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21. 发明申请

US20080006574A1 Membrane structure and method of making 有权
标题翻译：膜结构及制作方法
公开(公告)号：US20080006574A1
公开(公告)日：2008-01-10
申请号：US11480638
申请日：2006-07-05
申请人： Vidya Ramaswamy , Seth Thomas Taylor , James Anthony Ruud , Melissa Suzanne Sander , Anthony Yu-Chung Ku , Mohan Manoharan
发明人： Vidya Ramaswamy , Seth Thomas Taylor , James Anthony Ruud , Melissa Suzanne Sander , Anthony Yu-Chung Ku , Mohan Manoharan
IPC分类号： B01D29/00 , B01D71/04
CPC分类号： B01D67/0065 , B01D67/0088 , B01D69/02 , B01D2315/12 , B01D2321/168 , B01D2323/28 , B01D2323/286 , B01D2325/02 , Y10T156/10 , Y10T428/249953
摘要： A membrane structure is provided. The membrane structure includes a first layer having a plurality of pores; and a second layer disposed on, the first layer. The second layer has a plurality of unconnected pores. At least a portion of the plurality of unconnected pores of the second layer is at least partially filled with a filler such that the first layer is substantially free of the filler. At least a portion of the plurality of unconnected pores of the second layer is in fluid communication with at least one of the pores of the first layer. A method of making a membrane structure is provided. The method includes the steps of providing a first layer having a plurality of interconnected pores; disposing a second layer on the first layer, and filling at least a portion of the unconnected pores of the second layer with a filler such that the first layer is substantially free of the filler. Disposing a second layer includes depositing a metal layer on the first layer; and anodizing the metal layer to convert the metal layer into porous oxide layer.
摘要翻译：提供膜结构。膜结构包括具有多个孔的第一层; 以及设置在第一层上的第二层。第二层具有多个未连接的孔。第二层的多个未连接孔的至少一部分至少部分地填充有填料，使得第一层基本上不含填料。第二层的多个未连接孔的至少一部分与第一层的至少一个孔流体连通。提供了制造膜结构的方法。该方法包括提供具有多个互连孔的第一层的步骤; 在第一层上设置第二层，并用填料填充第二层的至少一部分未连接的孔，使得第一层基本上不含填料。布置第二层包括在第一层上沉积金属层; 并将金属层阳极氧化以将金属层转化为多孔氧化物层。

22. 发明授权

US08043418B2 Gas separator apparatus 有权
标题翻译：气体分离装置
公开(公告)号：US08043418B2
公开(公告)日：2011-10-25
申请号：US11608292
申请日：2006-12-08
申请人： James Anthony Ruud , Michael John Bowman , Kalya Vijaya Sarathy , Mohan Manoharan , Anthony Yu-Chung Ku , Vidya Ramaswamy , Patrick Roland Lucien Malenfant
发明人： James Anthony Ruud , Michael John Bowman , Kalya Vijaya Sarathy , Mohan Manoharan , Anthony Yu-Chung Ku , Vidya Ramaswamy , Patrick Roland Lucien Malenfant
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D61/38 , B01D67/0088 , B01D67/0093 , B01D69/10 , B01D69/141 , B01D71/024 , B01D71/027 , B01D71/028 , B01D71/40 , B01D71/44 , B01D2257/504 , B01D2325/10 , B01D2325/22 , Y02C10/10
摘要： An apparatus for separating at least one component from a mixture of a plurality of chemical species is provided. The apparatus comprises a membrane structure comprising a plurality of pores disposed within a matrix material to allow mass transport from a first surface of the membrane structure to a second surface of the membrane structure. The matrix material has a thermal conductivity of at least about 10 W/m/K; and a functional material disposed within at least a portion of the plurality of pores. The functional material has the property of promoting selective transport of at least one species through the membrane structure from the first surface to the second surface.
摘要翻译：提供了一种用于从多种化学物质的混合物中分离至少一种组分的装置。该装置包括膜结构，其包括设置在基质材料内的多个孔，以允许质量从膜结构的第一表面传输到膜结构的第二表面。基质材料具有至少约10W / m / K的热导率; 以及设置在所述多个孔的至少一部分中的功能材料。功能材料具有促进至少一种物质通过膜结构从第一表面到第二表面的选择性输送的性质。

23. 发明申请

US20100129639A1 SURFACE HAVING A NANOPOROUS COATING, METHODS OF MANUFACTURE THEREOF AND ARTICLES COMPRISING THE SAME 审中-公开
标题翻译：具有纳米涂层的表面，其制造方法和包含其的制品
公开(公告)号：US20100129639A1
公开(公告)日：2010-05-27
申请号：US12277802
申请日：2008-11-25
申请人： Tunc Icoz , Anthony Yu-Chung Ku , James Anthony Ruud
发明人： Tunc Icoz , Anthony Yu-Chung Ku , James Anthony Ruud
IPC分类号： B32B5/16 , B32B5/18 , B05D5/00 , B05D1/00 , B05D1/06 , B05D1/18
CPC分类号： C23C24/00 , B01B1/06 , B01D1/30 , F28F13/185 , H01L23/44 , H01L2924/0002 , Y10T428/249953 , Y10T428/249986 , H01L2924/00
摘要： Disclosed herein is an that includes a substrate; and a nanoporous coating disposed thereon; the nanoporous coating having a thickness of about 5 nanometers to about 10 micrometers; where an interface between the substrate and the nanoporous coating is disposed at an angle of about 60 degrees to about 120 degrees to a horizontal; the nanoporous coating being in contact with a liquid; the nanoporous coating being operative to improve the critical heat flux by an amount of about 20% to about 100% over a surface that does not have a nanoporous coating.
摘要翻译：这里公开的是包括基板; 和设置在其上的纳米多孔涂层; 所述纳米多孔涂层具有约5纳米至约10微米的厚度; 其中衬底和纳米多孔涂层之间的界面以与水平面成约60度至约120度的角度设置; 所述纳米多孔涂层与液体接触; 纳米多孔涂层可操作以在不具有纳米多孔涂层的表面上改善约20％至约100％的临界热通量。

24. 发明申请

US20090218275A1 MEMBRANE STRUCTURE AND METHOD OF MAKING 失效
标题翻译：膜结构和制备方法
公开(公告)号：US20090218275A1
公开(公告)日：2009-09-03
申请号：US12464272
申请日：2009-05-12
申请人： Vidya Ramaswamy , James Anthony Ruud , Anthony Yu-Chung Ku , William Hullinger Huber
发明人： Vidya Ramaswamy , James Anthony Ruud , Anthony Yu-Chung Ku , William Hullinger Huber
IPC分类号： B01D63/00 , B32B3/26
CPC分类号： B01D67/0062 , B01D69/12 , B01D71/022 , B01J2219/00835 , B01J2219/00907 , Y10T428/249981
摘要： A membrane structure is provided. The membrane structure includes a polymer layer having a plurality of pores; and a ceramic layer disposed on the polymer layer. The ceramic layer has a plurality of substantially unconnected pores. Each of the substantially unconnected pores is in fluid communication with at least one of the pores of the polymer layer. A method of manufacturing a membrane structure is provided. The method includes the steps of providing a polymer layer having a plurality of pores; and disposing a ceramic layer on the polymer layer. Disposing a ceramic layer includes depositing a metal layer on the polymer layer; and anodizing the metal layer to convert the metal layer into a porous layer. At least one of the depositing step and the anodizing step is performed as a continuous process. Alternatively, at least one of the depositing and the anodizing step is performed as a batch process.
摘要翻译：提供膜结构。膜结构包括具有多个孔的聚合物层; 以及设置在聚合物层上的陶瓷层。陶瓷层具有多个基本上未连接的孔。每个基本上未连接的孔与聚合物层的至少一个孔流体连通。提供一种制造膜结构的方法。该方法包括提供具有多个孔的聚合物层的步骤; 并在聚合物层上设置陶瓷层。布置陶瓷层包括在聚合物层上沉积金属层; 并阳极氧化金属层以将金属层转化为多孔层。沉积步骤和阳极氧化步骤中的至少一个作为连续工艺进行。或者，沉积和阳极化步骤中的至少一个作为分批处理进行。

25. 发明授权

US07396382B2 Functionalized inorganic membranes for gas separation 有权
标题翻译：用于气体分离的官能化无机膜
公开(公告)号：US07396382B2
公开(公告)日：2008-07-08
申请号：US11263165
申请日：2005-10-31
申请人： Anthony Yu-Chung Ku , James Anthony Ruud , Jennifer Lynn Molaison , Louis Andrew Schick , Vidya Ramaswamy
发明人： Anthony Yu-Chung Ku , James Anthony Ruud , Jennifer Lynn Molaison , Louis Andrew Schick , Vidya Ramaswamy
IPC分类号： B01D71/02
CPC分类号： B01D71/024 , B01D53/228 , B01D69/12 , B01D2323/08 , Y02C10/10
摘要： A porous membrane for separation of carbon dioxide from a fluid stream at a temperature higher than about 200° C. with selectivity higher than Knudsen diffusion selectivity. The porous membrane comprises a porous support layer comprising alumina, silica, zirconia or stabilized zirconia; a porous separation layer comprising alumina, silica, zirconia or stabilized zirconia, and a functional layer comprising a ceramic oxide contactable with the fluid stream to preferentially transport carbon dioxide. In particular, the functional layer may be MgO, CaO, SrO, BaO, La2O3, CeO2, ATiO3, AZrO3, AAl2O4, A1FeO3, A1MnO3, A1CoO3, A1NiO3, A2HfO3, A3CeO3, Li2ZrO3, Li2SiO3, Li2TiO3 or a mixture thereof; wherein A is Mg, Ca, Sr or Ba; A1 is La, Ca, Sr or Ba; A2 is Ca, Sr or Ba; and A3 is Sr or Ba.
摘要翻译：一种用于在高于约200℃的温度下将二氧化碳与流体物流分离的多孔膜，选择性高于克努森扩散选择性。多孔膜包括多孔支撑层，包括氧化铝，二氧化硅，氧化锆或稳定的氧化锆; 包括氧化铝，二氧化硅，氧化锆或稳定的氧化锆的多孔分离层和包含可与流体流接触以优先输送二氧化碳的陶瓷氧化物的功能层。特别地，功能层可以是MgO，CaO，SrO，BaO，La 2 O 3，CeO 2，ATiO 3 AZrO 3，AA 1，2 O 4，A 1，Fe 3，3， A 1，...，N 2，A 1，...，...，...，...，... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... NiO 3，3O 3，3O 3，3％，3％，3％，3％，3％ SUB 2 2 ZrO 3 3，Li 2 SiO 3 3，Li 2 TiO 3 或其混合物; 其中A为Mg，Ca，Sr或Ba; A 1是La，Ca，Sr或Ba; A 是Ca，Sr或Ba; 和A 3是Sr或Ba。

26. 发明申请

US20110030384A1 Syngas cleanup section with carbon capture and hydrogen-selective membrane 有权
标题翻译：具有碳捕获和氢选择性膜的合成气净化部分
公开(公告)号：US20110030384A1
公开(公告)日：2011-02-10
申请号：US12538327
申请日：2009-08-10
申请人： Anthony Yu-Chung Ku , Harish Radhakrishna Acharya , Parag Prakash Kulkarni , Scott Michael Miller , William Cook Livingood, III
发明人： Anthony Yu-Chung Ku , Harish Radhakrishna Acharya , Parag Prakash Kulkarni , Scott Michael Miller , William Cook Livingood, III
IPC分类号： F02C6/18 , C01B3/12 , B01J8/00
CPC分类号： C01B3/32 , C01B3/50 , C01B3/501 , C01B3/52 , C01B2203/0283 , C01B2203/0288 , C01B2203/0405 , C01B2203/044 , C01B2203/045 , C01B2203/0455 , C01B2203/047 , C01B2203/0475 , C01B2203/0485 , C01B2203/0495 , C01B2203/06 , C01B2203/145 , C01B2203/146 , C01B2203/84 , Y02E20/16 , Y02E20/18 , Y02P30/30
摘要： A syngas cleanup section includes a water-gas shift reactor, a first operation unit and a second operation unit. The first operation unit includes a high permeance membrane with H2/CO2 selectivity in flow communication with the water-gas shift reactor to provide a H2-rich permeate stream and an H2-poor retentate stream. The second operation unit recovers H2 and CO from the retentate stream to produce a single, CO2-rich product stream, the entire content of which has a minimum pressure of at least about 10.0 bar. In one embodiment, the second operation unit includes a membrane with Knudsen selectivity for permeating H2, CO and CO2. In this embodiment, the permeate streams are combined to produce a H2 and CO-rich fuel stream used by a combined cycle power generation unit to produce electricity, and the retentate stream is sent to a catalytic oxidation unit to produce the CO2-rich product stream. In another embodiment, the second operation unit is the catalytic oxidation unit.
摘要翻译：合成气净化部分包括水煤气变换反应堆，第一操作单元和第二操作单元。第一操作单元包括具有与水煤气变换反应器流动连通的H 2 / CO 2选择性的高渗透膜，以提供富H2的渗透物流和不良的滞留物流。第二操作单元从滞留物流中回收H 2和CO以产生单一的富含CO 2的产物流，其全部内容物具有至少约10.0巴的最小压力。在一个实施方案中，第二操作单元包括具有用于渗透H 2，CO和CO 2的Knudsen选择性的膜。在该实施方案中，将渗透物流组合以产生由联合循环发电单元使用的H 2和CO富燃料流以产生电力，并将滞留物流送至催化氧化装置以产生富含CO 2的产物流。在另一个实施方案中，第二操作单元是催化氧化单元。

27. 发明授权

US07488671B2 Nanostructure arrays and methods of making same 失效
标题翻译：纳米结构阵列及其制备方法
公开(公告)号：US07488671B2
公开(公告)日：2009-02-10
申请号：US11441581
申请日：2006-05-26
申请人： Reed Roeder Corderman , Anthony Yu-Chung Ku
发明人： Reed Roeder Corderman , Anthony Yu-Chung Ku
IPC分类号： H01L21/20 , H01L21/36
CPC分类号： H01L51/0012 , B82Y10/00 , H01L51/0048 , Y10S977/70 , Y10T428/24998 , Y10T428/249994
摘要： A method of making a nanostructure array including disposing a masking material on a nanoporous template such that a first number of the plurality of nanopores are fully coated while a second number of the plurality of nanopores are not-fully coated by the masking material is provided. The method includes forming the nanostructures within the plurality of nanopores that are not-fully coated by the masking material. A nanostructure array fabricated in accordance to above said method and devices based on the nanostructure array is also provided.
摘要翻译：提供一种制备纳米结构阵列的方法，包括在纳米多孔模板上设置掩模材料，使得第一数量的多个纳米孔被完全涂覆，同时第二数量的多个纳米孔未被掩模材料完全涂覆。该方法包括在被掩模材料未完全涂覆的多个纳米孔内形成纳米结构。还提供了根据上述方法制造的纳米结构阵列和基于纳米结构阵列的器件。

28. 发明授权

US08661830B2 Hybrid multichannel porous structure for hydrogen separation 有权
标题翻译：用于氢气分离的混合多通道多孔结构
公开(公告)号：US08661830B2
公开(公告)日：2014-03-04
申请号：US12610407
申请日：2009-11-02
申请人： Anthony Yu-Chung Ku , Kevin Paul McEvoy , Patrick Daniel Willson , Parag Parkash Kulkarni , Roger Allen Shisler , Anoop Muralidhara Kurup
发明人： Anthony Yu-Chung Ku , Kevin Paul McEvoy , Patrick Daniel Willson , Parag Parkash Kulkarni , Roger Allen Shisler , Anoop Muralidhara Kurup
IPC分类号： F02C1/00
CPC分类号： B01D63/066 , B01D53/22 , B01D53/228 , B01D69/12 , B01D71/022 , B01D2313/42 , C01B3/12 , C01B3/503 , C01B3/505 , C01B2203/0288 , C01B2203/0405 , C01B2203/0475 , C01B2203/0485 , C01B2203/84
摘要： A hybrid multichannel porous structure for processing between two fluid streams of different compositions includes a housing and one or more structures disposed within the cavity of the housing in a shell and tube configuration. Each structure includes a body made of a porous, inorganic material and a plurality of channels for processing an optional sweep stream. Each channel is coated with a membrane layer. A feed stream introduced into the housing is in direct contact with the structures such that a gas selectively permeates through the body and into the channels. The gas combines with the sweep stream to form a permeate that exits from each channel. The remaining feed stream forms a retentate that exits from the housing. The feed stream may consist of syngas containing hydrogen gas and the sweep stream may contain nitrogen gas. A power plant that incorporates the hybrid structure is disclosed.
摘要翻译：用于在不同组成的两个流体流之间加工的混合多通道多孔结构包括壳体和一个或多个结构，其以外壳和管结构设置在壳体的空腔内。每个结构包括由多孔无机材料制成的主体和用于处理可选的扫流的多个通道。每个通道涂有膜层。引入到壳体中的进料流与结构直接接触，使得气体选择性渗透通过主体并进入通道。气体与扫气流结合形成从每个通道排出的渗透物。剩余的进料流形成从壳体离开的滞留物。进料流可以由含氢气的合成气组成，并且吹扫流可以含有氮气。公开了并入混合结构的电厂。

29. 发明申请

US20120315496A1 METHOD OF FORMING AN OXIDE COATING THAT REDUCES ACCUMULATION OF RADIOACTIVE SPECIES ON A METALLIC SURFACE 审中-公开
标题翻译：形成氧化物涂层的方法，减少金属表面上的放射性物质的累积
公开(公告)号：US20120315496A1
公开(公告)日：2012-12-13
申请号：US13154702
申请日：2011-06-07
申请人： Young Jin Kim , Anthony Yu-Chung Ku , Rebecca Christine Malish , Thomas Alfred Caine , Lauraine Denault , Anthony Thomas Barbuto , Catherine Procik Dulka , Patrick Daniel Willson , Peter Louis Andresen
发明人： Young Jin Kim , Anthony Yu-Chung Ku , Rebecca Christine Malish , Thomas Alfred Caine , Lauraine Denault , Anthony Thomas Barbuto , Catherine Procik Dulka , Patrick Daniel Willson , Peter Louis Andresen
IPC分类号： B05D3/02 , B32B15/04 , B82Y30/00
CPC分类号： C23C18/1216 , B82Y30/00 , C23C18/1241 , C23C18/125 , C23C18/127 , C23C18/1283 , G21F9/001
摘要： A method of forming an oxide coating for reducing the accumulation of radioactive species on a metallic surface exposed to fluids containing charged particles is disclosed. The method includes preparing an aqueous colloidal suspension containing about 0.5 to about 35 weight percent of nanoparticles that contain at least one of titania and zirconia, and about 0.1% to about 10% 2-[2-(2-methoxyethoxy)ethoxy]acetic acid (C7H14O5) or polyfluorosufonic acid in water, depositing the aqueous colloidal suspension on the metallic surface, drying the aqueous colloidal suspension to form a green coating, and then heating the green coating to a temperature of up to 500° C. to densify the green coating to form an oxide coating having a zeta potential less than or equal to the electrical polarity of the charged particles so as to minimize deposition of the charged particles on the metallic surface. The nanoparticles have a diameter of up to about 200 nanometers.
摘要翻译：公开了一种形成用于减少放射性物质在暴露于含有带电粒子的流体的金属表面上的积聚的氧化物涂层的方法。该方法包括制备含有约0.5至约35重量％的含有二氧化钛和氧化锆中的至少一种的纳米颗粒和约0.1％至约10％的2- [2-（2-甲氧基乙氧基）乙氧基]乙酸的水性胶体悬浮液（C7H14O5）或多氟代磺酸在水中，将水性胶体悬浮液沉积在金属表面上，干燥水性胶体悬浮液以形成绿色涂层，然后将绿色涂层加热至高达500℃的温度，以使绿色涂覆以形成具有小于或等于带电粒子的电极性的ζ电位的氧化物涂层，以便最小化带电粒子在金属表面上的沉积。纳米颗粒的直径可达200纳米。

30. 发明申请

US20120135215A1 ZEOLITE MEMBRANE AND METHODS OF MAKING THE SAME 失效
标题翻译：沸石膜及其制备方法
公开(公告)号：US20120135215A1
公开(公告)日：2012-05-31
申请号：US12957151
申请日：2010-11-30
申请人： Kevin Paul McEvoy , Hrishikesh Keshavan , Anthony Yu-Chung Ku , Steven Mitchell Kuznicki , Weizhu An , Lan Wu , Paul Donald Swenson
发明人： Kevin Paul McEvoy , Hrishikesh Keshavan , Anthony Yu-Chung Ku , Steven Mitchell Kuznicki , Weizhu An , Lan Wu , Paul Donald Swenson
IPC分类号： C04B35/10 , B32B5/00 , C04B35/64
CPC分类号： C04B35/6303 , B01D67/0041 , B01D71/028 , B01D2323/08 , C04B35/117 , C04B35/19 , C04B35/195 , C04B35/6263 , C04B35/63416 , C04B2235/3217 , C04B2235/3218 , C04B2235/322 , C04B2235/3463 , C04B2235/5427 , C04B2235/5436 , C04B2235/5445
摘要： A free-standing zeolite membrane and a zeolite membrane supported on a support structure are disclosed. The free-standing zeolite membrane is fabricated by mixing zeolite particles and an optional inorganic binder, forming a green body, and sintering the green body at a sufficiently low temperature so as to prevent damage to the gas selectivity properties of the zeolite particles. The supported composite zeolite membrane is fabricated by mixing a sacrificial binder, an optional inorganic binder, boehmite sol and zeolite particles to form a slurry. The slurry is then coated onto a porous support structure, dried and sintered at a sufficiently low temperature so as to prevent damage to the gas selective properties of the zeolite particles. In both membranes, the zeolite particles span the entire thickness of the membrane to provide a high selectivity path for the flow of gas to pass therethrough.
摘要翻译：公开了一种独立的沸石膜和支撑在支撑结构上的沸石膜。独立沸石膜通过混合沸石颗粒和任选的无机粘合剂，形成生坯，并在足够低的温度下烧结生坯，以防止破坏沸石颗粒的气体选择性而制备。负载的复合沸石膜通过混合牺牲粘合剂，任选的无机粘合剂，勃姆石溶胶和沸石颗粒以形成浆料来制备。然后将浆料涂覆到多孔载体结构上，在足够低的温度下干燥和烧结，以防止损害沸石颗粒的气体选择性能。在两个膜中，沸石颗粒跨越膜的整个厚度，以提供气体流过其中的高选择性路径。

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