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21. 发明授权

US08735608B2 Process for preparing carbonate and diol products 有权
标题翻译：制备碳酸酯和二醇产品的方法
公开(公告)号：US08735608B2
公开(公告)日：2014-05-27
申请号：US13406728
申请日：2012-02-28
申请人： Xiankuan Zhang , Ray Montez
发明人： Xiankuan Zhang , Ray Montez
IPC分类号： C07D317/38 , C07C68/06
CPC分类号： C07D317/38
摘要： A method of forming a cyclic carbonate product is carried out by reacting an alkylene oxide, such as ethylene oxide, with carbon dioxide in the presence of a metal organic framework (MOF) catalyst with less than 0.5 mol % of any potassium or quaternary ammonium salts present based on moles of alkylene oxide feed in a reaction zone under reaction conditions to form a cyclic carbonate product. The cyclic carbonate product may be optionally fed as a crude carbonate product that does not undergo any purification or separation, other than the optional removal of any portion of unreacted alkylene oxide, carbon dioxide, and light hydrocarbon gases, to a second reaction zone containing a transesterification catalyst along with an aliphatic monohydric alcohol. The cyclic carbonate product and monohydric alcohol are allowed to react under reaction conditions to form the dialkyl carbonate and diol products.
摘要翻译：形成环状碳酸酯产物的方法是通过使环氧乙烷与环氧乙烷在金属有机骨架（MOF）催化剂存在下与少于0.5mol％的任何钾或季铵盐在反应条件下在反应区中以烯化氧原料的摩尔数存在，形成环状碳酸酯产物。环状碳酸酯产物可以任选地作为不经过任何纯化或分离的粗制碳酸酯产物进料，除了将任何部分未反应的氧化烯，二氧化碳和轻质烃气体任选地除去到含有酯交换催化剂和脂族一元醇。使环状碳酸酯产物和一元醇在反应条件下反应形成碳酸二烷基酯和二醇产物。

22. 发明授权

US08053609B2 Solid catalyst useful for converting an alkylene oxide to an alkylene glycol 有权
标题翻译：用于将烯化氧转化为亚烷基二醇的固体催化剂
公开(公告)号：US08053609B2
公开(公告)日：2011-11-08
申请号：US11872318
申请日：2007-10-15
申请人： William Crudge , Jaap Willem van Hal , Xiankuan Zhang
发明人： William Crudge , Jaap Willem van Hal , Xiankuan Zhang
IPC分类号： C07C27/00
CPC分类号： B01J31/08 , C07C29/106 , Y02P20/52 , C07C31/207 , C07C31/202 , C07C31/205
摘要： A solid (i.e., heterogeneous) catalyst useful for preparing an alkylene glycol from the corresponding alkylene oxide as well as a process for the catalytic hydration of an alkylene oxide to an alkylene glycol utilizing such a catalyst are provided. The catalyst of the present invention is based on an ion exchange resin including polystyrene crosslinked with from about 2 to about 10 weight (wt.) % divinyl benzene. The ion exchange resin further includes quaternary ammonium groups or quaternary phosphonium groups. The process includes reacting water and an alkylene oxide in at least one reactor under conditions to form an alkylene glycol, wherein the at least one reactor includes a catalyst based on an ion exchange resin that includes polystyrene crosslinked with from about 2 to about 10 weight (wt.) % divinyl benzene.
摘要翻译：提供了可用于从相应的烯化氧制备亚烷基二醇的固体（即非均相）催化剂，以及利用这种催化剂将烯化氧催化水合成亚烷基二醇的方法。本发明的催化剂基于包含用约2-约10重量％的二乙烯基苯交联的聚苯乙烯的离子交换树脂。离子交换树脂还包括季铵基或季鏻基。该方法包括在至少一个反应器中在形成亚烷基二醇的条件下使水和烯化氧反应，其中至少一个反应器包括基于离子交换树脂的催化剂，所述催化剂包括以约2至约10重量％ wt。）％二乙烯基苯。

23. 发明申请

US20090099393A1 SOLID CATALYST USEFUL FOR CONVERTING AN ALKYLENE OXIDE TO AN ALKYLENE GLYCOL 有权
标题翻译：固体催化剂用于将烷基氧化物转化为烷基甘氨酸
公开(公告)号：US20090099393A1
公开(公告)日：2009-04-16
申请号：US11872318
申请日：2007-10-15
申请人： William Crudge , Jaap Willem van Hal , Xiankuan Zhang
发明人： William Crudge , Jaap Willem van Hal , Xiankuan Zhang
IPC分类号： C07C29/10 , B01J31/06
CPC分类号： B01J31/08 , C07C29/106 , Y02P20/52 , C07C31/207 , C07C31/202 , C07C31/205
摘要： A solid (i.e., heterogeneous) catalyst useful for preparing an alkylene glycol from the corresponding alkylene oxide as well as a process for the catalytic hydration of an alkylene oxide to an alkylene glycol utilizing such a catalyst are provided. The catalyst of the present invention is based on an ion exchange resin including polystyrene crosslinked with from about 2 to about 10 weight (wt.) % divinyl benzene. The ion exchange resin further includes quaternary ammonium groups or quaternary phosphonium groups. The process includes reacting water and an alkylene oxide in at least one reactor under conditions to form an alkylene glycol, wherein the at least one reactor includes a catalyst based on an ion exchange resin that includes polystyrene crosslinked with from about 2 to about 10 weight (wt.) % divinyl benzene.
摘要翻译：提供了可用于从相应的烯化氧制备亚烷基二醇的固体（即非均相）催化剂，以及利用这种催化剂将烯化氧催化水合成亚烷基二醇的方法。本发明的催化剂基于包含用约2-约10重量％的二乙烯基苯交联的聚苯乙烯的离子交换树脂。离子交换树脂还包括季铵基或季鏻基。该方法包括在至少一个反应器中在形成亚烷基二醇的条件下使水和烯化氧反应，其中至少一个反应器包括基于离子交换树脂的催化剂，所述催化剂包括以约2至约10重量％ wt。）％二乙烯基苯。

24. 发明申请

US20070149792A1 Catalyst for epoxidation of an alkene to an alkene oxide, method of making and method of using thereof 有权
标题翻译：将烯烃环氧化成氧化烯的催化剂，其制备方法及其使用方法
公开(公告)号：US20070149792A1
公开(公告)日：2007-06-28
申请号：US11316031
申请日：2005-12-22
申请人： Xiankuan Zhang , Alla Khanmamedova
发明人： Xiankuan Zhang , Alla Khanmamedova
IPC分类号： C07D301/03
CPC分类号： C07D301/03
摘要： The present invention if for a catalyst for epoxidation of an alkene, such as ethylene, to an alkene oxide, such as ethylene oxide, on which silver has been deposited on alumina as a support which has been modified with certain weak base compounds, such as oxides of a Group 1A, Group 2A, Group 3A or the first transition series of the Periodic Table of Elements, and with a high temperature heat treatment. Optional promoters selected from the group consisting of compounds of Group 1A, Group 2A, Group 7A and Group 8 may be contacted with the alpha-alumina support in solution with a silver compound, with the catalyst precursor before calcination or with the catalyst after calcination. The catalyst is brought into contact with alkene and oxygen under reaction conditions to selectively convert the alkene to an alkene oxide.
摘要翻译：如果将用于将烯烃如乙烯的环氧化的催化剂用于氧化烯如氧化乙烯上的催化剂，其中银已经沉积在氧化铝上作为用某些弱碱化合物改性的载体，例如 1A组，2A组，3A组的氧化物或元素周期表的第一过渡系列，并进行高温热处理。选自由1A组，2A组，7A组和8组的化合物组成的组的选择性促进剂可以与溶液中的α-氧化铝载体与银化合物，煅烧前的催化剂前体或煅烧后的催化剂接触。催化剂在反应条件下与烯烃和氧接触以选择性地将烯烃转化为烯烃氧化物。

25. 发明授权

US07098367B2 Process for the preparation of alkylene glycols 有权
标题翻译：亚烷基二醇的制备方法
公开(公告)号：US07098367B2
公开(公告)日：2006-08-29
申请号：US10923961
申请日：2004-08-23
申请人： John S. Ledford , Jaap W. Van Hal , Xiankuan Zhang
发明人： John S. Ledford , Jaap W. Van Hal , Xiankuan Zhang
IPC分类号： C07C31/20 , C07C31/18
CPC分类号： C07C29/106 , C07C31/202 , C07C31/205 , C07C31/207
摘要： Disclosed is a process for the preparation of alkylene glycols from the corresponding alkylene oxide, such as ethylene glycol from ethylene oxide, in the presence of water, a catalyst and, optionally, carbon dioxide. The catalyst contains amines which are weak bases, specifically having pKa of at least 5.5, preferably 8 to 11. The amines may be primary, secondary, tertiary or a blend thereof or may be a compound having a structural combination of primary, secondary and/or tertiary amines.
摘要翻译：公开了在水，催化剂和任选的二氧化碳的存在下，从相应的环氧烷如乙二醇制备亚烷基二醇的方法。催化剂含有弱碱的胺，特别是具有至少5.5，优选8至11的pK a a。胺可以是伯，仲，叔或其共混物，或可以是具有伯，仲和/或叔胺的结构组合。

26. 发明申请

US20060069293A1 Process for the preparation of alkylene glycols 有权
标题翻译：亚烷基二醇的制备方法
公开(公告)号：US20060069293A1
公开(公告)日：2006-03-30
申请号：US10955796
申请日：2004-09-30
申请人： Jaap Van Hal , John Ledford , Xiankuan Zhang
发明人： Jaap Van Hal , John Ledford , Xiankuan Zhang
IPC分类号： C07C29/10
CPC分类号： C07C29/106 , C07C31/202
摘要： Disclosed is a process for the preparation of alkylene glycols from the corresponding alkylene oxide, such as ethylene glycol from ethylene oxide, in the presence of water, a catalyst and, optionally, carbon dioxide. The catalyst is a SALEN-type compound which contains an amino group and an oxy or hydroxy group connected by a hydrocarbon, such as an alkyl or an alkylaryl. The SALEN-type compounds may be Schiff bases, i.e., a condensate product of a primary amine with an aldehyde, ketone or an alcohol. The SALEN-type compound may be a mono or bis compound and may be complexed with a Group 4-14 metal, such as aluminum, tin, vanadium, chromium, manganese, iron, cobalt or platinum.
摘要翻译：公开了在水，催化剂和任选的二氧化碳的存在下，从相应的环氧烷如乙二醇制备亚烷基二醇的方法。催化剂是含有氨基和通过烃如烷基或烷基芳基连接的氧基或羟基的SALEN型化合物。 SALEN型化合物可以是席夫碱，即伯胺与醛，酮或醇的缩合产物。 SALEN型化合物可以是单或双化合物，并且可以与第4-14族金属如铝，锡，钒，铬，锰，铁，钴或铂络合。

27. 发明申请

US20050027134A1 Support for a catalyst for direct oxidation of propylene to propylene oxide, method of making and method of using catalyst 审中-公开
标题翻译：支持将丙烯直接氧化成环氧丙烷的催化剂，制备方法和使用催化剂的方法
公开(公告)号：US20050027134A1
公开(公告)日：2005-02-03
申请号：US10902627
申请日：2004-07-29
申请人： Patricia Hooks , David Sullivan , Michael Mier , Jaap van Hal , Xiankuan Zhang
发明人： Patricia Hooks , David Sullivan , Michael Mier , Jaap van Hal , Xiankuan Zhang
IPC分类号： B01J21/18 , B01J23/50 , B01J23/66 , B01J27/232 , B01J35/10 , C07D301/03 , C07D301/10
CPC分类号： C07D301/10 , B01J23/50 , B01J23/66 , B01J27/232 , B01J35/1009 , B01J35/1014
摘要： This invention is for a support for a silver-containing catalyst which can be used in a method of making an alkene oxide from an alkene and an oxygen-containing gas by oxidation of the alkene to the corresponding epoxide, such as propylene to propylene oxide. The support is an alkaline earth metal carbonate, such as calcium carbonate, and the shape of the support is not regular rhombohedral, cubic nor a blend of regular rhombohedral and cubic. Preferably, the shape of the support is scalenohedral, irregular rhombohedral, acicular or prismatic. The catalyst may contain optional promoters, such as potassium, chlorine, molybdenum, rhenium, tungsten, gold, thallium, yttrium, niobium, indium, barium, cobalt or cerium, and the support may contain an additional support material, such as an alkaline earth oxide.
摘要翻译：本发明涉及含银催化剂的载体，其可用于通过将烯烃氧化成相应的环氧化物如丙烯至环氧丙烷从烯烃和含氧气体制备烯烃的方法。载体是碱土金属碳酸盐如碳酸钙，并且载体的形状不是规则的菱面体，立方体，也不是常规的菱面体和立方体的混合物。优选地，支撑体的形状是斜面，不规则菱形，针状或棱柱状。催化剂可以含有任选的助催化剂，例如钾，氯，钼，铼，钨，金，铊，钇，铌，铟，钡，钴或铈，并且该载体可以含有另外的载体材料，氧化物。

28. 发明申请

US20050027133A1 Method of making a catalyst for direct oxidation of an alkene to an alkene oxide 审中-公开
标题翻译：制备用于将烯烃直接氧化成烯烃氧化物的催化剂的方法
公开(公告)号：US20050027133A1
公开(公告)日：2005-02-03
申请号：US10741385
申请日：2003-12-19
申请人： Patricia Hooks , David Sullivan , Michael Mier , Jaap van Hal , Xiankuan Zhang
发明人： Patricia Hooks , David Sullivan , Michael Mier , Jaap van Hal , Xiankuan Zhang
IPC分类号： B01J23/50 , B01J23/66 , B01J27/232 , B01J37/02 , C07D301/03
CPC分类号： B01J23/50 , B01J23/66 , B01J27/232 , B01J37/0203 , B01J37/0211
摘要： This invention is for a method of preparing a supported silver-containing catalyst for use in a process of making an alkene oxide from an alkene and an oxygen-containing gas by oxidation of the alkene to the corresponding epoxide. The catalyst contains metallic silver on a support. The catalyst may also contain small amount of compounds of metals or halides as promoters to improve selectivity, activity, conversion, stability or yield. The catalyst is prepared by forming a slurry of a silver compound, water and one or more organic compounds having at least one functional group of the formula —NX2, —OX or [(═O) (—OX)] wherein X is hydrogen or an alkyl of one to three carbon atoms, X being the same or different, and wherein at least one functional group is bound to a terminal carbon. This slurry is formed before contact with the support material to deposit silver on the support.
摘要翻译：本发明涉及一种制备负载的含银催化剂的方法，该催化剂用于通过烯烃氧化成相应的环氧化物从烯烃和含氧气体制备烯烃的方法。催化剂在载体上含有金属银。催化剂还可以含有少量金属或卤化物的化合物作为促进剂以提高选择性，活性，转化率，稳定性或产率。通过形成银化合物，水和一种或多种具有至少一个式-NX 2，-OX或[（= O）（ - O））的官能团的有机化合物的浆料制备催化剂，其中X是氢或一至三个碳原子的烷基，X相同或不同，并且其中至少一个官能团与末端碳键合。在与载体材料接触之前形成该浆液以在载体上沉积银。

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