解质膜，催化剂层和聚合物电解质燃料电池其使用聚对亚苯基烃类电解质。在结构式中，苯基具有直接键或氧原子，其可重复任意赋值。苯基的分支具有氢原子或质子传导位点，其可重复任意赋值。质子传导部位由-SO 3 SBH，-COOH，-PO 3，SB 3或-SO 2 SB 2组成，（R是烷基链或全氟烷基链）。版权所有（C）2008，JPO＆INPIT

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