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    • 23. 发明授权
    • Liquid detergent with copolymer additive
    • 液体洗涤剂与共聚添加剂
    • US5009805A
    • 1991-04-23
    • US424084
    • 1989-10-19
    • Johannes PernerPaul DiesselHeinrich HartmannWalter DenzingerAlfred OftringWillibald Schoenleben
    • Johannes PernerPaul DiesselHeinrich HartmannWalter DenzingerAlfred OftringWillibald Schoenleben
    • C11D3/32C11D3/37
    • C11D3/3773
    • Liquid detergent formulations contain as essential constituents a surfactant and 0.1-20% by weight of a copolymer which contains(a) 50-99 mol % of units of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, a half ester of a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, an ester of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a C.sub.2 -C.sub.30 -olefin, styrene, a C.sub.1 -C.sub.3 -alkylstyrene, a C.sub.1 -C.sub.28 -alkyl vinyl ether, a vinyl ester of a saturated C.sub.1 -C.sub.8 -monocarboxylic acid or a mixture thereof and(b) 50-1 mol % of units of an amide of a monoethylenically unsaturated C.sub.3 -C.sub.8 -carboxylic acid where the amide groups have the structure ##STR1## where R.sup.1 is C.sub.8 -C.sub.28 -alkyl or preferably ##STR2## R.sup.3 and R.sup.4 are each H, CH.sub.3 or C.sub.2 H.sub.5, R is C.sub.1 -C.sub.28 -alkyl,n is from 2 to 100 andR.sup.2 is H or R.sup.1,and has a K value of from 8 to 200, or a salt thereof.
    • 液体洗涤剂配方含有表面活性剂和0.1-20重量%的共聚物,其含有(a)50-99摩尔%的单烯属不饱和C3-C8-单羧酸单元,单烯属不饱和C4-C8-二羧酸 酸,单烯键式不饱和C4-C8-二羧酸的半酯,单烯属不饱和C3-C8-一元羧酸的酯,C2-C30-烯烃,苯乙烯,C1-C3-烷基苯乙烯,C1-C28- 烷基乙烯基醚,饱和C1-C8-一元羧酸的乙烯基酯或其混合物,和(b)50-1摩尔%的单烯属不饱和C 3 -C 8 - 羧酸的酰胺单元,其中酰胺基具有 其中R 1为C 8 -C 28 - 烷基或优选R 3和R 4各自为H,CH 3或C 2 H 5,R为C 1 -C 28 - 烷基,n为2至100,R 2为H或R 1,并且 的K值为8〜200,或其盐。
    • 24. 发明授权
    • Use of heterocyclic compounds as bleach activators or optical
brighteners in washing and cleaning agents
    • 在洗涤剂和清洁剂中使用杂环化合物作为漂白活化剂或荧光增白剂
    • US5286401A
    • 1994-02-15
    • US836279
    • 1992-03-03
    • Bernhard DungWolfgang TrieseltErwin HahnJohannes PernerAlfred Oftring
    • Bernhard DungWolfgang TrieseltErwin HahnJohannes PernerAlfred Oftring
    • C11D3/28C07D265/22C11D3/39C11D3/42C11D3/395D06L3/02D06L3/12
    • C07D265/22C11D3/392C11D3/42
    • Heterocyclic compounds which are useful as bleach activators or optical brighteners in washing and cleaning agents have the formula ##STR1## where the variables have the following meanings: X is O, S or the group N--R.sup.3, where R.sup.3 is hydrogen, C.sub.1 -C.sub.25 -alkyll C.sub.1 -C.sub.25 -acyl or an aryl group of up to12 carbon atoms,Y is CH or N,R.sup.1 for X=S or N--R.sup.3 is hydrogen, a C.sub.1 -C.sub.25 -alkyl or C.sub.2 -C.sub.25 -alkenyl group or a phenyl radical which may be additionally substituted by one or two C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, hydroxyl, carboxyl, sulfo, amino, C.sub.1 -C.sub.4 -acylamino, nitro or cyano groups or chlorine or bromine atoms, which substituents, if there are two of them, may be identical or different,R.sup.1 for X=O is phenyl, o-, m- or p-tolyl, p-chlorophenyl, m-nitrophenyl, m-methoxyphenyl or m-methylsulfonylphenyl,R.sup.2 for X=S or N--R.sup.3 is hydrogen, a C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, hydroxyl, carboxyl, sulfo, amino or C.sub.1 -C.sub.4 -acylamino group or a chlorine or bromine atom, andR.sup.2 for X=O is hydrogen.
    • 式(I)的杂环化合物,其中X代表O,S或NR 3基团,其中R 3代表氢,C 1 -C 25烷基,C 1 -C 25酰基或芳基,最多12个 碳原子,Y代表CH或N,R 1代表X = S或NR 3,氢,C 1 -C 25烷基或C 2 -C 25烯基或苯基残基,其可以另外被一个或多个 两个C 1 -C 4烷基,C 1 -C 4烷氧基,羟基,羧基,磺基,氨基,C 1 -C 4酰基氨基,硝基或氰基或氯或溴原子,其中两个取代基可以相同或不同,R 1, 代表X = O,苯基,邻 - ,对 - 或对甲苯基,对氯苯基,间硝基苯基,间甲氧基苯基或间甲基磺酰基苯基,R 2代表X = S或NR 3,氢 ,C 1 -C 4烷基,C 1 -C 4烷氧基,羟基,羧基,磺基,氨基或C 1 -C 4酰氨基或氯或溴原子,R 2代表X = O或氢,可用作漂白活化剂 或洗涤剂和清洁剂中的光学增亮剂。