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21. 发明授权

US4980355A Compositions for protecting plants against disease 失效
公开(公告)号：US4980355A
公开(公告)日：1990-12-25
申请号：US319017
申请日：1989-03-03
申请人： Helmut Zondler , Alfred Meyer , Wolfgang Eckhardt , Walter Kunz
发明人： Helmut Zondler , Alfred Meyer , Wolfgang Eckhardt , Walter Kunz
IPC分类号： A01N43/40 , A01N43/50 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/653 , C07D213/81 , C07D401/06 , C07D401/12 , C07D401/14 , C07D413/14
CPC分类号： C07D213/81 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/653 , C07D401/06 , C07D401/12 , C07D401/14
摘要： Novel substituted isonicotinic acid amides of the general formula ##STR1## in which X in ortho/ortho'-position are equal and represent fluorine, chlorine, bromine or iodine;Q.sub.1 is unsubstituted pyridimin-4-yl, or pyrimidin-4-yl substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.2 is unsubstituted pyrimidin-2-yl, or pyrimidin-2-yl substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.3 is unsubstituted pyrimidin-5-yl, or pyrimidin-5-yl substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.4 is pyridin-2-yl, pyridin-3-yl or pyridin-4-yl each of which is unsubstituted or substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.5 is pyridazin-3-yl or pyridazin-4-yl each of which is unsubstituted or substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.6 is unsubstituted pyrazin-2-yl, or pyrazin-2-yl substituted by R.sub.1, R.sub.2 and R.sub.3 ;R.sub.1, R.sub.2, R.sub.3 are hydrogen, halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl having from 1 to 3 halogen atoms, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.6 alkoxyalkyl, C.sub.1 -C.sub.6 thioalkyl, C.sub.1 -C.sub.6 haloalkoxy having from 1 to 5 halogen atoms, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 alkynyloxy, C.sub.3 -C.sub.6 thioalkenyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.3 -C.sub.6 cycloalkyl substituted by methyl, or nitro, cyano, the radical CH(OR.sub.4).sub.2 or COOR.sub.4 in which R.sub.4 is C.sub.1 -C.sub.4 alkyl; also phenyl, phenoxy, thiophenyl, benzyl, benzyloxy or thiobenzyl; or phenyl, phenoxy, thiophenyl, benzyl, benzyloxy or thiobenzyl each substituted at least once by C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 -alkoxy, C.sub.1 -C.sub.3 haloalkyl having from 1 to 3 halogen atoms, halogen, nitro or by cyano; and also N(R.sub.5)R.sub.6 in which R.sub.5 and R.sub.6, independently of one another, are each C.sub.1 -C.sub.6 alkyl; and furthermore piperidinyl, pyrrolidinyl, morpholinyl, imidazolyl or triazolyl, or piperidinyl, pyrrolidinyl, morpholinyl, imidazolyl or triazolyl each substituted by C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkyl having from 1 to 3 halogen atoms, halogen, nitro or by cyano.The novel active ingredients have plant-protecting properties and are suitable especially for the preventive protection of plants against attack by phytopathogenic microorganisms such as fungi, bacteria and viruses.

22. 发明授权

US4968344A Method for protecting plants against diseases 失效
标题翻译：保护植物免受疾病的方法
公开(公告)号：US4968344A
公开(公告)日：1990-11-06
申请号：US429884
申请日：1989-10-31
申请人： Walter Kunz , Theodor Staub , Jean-Pierre M e/ traux , Karl Hoegerle , Robert Nyfeler , Patricia A. Ahl Goy
发明人： Walter Kunz , Theodor Staub , Jean-Pierre M e/ traux , Karl Hoegerle , Robert Nyfeler , Patricia A. Ahl Goy
IPC分类号： A01N43/40 , C07D213/78 , C07D213/79 , C07D213/83 , C07D265/30 , C07D295/02
CPC分类号： C07D213/79 , A01N43/40 , C07D213/83
摘要： A process for immunizing healthy plants against plant diseases which process comprises the dressing and/or coating of seeds or the treatment of plants and/or their environment by using active ingredients of the formula ##STR1## in which Hal is halogen,X is oxygen or sulfur, andR is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkyl which interrupted by an oxygen or sulfur atom, C.sub.1 -C.sub.6 -alkyl which is substituted by halogen, cyano or the COO--C.sub.1 -C.sub.6 -alkyl radical, C.sub.3 -C.sub.5 -alkenyl which is unsubstituted or substituted by halogen, C.sub.3 -C.sub.5 -alkynyl which is unsubstituted or substituted by halogen, C.sub.3 -C.sub.6 -cycloalkyl which is unsubstituted or substituted by halogen or methyl, or a normal equivalent of a cation which is formed from a base or a basic compound.
摘要翻译：一种用于免疫健康植物以防止植物疾病的方法，该方法包括通过使用其中Hal为卤素的卤素为X的氧的活性成分，其中Hal为卤素，X为氧，或者为硫，R为氢，C1-C6烷基，被氧或硫原子间隔的C1-C6-烷基，被卤素，氰基或COO-C1-C6-烷基取代的C1-C6-烷基，未被取代或被卤素取代的C3-C5-烯基，未被取代或被卤素取代的C3-C5-炔基，未被取代或被卤素或甲基取代的C3-C5-炔基或阳离子的正常当量，由碱或碱性化合物形成。

23. 发明授权

US4963583A Beta-ionone derivatives as antifungal agents 失效
标题翻译： β-紫罗兰酮衍生物作为抗真菌剂
公开(公告)号：US4963583A
公开(公告)日：1990-10-16
申请号：US250201
申请日：1988-09-28
申请人： Walter Kunz
发明人： Walter Kunz
IPC分类号： A01N37/00 , A01N37/02 , A01N37/36 , A01N47/18 , A01N53/00 , C07C69/03 , C07C271/06 , C07C333/02
CPC分类号： C07C403/16 , C07B2200/07 , C07C2101/16
摘要： Novel 3-acyloxy-4-keto-.beta.-ionone derivatives of the formula I ##STR1## wherein Z is either the radical ##STR2## in which R.sub.1 represents C.sub.2 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy-C.sub.1 -C.sub.5 alkyl having a maximum number of 6 carbon atoms, cyclopropyl or cyclopropyl which is substituted by methyl or by halogen or represents the radical ##STR3## wherein R.sub.2 represents C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy-C.sub.1 -C.sub.5 alkyl having a maximum number of 6 carbon atoms, cyclopropyl or cyclopropyl which is substituted by methyl or by halogen and X represents either oxygen or sulphur, and ##STR4## display very effective microbicidal activity. They can especially be used in microbicidal compositions to control plant-pathogenic microorganisms, preferably fungi of the order Oomycetes.
摘要翻译：式I的新型3-酰氧基-4-酮-β-吩酮衍生物其中Z是其中R 1表示C 2 -C 5烷基，C 1 -C 5烷氧基-C 1 -C 5烷基的基团，具有最多6个碳原子的环丙基或环丙基，其被甲基或被卤素取代或代表基团，其中R 2表示C 1 -C 5烷基，C 1 -C 5烷氧基-C 1 -C 5烷基，最大数目为6 碳原子，被甲基或卤素取代的环丙基或环丙基，X表示氧或硫，并且（Ia）表示非常有效的杀微生物活性。它们可特别用于杀菌组合物中以控制植物病原微生物，优选卵菌纲的真菌。

24. 发明授权

US4931581A Process and a composition for immunizing plants against diseases 失效
标题翻译：用于免疫植物以防止疾病的方法和组合物
公开(公告)号：US4931581A
公开(公告)日：1990-06-05
申请号：US234241
申请日：1988-08-18
申请人： Rolf Schurter , Walter Kunz , Robert Nyfeler
发明人： Rolf Schurter , Walter Kunz , Robert Nyfeler
IPC分类号： C07D417/12 , A01N43/82 , A01N43/828 , C07D285/14 , C07D413/06 , C07D413/12 , C07D521/00 , C07F7/08 , C07F7/10 , C07F9/32 , C07F9/6515 , C07F9/6518 , C07F9/6539 , C07F9/6541 , C07H13/08 , C07H13/10 , C07H17/00 , C07H17/02
CPC分类号： C07D285/14 , A01N43/82 , C07D231/12 , C07D233/56 , C07D249/08 , C07D413/06 , C07D413/10 , C07D413/12 , C07F7/0812 , C07F9/6541 , C07H13/10
摘要： A method and composition for the immunization of healthy useful plants against plant diseases containing as active ingredients compounds of formula ##STR1## in which: X is hydrogen, halogen, hydroxy, methyl, methoxy, HOOC or MOOC;Y is hydrogen, halogen, SO.sub.3 H, SO.sub.3 M, nitro, hydroxy or amino, M being the molar equivalent of an alkali metal or alkaline earth metal ion that is formed from a corresponding base or basic compound; andZ is cyano or --CO--A;A represents either --OH or --SH, the hydrogen atom of which may also be replaced by the molar equivalent of an inorganic or organic cationic residue,or wherein A represents any other organic residue which has a molecular weight of less than 900 and which may also contain one, or more than one, hetero atom, including the salts of the phytophysiologically tolerable 7-carboxylic acid or 7-thiocarboxylic acid with primary, secondary or tertiary amines or with inorganic bases.
摘要翻译：含有作为活性成分的式（I）化合物的健康有益植物免疫植物病害的方法和组合物，其中：X是氢，卤素，羟基，甲基，甲氧基，HOOC或MOOC; Y是氢，卤素，SO 3 H，SO 3 M，硝基，羟基或氨基，M是由相应的碱或碱化合物形成的碱金属或碱土金属离子的摩尔当量; 和Z是氰基或-CO-A; A表示-OH或-SH，其氢原子也可被无机或有机阳离子残基的摩尔当量代替，或其中A表示分子量小于900的任何其它有机残基，还含有一个或多于一个杂原子，包括植物生理学上可耐受的7-羧酸或7-硫代羧酸与伯胺，仲胺或叔胺或与无机碱的盐。

25. 发明授权

US4894083A Herbicidal epoxides 失效
标题翻译：除草环氧化物
公开(公告)号：US4894083A
公开(公告)日：1990-01-16
申请号：US161812
申请日：1988-02-29
申请人： Hermann Rempfler , Walter Kunz
发明人： Hermann Rempfler , Walter Kunz
IPC分类号： A01N43/20 , C07D303/32
CPC分类号： A01N43/20 , C07D303/32
摘要： The invention relates to a herbicidal and plant growth regulating composition which contains as active ingredient a 2-benzoyl-2-phenyloxirane of formula I ##STR1## wherein each of m and n independently of the other is 0, 1, 2 or 3 and each of R and R' independently of the other is a halogen atom, a C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl or C.sub.1 -C.sub.4 haloalkoxy group or the nitro or cyano group or a phenoxy group which is substituted by (R).sub.m, in the form of a racemate or an optically active enantiomer.Some oxiranes are known as intermediates for the preparation of fungicides and others are novel. The herbicidal composition has selective action in rice crops and is active against grasses.

26. 发明授权

US4528284A Fungicidal 2-(azolylmethyl-1'-yl)-2-aryl-2-(cyano, alkoxycarbonyl, alkylthiocarbonyl and aminocarbonyl)-2-phosphorus acid esters 失效
标题翻译：杀真菌剂2-（吡唑基甲基-1'-基）-2-芳基-2-（氰基，烷氧基羰基，烷硫基羰基和氨基羰基）-2-磷酸酯
公开(公告)号：US4528284A
公开(公告)日：1985-07-09
申请号：US539217
申请日：1983-10-05
申请人： Wolfgang Eckhardt , Walter Kunz
发明人： Wolfgang Eckhardt , Walter Kunz
IPC分类号： A01N57/16 , A01N57/24 , A01N57/32 , C07D521/00 , C07F9/6506 , C07F9/6518 , C07F9/65
CPC分类号： C07D231/12 , A01N57/16 , A01N57/24 , C07D233/56 , C07D249/08 , C07F9/65061 , C07F9/65181
摘要： Phosphoric acid esters of the formula ##STR1## wherein X is CH or N,Ar is optionally substituted phenyl, diphenyl or naphthyl,R is cyano, carboxylic acid ester, carboxylic acid thioester or carboxylic acid amide.R.sub.10 is alkyl,R.sub.11 alkyl, alkoxy, alkylthio or phenyl, andY is sulfur.For R: the ester groups are alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl, alkyl interrupted by oxygen or sulfur and optionally substituted by halogen, phenyl, carboxylic acid ester, alkylcarbonyl, optionally substituted phenyl carbonyl, or a C.sub.5 or C.sub.6 heterocycle; the thioester groups are alkyl or optionally substituted phenyl or benzyl; the amide is optionally mono- or di-substituted by alkyl, cycloalkyl, optionally substituted phenyl or benzyl, or may form a C.sub.5 or C.sub.6 heterocyclic ring. The compounds are useful in controlling phytopathogenic fungi.
摘要翻译：其中X为CH或N，Ar为任选取代的苯基，二苯基或萘基，R为氰基，羧酸酯，羧酸硫酯或羧酸酰胺的式IMAMA的磷酸酯。 R10是烷基，R11烷基，烷氧基，烷硫基或苯基，Y是硫。对于R：酯基是烯基，炔基，环烷基，任选取代的苯基，被氧或硫中断的烷基，任选被卤素，苯基，羧酸酯，烷基羰基，任选取代的苯基羰基或C5或C6杂环取代; 硫酯基团是烷基或任意取代的苯基或苄基; 酰胺任选被烷基，环烷基，任选取代的苯基或苄基单取代或二取代，或可形成C5或C6杂环。这些化合物可用于控制植物病原真菌。

27. 发明授权

US4402953A Fungicidal N-(morpholinoacetyl)-anilines, compositions and use 失效
标题翻译：杀真菌N-（吗啉代乙酰） - 苯胺，组合物和用途
公开(公告)号：US4402953A
公开(公告)日：1983-09-06
申请号：US205356
申请日：1980-11-10
申请人： Adolf Hubele , Walter Kunz , Wolfgang Eckhardt
发明人： Adolf Hubele , Walter Kunz , Wolfgang Eckhardt
IPC分类号： A01N37/22 , A01N37/44 , A01N37/46 , A01P3/00 , C07C67/00 , C07C237/04 , C07C237/12 , C07C253/00 , C07C255/24 , C07C325/00 , C07C327/22 , C07C327/30 , C07D203/08 , C07D207/32 , C07D207/327 , C07D211/34 , C07D211/38 , C07D231/12 , C07D237/04 , C07D237/08 , C07D249/08 , C07D263/04 , C07D265/30 , C07D295/10 , C07D295/15 , C07D521/00 , A01N43/84 , C07D295/14
CPC分类号： C07D203/08 , A01N37/46 , C07D207/327 , C07D211/38 , C07D231/12 , C07D233/56 , C07D249/08 , C07D295/15
摘要： Amino aceto anilides of the formula I shown hereinafter are effective microbicides. They may be used to control fungi on plants or parts of plants or to prevent them from fungi attack.
摘要翻译：下文所示的式I的氨基乙酰苯胺是有效的杀微生物剂。它们可用于控制植物或植物部分上的真菌或防止真菌发生攻击。

28. 发明授权

US4296118A Fungicidal 3-[N-(pyrazol-1-yl-acetyl)-N-(substituted phenyl)]-amino-tetrahydro-2-furanones 失效
标题翻译：杀真菌剂3- [N-（吡唑-1-基 - 乙酰基）-N-（取代的苯基）] - 氨基 - 四氢-2-呋喃酮
公开(公告)号：US4296118A
公开(公告)日：1981-10-20
申请号：US180266
申请日：1980-08-22
申请人： Walter Kunz , Wolfgang Eckhardt , Adolf Hubele
发明人： Walter Kunz , Wolfgang Eckhardt , Adolf Hubele
IPC分类号： A01N43/08 , A01N43/16 , A01N43/56 , A01N43/653 , C07D307/33 , C07D307/68 , C07D405/12 , C07D521/00
CPC分类号： C07D307/33 , A01N43/08 , A01N43/56 , A01N43/653 , C07D231/12 , C07D233/56 , C07D249/08 , C07D307/68
摘要： N-Acylated N-phenyl-aminotetrahydro-2-furanones of tthe formula ##STR1## wherein R represents C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen,R.sub.1 represents C.sub.1 -C.sub.3 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen,R.sub.2 represents hydrogen, C.sub.1 -C.sub.3 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen,R.sub.3 represents hydrogen or methyl, with the total number of C atoms of the substituents R, R.sub.1, R.sub.2 and R.sub.3 in the phenyl ring not exceeding the number 8,R.sub.4 represents hydrogen or methyl, whileR.sub.5 represents one of the following groups: an alkylthioalkyl or alkoxyalkyl group having 2 to 5 carbon atoms or an alkoxyalkoxymethyl group having a maximum of 6 carbon atoms, a 2-furanyl or 2-tetrahydrofuranyl group optionally substituted by halogen, a 1,2,4-triazolymethyl group, a 1,2-pyrazolylmethyl group, or a group -CH.sub.2 -OR.sub.6 in which R.sub.6 represents a 5- or 6-membered heterocycle having oxygen as the hetero atom are valuable fungicidal active substances. They can be used as fungicidal compositions, particularly for combating phytopathogenic fungi, e.g. against downy mildew on potatoes, tomatoes, grape vines and sugar beet and other plants. The novel compounds have a systemic action.
摘要翻译：其中R代表C1-C4烷基，C1-C4-烷氧基或卤素，R1代表C1-C3-烷基，C1-C4-烷氧基或卤素的N-酰基化N-苯基 - 氨基四氢-2-呋喃酮，R 2表示氢，C 1 -C 3 - 烷基，C 1 -C 4 - 烷氧基或卤素，R 3表示氢或甲基，苯基环中取代基R，R 1，R 2和R 3的C原子总数不超过 8，R 4表示氢或甲基，而R 5表示以下基团之一：烷基硫代烷基或碳原子数2〜5的烷氧基烷基或最多6个碳原子的烷氧基烷氧基甲基，2-呋喃基或2-四氢呋喃基被卤素取代，1,2,4-三唑甲基，1,2-吡唑基甲基或基团-CH2-OR6，其中R6表示具有氧作为杂原子的5-或6-元杂环是有价值的杀真菌剂活性物质。它们可以用作杀真菌组合物，特别是用于防治植物病原真菌，例如，反对马铃薯，西红柿，葡萄藤和甜菜等植物的霜霉病。新化合物具有全身作用。

29. 发明授权

US4153712A Pyrazolylacetanilide compounds and fungicidal compositions 失效
标题翻译：吡唑基乙酰苯胺化合物和杀真菌组合物
公开(公告)号：US4153712A
公开(公告)日：1979-05-08
申请号：US905313
申请日：1978-05-12
申请人： Adolf Hubele , Walter Kunz , Wolfgang Eckhardt
发明人： Adolf Hubele , Walter Kunz , Wolfgang Eckhardt
IPC分类号： A01N37/46 , C07D203/08 , C07D207/32 , C07D207/327 , C07D211/10 , C07D211/38 , C07D231/12 , C07D249/08 , C07D265/30 , C07D295/15 , A01N9/22 , C07D231/16
CPC分类号： C07D203/08 , A01N37/46 , C07D207/327 , C07D211/10 , C07D211/38 , C07D231/12 , C07D249/08 , C07D265/30 , C07D295/15
摘要： Amino aceto anilides of the formula I shown hereinafter are effective microbicides. They may be used to control fungi on plants or parts of plants or to protect them from fungi attack.
摘要翻译：下文所示的式I的氨基乙酰苯胺是有效的杀微生物剂。它们可用于控制植物或植物部分上的真菌或保护它们免受真菌攻击。

30. 发明授权

US4143155A Sulfonylglycolic anilide fungicides 失效
标题翻译： SULFONYLGLYCOLIC ANILIDE FUNGICIDES
公开(公告)号：US4143155A
公开(公告)日：1979-03-06
申请号：US832752
申请日：1977-09-12
申请人： Adolf Hubele , Wolfgang Eckhardt , Walter Kunz
发明人： Adolf Hubele , Wolfgang Eckhardt , Walter Kunz
IPC分类号： A01N37/22 , A01N41/02 , A01N41/04 , A01N41/08 , A01N43/08 , A01P3/00 , C07C67/00 , C07C233/47 , C07C301/00 , C07C309/63 , C07C309/65 , C07C309/66 , C07C309/70 , C07C327/22 , C07D307/33 , A61K31/255 , A61K31/335 , C07C143/68 , C07D307/32
CPC分类号： C07D307/33 , A01N41/04 , A01N41/08 , A01N43/08
摘要： Compounds of the formula I ##STR1## wherein R.sub.1 represents C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen,R.sub.2 represents hydrogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen,R.sub.3 represents hydrogen, C.sub.1 -C.sub.3 alkyl or halogen, andR.sub.4 represents hydrogen or methyl, with the proviso that the total number of carbon atoms contained by the substituents R.sub.1, R.sub.2, R.sub.3 and R.sub.4 does not exceed 8,X represents ##STR2## and R.sub.5 represents hydrogen or methyl andR.sub.6 represents C.sub.1 -C.sub.6 alkyl which is unsubstituted or substituted by halogen or represents C.sub.2 -C.sub.4 alkenyl or C.sub.3 -C.sub.6 cycloalkyl or the group --N(R.sub.7)R.sub.8, in which R.sub.7 represents hydrogen or C.sub.1 -C.sub.4 alkyl and R.sub.8 represents C.sub.1 -C.sub.6 alkyl which is unsubstituted or substituted by halogen, which are useful in combatting microorganisms in particular phytopathogenic fungi.

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