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    • 23. 发明授权
    • Conjugated diene polymer manufacturing method, polybutadiene, and rubber composition utilizing the same
    • 共轭二烯聚合物制造方法,聚丁二烯和使用其的橡胶组合物
    • US08283401B2
    • 2012-10-09
    • US13133084
    • 2009-12-04
    • Masato MurakamiKoji ShibaTakeshi ShodaMitsuharu Anbe
    • Masato MurakamiKoji ShibaTakeshi ShodaMitsuharu Anbe
    • C08K3/34C08L9/00
    • C08F4/545C08F36/04C08K3/36C08K5/548C08L7/00C08L9/00C08L2666/08
    • Provided by using a catalyst containing an yttrium compound is conjugated diene polymer with very low solution viscosity, improved workability, high degree of branching, and high content of cis-1,4 structures. Also provided is a rubber composition utilizing the polymer and allowing excellent dispersion of reinforcing agent. According to a method of manufacturing a conjugated diene polymer characterized by polymerizing a conjugated diene at 50 to 120° C. in the presence of a catalyst obtained from (A) an yttrium compound, (B) an ionic compound consisting of a non-coordinating anion and a cation, and (C) an organoaluminum compound, the conjugated diene polymer has the following characteristics that: (1) a ratio (Tcp/ML1+4) between a 5 wt % toluene solution viscosity (Tcp) measured at 25° C. and a Mooney viscosity (ML1+4) at 100° C. is 0.1 to 1.2; and (2) a content of cis-1,4 structures is 80% or higher, and a content of 1,2 structures is lower than 5%.
    • 通过使用含有钇化合物的催化剂提供的是具有非常低的溶液粘度,改进的加工性,高支化度和高含量的顺式-1,4结构的共轭二烯聚合物。 还提供了一种利用该聚合物的橡胶组合物,并且能够提供增强剂的优异分散性。 根据制备共轭二烯聚合物的方法,其特征在于在(A)钇化合物得到的催化剂存在下,在50〜120℃下共聚共轭二烯,(B)由非配位的 阴离子和阳离子,和(C)有机铝化合物,共轭二烯聚合物具有以下特性:(1)在25℃下测量的5重量%甲苯溶液粘度(Tcp)之间的比率(Tcp / ML1 + 4) 在100℃下的门尼粘度(ML1 + 4)为0.1〜1.2; 和(2)顺式-1,4结构的含量为80%以上,1,2结构的含量低于5%。
    • 27. 发明授权
    • Oxide superconductor and process for producing same
    • 氧化物超导体及其制造方法
    • US06413624B1
    • 2002-07-02
    • US09521271
    • 2000-03-08
    • Masaru TomitaMasato Murakami
    • Masaru TomitaMasato Murakami
    • B23B2704
    • H01L39/126H01L39/247Y10T428/249955
    • An oxide superconductor is capable of assuring a high trapped magnetic field and maintaining its performance for a long period of time without being affected by internal or external forces, such as thermal strain or by corrosive environments. The oxide superconductor contains a resin impregnated layer incorporated with a filler material having a low value of linear thermal expansion coefficient, or contains the resin impregnated layer or a resin impregnated layer incorporated with a filler material and covered with a resin layer incorporated with the filler material having a low value of linear thermal expansion coefficient, or contains an oxide superconductive bulk body having an adhesively covering layer of resin impregnated fabric on the outside surface, or contains an oxide superconductive bulk body having on the surface thereof a resin or a resin-impregnated layer dispersedly incorporated with a filler material.
    • 氧化物超导体能够确保高的捕获磁场并保持其长时间的性能而不受内部或外部力(例如热应变或腐蚀性环境)的影响。 氧化物超导体包含与线膨胀系数低的填充材料结合的树脂浸渍层,或者包含树脂浸渍层或与填充材料结合的树脂浸渍层,并覆盖有填充材料的树脂层 具有低的线性热膨胀系数,或包含在外表面上具有树脂浸渍织物的粘合覆盖层的氧化物超导体,或者包含氧化物超导体,其表面上具有树脂或树脂浸渍 层分散结合有填料。
    • 30. 发明授权
    • Superconductor and method of producing same
    • 超导体及其制造方法
    • US5525584A
    • 1996-06-11
    • US452138
    • 1995-05-26
    • Masato MurakamiSang-Im YooNaomichi SakaiHiroshi TakaichiTakamitsu HiguchiShoji Tanaka
    • Masato MurakamiSang-Im YooNaomichi SakaiHiroshi TakaichiTakamitsu HiguchiShoji Tanaka
    • H01L39/12H01B12/00
    • H01L39/126Y10S505/742Y10S505/778Y10S505/779Y10S505/785
    • A high critical temperature and high critical current density superconductor is disclosed which contains a metal oxide expressed by the following formula (I):(R.sup.1.sub.1-x,Ba.sub.x)Ba.sub.2 Cu.sub.3 O.sub.d (I)wherein R.sup.1 stands for at least one element selected from the group consisting of La, Nd, Sm, Eu and Gd, x is a number greater than 0 but not greater than 0.5 and d is a number between 6.2 and 7.2. Fine phases of RE211, RE422 and/or a metal oxide expressed by the formula (R.sup.2.sub.1-z, Ba.sub.z) (Ba.sub.1-y, R.sup.2.sub.y).sub.2 Cu.sub.3 O.sub.p (R.sup.2 =La, Nd, Sm, Eu or Gd) may be dispersed in a matrix of the matrix phase of the formula (I). The above superconductor may be obtained by cooling a melt having a temperature of 1,000.degree.-1,300.degree. C. and containing R.sup.1, Ba, Cu and O at a cooling rate of 5.degree. C./hour or less under a partial pressure of oxygen of between 0.00001 and 0.05 atm, followed by annealing at 250.degree.-600.degree. C. in an oxygen atmosphere.
    • 公开了一种高临界温度和高临界电流密度超导体,其包含由下式(I)表示的金属氧化物:(R11-x,Bax)Ba2Cu3Od(I)其中R1代表选自以下的至少一种元素: 的La,Nd,Sm,Eu和Gd,x是大于0但不大于0.5的数,d是6.2和7.2之间的数。 RE211,RE422和/或由式(R21-z,Baz)(Ba1-y,R2y)2Cu3Op(R2 = La,Nd,Sm,Eu或Gd)表示的金属氧化物的细相可以分散在基质 的式(I)的基质相。 上述超导体可以通过在5℃/小时以下的冷却速度下,在温度为1000〜-1300℃的温度下冷却含有R 1,Ba,Cu和O的熔体, 在0.00001和0.05atm之间,然后在氧气氛中在250-600℃退火。