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21. 发明授权

US5294694A Electromagnetic radiation absorbers and modulators comprising polyaniline 失效
标题翻译：包括聚苯胺的电磁辐射吸收剂和调节剂
公开(公告)号：US5294694A
公开(公告)日：1994-03-15
申请号：US918709
申请日：1992-07-27
申请人： Arthur J. Epstein , John M. Ginder , Mitchell G. Roe , Hamid Hajiseyedjavdi
发明人： Arthur J. Epstein , John M. Ginder , Mitchell G. Roe , Hamid Hajiseyedjavdi
IPC分类号： C08G73/02 , D01F6/76 , D06M10/10 , D06M15/61 , G02F1/361 , H01B1/12 , C08G65/38 , B05D3/02 , B05D3/06 , C08G73/00
CPC分类号： C08G73/0266 , D01F6/76 , D06M10/10 , D06M15/61 , G02F1/3611 , H01B1/128
摘要： A method is provided for absorbing electromagnetic radiation using a polyaniline composition, wherein the radiation is infrared, visible light, ultraviolet, radar, or microwave radiation. Also provided is a method for reducing the detectability by radar of an object by increasing the absorption of radar waves and thereby decrease the reflection of the radar waves by applying to the object a polyaniline composition or a partially protonated salt thereof.
摘要翻译：提供了一种使用聚苯胺组合物吸收电磁辐射的方法，其中辐射是红外线，可见光，紫外线，雷达或微波辐射。还提供了一种通过增加雷达波的吸收来减少雷达对物体的可检测性的方法，从而通过向对象施加聚苯胺组合物或其部分质子化的盐来减少雷达波的反射。

22. 发明授权

US5250163A Proton concentration sensor/modulator for sulfonated and hydroxylated polyaniline electrodes 失效
标题翻译：用于磺化和羟基化聚苯胺电极的质子浓度传感器/调制器
公开(公告)号：US5250163A
公开(公告)日：1993-10-05
申请号：US800363
申请日：1991-11-27
申请人： Arthur J. Epstein , Jiang Yue , David R. Burley
发明人： Arthur J. Epstein , Jiang Yue , David R. Burley
IPC分类号： G01N27/30 , G01N27/26
CPC分类号： G01N27/4167
摘要： Broadly, the present invention takes advantage of the ability of self-protonated sulfonated polyaniline (SPAN) to sense and/or modulate pH of a medium in the vicinity of a SPAN electrode. Accordingly, one aspect of the present invention is directed to a method for sensing pH of a medium in the vicinity of a sensing electrode wherein a SPAN electrode and a counter-electrode are placed in a medium and an indicia of said SAN correlative with the pH of said medium is monitored. As another aspect of the present invention, the pH of a medium in the vicinity of a sensing electrode is modulated by placing a SPAN electrode in the medium and applying a voltage to the electrode to controllably emit or absorb protons from said electrode to modulate the pH of the medium in the vicinity of the electrode. As a further aspect of the present invention, the activity/state of a biosensor/catalyst is sensed for the activity/state correlative with pH. As a further aspect of the present invention, the activity/state of a biosensor/catalyst, where the activity/state is correlative with pH, is controlled by associating the biosensor/catalyst with a SPAN electrode in contact with a medium containing said biosensor/catalyst, and applying a voltage to said electrode to controllably emit or absorb protons from said electrode to control the activity/state of said biosensor/catalyst.
摘要翻译：广泛地，本发明利用自质子化磺化聚苯胺（SPAN）在SPAN电极附近感测和/或调节介质的pH的能力。因此，本发明的一个方面涉及一种用于感测感测电极附近的介质的pH的方法，其中将SPAN电极和对电极放置在介质中，并且所述SAN的标记与pH相关的所述介质被监测。作为本发明的另一方面，通过将SPAN电极放置在介质中并向电极施加电压来调制感测电极附近的介质的pH，以可控制地从所述电极发射或吸收质子以调节pH 介质在电极附近。作为本发明的另一方面，检测与pH相关的活性/状态的生物传感器/催化剂的活性/状态。作为本发明的另一方面，活性/状态与pH相关的生物传感器/催化剂的活性/状态通过将生物传感器/催化剂与含有所述生物传感器/催化剂的介质接触的SPAN电极相关联来控制，催化剂，并向所述电极施加电压以可控制地从所述电极发射或吸收质子，以控制所述生物传感器/催化剂的活性/状态。

23. 发明授权

US5093439A Processes for preparation of sulfonated polyaniline compositions and uses thereof 失效
标题翻译：制备磺化聚苯胺组合物的方法及其用途
公开(公告)号：US5093439A
公开(公告)日：1992-03-03
申请号：US529012
申请日：1990-05-25
申请人： Arthur J. Epstein , Jiang Yue
发明人： Arthur J. Epstein , Jiang Yue
IPC分类号： C08G73/02 , G02F1/01 , G11B7/244 , H01B1/12 , H01M4/60 , H05K9/00
CPC分类号： H01M4/60 , C08G73/0266 , G02F1/0126 , G11B7/244 , G11B7/245 , H01B1/128 , Y10T428/2913 , Y10T428/2982 , Y10T428/31942 , Y10T428/31949
摘要： Sulfonic acid-substituted polyaniline compositions and their derivatives are produced by reacting a polyaniline polymer with SO.sub.3 gas. The sulfonated polyaniline compositions have faster electronic and optical responses to electrochemical potentials and improved environmental stability solubility than the parent polyaniline polymer.
摘要翻译：磺酸取代的聚苯胺组合物及其衍生物通过聚苯胺聚合物与SO 3气体反应制备。磺化聚苯胺组合物对电化学电位具有更快的电子和光学响应，并且比母体聚苯胺聚合物具有改善的环境稳定性溶解性。

24. 发明授权

US08326389B2 System for in vivo biosensing based on the optical response of electronic polymers 失效
标题翻译：基于电子聚合物的光学响应的体内生物传感系统
公开(公告)号：US08326389B2
公开(公告)日：2012-12-04
申请号：US12517966
申请日：2007-12-05
申请人： Arthur J. Epstein , Louis R. Nemzer
发明人： Arthur J. Epstein , Louis R. Nemzer
IPC分类号： A61B5/1455
CPC分类号： A61B5/14735 , A61B5/14532 , A61B5/14546 , A61B5/1459 , A61B5/14865 , A61B5/681
摘要： A system for continuous in vivo biosensing of specific analyte molecule concentrations based on the dynamic optical properties of electronic polymers is disclosed. The biosensor system includes at least one implant member subcutaneously exposed to the interstitial fluid of the subject, and a reader member at least temporarily positioned over the implant member to probe it with light of specific wavelengths through the skin. The system has many potential applications, including the real-time monitoring of blood glucose levels in diabetics as a method to supplement or replace conventional capillary blood testing.
摘要翻译：公开了一种基于电子聚合物的动态光学性质的特定分析物分子浓度的连续体内生物传感的系统。生物传感器系统包括皮下暴露于受试者的间质液体的至少一个植入物构件，以及读取器构件，其至少临时定位在植入构件上方，以通过皮肤的特定波长的光探测它。该系统具有许多潜在应用，包括实时监测糖尿病患者的血糖水平，作为补充或替代常规毛细血管血液检测的方法。

25. 发明申请

US20110229706A1 ALIGNED NANOSTRUCTURED POLYMERS 有权
标题翻译：对准的纳米结构聚合物
公开(公告)号：US20110229706A1
公开(公告)日：2011-09-22
申请号：US11731974
申请日：2007-04-02
申请人： Arthur J. Epstein , Nan-Rong Chiou , Ly James Lee , Chunmeng Lu
发明人： Arthur J. Epstein , Nan-Rong Chiou , Ly James Lee , Chunmeng Lu
IPC分类号： B32B5/02 , C08G73/02 , B05D5/12 , B05D3/10 , C08J7/18 , B05D1/12 , H01J19/30 , C25D5/56 , C07H21/04
CPC分类号： C08G73/0266 , B82Y30/00 , B82Y40/00 , D01D5/38 , D01F6/76 , H01B1/128 , H01L51/5215 , Y10T428/249924
摘要： Novel, simple methods are presented directed to the synthesis of aligned nanofibers of polyaniline and substituted derivatives on a substrate. The production of these fibers is achieved via various methods by controlling the concentration of aniline monomer or substituted aniline derivatives or an oxidant in the reaction medium and maintaining said concentration at a level much lower than conventional polyaniline synthesis methods. Methods are disclosed relating to the use of a permeable membrane to control the release of a monomer and/or oxidant as well as a bulk polymerization method.
摘要翻译：提出了一种简单的方法，用于合成基板上聚苯胺和取代衍生物的取向纳米纤维。这些纤维的生产通过各种方法通过控制苯胺单体或取代的苯胺衍生物或反应介质中的氧化剂的浓度来实现，并将该浓度保持在比常规聚苯胺合成方法低得多的水平。公开了关于使用可渗透膜来控制单体和/或氧化剂的释放以及本体聚合方法的方法。

26. 发明授权

US07071290B2 Polymers and oligomers, their synthesis, and electronic devices incorporating same 失效
公开(公告)号：US07071290B2
公开(公告)日：2006-07-04
申请号：US11116580
申请日：2005-04-28
申请人： Arthur J. Epstein , Daike Wang
发明人： Arthur J. Epstein , Daike Wang
IPC分类号： C08G73/06
CPC分类号： C07D213/30 , C07C15/58 , C07D213/24 , C07D213/53 , C07D215/12 , C08G61/122
摘要： The invention relates to polymers and oligomers, methods of their synthesis, and electronic devices comprising them.

27. 发明授权

US06777532B2 Polymers and oligomers, their synthesis, and electronic devices incorporating same 失效
标题翻译：聚合物和低聚物，它们的合成以及结合其的电子器件
公开(公告)号：US06777532B2
公开(公告)日：2004-08-17
申请号：US10084866
申请日：2002-02-28
申请人： Arthur J. Epstein , Daike Wang
发明人： Arthur J. Epstein , Daike Wang
IPC分类号： C08G7306
CPC分类号： C07D213/30 , C07C15/58 , C07D213/24 , C07D213/53 , C07D215/12 , C08G61/122
摘要： The invention relates to polymers and oligomers, methods of their synthesis, and electronic devices comprising them.
摘要翻译：本发明涉及聚合物和低聚物，它们的合成方法和包含它们的电子器件。

28. 发明授权

US06621100B2 Polymer-, organic-, and molecular-based spintronic devices 失效
标题翻译：聚合物，有机和基于分子的自旋电子器件
公开(公告)号：US06621100B2
公开(公告)日：2003-09-16
申请号：US10045543
申请日：2001-10-26
申请人： Arthur J. Epstein , Vladimir N. Prigodin
发明人： Arthur J. Epstein , Vladimir N. Prigodin
IPC分类号： H01L5100
CPC分类号： H01L51/0508 , B82Y10/00 , B82Y25/00 , G11B5/3909 , G11B2005/3996 , G11C11/16 , G11C13/0014 , G11C13/0016 , G11C13/04 , H01F1/42 , H01F10/32 , H01F10/325 , H01F10/3254 , H01F10/3281 , H01L51/0051 , H01L51/05 , H01L51/5012 , H01L51/52
摘要： This invention relates to organic based spintronic devices, and electronic devices comprising them, including spin valves, spin tunnel junctions, spin transistors and spin light-emitting devices. New polymer-, organic- and molecular-based electronic devices in which the electron spin degree of freedom controls the electric current to enhance device performance. Polymer-, organic-, and molecular-based spintronic devices have enhanced functionality, ease of manufacture, are less costly than inorganic ones. The long spin coherence times due to the weak spin-orbit interaction of carbon and other low atomic number atoms that comprise organic materials make them ideal for exploiting the concepts of spin quantum devices. The hopping mechanism of charge transport that dominates in semiconducting polymers (vs. band transport in crystalline inorganic semiconductors) enhances spin-magneto sensitivity and reduces the expected power loss.
摘要翻译：本发明涉及有机基自旋电子器件，以及包括它们的电子器件，包括自旋阀，自旋隧道结，自旋晶体管和自旋发光器件。新的聚合物，有机和基于分子的电子器件，其中电子自由度控制电流以增强器件性能。聚合物，有机和基于分子的自旋电子器件具有增强的功能，易于制造，成本比无机材料成本低。由于包含有机材料的碳和其他低原子数原子的自旋轨道相互作用弱，长的自旋相干时间使其成为开发自旋量子器件概念的理想选择。主导半导体聚合物（与结晶无机半导体中的带传输）电荷转移的跳跃机制增强了自旋磁感应灵敏度并降低了预期的功率损耗。

29. 发明授权

US5463014A Electromagnetic radiation absorbers and modulators comprising polyaniline 失效
标题翻译：包括聚苯胺的电磁辐射吸收剂和调节剂
公开(公告)号：US5463014A
公开(公告)日：1995-10-31
申请号：US193229
申请日：1994-02-08
申请人： Arthur J. Epstein , Mitchell G. Roe , John M. Ginder , Hamid Hajiseyedjavadi , Jinsoo Joo
发明人： Arthur J. Epstein , Mitchell G. Roe , John M. Ginder , Hamid Hajiseyedjavadi , Jinsoo Joo
IPC分类号： C08G73/02 , D01F6/76 , D06M10/10 , D06M15/61 , G02F1/361 , H01B1/12 , C08G65/38 , B05D3/02 , B05D3/06
CPC分类号： D01F6/76 , C08G73/0266 , D06M10/10 , D06M15/61 , G02F1/3611 , H01B1/128
摘要： A method of providing electronic shielding comprising providing a layer of a polyaniline composition on the object to be shielded, whereby the entrance and egress of electromagnetic radiation is prevented. Also presented herein is a method of changing the absorption by a polyaniline composition of electromagnetic radiation by modifying the chemical structure and crystallinographic order of the polyaniline composition, wherein said composition comprises a composition of the formula ##STR1## where y can be equal to or greater than zero, and R.sup.1 and R.sup.2 are independently selected from the group consisting of --H, --OCH.sub.3, --F, --Cl, --Br, --I, --NR.sup.3.sub.2, --NHCOR.sup.3, --OH, --O, --SR.sup.3, --OR.sup.3, --OCOR.sup.3, --NO.sub.2, --COOH, --COOR.sup.3, --R.sup.3 SO.sub.3 H, --COR.sup.3, --CHO, and --CN, where R.sup.3 is a C.sub.1 to C.sub.8 alkyl, aryl, or aralkyl group.
摘要翻译：一种提供电子屏蔽的方法，包括在待屏蔽物体上提供聚苯胺组合物层，从而防止电磁辐射的入射和出射。本文还提出了通过改变聚苯胺组合物的化学结构和结晶度来改变聚苯胺组合物的电磁辐射的吸收的方法，其中所述组合物包含式“IMAGE”的组合物，其中y可以等于或大于 R 1和R 2独立地选自-H，-OCH 3，-F，-Cl，-Br，-I，-NR 32，-NHCOR 3，-OH，-O，-SR 3，-OR 3 ，-OCOR 3，-NO 2，-COOH，-COOR 3，-R 3 SO 3 H，-COR 3，-CHO和-CN，其中R 3是C 1至C 8烷基，芳基或芳烷基。

30. 发明授权

US5135696A Process for forming fibers of sulfonated polyaniline compositions and uses thereof 失效
标题翻译：形成磺化聚苯胺组合物的方法及其用途
公开(公告)号：US5135696A
公开(公告)日：1992-08-04
申请号：US529024
申请日：1990-05-25
申请人： Arthur J. Epstein , Jiang Yue
发明人： Arthur J. Epstein , Jiang Yue
IPC分类号： C08G73/02 , G02F1/01 , G11B7/244 , H01B1/12 , H01M4/60 , H05K9/00
CPC分类号： H05K9/009 , C08G73/0266 , G02F1/0126 , G11B7/244 , G11B7/245 , H01B1/128 , H01M4/60
摘要： Methods for producing fibers of self-protonated sulfonic acid-substituted polyaniline compositions. The sulfonated polyaniline compositions have faster electronic and optical responses to electrochemical potentials comparing to its parent polyaniline, improved environmental stability, and improved solubility than the parent polymer, polyaniline.
摘要翻译：自质子化磺酸取代聚苯胺组合物纤维的制备方法。与其母体聚苯胺相比，磺化聚苯胺组合物具有比其母体聚苯胺更高的电化学势和光学响应，改善的环境稳定性和改善的溶解性。

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