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21. 发明授权

US07597964B2 Thermally tempered coated article with transparent conductive oxide (TCO) coating 失效
标题翻译：具有透明导电氧化物（TCO）涂层的热回火涂层制品
公开(公告)号：US07597964B2
公开(公告)日：2009-10-06
申请号：US11194730
申请日：2005-08-02
申请人： Alexey Krasnov
发明人： Alexey Krasnov
IPC分类号： B32B17/06
CPC分类号： C23C14/086 , C03C17/2453 , C03C23/007 , C03C2217/211 , C03C2217/228 , C03C2217/23 , C03C2218/154 , C03C2218/32 , C23C14/5806
摘要： A method of making a coated article including a transparent conductive oxide (TCO) film supported by a tempered glass substrate is provided. Initially, an amorphous metal oxide film is sputter-deposited onto a non-tempered glass substrate, either directly or indirectly. The glass substrate with the amorphous film thereon is then thermally tempered using high temperatures. The thermal tempering causes the amorphous film to be transformed into a crystalline transparent conductive oxide (TCO) film. The heat used in the thermal tempering of the glass substrate causes the amorphous film to turn into a crystalline film, causes the visible transmission of the film to increase, and/or causes the film to become electrically conductive.
摘要翻译：提供一种制造包括由钢化玻璃基板支撑的透明导电氧化物（TCO））膜的涂覆制品的方法。最初，将非晶金属氧化物膜直接或间接地溅射沉积到非强化玻璃基板上。然后将其上具有非晶膜的玻璃基板用高温进行热回火。热回火使得非晶膜转变成晶体透明导电氧化物（TCO）膜。在玻璃基板的热回火中使用的热量导致非晶膜变成结晶膜，导致膜的可见透射增加和/或导致膜变得导电。

22. 发明申请

US20090194155A1 Front electrode having etched surface for use in photovoltaic device and method of making same 审中-公开
标题翻译：具有用于光伏器件的蚀刻表面的前电极及其制造方法
公开(公告)号：US20090194155A1
公开(公告)日：2009-08-06
申请号：US12068119
申请日：2008-02-01
申请人： Willem den Boer , Alexey Krasnov , John A. Vanderploeg
发明人： Willem den Boer , Alexey Krasnov , John A. Vanderploeg
IPC分类号： H01L31/00 , C23C14/34
CPC分类号： H01L31/022466 , H01L31/0236 , H01L31/1884 , Y02E10/50
摘要： Certain example embodiments of this invention relate to a photovoltaic (PV) device including an electrode such as a front electrode/contact, and a method of making the same. In certain example embodiments, the front electrode has a textured (e.g., etched) surface that faces the photovoltaic semiconductor film of the PV device. In certain example embodiments, the front electrode is formed on a flat or substantially flat (non-textured) surface of a glass substrate (e.g., via sputtering), and the surface of the front electrode is textured (e.g., via etching). In completing manufacture of the PV device, the etched surface of the front electrode faces the active semiconductor film of the PV device.
摘要翻译：本发明的某些示例性实施例涉及包括诸如前电极/触点的电极的光伏（PV）装置及其制造方法。在某些示例性实施例中，前电极具有面向PV器件的光电半导体膜的有纹理（例如蚀刻）的表面。在某些示例性实施例中，前电极形成在玻璃基板（例如，通过溅射）的平坦或基本上平坦的（非纹理的）表面上，并且前电极的表面是有纹理的（例如通过蚀刻）。在完成PV器件的制造中，前电极的蚀刻表面面对PV器件的有源半导体膜。

23. 发明申请

US20080308146A1 Front electrode including pyrolytic transparent conductive coating on textured glass substrate for use in photovoltaic device and method of making same 审中-公开
标题翻译：前电极包括用于光伏器件的纹理化玻璃基板上的热解透明导电涂层及其制造方法
公开(公告)号：US20080308146A1
公开(公告)日：2008-12-18
申请号：US11812078
申请日：2007-06-14
申请人： Alexey Krasnov , Scott V. Thomsen
发明人： Alexey Krasnov , Scott V. Thomsen
IPC分类号： H01L31/0236 , B29D11/00 , H01L31/0216 , H01L31/0224
CPC分类号： H01L31/18 , H01L31/02366 , Y02E10/50
摘要： A photovoltaic device includes a front electrode on a textured front glass substrate. In certain example embodiments, the glass substrate is textured via roller(s) and/or etching to form a textured surface. Thereafter, a front electrode is formed on the textured surface of the glass substrate via pyrolysis. The front electrode may be of or include a transparent conductive oxide (TCO) such as tin oxide and/or fluorinated tin oxide in certain example embodiments. In certain example instances, this is advantageous in that efficiency of the photovoltaic device can be improved by increasing light absorption by the active semiconductor via both increasing light intensity passing through the front glass substrate and front electrode, and increasing the light path in the semiconductor photovoltaic conversion layer.
摘要翻译：光电器件包括在纹理化的前玻璃基板上的前电极。在某些示例性实施例中，玻璃基板通过辊纹理和/或蚀刻以形成纹理表面。此后，通过热解在玻璃基板的纹理化表面上形成前电极。在某些示例性实施方案中，前电极可以是或包括透明导电氧化物（TCO），例如氧化锡和/或氟化氧化锡。在某些示例中，这是有利的，因为可以通过增加通过前玻璃基板和前电极的光强度增加有源半导体的光吸收来增加光电器件的效率，并且增加半导体光伏转换层。

24. 发明申请

US20080182032A1 Method of making heat treated coated article using diamond-like carbon (DLC) coating and protective film 失效
标题翻译：使用类金刚石碳（DLC）涂层和保护膜制造热处理涂层制品的方法
公开(公告)号：US20080182032A1
公开(公告)日：2008-07-31
申请号：US11806674
申请日：2007-06-01
申请人： Alexey Krasnov , Rudolph Hugo Petrmichl , Jiangping Wang , Nestor P. Murphy , Maximo Frati , Jose Nunez-Regueiro
发明人： Alexey Krasnov , Rudolph Hugo Petrmichl , Jiangping Wang , Nestor P. Murphy , Maximo Frati , Jose Nunez-Regueiro
IPC分类号： C23C14/00 , B05D3/02
CPC分类号： C03C17/3441 , C03C23/007 , C03C2217/78 , C03C2218/322 , C03C2218/328 , C03C2218/355
摘要： There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. The method may include heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) or other type of carbon, with a protective film thereon. In certain example embodiments, the protective film may be of or include a layer of or including SnOx prior to HT. Optionally, a release layer of a material such as zinc oxide may be provided between the SnOx and the DLC. Following and/or during heat treatment the SnOx transforms into SnOy (y>x) so that stress is created due to the SnOx to SnOy transition. Then, during quenching, stress relief may occur which causes the layer to buckle, creating cracks which may act as liquid channels that permit the sacrificial film to be easily removed via washing or the like.
摘要翻译：提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。该方法可以包括用至少一层或类金刚石碳（DLC）或其他类型的碳涂覆的玻璃基板与其上的保护膜进行热处理。在某些示例性实施方案中，保护膜可以是或包含HT之前的或包括SnO x的层。任选地，可以在SnO x和DLC之间提供诸如氧化锌的材料的剥离层。在热处理之后和/或在热处理期间，SnO x x x转换成SnO y（y> x），使得由于SnO x x（x）到SnO y y转换。然后，在淬火期间，可能发生应力消除，这导致该层弯曲，产生可能作为允许通过洗涤等容易地除去牺牲膜的液体通道的裂纹。

25. 发明申请

US20080105299A1 Front electrode with thin metal film layer and high work-function buffer layer for use in photovoltaic device and method of making same 审中-公开
标题翻译：具有薄金属膜层的前电极和用于光伏器件的高功函数缓冲层及其制造方法
公开(公告)号：US20080105299A1
公开(公告)日：2008-05-08
申请号：US11591676
申请日：2006-11-02
申请人： Alexey Krasnov
发明人： Alexey Krasnov
IPC分类号： H01L31/0224 , H01L31/04
CPC分类号： H01L31/022425 , H01L31/022466 , Y02E10/50
摘要： This invention relates to a front electrode or contact for use in an electronic device such as a photovoltaic device. In certain example embodiments, the front electrode of the photovoltaic device includes a highly conductive metal film and a thin high work-function buffer layer. The high-work function buffer layer is located between the metal film and the uppermost semiconductor layer so as to provide for substantial work-function matching between the metal film and the high work-function uppermost semiconductor layer so as to reduce a potential barrier for holes extracted from the device by the front electrode/contact. Optionally, a layer such as a transparent conductive oxide (TCO) or a dielectric may be provided between a front glass substrate and the metal film.
摘要翻译：本发明涉及一种用于诸如光伏器件的电子设备中的前电极或触头。在某些示例性实施例中，光伏器件的前电极包括高导电金属膜和薄的高功函数缓冲层。高功函数缓冲层位于金属膜和最上半导体层之间，以便在金属膜和高功函数最上半导体层之间提供基本的功函数匹配，以减少孔的势垒通过前电极/触点从设备中提取。可选地，可以在前玻璃基板和金属膜之间设置诸如透明导电氧化物（TCO）或电介质的层。

26. 发明申请

US20070275252A1 Method of making thermally tempered coated article with transparent conductive oxide (TCO) coating in color compression configuration, and product made using same 失效
标题翻译：以彩色压缩构造制造透明导电氧化物（TCO）涂层的热回火涂层制品的方法，以及使用其制造的产品
公开(公告)号：US20070275252A1
公开(公告)日：2007-11-29
申请号：US11438704
申请日：2006-05-23
申请人： Alexey Krasnov
发明人： Alexey Krasnov
IPC分类号： B32B17/06 , B32B15/00 , C23C14/00
CPC分类号： C03C17/3417 , C03C17/002 , C03C17/3423
摘要： Example embodiments of this invention relate to a method of making a thermally tempered coated article including a transparent conductive oxide (TCO) film in a color compression configuration supported by a tempered glass substrate. A coated article, that is thermally tempered and made by such a process, is also provided. Coated articles according to certain example non-limiting embodiments of this invention may be used in applications such as solar cells, oven doors, electrostatic discharge glass, solar control windows, defrosting windows, or other types of windows in certain example instances.
摘要翻译：本发明的实施例涉及一种制造热回火涂层制品的方法，该制品包括由钢化玻璃基板支撑的彩色压缩构型的透明导电氧化物（TCO）膜。还提供了通过这种方法进行热回火并制成的涂覆制品。根据本发明的非限制性实施例的涂覆制品可用于某些示例性实例中的太阳能电池，烤箱门，静电放电玻璃，太阳能控制窗，除霜窗或其它类型的窗户。

27. 发明申请

US20070031682A1 Method of making thermally tempered coated article with transparent conductive oxide (TCO) coating and product made using same 失效
公开(公告)号：US20070031682A1
公开(公告)日：2007-02-08
申请号：US11194730
申请日：2005-08-02
申请人： Alexey Krasnov
发明人： Alexey Krasnov
IPC分类号： C23C14/00 , B32B17/06
CPC分类号： C23C14/086 , C03C17/2453 , C03C23/007 , C03C2217/211 , C03C2217/228 , C03C2217/23 , C03C2218/154 , C03C2218/32 , C23C14/5806
摘要： A method of making a coated article including a transparent conductive oxide (TCO) film supported by a tempered glass substrate is provided. Initially, an amorphous metal oxide film is sputter-deposited onto a non-tempered glass substrate, either directly or indirectly. The glass substrate with the amorphous film thereon is then thermally tempered using high temperatures. The thermal tempering causes the amorphous film to be transformed into a crystalline transparent conductive oxide (TCO) film. The heat used in the thermal tempering of the glass substrate causes the amorphous film to turn into a crystalline film, causes the visible transmission of the film to increase, and/or causes the film to become electrically conductive.

28. 发明授权

US06784602B2 Organic electroluminescent device 失效
标题翻译：有机电致发光器件
公开(公告)号：US06784602B2
公开(公告)日：2004-08-31
申请号：US09983569
申请日：2001-10-25
申请人： Peter G. Hofstra , Alexey Krasnov
发明人： Peter G. Hofstra , Alexey Krasnov
IPC分类号： H05B3322
CPC分类号： H01L51/5281 , H01L51/5203 , Y10S428/917
摘要： The present invention provides a novel organic electroluminescent device having an optical interference member which reduces the overall reflectance from the device. The invention is particularly suited to current-driven organic displays having an anode, an electroluminescent layer and a cathode, where at least one optical interference member is placed between two of the layers and thus forms part of the electrical circuit required to excite the display. The optical interference member is chosen to have a thickness which causes at least some destructive optical interference of ambient light incident on the display. In addition, the material(s) of the optical interference member are chosen to have a work function which is compatible with the highest occupied molecular orbital, or the lowest unoccupied molecular orbital of the electroluminescent layer, depending on the location of the optical interference member in relation to the anode, cathode and electroluminescent layer.
摘要翻译：本发明提供了一种具有光学干涉构件的新型有机电致发光器件，其降低了来自器件的总体反射率。本发明特别适用于具有阳极，电致发光层和阴极的电流驱动的有机显示器，其中至少一个光学干涉构件位于两个层之间，从而形成激发显示器所需的电路的一部分。光学干涉构件被选择为具有导致入射在显示器上的环境光的至少一些破坏性光学干涉的厚度。此外，根据光学干涉构件的位置，光学干涉构件的材料被选择为具有与最高占据分子轨道或电致发光层的最低未占分子轨道相适应的功函数相对于阳极，阴极和电致发光层。

29. 发明授权

US09423533B2 Patterned glass cylindrical lens arrays for concentrated photovoltaic systems, and/or methods of making the same 有权
公开(公告)号：US09423533B2
公开(公告)日：2016-08-23
申请号：US12662624
申请日：2010-04-26
申请人： Alexey Krasnov , Willem den Boer
发明人： Alexey Krasnov , Willem den Boer
IPC分类号： G01C21/02 , G02B3/00 , C03B18/14 , H01L31/052 , H01L31/054 , F24J2/08
CPC分类号： G02B3/0062 , C03B18/14 , F24S23/31 , G02B3/005 , G02B3/0056 , H01L31/0521 , H01L31/0543 , H01L31/0547 , Y02B10/20 , Y02E10/52
摘要： Certain example embodiments of this invention relate to patterned glass that can be used as a cylindrical lens array in a concentrated photovoltaic application, and/or methods of making the same. In certain example embodiments, the lens arrays may be used in combination with strip solar cells and/or single-axis tracking systems. That is, in certain example embodiments, lenses in the lens array may be arranged so as to concentrate incident light onto respective strip solar cells, and the entire assembly may be connected to a single-axis tracking system that is programmed to follow the East-West movement of the sun. A low-iron glass may be used in connection with certain example embodiments. Such techniques may advantageously help to reduce cost per watt related, in part, to the potentially reduced amount of semiconductor material to be used for such example embodiments.

30. 发明授权

US09202958B2 Photovoltaic systems and associated components that are used on buildings and/or associated methods 有权
标题翻译：用于建筑物和/或相关方法的光伏系统和相关组件
公开(公告)号：US09202958B2
公开(公告)日：2015-12-01
申请号：US13288520
申请日：2011-11-03
申请人： Alexey Krasnov
发明人： Alexey Krasnov
IPC分类号： H01L31/048 , H01L31/054 , H02S20/26
CPC分类号： H01L31/0543 , H02S20/26 , Y02A30/62 , Y02B10/12 , Y02E10/52 , Y10T29/49355
摘要： Certain example embodiments relate to building integrated photovoltaic (BIPV) or building adapted photovoltaic (BAPV) systems and components thereof. In certain example embodiments a component includes an asymmetric glass substrate that includes at least first, second, and third surfaces. The third surface can be laminated to a photovoltaic sub-assembly. The first surface can structured to be angled away from a vertical plane of a building at an angle of between 5 and 40 degrees. The first surface may be longer than the second surface.
摘要翻译：某些示例性实施例涉及构建集成光伏（BIPV）或建筑物适应的光伏（BAPV）系统及其组件。在某些示例性实施例中，部件包括至少包括第一，第二和第三表面的不对称玻璃基板。第三表面可以层压到光伏子组件上。第一表面可以构造成以5至40度的角度远离建筑物的垂直平面倾斜。第一表面可以比第二表面长。

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